WO2006093070A1 - 水処理システム - Google Patents
水処理システム Download PDFInfo
- Publication number
- WO2006093070A1 WO2006093070A1 PCT/JP2006/303549 JP2006303549W WO2006093070A1 WO 2006093070 A1 WO2006093070 A1 WO 2006093070A1 JP 2006303549 W JP2006303549 W JP 2006303549W WO 2006093070 A1 WO2006093070 A1 WO 2006093070A1
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- WO
- WIPO (PCT)
- Prior art keywords
- membrane separation
- water
- reaction tank
- tank
- treatment
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/16—Feed pretreatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/147—Microfiltration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D65/00—Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
- B01D65/02—Membrane cleaning or sterilisation ; Membrane regeneration
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
- C02F3/12—Activated sludge processes
- C02F3/1236—Particular type of activated sludge installations
- C02F3/1268—Membrane bioreactor systems
- C02F3/1273—Submerged membrane bioreactors
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2311/00—Details relating to membrane separation process operations and control
- B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2315/00—Details relating to the membrane module operation
- B01D2315/06—Submerged-type; Immersion type
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2321/00—Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
- B01D2321/18—Use of gases
- B01D2321/185—Aeration
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/18—Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/22—Controlling or regulating
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5281—Installations for water purification using chemical agents
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Definitions
- the present invention relates to a water treatment system and relates to a technique for performing advanced wastewater treatment using a membrane separation device.
- this type of water treatment technology includes, for example, one described in Japanese Patent Application Laid-Open No. 2004-840. This technique will be described with reference to FIG.
- the septic tank sludge and human waste 41 are led to the aeration tank 42, and biological treatment with microorganisms or the like is performed in the aeration tank 42.
- the biologically treated water subjected to the biological treatment is sent to the first membrane separation device 44 through the biological treatment water tank 43 and separated into the concentrated sludge 45 and the membrane separation water 46 in the membrane separation device 44.
- Concentrated sludge 45 is partially returned to the aeration tank 42 and biological treatment water tank 43 as return sludge, and the remaining concentrated sludge is sent to the dehydrator 47 continuously or intermittently.
- the membrane separation water 46 is mixed with the coagulating agent in the mixing tank 48 and then led to the coagulation tank 49. After flocs are formed in the coagulation tank 49, it is led to the coagulation membrane raw water tank 50, and then the second membrane separation device 51. In the membrane separation device 51, it is separated into agglomerated and concentrated sludge 52 and agglomerated membrane separation water 53.
- the agglomerated membrane separation water 53 is led out of the system, a part of the agglomerated concentrated sludge 52 is returned to the agglomerated membrane raw water tank 50, and the remainder is continuously fed to the dehydrator 47 as a sludge slurry together with the remainder of the concentrated sludge 45. Supply and dehydrate.
- the dehydrated dewatered sludge 55 is led out of the system, and the dehydrated separation liquid 56 separated from the sludge is continuously returned to the biological treatment tank 43.
- the sewage treatment apparatus 30 includes a pretreatment facility 31, a first flocculation separation facility 32, a biological treatment facility 33, a second flocculation separation facility 34, an acid bath 35, an adsorption facility 36, a desalination facility 37, and a drying facility 38. And 39 discharge facilities.
- the pretreatment facility 31 performs pretreatment such as preparation and homogenization of the amount and quality of sewage. is there.
- the first flocculation / separation facility 32 performs the flocculation / precipitation separation process, and is arranged adjacent to the downstream of the pretreatment facility 31.
- the biological treatment facility 33 performs biological treatment, and is disposed adjacent to the downstream side of the first coagulation / separation facility 32.
- the second flocculation / separation facility 34 performs the flocculation membrane filtration separation process, and is arranged adjacent to the downstream of the biological treatment facility 33.
- the oxidation facility 35 performs accelerated oxidation treatment, and is disposed adjacent to the downstream side of the second coagulation separation facility 34.
- the adsorption facility 36 performs an adsorption process and is disposed adjacent to the downstream of the oxidation facility 35.
- the desalination equipment 37 performs desalination treatment and is arranged adjacent to the downstream of the adsorption equipment 36.
- the drying equipment 38 is for taking out solid salt, and is arranged adjacent to the downstream of the desalting equipment 37.
- the discharge facility 39 discharges the final treated water to the public water area and is located adjacent to the downstream of the desalination facility 37.
- the biologically treated water biologically treated in the aeration tank 42 is converted into membranes in multiple stages by the first membrane separation device 44 and the second membrane separation device 51.
- the second membrane separation device 51 performs coagulation membrane separation using a coagulant.
- the first coagulation separation facility 32 performs coagulation sedimentation separation treatment
- the biological treatment facility 33 performs biological treatment
- the second coagulation separation facility 34 performs aggregation membrane filtration separation. Process and perform advanced processing.
- the extracellular substrate is depleted for the microorganisms in the reaction tank.
- the microorganisms contained in the sludge flocs cause self-degradation, and the sludge flocs disperse with a high strength.
- the membrane surface of the membrane separation device tends to be clogged due to the dispersed fine sludge and the small solid matter of microorganisms generated by the self-decomposition of microorganisms.
- the present invention solves the above-described problems, and in the case where treated water after biological treatment is treated with a membrane separator, the membrane surface can be prevented from being blocked and the amount of the flocculant used can be reduced.
- An object is to provide a processing system.
- the raw water to be treated flowing into the system flows into the reaction tank of the membrane separation step through the biological treatment step, and the flocculant is used in the membrane separation step.
- a water treatment system for performing membrane separation treatment comprising: raw water supply means for supplying the raw water to be treated to the reaction tank; and a flocculant addition means for adding the flocculant. .
- the BOD concentration in the reaction tank of the membrane separation process is low (for example, 20 mgZL or less), and the amount of sludge generated is extremely low! / ⁇
- an appropriate amount of raw water to be treated is supplied to the reaction tank by the raw water supply means, and the flocculant is added by the flocculant addition means.
- an organic polymer flocculant that disintegrates under turbulent conditions 1 and hardly biodegrades is desirable.
- the flocculant is added to the reaction tank alone, and some of the flocculant is mixed with the raw water to be treated in advance and then supplied to the reaction tank together with the raw water to be treated. Addition of the flocculant is performed at a certain ratio to the input amount of raw water to be treated.
- the addition ratio of the flocculant is a certain ratio (the amount of flocculant per sludge concentration) with respect to the amount of sludge generated or sludge reduced in the reaction tank. By setting this addition ratio, it becomes possible to optimize the addition amount of the flocculant. Alternatively, measure the amount of coagulant contained in the excess sludge discharged from the reaction tank, determine the amount of coagulant that is deficient from the measured value based on empirical rules, and use it as the amount of coagulant to replenish the obtained deficiency. Is possible.
- the membrane separation process in the membrane separation step may be performed by immersing the membrane separation means in the reaction tank or by placing the membrane separation means outside the reaction tank.
- the raw water to be treated flowing into the system flows sequentially into the reaction tank of the membrane separation step through the pretreatment step and the biological treatment step, and the flocculant is used in combination in the membrane separation step.
- a water treatment system for performing membrane separation treatment comprising: treated water supply means for supplying treated water in the pretreatment step to the reaction tank; and a flocculant adding means for adding the flocculant. To do.
- the BOD concentration in the reaction tank of the membrane separation process is low (for example, 20 mgZL or less), and the amount of sludge generated is extremely low! /
- an appropriate amount of treated water from the pre-treatment process is supplied to the reaction tank by the pre-treatment water supply means, and the coagulant is added by the coagulant addition means.
- the flocculant is added to the reaction tank alone, and some of the flocculant is mixed in advance with the treated water in the pretreatment step and then supplied to the reaction tank together with the treated water. Addition of the flocculant is performed at a constant rate with respect to the input amount of the treated water.
- the addition ratio of the flocculant is a fixed ratio (the amount of flocculant per sludge concentration) with respect to the amount of sludge generated or sludge reduced in the reaction tank. By setting this addition ratio, it becomes possible to optimize the addition amount of the flocculant. Alternatively, measure the amount of coagulant contained in the excess sludge discharged from the reaction tank, determine the amount of coagulant that is deficient from the measured value based on empirical rules, and use it as the amount of coagulant to replenish the obtained deficiency. Is possible.
- the water treatment system of the present invention is characterized in that the pretreatment step is a solid-liquid separation treatment step or a dissolution treatment step.
- the solid-liquid separation treatment step may be performed using a screen, or precipitation separation, filtration separation, and aggregation separation using a flocculant can be applied.
- the dissolution process involves crushing residue and physicochemical dissolution of SS.
- the water treatment system of the present invention is configured such that the effluent water from the biological treatment tank that forms the biological treatment process is precipitated between the biological treatment process and the membrane separation process, and the separated water is transferred to the reaction tank of the membrane separation process.
- a precipitation treatment means to be supplied and a mixed solution supply means for directly supplying the effluent water of the biological treatment tank to the reaction tank in the membrane separation step without passing through the precipitation treatment means are provided.
- the separation water that has passed through the precipitation treatment means is introduced into the reaction tank of the membrane separation step, and the effluent water from the biological treatment tank is supplied to the reaction tank in an appropriate amount without passing through the precipitation treatment means.
- the amount of flocculant added is suppressed by adjusting the sludge concentration in the reaction tank.
- the water treatment system of the present invention comprises a submerged membrane separator in the reaction tank of the membrane separation step, and the submerged membrane separator is disposed below the membrane separator and the membrane separator.
- Control means for controlling the amount of aeration of the diffuser and the control means flows out through the membrane differential pressure of the membrane separation means, the inflow amount of the load flowing into the reaction tank, the water level in the reaction tank, and the membrane separation means.
- the aeration amount of the diffuser is controlled using at least one of the outflow amounts of the membrane permeate as a control index.
- the raw water to be treated or the treated water of the pretreatment step is used for the membrane separation treatment of the effluent from the biological treatment tank that forms the biological treatment step in the membrane separation step.
- the membrane surface of the membrane separation means can be blocked and the amount of coagulant used can be suppressed.
- FIG. 1 is a flowchart showing a water treatment system according to Embodiment 1 of the present invention.
- FIG. 2 is a schematic diagram showing a submerged agglomerated membrane separation tank in the same example.
- FIG. 3 is a flowchart showing a water treatment system according to Embodiment 2 of the present invention.
- FIG. 4 is a flowchart showing a water treatment system according to Embodiment 3 of the present invention.
- the water treatment system includes a first settling tank 2 in which the primary treatment process is a pretreatment process, a biological treatment tank 3 in which the secondary treatment process is a biological treatment process, and a precipitation tank 4 as a precipitation treatment means.
- the tertiary treatment process consists of a submerged agglomerated membrane separation tank 5 in the membrane separation process.
- the first sedimentation tank 2 performs solid-liquid separation treatment on the raw water 1 to be treated flowing into the system, and the biological treatment tank 3 biologically treats primary treated water that is treated water flowing out from the first precipitation tank 2.
- the sedimentation tank 4 performs solid-liquid separation treatment of the effluent flowing from the biological treatment tank 3, and the submerged aggregate membrane separation tank 5 biologically treats the separated water that is the secondary treated water flowing out of the sedimentation tank 4.
- the force provided with the sedimentation tank 4 The effluent water from the biological treatment tank 3 can be directly supplied to the submerged aggregation membrane separation tank 5 for biological treatment.
- the submerged agglomerated membrane separation tank 5 is obtained by immersing the submerged membrane separator 7 in the reaction tank 6, but it is also possible to adopt a configuration in which the membrane separator is arranged outside the reaction tank 6. .
- the operation of the water treatment system in the first embodiment is based on continuous treatment, but operation in which batch treatment is performed in each tank is also possible.
- the water treatment system has a main flow path system 8 that sequentially connects the first sedimentation tank 2, the biological treatment tank 3, the sedimentation tank 4, and the submerged aggregation membrane separation tank 5.
- the primary treated water supply system 9 that serves as a treated water supply means for supplying primary treated water to the reaction tank 6, and the effluent from the biological treatment tank 3 without passing through the settling tank 4 And a liquid mixture supply system 10 for supplying directly to 6.
- the submerged agglomerated membrane separation tank 5 has a coagulant supply system 11 as a coagulant addition means for supplying the coagulant to the reaction tank 6, and the coagulant supply system 11 is in the middle of the raw water supply system 9. It is also possible to connect them.
- the biological treatment tank 3 has an aeration device, and a pump and a valve device are appropriately provided in the main flow path 8, the primary treated water supply system 9, and the mixed liquid supply system 10. Provided.
- the submerged membrane separation device 7 includes a plurality of flat plate membrane cartridges 21 and an air diffuser 22 for ejecting a membrane-cleaning gas from below the case 23.
- a blower 24 for supplying air to the device 22 is arranged outside the tank.
- Each membrane cartridge 21 communicates with a permeate discharge pipe 25 via a water collection pipe (not shown).
- This submerged membrane separation device 7 aspirates the activated sludge mixed liquid in the tank with the air ejected from the air diffuser 22, and uses the air as the membrane surface cleaning gas on the membrane surface of the membrane cartridge 21. Let it work.
- the submerged membrane separator 7 applies a driving pressure to the membrane cartridge 21 by the suction pump 26, and the activated sludge mixed liquid in the tank is filtered by the membrane cartridge 21.
- the permeate that has passed through the membrane cartridge 21 is led out of the tank through the permeate outlet pipe 25 as treated water.
- the membrane cartridge 21 can be gravity filtered using the water head in the tank as the driving pressure.
- the aeration air ejected from the diffuser 22 generates an upward flow of the mixed liquid in the tank, and the upward flow including the air bubbles and the mixed liquid force in the tank cleans the film surface of the membrane cartridge 21. Therefore, it prevents the malfunction of the separation function by suppressing the decrease of the separation function.
- the pretreatment step is initially composed of the settling tank 2, and the pretreatment method is appropriately selected according to the properties of the raw water 1 to be treated. For example, when the raw water 1 to be treated contains coarse residue, solid-liquid separation is performed using a screen. By removing the coarse residue, blockage of the membrane cartridge 21 and the air diffuser 22 in the submerged membrane separator 7 is prevented.
- the BOD concentration of the raw water 1 to be treated is too large, which may adversely affect the biodegradable substance concentration and COD concentration in the treated water of the submerged membrane separation device 7, sedimentation separation and filtration
- the BOD concentration of the primary treated water flowing into the biological treatment process is reduced, and the increase in the MLSS concentration in the reaction tank 6 is suppressed.
- the submerged aggregate membrane separation tank 5 is provided with a water level meter 12 in the reaction tank 6, a main flow path 8 connected to the reaction tank 6, a primary treated water supply system 9, and a mixed liquid supply system.
- the flow meter 13, 14, 15 is installed in 10
- the flow meter 16 and the pressure gauge 17 are installed in the permeate outlet pipe 25, and the control device 18 is the flow meter 13, 14, 15, 16 and pressure gauge 17.
- the operation of the blower 24 and the suction pump 26 is controlled based on the measured value.
- Example 1 the primary treated water supply system 9 is provided.
- the present invention provides raw water as a raw water supply means for supplying the raw water 1 to be treated to the reaction tank 6 as Example 2. It is also possible to provide a supply system 18.
- the raw water supply system 18 is connected to the primary treated water supply system 9, and the primary treated water and the raw water 1 to be treated are selectively mixed or reacted. It is also possible to supply to tank 6.
- the raw water 1 to be processed flowing into the system is first processed through the sedimentation tank 2, the biological treatment tank 3, and the submerged aggregation membrane separation tank 5 in this order.
- the BOD concentration in 6 is low (for example, 20 mgZL or less), the amount of sludge generated in the reaction tank 6 becomes extremely small.
- an appropriate amount of primary treated water is supplied from the primary treated water supply system 9 to the reaction tank 6 of the submerged aggregation membrane separation tank 5.
- an appropriate amount of raw water 1 to be treated is supplied from the raw water supply system 18, and in Example 3, at least one of primary treated water and raw water 1 to be treated is supplied.
- the BOD concentration in the reaction tank 6 is adjusted to increase the amount of sludge generated in the reaction tank 6, and a predetermined amount of the flocculant supply system 11 is used. Add flocculant.
- the organic component and SS in the reaction tank 6 are increased, and the properties of the liquid mixture (membrane separation target liquid) in the reaction tank 6 are changed to floc formation. Adjust to an appropriate sludge concentration, and coagulate organic components (soluble substances) and SS (solid matter) with a flocculant to form a sufficiently large sludge floc.
- the flocculant is added to the reaction vessel 6 alone, but it is also possible to add the flocculant to the raw water 1 to be treated in the middle of the raw water supply system 9. In this case, the flocculant is added at a constant rate to the amount of raw water 1 to be treated, and the flocculant is mixed in advance. Supply target raw water 1 to reaction tank 6.
- the addition ratio of the flocculant can be optimized by adding the flocculant at a constant ratio (the amount of flocculant per sludge concentration) with respect to the amount of sludge generation or sludge reduction. It becomes.
- measure the amount of coagulant contained in the excess sludge discharged from the reaction tank 6, determine the amount of coagulant that is insufficient in the measured value, based on empirical rules, and use it as the coagulant amount to replenish the obtained shortage. Is also possible.
- the amount of the flocculant added is determined as follows. When the sludge concentration in reactor 6 increases
- the flocculant is adsorbed on the sludge floc
- the flocculant concentration A (mg / L) in the reaction tank 6 is proportional to the sludge concentration B (mg / L)
- the flocculant concentration C per sludge concentration is C.
- the amount of flocculant added E (mgZd) per day is obtained for the amount of sludge increase D (mgZd) per day in the reaction tank 6.
- the amount of flocculant added per day (mgZd) is determined by the following formula.
- sludge decrease rate in reaction tank 6 MLSS decrease rate MLSS increase rate
- sludge concentration decrease rate MLSS concentration decrease rate MLSS concentration increase rate
- the conventional method that is, the soluble COD concentration in the reaction tank 6, the COD concentration in the effluent water flowing out from the reaction tank 6, the turbidity, etc. are measured, and these measured values are appropriate values.
- the flocculant can be added more simply than the method of adding the flocculant.
- stirring is performed in the reaction tank 6, either a mechanical type or a pneumatic type can be employed.
- the aeration is performed by the diffuser 22 of the submerged aggregation membrane separation tank 5.
- Fig. 5 shows the relationship between the negative pressure increase rate (kPaZd) and the MLSS concentration (mgZL) when the submerged membrane separator 7 of the submerged agglomeration membrane separation tank 5 is operated in the arch
- Negative pressure increase acceleration indicates that the larger the value, the more easily the membrane gets dirty.
- the quality of the raw water 1 to be treated is not constant and varies.
- the increase in sludge in the reaction tank 6 changes, and the increase in sludge causes an increase in the amount of flocculant used.
- it is required to control the amount of increase in sludge within an appropriate range even if the water quality fluctuates.
- This sludge increase amount is controlled by considering the quality of the raw water 1 to be treated and the quality of the secondary treated water in the biological treatment tank 3, and the mixing conditions of the primary treated water or the raw water 1 to be treated and the secondary treated water. It is done by changing. However, this control is an advanced control that requires a lot of experience.
- the submerged membrane separation device 7 when the submerged membrane separation device 7 is operated under a load condition where the MLSS concentration in the reaction vessel 6 is low, the water quality fluctuation of the raw water 1 to be treated is the mixture in the reaction vessel 6 Sensitive to the filterability. For this reason, sludge is generated in real time according to fluctuations in water quality Although it is necessary to control the amount of production, real-time control is virtually impossible because it is difficult to perform water quality analysis quickly.
- the BOD concentration in the secondary treated water is lowered, and therefore, it can be dealt with by adjusting the mixing ratio of the primary treated water.
- the BOD concentration of secondary treated water increases and the amount of water decreases. In this state, in order to maintain the water quality and amount of the permeate in the submerged agglomerated membrane separation tank 5, it is necessary to increase the amount of coagulant used.
- BOD is 3 (mg / L) in biologically treated water (secondary treated water), and the raw water The BOD is 7 (mg / L) due to the inflow water into the reaction tank that is made by mixing 1:10 with biologically treated water.
- BOD of raw water (raw water to be treated 1) is 150 (mg / L) and standard, BOD is 20 (mg / L) for biologically treated water (secondary treated water).
- the BOD is 32 (mg / L) with the inflow water to the reaction tank mixed at 1:10.
- BOD of raw water is as large as 500 (mg / L). Sometimes, BOD is 150 (mg / L) in biologically treated water (secondary treated water in biological treatment tank 3). The BOD is 182 (mg / L) due to the inflow water into the reaction tank that is mixed with biologically treated water at 1:10.
- the BOD load CZT X is 0.02 and stable. If the water quality of the raw water 1 to be treated fluctuates greatly, the BO D load CZTX becomes 0.1 and sludge growth increases, and by-product metabolites (noopolymers) produced by microorganisms, the filterability of the mixture in the tank becomes unsuitable for membrane separation.
- the control device 18 has at least one of the transmembrane differential pressure acting on the membrane cartridge 21, the inflow amount of the load flowing into the reaction tank 6, the water level in the reaction tank 6, and the outflow amount of the membrane permeate.
- the air volume of the air diffuser 22 is controlled using one of them as a control index.
- the transmembrane pressure difference is measured with a pressure gauge 17.
- the inflow of the load flowing into the reaction tank 6 is the amount of water flowing into the reaction tank 6 through the main flow path 8, the primary treated water supply system 9, and the mixed liquid supply system 10, and is measured by the flow meters 13, 14, and 15. .
- the water level in the reaction tank 6 is measured with a water level meter 12, and the flow rate of the membrane permeate is measured with a flow meter 16.
- the transmembrane pressure is an index that indirectly indicates the membrane surface blocking state of the membrane separation device, and the membrane surface tends to be clogged when the transmembrane pressure increases. For this reason, when the transmembrane differential pressure measured by the pressure gauge 17 rises, the operation of the blower 24 is controlled to increase the amount of air blown by the air diffuser 22.
- the amount of permeate that has passed through the membrane cartridge 21 is measured by the flow meter 16, and the amount of flowing water flowing into the reaction tank 6 is measured by the flow meters 13, 14, and 15. Alternatively, measure the water level in reaction tank 6 with water level gauge 12.
- the flux is displayed as an instantaneous flux, and the amount of water flowing into the reaction tank 6 is displayed as the amount of inflow wastewater.
- the inflow wastewater amount (measured at flow meters 13, 14, and 15)
- the operation of the suction pump 26 is controlled so that the instantaneous flux is doubled
- the operation of the blower 24 is controlled so that the aeration volume is 150%.
- the aeration volume can also be controlled by the combination of the transmembrane differential pressure measured by the pressure gauge 17, the inflow measured by the flow meters 13, 14, and 15, and the water level measured by the water level gauge 12. It is.
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- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Activated Sludge Processes (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002597756A CA2597756C (en) | 2005-02-28 | 2006-02-27 | Water treatment system |
JP2007505909A JP4874231B2 (ja) | 2005-02-28 | 2006-02-27 | 水処理システム |
EP06714686A EP1897857A4 (en) | 2005-02-28 | 2006-02-27 | WATER TREATMENT SYSTEM |
US11/884,377 US7931802B2 (en) | 2005-02-28 | 2006-02-27 | Water treatment system |
CN2006800061672A CN101128398B (zh) | 2005-02-28 | 2006-02-27 | 水处理系统 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005-052174 | 2005-02-28 | ||
JP2005052174 | 2005-02-28 |
Publications (1)
Publication Number | Publication Date |
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WO2006093070A1 true WO2006093070A1 (ja) | 2006-09-08 |
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US (1) | US7931802B2 (ja) |
EP (1) | EP1897857A4 (ja) |
JP (1) | JP4874231B2 (ja) |
CN (1) | CN101128398B (ja) |
CA (1) | CA2597756C (ja) |
WO (1) | WO2006093070A1 (ja) |
Cited By (6)
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JP2007222814A (ja) * | 2006-02-24 | 2007-09-06 | Hitachi Ltd | 凝集剤注入量制御方法及び制御コントローラ |
JP2010137216A (ja) * | 2008-11-11 | 2010-06-24 | Kobelco Eco-Solutions Co Ltd | 膜分離活性汚泥処理装置および膜分離活性汚泥処理方法 |
JP2012000585A (ja) * | 2010-06-18 | 2012-01-05 | Kubota Corp | 汚水処理設備、汚水処理方法及び汚水処理設備の改築方法 |
JP2013202525A (ja) * | 2012-03-28 | 2013-10-07 | Mitsubishi Rayon Co Ltd | 排水処理システムおよび排水処理方法 |
JP2015163388A (ja) * | 2014-01-31 | 2015-09-10 | 三菱レイヨン株式会社 | 廃水処理方法および廃水処理システム |
WO2023127347A1 (ja) * | 2021-12-27 | 2023-07-06 | 株式会社クボタ | 廃水処理方法および廃水処理システム |
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US9358505B2 (en) | 2009-09-03 | 2016-06-07 | General Electric Company | Gas sparger for an immersed membrane |
US9364805B2 (en) | 2010-10-15 | 2016-06-14 | General Electric Company | Integrated gas sparger for an immersed membrane |
JP5782931B2 (ja) * | 2011-09-05 | 2015-09-24 | 富士電機株式会社 | 水処理方法及び水処理装置 |
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US9463419B2 (en) | 2012-01-09 | 2016-10-11 | General Electric Company | Pulse aeration for immersed membranes |
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CN104817222B (zh) * | 2014-01-31 | 2019-09-17 | 三菱化学株式会社 | 废水处理方法以及废水处理装置 |
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JP6268660B1 (ja) * | 2017-05-18 | 2018-01-31 | 三菱重工環境・化学エンジニアリング株式会社 | 生物処理装置、生物処理方法、及びプログラム |
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- 2006-02-27 CA CA002597756A patent/CA2597756C/en not_active Expired - Fee Related
- 2006-02-27 CN CN2006800061672A patent/CN101128398B/zh not_active Expired - Fee Related
- 2006-02-27 WO PCT/JP2006/303549 patent/WO2006093070A1/ja active Application Filing
- 2006-02-27 EP EP06714686A patent/EP1897857A4/en not_active Withdrawn
- 2006-02-27 US US11/884,377 patent/US7931802B2/en not_active Expired - Fee Related
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JP2007222814A (ja) * | 2006-02-24 | 2007-09-06 | Hitachi Ltd | 凝集剤注入量制御方法及び制御コントローラ |
JP2010137216A (ja) * | 2008-11-11 | 2010-06-24 | Kobelco Eco-Solutions Co Ltd | 膜分離活性汚泥処理装置および膜分離活性汚泥処理方法 |
JP2012000585A (ja) * | 2010-06-18 | 2012-01-05 | Kubota Corp | 汚水処理設備、汚水処理方法及び汚水処理設備の改築方法 |
JP2013202525A (ja) * | 2012-03-28 | 2013-10-07 | Mitsubishi Rayon Co Ltd | 排水処理システムおよび排水処理方法 |
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WO2023127347A1 (ja) * | 2021-12-27 | 2023-07-06 | 株式会社クボタ | 廃水処理方法および廃水処理システム |
Also Published As
Publication number | Publication date |
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EP1897857A4 (en) | 2012-01-25 |
CA2597756C (en) | 2010-01-05 |
US7931802B2 (en) | 2011-04-26 |
JPWO2006093070A1 (ja) | 2008-08-07 |
CN101128398A (zh) | 2008-02-20 |
JP4874231B2 (ja) | 2012-02-15 |
EP1897857A1 (en) | 2008-03-12 |
US20090236275A1 (en) | 2009-09-24 |
CA2597756A1 (en) | 2006-09-08 |
CN101128398B (zh) | 2011-01-26 |
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