WO2006085762A1 - Process and apparatus for conversion of biomass - Google Patents

Process and apparatus for conversion of biomass Download PDF

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Publication number
WO2006085762A1
WO2006085762A1 PCT/NL2006/000073 NL2006000073W WO2006085762A1 WO 2006085762 A1 WO2006085762 A1 WO 2006085762A1 NL 2006000073 W NL2006000073 W NL 2006000073W WO 2006085762 A1 WO2006085762 A1 WO 2006085762A1
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WO
WIPO (PCT)
Prior art keywords
reactor
acid
process according
biomass
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/NL2006/000073
Other languages
English (en)
French (fr)
Other versions
WO2006085762A8 (en
Inventor
Robert Reurd Christophor Bakker
Jacob Hendrik Obbo Hazewinkel
Johannes Wouterus Van Groenestijn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO
Agrotechnology and Food Innovations BV
Techno Invent Ingenieursbureau voor Milieutechniek BV
Original Assignee
Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO
Agrotechnology and Food Innovations BV
Techno Invent Ingenieursbureau voor Milieutechniek BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA002597554A priority Critical patent/CA2597554A1/en
Priority to MX2007009733A priority patent/MX2007009733A/es
Priority to NZ560874A priority patent/NZ560874A/en
Priority to EA200701702A priority patent/EA015121B1/ru
Priority to EP06716616A priority patent/EP1859101A1/en
Priority to AP2007004142A priority patent/AP2242A/xx
Priority to AU2006213183A priority patent/AU2006213183B2/en
Priority to BRPI0607344-1A priority patent/BRPI0607344A2/pt
Priority to JP2007555042A priority patent/JP4834680B2/ja
Priority to CN200680011001XA priority patent/CN101155958B/zh
Application filed by Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO, Agrotechnology and Food Innovations BV, Techno Invent Ingenieursbureau voor Milieutechniek BV filed Critical Nederlandse Organisatie voor Toegepast Natuurwetenschappelijk Onderzoek TNO
Publication of WO2006085762A1 publication Critical patent/WO2006085762A1/en
Priority to US11/837,156 priority patent/US7501025B2/en
Anticipated expiration legal-status Critical
Priority to NO20074201A priority patent/NO20074201L/no
Publication of WO2006085762A8 publication Critical patent/WO2006085762A8/en
Ceased legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • D21C11/0007—Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C11/00—Regeneration of pulp liquors or effluent waste waters
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00—Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04—Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M23/00—Constructional details, e.g. recesses, hinges
    • C12M23/20—Material Coatings
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M25/00—Means for supporting, enclosing or fixing the microorganisms, e.g. immunocoatings
    • C12M25/16—Particles; Beads; Granular material; Encapsulation
    • C12M25/18—Fixed or packed bed
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M29/00—Means for introduction, extraction or recirculation of materials, e.g. pumps
    • C12M29/24—Recirculation of gas
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12M—APPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M41/00—Means for regulation, monitoring, measurement or control, e.g. flow regulation
    • C12M41/26—Means for regulation, monitoring, measurement or control, e.g. flow regulation of pH
    • C—CHEMISTRY; METALLURGY
    • C13—SUGAR INDUSTRY
    • C13K—SACCHARIDES OBTAINED FROM NATURAL SOURCES OR BY HYDROLYSIS OF NATURALLY OCCURRING DISACCHARIDES, OLIGOSACCHARIDES OR POLYSACCHARIDES
    • C13K1/00—Glucose; Glucose-containing syrups
    • C13K1/02—Glucose; Glucose-containing syrups obtained by saccharification of cellulosic materials
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
    • C12P2201/00—Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel

Definitions

  • the invention is directed to a process for the conversion of biomass, in particular the conversion of lignocellulose-containing biomass into fermentable sugars.
  • the invention is further directed to apparatus suitable for carrying out such processes.
  • Renewable materials will play an increasingly important role in the future.
  • Biological conversion processes will be important in producing valuable products, such as ethanol, from renewable starting materials, such as biomass.
  • a bottle-neck in converting biomass is formed by the step in which the release of carbohydrates from lignocellulose, which is the main constituent of biomass, is to be carried out.
  • biocatalysts ⁇ e.g. microorganisms
  • a known technique for this purpose is strong acid treatment, which is described for instance in US-A-5 562 777, US-A-5 580 389, US-A-5 597 714, US-A-5 620 877, US-A-5 726 046, US-A-5 782 982, US-A-5 820 687, US-A-6 054611 and US-A-6 239 198.
  • WO-A-94/23071 describes a method for producing sugars from materials containing cellulose and hemicellulose. The method comprises decrystallization and hydrolysis of the cellulose and hemicellulose with an acid and separation of the hydrolysate into sugars and acid.
  • US-A-4 427 584 describes a stepwise process for converting crystalline ⁇ -cellulose to amorphous ⁇ -cellulose with liquid or gaseous sulphur trioxide to cause decrystallization of the ⁇ -cellulose followed by hydrolysis of the treated fibers to produce sugars.
  • the known techniques for converting cellulosic materials into fermentable products usually require the presence of a mechanical stirring device to obtain sufficient mixing of the cellulosic material and the strong acid. In practice this often leads to complications, because of the combination of moving parts and strong acid, which gives rise to corrosion problems.
  • the cellulosic materials also generally require mechanical pretreatment to obtain the required particle size (usually 10 mm in diameter, or less), and water content (in general less than 10%).
  • the known techniques require chopping or grinding of the cellulosic materials to a particle size not greater than 10 mesh, in order to overcome the difficulty of providing good contact between the strong acid and the cellulosic material. This small particle size is also required to allow for suspension of the cellulosic materials in a hot air stream.
  • this objective can be met by providing a process in which a packed bed or heap of biomass is brought into contact with acid, and with a gas as the continuous phase. During this process, the biomass is broken down to a particle size of 10 mm or larger.
  • the contacting is carried out by cocurrently contacting the biomass with acid and countercurrently with a gas.
  • the biomass may be mixed with an inert material with a large specific surface such as plastic pall rings to warrant the required structural strength of the packed biomass and ensure a good distribution of gas and liquid.
  • the present invention is directed to a process for converting biomass into fermentable sugars comprising contacting in a reactor said biomass with an acid, while passing a gas stream through said reactor, wherein said gas is an inert gas which is able to take up water, thereby effectively changing the pH in the reactor.
  • a gas stream By passing the gas stream through the reactor, evaporation of water from the acid solution can be changed and the acid concentration and thus the pH and the moisture content can effectively be controlled.
  • the gas stream assists in providing a homogeneous distribution of acid throughout the reactor, without requiring mechanical stirring means.
  • the acid used may be any strong acid known in the art to be suitable for this purpose, such as hydrochloric acid, phosphoric acid, hydrofluoric acid and sulphuric acid. Sulphuric acid is most preferred, because it may be removed using biological processes.
  • sulphuric acid may be employed in the form of (gaseous) sulphur trioxide that is added to the aqueous phase present in the reactor.
  • the acid is added, e.g. by spraying it from the top of the reactor.
  • SO3 is added.
  • water can be added so that an aqueous phase having the desired acid concentration is obtained.
  • the gas is fed, preferably from the bottom of the reactor.
  • the acid used in the reactor may be recirculated back into the reactor, depending on the degree of depolymerization of the biomass.
  • the gas stream is circulated.
  • the gas flow rate may be adjusted so that the pH of the solution, which may be constantly monitored e.g. by means of pH electrodes, is kept at the desired level.
  • the concentration of the acid is controlled at 70 - 75 wt.%, based on the weight of acid (expressed as kg H2SO4 per kg dry cellulosic material) and water present in said reactor.
  • the depolymerisation can be carried out at a more or less constant and high acid concentration.
  • the lignocellulose is converted into a viscous slurry which flows downwards to the bottom of the reactor, where it may be collected.
  • the product containing depolymerized cellulose and hemicellulose may be removed from the reactor and fed to a subsequent processing step, optionally after a sieving step to remove coarse unconverted parts.
  • the depolymerization process is generally carried out in a batch process. It may also be carried out in a semi- continuous manner: biomass is fed into the reactor while the gas and acid are circulated, until the volume of unconverted matter is such its removal from the reactor is required.
  • Another advantage of the process of the present invention is that non-converted material, which is often formed by contamination in the biomass feed (such as sand or pieces of plastic), remains in the reactor, and can be removed therefrom relatively easily after the reaction is completed.
  • the acid consumption of the process of the present invention is minimized. Furthermore, even large pieces of biomass, such as large chunks of wood, may be converted effectively. Because the acid concentration and moisture content can be controlled relatively easily by the process of the present invention, the type of feed that can be used may vary widely in water content, which adds to the versatility of the process.
  • the gas that is used for passing through the reactor may in principle be any gas that is able to take up water in a sufficient amount.
  • the gas is inert with respect to the acid treatment process, i.e. it does not interfere with the acid treatment process.
  • this gas comprises CO2 (typically more than 90 vol.%, e.g. more than 99 vol.%), because CO2 can be obtained from a subsequent fermentation step, in which the biomass that is converted by the acid treatment is converted to e.g. ethanol.
  • CO2 typically more than 90 vol.%, e.g. more than 99 vol.%
  • CO2 can be obtained from a subsequent fermentation step, in which the biomass that is converted by the acid treatment is converted to e.g. ethanol.
  • Another advantage of CO2 is that it helps to suppress the formation of undesired products, in particular oxidation products.
  • gases suitable gases include nitrogen (N2) and air.
  • the gas stream comprises preferably a component selected from the group consisting of CO2, nitrogen, air, and combinations thereof.
  • the gas stream In view of process economics, it is preferred to circulate the gas stream. This involves removing water from the gas stream before it is fed back to the reactor. Water may be removed using known techniques, such as cooling to a sufficiently low temperature. It was found that a temperature of ca. 0 - 4 0 C, provides for a gas that is sufficiently dry. Good results are obtained with a temperature of about 2 0 C.
  • the acid used in the reactor is preferably sulphuric acid.
  • This can be fed as concentrated H2SO4 (e.g. 90 wt.% or more) to the reactor, but it is also possible to have sulphuric acid formed in situ by adding sulphur trioxide gas to the reactor, which yields sulphuric acid when dissolved in water: SO3 + H2O ⁇ H2SO4.
  • the sulphur trioxide may be obtained from a different process step in which sulphur compounds are burnt using oxygen or air.
  • a sulphur compound is hydrogen sulphide, which can be obtained from a sulphate reduction step that may be employed to remove sulphur compounds from the products.
  • the gas velocity through the bed is kept relatively low (e.g. below 0.5 m/s) so that the pressure drop across the bed is limited (e.g. to about 50 mm H2O).
  • the pressure in the reactor can be atmospheric, or slightly higher.
  • the temperature in the reactor is preferably from 60 - 100 0 C, more preferably from 75 - 85 0 C, since this already provides for a suitable rate of reaction, while at the same time excessive evaporation of water is avoided.
  • the amount of acid is low. Preferably less than 2 kg acid per kg of dry matter is present, more preferably 1.2 - 1.4 kg H2SO4 per kg of dry matter.
  • the prior art techniques for treatment of biomass with strong acids generally employs much more acid than 2 kg acid per kg of dry matter.
  • the concentration of the acid is preferably controlled at 70 - 75 wt.%, based on the weight of acid (expressed as kg H2SO4per kg of dry matter) and water present in said reactor.
  • An apparatus for carrying out the process of the present invention typically comprise a non-stirred batch reactor vessel, which may conveniently be constructed of concrete (which is cheap and robust), which is provided on the inside with an acid resistant lining, such as a TeflonTM lining or a PVC lining.
  • the reactor is further provided with gas entry and gas exit means, as well as means for feeding acid, in particular one or more spraying nozzles for distributing acid solution.
  • the equipment may further comprise a heater for heating the gas entry stream before it enters the reactor.
  • the lignocellulose depolymerises and forms a slurry. The slurry moves downward and is collected in the bottom part of the reactor.
  • the apparatus for carrying out the invention may further comprise a pump for pumping out the slurry from the reactor. It may further comprise one or more sieves to remove course parts from the product stream.
  • the product obtained from the process of the present invention may be further processed in subsequent steps. Typically this involves the addition of water which effects the hydrolysis of the depolymerized cellulose and hemicellulose into oligomeric or monomeric sugars.
  • the lignin may be precipitated and can be filtered off in a filtration step.
  • Carbonate and bicarbonate that is present in the solution is converted into CO2, which may be collected at the top of the reactor wherein this step is carried out.
  • This CO 2 stream may be used for passing through the reactor where the biomass is hydrolysed to oligomeric or monomeric sugars.

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Genetics & Genomics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Engineering & Computer Science (AREA)
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  • Processing Of Solid Wastes (AREA)
  • Preparation Of Compounds By Using Micro-Organisms (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
PCT/NL2006/000073 2005-02-11 2006-02-13 Process and apparatus for conversion of biomass Ceased WO2006085762A1 (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
JP2007555042A JP4834680B2 (ja) 2005-02-11 2006-02-13 バイオマスの転化のための方法及び装置
NZ560874A NZ560874A (en) 2005-02-11 2006-02-13 Process and apparatus for conversion of biomass
EA200701702A EA015121B1 (ru) 2005-02-11 2006-02-13 Способ и аппарат для конверсии биомассы
EP06716616A EP1859101A1 (en) 2005-02-11 2006-02-13 Process and apparatus for conversion of biomass
AP2007004142A AP2242A (en) 2005-02-11 2006-02-13 Process and apparatus for conversion of biomass.
AU2006213183A AU2006213183B2 (en) 2005-02-11 2006-02-13 Process and apparatus for conversion of biomass
BRPI0607344-1A BRPI0607344A2 (pt) 2005-02-11 2006-02-13 processo e aparelho para a conversço de biomassa celulàsica em aÇécares fermentÁveis
CA002597554A CA2597554A1 (en) 2005-02-11 2006-02-13 Process and apparatus for conversion of biomass
MX2007009733A MX2007009733A (es) 2005-02-11 2006-02-13 Proceso y aparato para conversion de biomasa.
CN200680011001XA CN101155958B (zh) 2005-02-11 2006-02-13 转化生物质的方法和设备
US11/837,156 US7501025B2 (en) 2005-02-11 2007-08-10 Process and apparatus for the conversion of biomass
NO20074201A NO20074201L (no) 2005-02-11 2007-08-16 Fremgangsmate og anordning for omdanning av biomasse

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP05075352A EP1690980A1 (en) 2005-02-11 2005-02-11 Process and apparatus for conversion of biomass
EP05075352.4 2005-02-11

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US11/837,156 Continuation US7501025B2 (en) 2005-02-11 2007-08-10 Process and apparatus for the conversion of biomass

Publications (2)

Publication Number Publication Date
WO2006085762A1 true WO2006085762A1 (en) 2006-08-17
WO2006085762A8 WO2006085762A8 (en) 2007-11-29

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Application Number Title Priority Date Filing Date
PCT/NL2006/000073 Ceased WO2006085762A1 (en) 2005-02-11 2006-02-13 Process and apparatus for conversion of biomass

Country Status (16)

Country Link
US (1) US7501025B2 (https=)
EP (2) EP1690980A1 (https=)
JP (1) JP4834680B2 (https=)
KR (1) KR101262408B1 (https=)
CN (1) CN101155958B (https=)
AP (1) AP2242A (https=)
AU (1) AU2006213183B2 (https=)
BR (1) BRPI0607344A2 (https=)
CA (1) CA2597554A1 (https=)
EA (1) EA015121B1 (https=)
MX (1) MX2007009733A (https=)
NO (1) NO20074201L (https=)
NZ (1) NZ560874A (https=)
UA (1) UA89814C2 (https=)
WO (1) WO2006085762A1 (https=)
ZA (1) ZA200707104B (https=)

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US7943363B2 (en) 2008-07-28 2011-05-17 University Of Massachusetts Methods and compositions for improving the production of products in microorganisms
US8168840B2 (en) 2008-06-25 2012-05-01 Kior Inc. Biomass pretreatment process
JP2014209906A (ja) * 2008-03-14 2014-11-13 バージニア テック インテレクチュアル プロパティースインコーポレイテッド リグノセルロースバイオマスを分画するシステム

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HUE025623T2 (en) * 2009-03-03 2016-04-28 Poet Res Inc A method of fermenting biomass for ethanol production
JP5223836B2 (ja) * 2009-10-02 2013-06-26 株式会社Ｉｈｉ 有機物の処理方法及び処理装置
US8383864B2 (en) * 2009-12-08 2013-02-26 Iowa State University Research Foundation, Inc. Method for the conversion of cellulose and related carbohydrate materials to low-molecular-weight compounds
US8686192B2 (en) 2009-12-08 2014-04-01 Iowa State University Research Foundation, Inc. Method for the conversion of cellulose and related carbohydrate materials to low-molecular-weight compounds
WO2011116317A1 (en) 2010-03-19 2011-09-22 Poet Research, Inc. System for the treatment of biomass
CA2795503C (en) 2010-03-19 2020-02-18 Poet Research, Inc. System for treatment of biomass to facilitate the production of ethanol
US8394177B2 (en) * 2010-06-01 2013-03-12 Michigan Biotechnology Institute Method of separating components from a gas stream
CN103201395B (zh) 2010-06-26 2016-03-02 威尔迪亚有限公司 糖混合物及其生产和使用方法
IL206678A0 (en) 2010-06-28 2010-12-30 Hcl Cleantech Ltd A method for the production of fermentable sugars
IL207329A0 (en) 2010-08-01 2010-12-30 Robert Jansen A method for refining a recycle extractant and for processing a lignocellulosic material and for the production of a carbohydrate composition
IL207945A0 (en) 2010-09-02 2010-12-30 Robert Jansen Method for the production of carbohydrates
US8246788B2 (en) * 2010-10-08 2012-08-21 Teal Sales Incorporated Biomass torrefaction system and method
WO2012099967A1 (en) 2011-01-18 2012-07-26 Poet, Llc Systems and methods for hydrolysis of biomass
EP2689862B1 (en) * 2011-03-22 2018-07-04 Showa Denko K.K. Pre-treatment method for plant biomass hydrolysis reaction raw materials and plant biomass saccharification method
WO2012137201A1 (en) 2011-04-07 2012-10-11 Hcl Cleantech Ltd. Lignocellulose conversion processes and products
US9982317B2 (en) 2011-07-07 2018-05-29 Poet Research, Inc. Systems and methods for acid recycle
WO2013055785A1 (en) 2011-10-10 2013-04-18 Virdia Ltd Sugar compositions
EP2878614A1 (en) 2012-05-03 2015-06-03 Virdia Ltd. Methods for treating lignocellulosic materials
US9493851B2 (en) 2012-05-03 2016-11-15 Virdia, Inc. Methods for treating lignocellulosic materials
KR101479675B1 (ko) * 2012-12-20 2015-01-08 씨제이제일제당 주식회사 리그노술포네이트 제조방법, 상기 방법으로 제조된 리그노술포네이트, 및 이를 포함하는 혼화제 및 콘크리트
US11078548B2 (en) 2015-01-07 2021-08-03 Virdia, Llc Method for producing xylitol by fermentation
BR112017025322A8 (pt) 2015-05-27 2022-08-23 Virdia Inc Processos integrados para recuperação de hidrolisato celulósico após hidrólise de polpa de celulose
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