WO2007066410A1 - Film de transfert isolant avec excellent brillant métallique, son processus de fabrication, et article moulé réalisé avec ledit film de transfert - Google Patents

Film de transfert isolant avec excellent brillant métallique, son processus de fabrication, et article moulé réalisé avec ledit film de transfert Download PDF

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Publication number
WO2007066410A1
WO2007066410A1 PCT/JP2005/022657 JP2005022657W WO2007066410A1 WO 2007066410 A1 WO2007066410 A1 WO 2007066410A1 JP 2005022657 W JP2005022657 W JP 2005022657W WO 2007066410 A1 WO2007066410 A1 WO 2007066410A1
Authority
WO
WIPO (PCT)
Prior art keywords
thin film
layer
water
film
insulating
Prior art date
Application number
PCT/JP2005/022657
Other languages
English (en)
Japanese (ja)
Inventor
Seiichi Umekage
Yukiyoshi Soma
Original Assignee
Reiko Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reiko Co., Ltd. filed Critical Reiko Co., Ltd.
Priority to PCT/JP2005/022657 priority Critical patent/WO2007066410A1/fr
Priority to JP2006554390A priority patent/JP3955084B1/ja
Priority to JP2006169777A priority patent/JP2007160918A/ja
Publication of WO2007066410A1 publication Critical patent/WO2007066410A1/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00—Ancillary operations in connection with laminating processes
    • B32B38/10—Removing layers, or parts of layers, mechanically or chemically
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
    • B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
    • B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
    • B44C1/17—Dry transfer

Definitions

  • 0001 which relates to a film that is capable of stable quality transfer of a pattern that is excellent in metal and has good insulation, its manufacturing method, and molding using it.
  • a water-soluble paint is partially provided on the metal in order to obtain a metal having an insulating pattern having a metal stream, and a metal and a transparent material () are laminated on it, followed by washing with water and drying.
  • the above-mentioned item (i) is also used as a material for the packaging material. However, for example, i made the metal a very discontinuous insulation () (
  • the insulating film contains water vapor and metal The above problem was solved by laminating water resistance.
  • the feature is that the insulation is manufactured by bonding after the metal and water are left.
  • Mitsui has a protective layer, an insulating layer, a metal layer, and an aqueous layer on a plastic layer.
  • the metal layer and the aqueous layer are laminated on the same layer.
  • “insulating, metal, and water-based are laminated together” means that the insulation, metal, and water-based are the same, and the metal film is laminated on the film and water-resistant is laminated on the metal film. thing . Further, the protection, insulation, metal, and water-based layers are not simply laminated, but the protection, insulation, metal, and water-based layers are laminated together.
  • the water-soluble paint should not be present in the condition that the water-soluble paint is present for protection.
  • insulation metal
  • the membrane is an island structure
  • the thickness of the membrane is 3 to OO
  • the resin material used in the water penetrates to the protection. Therefore, it is preferable to lower the amount of the material to be tainted, so that the aqueous teing method is preferably the sto method.
  • the water-based coating was made to be in a state where it was difficult to remove the water-soluble coating (in order to prevent the water-soluble coating from being buried flat on the porous water-soluble coating), especially 3 to 2 below the water-soluble coating.
  • this water level should be set between -O m and -m degrees, especially -2 m below.
  • water-based resins that are usually used for towing such as stainless steel-based resin, acrylic resin, salt-based resin, and vinyl-based resin, may be used, but in the ind When applied, it is preferred to use cross-linked fats, for example tan-based actinic fats depending on the iso-aneto.
  • the insulation in 001 is a metal film that has both insulation and insulation, and can be provided according to the conventional technique.
  • the island size is A ⁇ 2 x ( ⁇ 2 4) and the island spacing is 2 A ⁇ 5 A (2 ⁇ 5).
  • Indium ,,,, bis, titanium, cum, iron, gallium, gem, or a metal selected from the group consisting of gold, tin, and indium are preferable.
  • Soluble paint film should be ⁇ 5 of the part where no soluble paint film is present. Insulation here means that the insulation pressure is higher.
  • 002 Aim may have a primer between the plastic layers.
  • Ming-im it is possible to provide the above-mentioned on the plastic-imme by providing the coloring, and by doing so, it is possible to stabilize a metal pattern having a coloring pattern on the surface. It becomes possible to manufacture an insulation imprint that can be transferred.
  • the thickness of the film is preferably 8 to 8 degrees if it is set to OO degrees, and a sufficient effect can be obtained with an angle of 3 to 3 degrees.
  • the water formed on the metal it is possible to manufacture a stable insulation with good quality. I like it. If the thickness is 0, the corrosion resistance becomes poor, and if it exceeds OO, cracks are likely to occur particularly in the metal film during transfer, and as a result, the corrosion resistance also decreases.
  • a water-soluble paint was applied on the pattern (of the pattern) on the protective layer to form a soluble paint, and then insulation and metal were provided on the entire surface and water resistance was added. Since the water-soluble paint is removed by washing with water after the provision of the water-soluble paint, the pattern is removed when the water-soluble paint is dissolved and the metal, water-based, and water-soluble paint is dissolved. In parts where water-soluble paint penetrates to the protective surface, the protection, insulation, metal and water are laminated, so in the parts where water-soluble paint is not present, protection, insulation, metal and water are laminated, Metal and water remain in the desired pattern with high precision, forming a metallic pattern.
  • a synthetic resin such as, for example, a pointintium, a poppinim, a pocobonnetim, a potinim, a potin, a pointin. Examples include a steam, a pore, and a pot act.
  • a te-based, a ste-based, a ki-based, an ac-based, a tan-based, a wax-based polymer or a polymer it is preferable to use one or more of a te-based, a ste-based, a ki-based, an ac-based, a tan-based, a wax-based polymer or a polymer.
  • a te-based a ste-based, a ki-based, an ac-based, a tan-based, a wax-based polymer or a polymer.
  • water-soluble substances such as dong, methices, methices, gelatin and starch can be used. Also, the water-soluble paint may be mixed with the constitution.
  • a band phone that is a molded product obtained using Ming-im is of the same quality as above, but the mobile phone (wavenumber 8z, 5Gz, gGz, 2Gz band, etc.) Therefore, even when using the present invention for a mobile phone of the type that has a built-in antenna, it is possible to add a metal gap to the antenna storage part and secure radio wave transmission. In order to do so, it is necessary to adopt a method such as revealing the part where the antenna is built-in.
  • the bright im is a laminate of the above-mentioned, protection, insulation, metal, and water-based,
  • the film Since the film is an island structure, it is easy to get into the insulating surface, but in the case of an insulating film, the insulating film does not fall off or cause rubbing, so a desired pattern with a metal It is possible to provide an insulating film that can be transferred.
  • the resin used in water is a tan-based or tan-based resin based on iso-aneto
  • the heat resistance will be improved, so that the position of the curved surface part and the gate part will not be limited to the part, but also to the part. Even if the position of the part is in the center where more heat is required, cracks are less likely to occur in the get part, and the shape of molding and plastics will spread.
  • the insulating film does not disappear due to corrosion without exceeding 6, so it can be used in a very wide range of applications.
  • the thickness is made of ac-melane type
  • 5 is made of acryl type, which is made of acryl type
  • 5 g 2 tins (with a portion of the paint in the absence of soluble paint)
  • a laminated film (was obtained by using the film having the brightness of a tin-tin film.
  • Water-based polymer consisting of ambi polymer
  • the layer was composed of two layers, tin-am water-based was laminated to the same with metal deposits, and tin am-water was laminated to obtain the clear im.
  • step 1 On the tom of the im (), obtained in step 1, a material consisting of an ac-urethane type was applied by the stove method to provide a water-thickness. As a result, the water-soluble paint and the tin-ammonium aqueous solution on the water-soluble paint were removed, and a time was obtained in which the tin-ammonium-aqueous part of the water-soluble paint was not present. The tin film had no tin film. A layer of a water-based aqueous system of the same time is provided, and a water-based layer of a titanium-based tin-toam tin-aqua-based system is formed. To obtain a clear aluminum film. 002 Im production
  • the obtained im () was washed with water to remove the water-soluble paint and the tin-am on the water-soluble paint, and at the same time, the tin-am remaining in the part where the water-soluble paint did not exist was obtained.
  • the resulting Tim is the part where the water-soluble paint does not exist, and the Mari is originally tin.
  • the metal used for the insulating film is a metal that has a relatively weak adhesion to the insulating film, it is necessary to increase the adhesion to the tin protection, especially if the pattern made of water-soluble paint is thin. Since it is necessary to increase the pressure of water used in the washing process, higher adhesion is required.
  • a transparent cell was used to manufacture a mobile phone.
  • the ind type there are two types of methods when the position of the gate part for pouring fat is provided at the center of () (more heat resistance of the i is required) and at the position of (2). At that time, they manufactured their own mobile phones.
  • the water-based am-tin composed of transparent ac-bi-polymer is sequentially arranged, and the water-based am-tin film is laminated on the same layer with metal ridges, and the water-based am-tin is laminated.
  • Insulation 2 of the pattern part with a swamp had good insulation. Also, when the position of the gate part in () is in the center, no cracks occur in the face part, but a small amount of cracks occur in the gate part, and the temperature rise between cracks C 54 and 6 CX 8 X 96 is high. Some metal loss in the humidity test When the position of the gate part of (3/3) (2) was, no cracks were observed on the surface part and the gate, and the appearance was not seen even in the high temperature and high humidity test between 65C 54 and 6C 8 X96. It became a practical product that holds a beautiful metal pattern.
  • Am tin was sequentially deposited, and an aqueous am tin film was laminated on the same with a metal stream to obtain a mobile phone with laminated aqueous am tin.
  • Insulation 2 of the pattern part with a swamp had good insulation.
  • the position of the gate part in () is in the center and when the position of the gate part in (2) is, there is no misalignment between the face part and the gate part.
  • the appearance of the CX8 X96 during the high temperature and high humidity test showed the practicality of retaining a beautiful metal pattern with the appearance.
  • the two types of charging tales were manufactured in the same manner as in Example 3 using the above image.
  • a metal such as an aluminum film which usually has the above-mentioned force and force, causes cracks and deteriorates its durability.
  • Akira-no-i can be used for mobile phones and audio products because it is possible to reliably transfer a durable and durable pattern to various plastic surfaces. It can be widely used for various purposes.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Laminated Bodies (AREA)
  • Decoration By Transfer Pictures (AREA)

Abstract

L’invention concerne un film de transfert obtenu par formation d’une couche détachable et d’une couche de protection sur un film plastique, application par motifs d’une couche d’enduction soluble dans l’eau à la couche de protection, avant de former de manière successive un mince film de métal isolant et un mince film d’oxyde de métal, de former une couche de résine résistante à l’eau sur le mince film d’oxyde de métal, avant de laver la structure multicouche résultant avec de l’eau pour supprimer la couche d’enduction soluble dans l’eau et le mince film de métal isolant, le mince film d’oxyde de métal, et la couche de résine résistante à l’eau superposés sur la couche d’enduction soluble dans l’eau tout en laissant ces éléments du mince film de métal isolant, le mince film d’oxyde de métal, et la couche de résine résistante à l’eau sous laquelle la couche d’enduction soluble dans l’eau est absente, avant de constituer une couche adhésive. Ce film de transfert présente une qualité exceptionnelle et ne souffre pas de rayures ou d’arrachement du mince film de métal isolant. Il est excellent en matière d’aspect et de durabilité et permet le transfert d’un dessin possédant un excellent brillant métallique.
PCT/JP2005/022657 2005-12-09 2005-12-09 Film de transfert isolant avec excellent brillant métallique, son processus de fabrication, et article moulé réalisé avec ledit film de transfert WO2007066410A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
PCT/JP2005/022657 WO2007066410A1 (fr) 2005-12-09 2005-12-09 Film de transfert isolant avec excellent brillant métallique, son processus de fabrication, et article moulé réalisé avec ledit film de transfert
JP2006554390A JP3955084B1 (ja) 2005-12-09 金属光沢に優れた絶縁性転写フィルム、その製造方法、及びそれを使用した成形品
JP2006169777A JP2007160918A (ja) 2005-12-09 2006-06-20 金属光沢に優れた絶縁性転写フィルム、その製造方法、及びそれを使用した成形品

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2005/022657 WO2007066410A1 (fr) 2005-12-09 2005-12-09 Film de transfert isolant avec excellent brillant métallique, son processus de fabrication, et article moulé réalisé avec ledit film de transfert

Publications (1)

Publication Number Publication Date
WO2007066410A1 true WO2007066410A1 (fr) 2007-06-14

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PCT/JP2005/022657 WO2007066410A1 (fr) 2005-12-09 2005-12-09 Film de transfert isolant avec excellent brillant métallique, son processus de fabrication, et article moulé réalisé avec ledit film de transfert

Country Status (1)

Country Link
WO (1) WO2007066410A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009006612A (ja) * 2007-06-28 2009-01-15 Nissha Printing Co Ltd 加飾シート、加飾シートの製造方法および加飾成形品の製造方法
JP2009006613A (ja) * 2007-06-28 2009-01-15 Nissha Printing Co Ltd 加飾シート、加飾シートの製造方法および加飾成形品の製造方法
WO2011021829A3 (fr) * 2009-08-18 2012-10-11 Lg Electronics Inc. Film décoratif destiné à être fixé à une surface extérieure d'un appareil domestique et procédé pour sa fabrication
CN110475445A (zh) * 2019-07-19 2019-11-19 武汉和时利自动化系统工程有限公司 一种应用于地下潮湿环境的耐潮耐腐蚀型plc控制柜

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0327999A (ja) * 1989-06-27 1991-02-06 Reiko Co Ltd 転写材料の製造方法
JPH1035086A (ja) * 1996-07-26 1998-02-10 Dainippon Printing Co Ltd 三次元成形品絵付け用転写フィルム
JP2001353997A (ja) * 2000-06-13 2001-12-25 Reiko Co Ltd 絶縁性金属薄膜を部分的に有するインモールド成形用転写材料及びそれを使用して得る成形品
JP3643904B1 (ja) * 2004-10-28 2005-04-27 尾池工業株式会社 金属蒸着フィルムの製造方法及び金属蒸着フィルム

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0327999A (ja) * 1989-06-27 1991-02-06 Reiko Co Ltd 転写材料の製造方法
JPH1035086A (ja) * 1996-07-26 1998-02-10 Dainippon Printing Co Ltd 三次元成形品絵付け用転写フィルム
JP2001353997A (ja) * 2000-06-13 2001-12-25 Reiko Co Ltd 絶縁性金属薄膜を部分的に有するインモールド成形用転写材料及びそれを使用して得る成形品
JP3643904B1 (ja) * 2004-10-28 2005-04-27 尾池工業株式会社 金属蒸着フィルムの製造方法及び金属蒸着フィルム

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009006612A (ja) * 2007-06-28 2009-01-15 Nissha Printing Co Ltd 加飾シート、加飾シートの製造方法および加飾成形品の製造方法
JP2009006613A (ja) * 2007-06-28 2009-01-15 Nissha Printing Co Ltd 加飾シート、加飾シートの製造方法および加飾成形品の製造方法
WO2011021829A3 (fr) * 2009-08-18 2012-10-11 Lg Electronics Inc. Film décoratif destiné à être fixé à une surface extérieure d'un appareil domestique et procédé pour sa fabrication
US9278504B2 (en) 2009-08-18 2016-03-08 Lg Electronics Inc. Decorative film to be attached to outside surface of home appliance and method for manufacturing the same
CN110475445A (zh) * 2019-07-19 2019-11-19 武汉和时利自动化系统工程有限公司 一种应用于地下潮湿环境的耐潮耐腐蚀型plc控制柜

Also Published As

Publication number Publication date
JPWO2007066410A1 (ja) 2009-05-14
JP3955084B2 (fr) 2007-08-08

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