WO2006102799A1 - Procedes pour realiser des tissus peints a la main - Google Patents

Procedes pour realiser des tissus peints a la main Download PDF

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Publication number
WO2006102799A1
WO2006102799A1 PCT/CN2005/000876 CN2005000876W WO2006102799A1 WO 2006102799 A1 WO2006102799 A1 WO 2006102799A1 CN 2005000876 W CN2005000876 W CN 2005000876W WO 2006102799 A1 WO2006102799 A1 WO 2006102799A1
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Prior art keywords
hand
dyeing
painted
dye
fabrics
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PCT/CN2005/000876
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English (en)
French (fr)
Inventor
Ning Cai
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Shenzhen Houyu Fashion Co., Ltd.
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Application filed by Shenzhen Houyu Fashion Co., Ltd. filed Critical Shenzhen Houyu Fashion Co., Ltd.
Publication of WO2006102799A1 publication Critical patent/WO2006102799A1/zh

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06QDECORATING TEXTILES
    • D06Q1/00Decorating textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/62General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
    • D06P1/628Compounds containing nitrogen
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/6422Compounds containing nitro or nitroso groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/642Compounds containing nitrogen
    • D06P1/649Compounds containing carbonamide, thiocarbonamide or guanyl groups
    • D06P1/6491(Thio)urea or (cyclic) derivatives
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673Inorganic compounds
    • D06P1/67333Salts or hydroxides
    • D06P1/6735Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/001Special chemical aspects of printing textile materials

Definitions

  • the invention relates to a hand-painted coloring and dyeing method for fabrics, which is a new or hand-painted art finishing process for cloth, yarn and garment. Background technique
  • the current coloring of fabric garments is mainly two methods of dyeing and printing.
  • the finished fabrics of fabrics or garments are dyed by a single color, and the style is monotonous; the finished pattern produced by the printing method has a single shape and a small color change, so
  • the garments made by these two methods can not meet the variety and individual needs of the market.
  • the traditional tie-dye and batik methods produce rougher patterns, more abstract styles, and relatively less pattern changes. Summary of the invention
  • the technical solution of the present invention is a method for hand-painted coloring of fabrics, which mainly comprises the following steps:
  • the pretreatment of step (1) is water washing or penetrant pretreatment.
  • the stretcher of the step (2) the silk thin fabric flattens the fabric with a frame; the medium thick elastic fabric is fixed with a pin on the foam board.
  • the hand-painted colored paste is one or more of sodium alginate, etherified seed gum, emulsified paste, starch ether, gelatin, or cellulose ether.
  • step (3) for cotton, viscose, and partial silk fabrics, reactive dyes, dye components and their mass percentages are as follows:
  • the dye groups are:
  • disperse dyes are used for polyester fabrics.
  • the components of the dye composition and their mass percentages are:
  • Step (3) is hand-painted using one or more of pen dyeing, brushing, spray dyeing, rubbing, needle hooking, sprinkling, auxiliary dyeing, or anti-staining.
  • Step (4) The process of steaming and dyeing after hand-painting is as follows: steaming after hand-painting; washing to remove floating color, and finally drying.
  • Step (3) When the reactive dye is used for hand-painting, the step (4) is washed with water to remove the color, then soaped, soaped, and then washed and dried.
  • the invention has the beneficial effects of: creating and perfecting a hand-painted fabric or garment with rich color variations, fashionable effects and individualized style by improving the production process and processing the hand-painted products with artistic effects by using modern dyeing and finishing technology. . detailed description
  • the hand-painted coloring dyeing method of the fabric of the invention mainly comprises the following steps:
  • the fabric of the step (1) comprises woolen, knitted, woven garments or fabrics, and the main raw materials are medium-thick fabrics such as cotton, viscose, silk, wool, rabbit, polyester.
  • the fabric pretreatment of step (2) is: according to the processing method of the garment and the nature of the fabric, water washing and penetrant pretreatment. Washing is a conventional low-temperature or high-temperature water washing method of known technology; osmotic agent pretreatment: a penetrant treatment is applied to a fabric having poor water absorption, which makes it water-absorbent, increases the wetting property of the dye on the fabric, and makes hand-painted production easier.
  • the penetrant can be made of an ethylene oxide adduct of nonylphenol and octylphenol and a low carbon fatty alcohol ethylene oxide condensate, a fatty alcohol polyoxyethylene ether, ethylene oxide, epoxidizing propylene and higher fatty alcohol.
  • an ether product such as penetrant JFC, penetrant T and other penetrants or wetting agents.
  • Step (3) of the blouse In this step, there is a difference between the silk thin fabric and the medium thick elastic fabric.
  • the silk thin fabric flattens the fabric with a frame. Since the fabric is light, the middle hang will not fall; if the fabric is medium Thick elastic fabric, the method of flattening the fabric by the frame will make the suspended fabric fall and affect the hand-painted production and hand-painted artistic effect; for example, the platen method for garment printing, because most of the hand-painted is dyed liquid, It is easy to stain the platen and affect the use. Therefore, the unique foam board is fixed by the pin, which makes the fabric easy to disassemble, easy to wash after staining, and can be reused many times.
  • Step (4) Hand-painted coloring The dyes used are reactive dyes, acid, neutral, and dispersion dyes such as Reactive Brilliant Blue K-R, Reactive Brilliant Red X-3B, Reactive Green KE-4B, Bisazo Type navy blue acid dye, neutral pink BL106; disperse lemon yellow 302, etc., the dye composition is as follows, the percentage is the mass percentage (the same below):
  • Surfactants are added when hand-painted on various tarpaulins, or when special effects are required on the screen.
  • Surfactants are one or more of the prior art cationic, nonionic, anionic and zwitterionic acids, such as fatty alcohol epoxy oxime condensates. Addition of various other auxiliaries Depending on the type of dye, it is determined whether or not it is added and added.
  • a fatty alcohol epoxy oxime condensate can be used as the surfactant herein.
  • the paste may be sodium alginate, an emulsified paste or the like.
  • an appropriate amount such as 0 to 3% of printing acid can be added as needed.
  • a fatty alcohol ethylene oxide condensate can be used as the surfactant herein.
  • disperse dyes are suitable, and the preferred formula is:
  • an appropriate amount such as 0 to 3% of printing acid can be added as needed.
  • a fatty alcohol epoxy oxime condensate can be used as the surfactant herein.
  • the hand-painting uses pen dyeing, brushing, spray dyeing, rubbing, needle hooking, sprinkling, auxiliary dyeing, and dyeing.
  • the pen dyeing and brushing are used to draw the dyeing liquid directly on the fabric or garment according to the design pattern with various pen-type tools such as a brush, a pen, and a brush.
  • Spraying is to spray the dye onto the fabric using a watering can or spray gun.
  • the needle hook is used to hook the dye slurry and the like on the fabric or the garment according to the design pattern.
  • auxiliaries of different styles and effects can be dyed or dropped or pen-dyed or screen-printed, or any two or more ways can be hand-painted onto fabric or garment.
  • Anti-dyeing Use anti-dyeing agent to use the needle hook or brush method to first apply anti-dyeing agent on the cloth surface, and then hand-paint it in wet or dry state. After drying and steaming, the cloth surface with anti-dyeing agent will appear. White or light floral pattern.
  • the anti-dyeing agent is different from the anti-dyeing in printing. If the medium-thick fabric is mainly produced, the dyeing solution is used for hand-painting. If the anti-staining agent in the printing is used, the anti-dyeing effect is not good, so the anti-staining effect of the polymer surfactant is adopted. Dyeing agent to enhance its anti-staining effect.
  • Step (5) The process of steaming and dyeing after hand-painting is: steamed after hand-painting; washed (floating color); finally dried.
  • the steaming process conditions are steaming (or baking) at 102 to 190 ° C for 2 to 60 minutes, and the water washing can be carried out by the prior art.
  • steaming or baking
  • the steaming process of reactive dyes is: steaming at 102 ⁇ 105 °C for 2 ⁇ 30 minutes, or baking at 150 °C for 3 ⁇ 5 minutes; steaming process of acidic and neutral dyes is: 102 ⁇ 105° C steaming 40 ⁇ 60 minutes; the steaming process of disperse dyes is: 1.47 X 10 5 ⁇ 1.76 X 10 5 Pa, 128 ⁇ 130 ° C, 20 ⁇ 30 minutes, or 175 ⁇ 185 °C, 6 ⁇ 10 minutes .
  • a neutral dye is used in the hand-painting process, use the low temperature (such as 50 ° C) water wash (go to float) in the prior art; if the disperse dye is used in the hand-painting process, it can be used in 801 water 3 ⁇ 43 ⁇ 4 (to float). If the reactive dye is used in the hand-painting process, it can be further soaped after washing with water to remove the color.
  • hand-painted auxiliaries containing fixing agents are used in hand-painting, they can be directly soaped without dyeing to form finished products, or they can be re-dyed while soaping. At this time, the background color of the hand-painted clothing is mainly medium and light.
  • the fixing agent is cationic and has strong adsorption with anionic dyes
  • the part of the cloth without the fixing agent is not dyed by the action of the white antifouling agent, but there is
  • the dye fixing agent dyes the dye due to the strong adsorption of the fixing agent.
  • the color of the hand-painted clothing must be medium-light, otherwise the effect is not obvious due to the lower dye uptake rate.
  • the dye added is a kind of pure color light, it can be dyed due to the different background colors.
  • the color of the light greatly enriches the color of the cloth and makes it richer in layers.
  • the amount of dye used in soaping and dyeing should not be too high, otherwise the overall color of the garment will be colored.
  • the hand-painted various methods are used to draw the dyeing liquid on the cloth surface according to the design pattern.
  • the hand-painted auxiliary dyeing such as the fixing agent and the penetrating agent, is performed, and the hand-painted pattern is finished and dried.
  • 102 ° C steam After steaming for 10 minutes, after washing with cold water, it is soaped and dyed, using 8g/L of white antifouling agent, 10g/L of detergent, and lg/L of dye active green KE-4B, at 85°C. 10 minutes. Soak and dye, then wash and dry in cold water. '

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Description

织物手绘着色染色方法
技术领域
本发明涉及织物手绘着色染色方法, 是一种对布匹、 纱线、 成衣的 局部或全部的手绘艺术整理新工艺。 背景技术
目前的织物成衣的着色主要为染色和印花两种方法, 织物或成衣利 用染色的方法制成的成品色彩单一, 风格单调; 利用印花的方法制成的 成品图案造型单一, 色彩变化较小, 因此利用此两种方法制成的服装均 不能满足现在市场上的多品种、 个性化的需求。 传统扎染、 蜡染方法制 成的成品花型较粗犷、 风格较抽象, 图案层次变化相对较少。 发明内容
为了克服现有技术手绘工艺无法创造及完善一种生产具有色彩变化 丰富、 时尚效果浓厚、 风格个性化的手绘织物或成衣的缺点而提供一种 具有极富艺术效果的手绘成品的手绘着色染色方法。
为解决上述技术问题, 本发明的技术方案是, 一种织物手绘着色染 色方法, 其主要包括以下步骤:
(1)预处理;
(2)绷衫;
(3) 手绘着色,使用的染料采用活性染料、酸性、中性、或分散染料, 染料组合物中各组份及其质量百分含量为:
糊料 0〜12%
染料 0~15%
尿素 1〜15% 0-8%
间硝基苯磺酸钠 0~3%
表面活性剂 0~3%
加水合成 100%
(4)汽蒸固色;
(5)水洗后整理。
所述步骤 (1 ) 的预处理是水洗或渗透剂预处理。
所述步骤 (2) 之绷衫: 真丝薄型织物以框架将织物拉平; 中厚型弹 性织物在泡沬板上用大头针固定。
步骤 (3 )手绘着色的糊料为海藻酸钠、 醚化种子胶、 乳化糊、 淀粉 醚、 龙胶、 或纤维素醚中的一种或几种。
步骤 (3 ) 中, 对于棉、 粘胶、 部分丝织物, 适用活性染料, 染料组 合物各组份及其质量百分含量为:
0-12%
Figure imgf000003_0001
3%~15%
1%~8%
间硝基苯磺酸钠 1%~3%
表面活性剂 0%~3%
对于羊毛、 羊绒、 兔绒 丝绸织物, 适用酸性、 中性染料, 染料组 为:
0-12%
Figure imgf000003_0002
3%~15%
表面活性剂 0%~3% 印染酸 0-3%
对于涤纶织物, 适用分散类染料, 染料组合物各组份及其质量百分 含量为:
糊料 0〜12%
染料 0〜15%
尿素 2%~15%
表面活性剂 0%~3%
印染酸 0〜3%。
步骤 (3 ) 的手绘采用笔染、 刷染、 喷染、 拓印、 针勾、 洒染、 助剂 点染、 或防染中的一种或几种。
步骤 (4) 手绘后蒸洗染的工艺流程为: 手绘后蒸化; 水洗去浮色, 最后烘干。
步骤 (3 ) 手绘着色使用活性染料时, 步骤 (4) 水洗去浮色后进行 皂洗, 皂洗后再水洗烘干。
步骤 (3 ) 手绘过程中使用含有固色剂的手绘助剂时, 步骤 (4) 的 皂洗同时进行再染色。
皂洗及染色使用:
白地防污剂 2g/L〜15g/L
净洗剂 2g/L~15g/L
染料 5g/L
在 80°C~90°C下进行 5~15分钟。
本发明的有益效果是: 通过改进生产工艺和利用现代染整技术加工 具有极富艺术效果的手绘成品, 创造并完善一种生产具有色彩变化丰富、 时尚效果浓厚、 风格个性化的手绘织物或成衣。 具体实施方式
本发明的织物手绘着色染色方法主要包括以下步骤:
( 1 ) 织物水洗前处理;
(2) 预处理烘干;
(3 ) 绷衫;
(4) 手绘着色;
(5 ) 汽蒸固色;
(6) 水洗后整理。
步骤(1 )之织物包括毛织、针织、梭织成衣或面料, 主要原料为棉、 粘胶、 丝绸、 羊毛、 兔绒、 涤纶等中厚型织物。
步骤 (2) 的织物预处理是: 按成衣的加工方式和面料性质, 分水洗 和渗透剂预处理两种方式。 水洗为公知技术常规低温或高温水洗; 渗透 剂预处理: 针对吸水性不佳的织物采用渗透剂处理, 使其具有吸水性, 增加染料对织物的浸润性能, 使手绘生产更易于进行。 渗透剂可用壬基 酚和辛基苯酚的环氧乙烯加成物和低碳脂肪醇环氧乙烷缩合物, 脂肪醇 聚氧乙烯醚, 环氧乙烷、 环氧丙垸与高级脂肪醇制成的醚类产品, 如渗 透剂 JFC、 渗透剂 T等各类渗透剂或润湿剂。
步骤(3 )之绷衫: 此步骤中对于真丝薄型织物及中厚型弹性织物有 区别, 真丝薄型织物以框架将织物拉平, 由于此种织物较轻, 中间悬空 不会下坠; 若织物为中厚型弹性成衣织物, 以框架将织物拉平的方法会 使悬空的织物下坠而影响其手绘生产的进行和手绘艺术效果; 如采用成 衣印花用的台板方式, 由于手绘所用大部分为染液, 易沾污台板而影响 使用, 因此选用独特的泡沫板用大头针固定的方式, 既使织物方便拆卸, 沾污后水洗容易, 并可多次重复利用。 步骤 (4) 之手绘着色: 其使用的染料采用活性染料、 酸性、 中性、 分散等染料种类, 如活性艳蓝 K -R、 活性艳红 X-3B、 活性绿 KE-4B, 双偶氮型藏青色酸性染料, 中性桃红 BL106; 分散柠檬黄 302等, 染料 组合物的配方如下, 百分数为质量百分含量 (下文同) :
糊料 0~12%
染料 0〜15%
尿素 1-15%
碳酸氢钠 0〜8%
间硝基苯磺酸钠 0〜3%
表面活性剂 0~3%
加水合成 100%
糊料可用海藻酸钠、 醚化种子胶、 乳化糊、 淀粉醚、 龙胶、 纤维素 醚等。 糊料的添加量视手绘要求和效果而定, 用量优选为 0~6%之间。
表面活性剂是在各种防水布面手绘时的添加物, 或画面需出现特殊 效果时添加。 表面活性剂是现有技术的阳离子、 非离子、 阴离子和两性 离子中的一种或数种, 如脂肪醇环氧乙垸縮合物。 其它各种助剂的添加 视染料种类的不同来决定其是否添加及其添加量。
对于棉、 粘胶、 部分丝织物, 适用活性染料, 其配方优选为:
染料 0~15% (依色光要求而定)
尿素 3%~15%
碳酸氢钠 1%~8%
间硝基苯磺酸钠 1%~3%
表面活性剂 0%~3%
糊料 0~12%
此处的表面活性剂可使用脂肪醇环氧乙垸縮合物。 糊料可为海藻酸钠、 乳化糊等。
对于羊毛、 羊绒、 兔绒、 丝绸等织物, 适用酸性、 弱酸性、 中性类 染料, 其优选配方为:
Figure imgf000007_0001
3%~15%
表面活性剂 0%~3%
糊料 0-12%
其中, 可根据需要加入适量如 0~3%印染酸。
此处的表面活性剂可使用脂肪醇环氧乙烷縮合物。
对于涤纶织物等, 适用分散类染料, 其优选配方为:
染料 0~15%
尿素 2%~15%
表面活性剂 0%~3%
糊料 0~12%
其中, 可根据需要加入适量如 0~3%印染酸。
此处的表面活性剂可使用脂肪醇环氧乙垸缩合物。
该步骤中, 手绘采用笔染、 刷染、 喷染、 拓印、 针勾、 洒染、 助剂 点染、 防染。
其中笔染、 刷染为用毛笔、 排笔、 毛刷等各类笔型工具按照设计花 型直接将染液绘在织物或成衣上。
喷染为使用喷壶或喷枪将染液喷在织物上。
针勾为使用针管将染液浆料等按设计花型勾在织物或成衣上。
助剂点染: 按设计花型将各种不同风格和效果的手绘助剂点染或滴 画或笔染或丝网刷印等或任意至少两种以上方式手绘到织物或成衣上。 防染: 用防染剂利用针勾或笔刷的方法先在布面刷上防染剂, 在湿 或干的状态下再手绘, 烘干、 蒸洗后, 有防染剂的布面会出现白色或浅 色花纹。 防染剂与印花中的防染不同, 若主要生产中厚型织物, 采用染 液进行手绘, 如果使用印花中的防染剂, 其防染效果不佳, 故采用高分 子表面活性剂的防染剂, 加强其防染效果。
步骤 (5 )手绘后蒸洗染的工艺流程为: 手绘后蒸化; 水洗 (浮色洗 净) ; 最后烘干。
手绘后蒸洗工艺条件为 102~190°C汽蒸 (或焙供) 2~60分钟,水洗以现 有技术进行即可。 对于棉、 粘胶、 部分丝织物, 蒸洗 4~30分钟; 对于羊 毛、羊绒、兔绒、丝绸等,蒸洗 40〜60分钟;对于涤纶织物等,蒸洗 40〜60 分钟。 活性染料的蒸化工艺为: 102〜105°C汽蒸 2~30分钟, 或焙烘法为 150°C焙烘 3〜5分钟;酸性、中性染料的蒸化工艺为: 102~105°C汽蒸 40〜60 分钟; 分散类染料的蒸化工艺为: 1.47 X 105~1.76 X 105Pa, 128~130°C , 20〜30分钟, 或 175~185°C, 6~10分钟。
若手绘过程中使用中性染料, 采用现有技术的低温 (如 50°C ) 水洗 (去浮色) ; 若手绘过程中使用分散染料, 于 801水¾¾ (去浮色) 即可。 若手绘过程中使用活性染料, 还可在水洗去浮色后进一步皂洗。
手绘中若还使用了含有固色剂类的手绘助剂, 可以直接皂洗无需再 染色而形成成品,也可在皂洗同时进行再染色。 此时, 手绘服装底色以中 浅色为主。
当皂洗同时进行再染色时, 水洗去浮色以及局部染色同时进行。 此 种方法与手绘生产中所用助剂有关。
皂洗及染色使用:
白地防污剂 2g/L〜15g/L
净洗剂 2g/L~15g/L 染料 5g/L
在 80°C~90°C下进行 5~15分钟。
由于固色剂为阳离子类, 与阴离子染料有强烈的吸附性, 因此在高 温皂洗过程中, 布面无固色剂的部分由于白地防污剂的作用, 染料不会 上染, 但在有固色剂的部位由于固色剂的强烈吸附作用而使染料上染。 手绘服装底色必须以中浅色为佳, 否则由于染料再次上染率较低而效果 不明显。
效果: 由于手绘后布面各处色光不同, 使用此种方法使其再上染后, 虽然加入的染料是一种纯色光, 但由于底色的不同而可以拼染出现各种 不同于手绘时的色光, 大大丰富了布面的色彩, 使其层次更丰富。
皂洗及染色中染料用量不宜过高, 否则会使服装整体搭色。
例一
本例以白色棉质厚型成衣的手绘着色为例具体阐述。
步骤(1 )将该棉质成衣水洗; 步骤 (2)采用渗透剂 JFC处理烘干, 使其具有吸水性, 增加染料对织物的浸润性能, 使手绘生产更易于进行; 步骤 (3) 选用泡沫板用大头针固定的方式固定棉质成衣。
步骤 (4) 根据设计花型, 使用活性红 K-2BP、 活性红棕 K-B3R等 活性染料, 配制多种色彩染料水溶液, 如配方为:
活性红 K-2BP 0.4%
活性红棕 K-B3R 0.3%
尿素 3%
碳酸氢钠 2%
间硝基苯磺酸钠 1%
利用手绘的各种方法按设计花型将染液绘在布面上, 手绘后, 再进 行手绘助剂点染, 如固色剂和渗透剂, 手绘花型完成后, 烘干。 102°C汽 蒸 10分钟, 冷水洗净浮色后, 进行皂洗及染色, 使用白地防污剂 8g/L, 净洗剂 10g/L, 染料活性绿 KE-4B为 lg/L, 在 85°C下进行 10分钟。皂洗 及染色后再冷水洗净烘干。 '
效果: 由于手绘后布面各处色光不同, 蒸洗再上染后, 虽然加入的 染料是一种纯色光, 但由于底色的不同而可以拼染出现各种不同于手绘 时的色光, 大大丰富了布面的色彩, 使其层次更丰富。

Claims

权利要求书
1、 一种织物手绘着色染色方法, 其主要包括以下步骤:
( 1 ) 预处理 5
(2) 绷衫;
(3 ) 手绘着色, 使用的染料采用活性染料、 酸性、 中性、 或分 散染料, 染料组合物中各组份及其质 t百分含量为:
0-12%
染料 0- 15%
1- 15%
0〜8%
间硝基苯磺酸钠 0-3%
表面活性剂 0-3%
加水合成 100%
(4) 汽蒸固色;
(5) 水洗后整理。
2、 如权利要求 1所述的织物手绘着色染色方法, 其特征在于: 所述 步骤 (1 ) 的预处理是水洗或渗透剂预处理。
3、 如权利要求 1所述的织物手绘着色染色方法, 其特征在于: 所述 步骤 (2) 之绷衫: 真丝薄型织物以框架将织物拉平; 中厚型弹性织物在 泡沫板上用大头针固定。
4、 如权利要求 1所述的织物手绘着色染色方法, 其特征在于: 步骤 (3 )手绘着色的糊料为海藻酸钠、醚化种子胶、 乳化糊、 淀粉醚、 龙胶、 或纤维素醚中的一种或几种。 5、 如权利要求 1所述的织物手绘着色染色方法, 其特征在于: 步骤 (3 ) 中, 对于棉、 粘胶、 部分丝织物, 适用活性染料, 染料组合物各组 份及其质量百分含量为:
糊料 0-12%
染料 0-15%
尿素 3%~15%
碳酸氢钠 1%~8%
间硝基苯磺酸钠 1%〜3%
表面活性剂 0%~3%
对于羊毛、 羊绒、 兔绒- 丝綢织物, 适用酸性、 中性染料, 染料组 合物各组份及其质量百分含』:为:
糊料 0-12%
染料 0-15%
3%~15%
表面活性剂 0%~3%
印染酸 0-3%
对于涤纶织物, 适用分散类染料, 染料组合物各组份及其质量百分 含量为:
0-12%
染料 0-15%
2%~15%
表面活性剂 0%~3%
印染酸 0-3%
6、 如权利要求 1所述的织物手绘着色染色方法, 其特征在于: 步骤
(3 ) 手绘采用笔染、 刷染、 喷染、 拓印、 针勾、 洒染、 助剂点染、 或防 染中的一种或几种。
7、 如权利要求 1所述的织物手绘着色染色方法, 其特征在于: 步骤
(4)手绘后蒸洗染的工艺流程为: 手绘后蒸化; 水洗去浮色, 最后烘干。
8、 如权利要求 7所述的织物手绘着色染色方法, 其特征在于: 步骤 (3 ) 手绘着色使用活性染料时, 步骤 (4) 水洗去浮色后进行皂洗, 皂 洗后再水洗烘干。
9、 如权利要求 8所述的织物手绘着色染色方法, 其特征在于: 步骤 (3 ) 手绘过程中使用含有固色剂的手绘助剂时, 步骤 (4) 的皂洗同时 进行再染色。
10、 如权利要求 9所述的织物手绘着色染色方法, 其特征在于: 皂 洗及染色使用:
白地防污剂 2g/L~15g/L
净洗剂 2g/L~15g/L
染料 5g/L
在 80° (:〜 90°C下进行 5~15分钟。
PCT/CN2005/000876 2005-04-01 2005-06-17 Procedes pour realiser des tissus peints a la main WO2006102799A1 (fr)

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