WO2005098485A1 - 光制御シート及びそれを用いた面光源 - Google Patents

光制御シート及びそれを用いた面光源 Download PDF

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Publication number
WO2005098485A1
WO2005098485A1 PCT/JP2005/006458 JP2005006458W WO2005098485A1 WO 2005098485 A1 WO2005098485 A1 WO 2005098485A1 JP 2005006458 W JP2005006458 W JP 2005006458W WO 2005098485 A1 WO2005098485 A1 WO 2005098485A1
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WO
WIPO (PCT)
Prior art keywords
light
prism
control sheet
sheet
light control
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2005/006458
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English (en)
French (fr)
Japanese (ja)
Inventor
Yasumaro Toshima
Susumu Kurishima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kimoto Co Ltd
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Kimoto Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kimoto Co Ltd filed Critical Kimoto Co Ltd
Priority to JP2006512056A priority Critical patent/JP4695071B2/ja
Priority to EP05727520A priority patent/EP1734384A4/en
Priority to US10/594,723 priority patent/US7535642B2/en
Publication of WO2005098485A1 publication Critical patent/WO2005098485A1/ja
Anticipated expiration legal-status Critical
Priority to KR1020067023075A priority patent/KR101072036B1/ko
Ceased legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B6/00Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings
    • G02B6/0001Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems
    • G02B6/0011Light guides; Structural details of arrangements comprising light guides and other optical elements, e.g. couplings specially adapted for lighting devices or systems the light guides being planar or of plate-like form
    • G02B6/0033Means for improving the coupling-out of light from the light guide
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0205Diffusing elements; Afocal elements characterised by the diffusing properties
    • G02B5/021Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures
    • G02B5/0226Diffusing elements; Afocal elements characterised by the diffusing properties the diffusion taking place at the element's surface, e.g. by means of surface roughening or microprismatic structures having particles on the surface
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/02Diffusing elements; Afocal elements
    • G02B5/0273Diffusing elements; Afocal elements characterized by the use
    • G02B5/0278Diffusing elements; Afocal elements characterized by the use used in transmission
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/04Prisms
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/04Prisms
    • G02B5/045Prism arrays

Definitions

  • the present invention relates to a light control sheet constituting a part of a surface light source suitably used as a knock light or the like of a liquid crystal display, and a surface light source using the light control sheet.
  • a surface light source called an edge light type backlight is used for a liquid crystal display and the like.
  • a light guide plate provided with a light source such as a cold cathode tube on at least one side surface, a light reflection sheet is laminated on a surface opposite to the light emission surface, and light is diffused to the light emission surface.
  • a plurality of functional films and upward prism sheets are laminated.
  • a surface light source there is one that employs a prism sheet called a downward facing prism sheet.
  • a general prism sheet is designed so that the prism surface becomes the light exit surface, while a downward prism sheet is designed so that the prism surface becomes the light incident surface! It is.
  • the viewing angle is widened by arranging the light diffusing sheet on the surface of the downward prism sheet opposite to the prism surface, and furthermore, irregularities are formed on the surface of the light diffusing sheet facing the downward prism sheet.
  • Surface light that eliminates the occurrence of rainbow ring patterns The source element is described in Patent Document 1.
  • the light-diffusing sheet having an uneven surface has a problem that when the uneven surface comes into contact with the prism sheet, the contact surface is damaged and the display quality of the display device using the surface light source element is deteriorated. . For this reason, it is necessary to provide a space between the prism sheet and the light diffusing sheet so that they are not in contact with each other, which hinders the reduction in the thickness of the surface light source element.
  • Patent Document 1 Japanese Patent Application Laid-Open No. 2003-329812
  • a light control film including a downward prism sheet and a light diffusing sheet having an uneven surface on a surface facing the downward prism sheet, which solves the problem of scratches between constituent members. It is intended to provide a control sheet. It is another object of the present invention to provide a surface light source that does not cause deterioration in display quality due to damage to constituent members when combined with a display device such as a liquid crystal display panel.
  • the light control sheet provided by the present invention includes at least a light diffusing film and a prism sheet, and the light diffusing film has a light diffusing surface on one surface and an uneven surface on the other surface.
  • the prism sheet has a prism surface on one surface and a smooth surface on the other surface.
  • the smooth surface comprises at least a smooth layer containing a comb polymer, and the uneven surface of the light diffusing film and the smooth surface of the prism sheet face each other.
  • the light control sheet of the present invention is a light control sheet having at least a light diffusing film and a prism sheet, and the light diffusing film has a light diffusing surface on one surface.
  • the prism sheet has a prism surface on one surface and an uneven surface on the other surface. The smooth surface of the light diffusing film and the uneven surface of the prism sheet face each other.
  • the comb polymer has a trunk portion and a branch portion, and each of the trunk portion and the branch portion has a configuration in which a monomer is polymerized, and the main component of the monomer constituting the trunk portion is the former.
  • the composition may be different from the main component of the monomer constituting the branch portion.
  • the comb polymer a polymer obtained by copolymerizing the monomer serving as the trunk portion and the macromonomer serving as the branch portion can be used, and the main component of the monomer serving as the trunk portion is acrylic.
  • non-acrylic monomer a styrene monomer can be used.
  • the comb polymer may be constituted so as to account for 40% by weight or more of the components of the smooth layer.
  • the surface light source provided by the present invention includes a light source, a light guide plate having the light source disposed at an end, and a light control sheet disposed on a light exit surface of the light guide plate.
  • the light control sheet is arranged such that the prism surface of the prism sheet and the light exit surface of the light guide plate face each other.
  • the light control sheet of the present invention when employed as a member as a surface light source, a rainbow-like ring-shaped pattern is not generated without impairing the front luminance and the viewing angle, and further, the constituent members It is also possible to solve the problem of mutual damage. Further, when a surface light source having the light control sheet as a constituent member is combined with a display device such as a liquid crystal display panel, the display quality is not deteriorated due to scratches.
  • the light control sheet 1 of the present invention includes a laminated light diffusing film 2 and a prism sheet 3 as shown in FIG. 1 or FIG.
  • the light diffusing film 2 used here has a light diffusing surface 11 on one surface as shown in FIG. 1 and a force having an uneven surface 12 on the other surface, or one surface as shown in FIG. This has a light diffusing surface 11 and a smooth surface 14 on the other surface.
  • the prism sheet 3 used here has a force having a prism surface 16 on one surface and a smooth surface 15 on the other surface as shown in FIG. 1, or As shown in FIG. 2, one surface has a prism surface 16 and the other surface has an uneven surface 13.
  • the uneven surfaces 12 and 13 of the light diffusing film 2 and the prism sheet 3 are formed on the transparent polymer films 21 and 31 serving as the base material. , 32 can be formed.
  • the surfaces of the transparent polymer films 21 and 31 may be directly processed into the uneven shape to form the uneven surfaces 12 and 13.
  • the smooth surfaces 14, 15 of the light diffusing film 2 and the prism sheet 3 are formed by disposing smooth layers 23, 33 on the transparent polymer films 21, 31 on the surfaces.
  • the smooth layers 23 and 33 are made of a material containing a comb polymer.
  • the light-diffusing surface 11 of the light-diffusing film 2 may be formed by directly covering the surface of a transparent polymer film 21 as long as the light-diffusing function can be obtained.
  • the light diffusion layer 24 may be arranged on the surface of the transparent polymer film 21 as shown in FIG. 1 and FIG.
  • the prism surface 16 of the prism sheet 3 directly calories the surface of the transparent polymer sheet 31 as long as it has a structure for raising incident light in the normal direction of the prism sheet 3.
  • the structure may be such that a prism layer 34 having a prism shape is arranged on the surface of the transparent polymer film 31 as shown in FIGS.
  • the transparent polymer films 21 and 31 impair the transparency of polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polycarbonate, polyethylene, polypropylene, polystyrene, triacetyl cellulose, acryl, polyvinyl chloride, and the like.
  • a polyethylene terephthalate film that has been stretched, particularly biaxially stretched, is preferred because of its excellent mechanical strength and dimensional stability.
  • those having improved adhesion to the uneven layer 22, the smooth layers 23, 33, the light diffusion layer 24, the prism layer 34, etc. by applying a corona discharge treatment to the surface or providing an easy adhesion layer are also preferably used. It is possible.
  • the thickness of the transparent polymer films 21 and 31 is appropriately selected depending on the material to be applied, but the thickness is generally 25 to 500 ⁇ m, preferably 25 to 200 ⁇ m. In particular, in order to cope with thinning as a surface light source, 25 to 50 m is suitable.
  • the uneven surfaces 12, 13 provided on one of the light diffusing film 2 and the prism sheet 3 are formed of a transparent polymer film 21, which can be directly covered with the transparent polymer films 21, 31. Layers 22 and 32 may be formed on the surface of 31 to make the surface uneven.
  • the concave and convex surface shape is not originally limited as long as the object of the present invention can be achieved, but in particular, the arithmetic average roughness is 0.5 m or less.
  • the average interval between the irregularities is 80 m or less.
  • the arithmetic average roughness and the average interval between the irregularities mean the arithmetic average roughness and the average interval between the irregularities according to JIS-B0601: 1994, and are values measured by a surface roughness measuring instrument. By setting the arithmetic average roughness of the uneven surfaces 12 and 13 to 0.5 m or less, when the light control sheet 1 of the present invention is used as a surface light source, sufficient front luminance and viewing angle as a surface light source are impaired. It can be difficult.
  • the average interval between the irregularities is 80 m or less, it is easy to suppress the occurrence of a rainbow-like ring-shaped pattern when the light control sheet 1 of the present invention is used as a surface light source. Furthermore, from the viewpoint of facilitating the average interval between the irregularities to be 80 m or less, it is preferable to set the arithmetic average roughness to 0.15 m or more.From the viewpoint of facilitating the arithmetic average roughness to 0.5 m or less. In addition, it is preferable that the average interval between the irregularities is 60 m or more.
  • the method of forming the irregularities on the irregular surfaces 12 and 13 is not particularly limited as long as the irregularities can be formed.
  • the irregular surfaces are directly formed on the surfaces of the transparent polymer films 21 and 31.
  • the specific shape is transferred to the surface by contacting it with a shaped film etc. having a specific surface shape. It is possible to form.
  • the concavo-convex layers 22 and 32 apply resin to the transparent polymer films 21 and 31, and transfer the shape of the resin in an uncured or semi-cured state using a molding film or the like. Is possible.
  • the uneven layers 22 and 32 are formed of a material containing a binder resin and particles.
  • the surface shape of the concavo-convex layers 22 and 32 containing the binder resin and the particles depends on factors such as the thickness of the layer, the mixing ratio of the binder resin and the particles, the particle diameter, and the number of particles per unit area. Can be adjusted.
  • the uneven shape is adjusted in consideration of the optical characteristics of the light control sheet.
  • the binder resin constituting the concavo-convex layers 22 and 32 includes polyester resin and acrylic resin. Resin, polyester acrylate resin, polyurethane acrylate resin, epoxy phthalate resin, cellulose resin, acetal resin, bur resin, polyethylene resin, polystyrene resin, Thermoplastic resins such as polypropylene resin, polyamide resin, polyimide resin, melamine resin, phenol resin, silicone resin and fluorine resin, thermosetting resin, ionizing radiation curing A resin having optical transparency, such as a hydrophilic resin, can be used.
  • preferred resins include acrylic resins having high transparency while having weather resistance, and particularly preferably acrylic polyurethanes of a two-component curing type, which are tough even when filled with a large amount of resin particles. It is desirable to use an OH number that increases the crosslink density so that a coating film can be obtained.
  • the particles contained in the uneven layers 22, 32 include extenders such as calcium carbonate, magnesium carbonate, barium sulfate, silica, aluminum hydroxide, kaolin, clay, and talc, acrylic resin particles, Synthetic resin particles such as polystyrene resin particles, polyurethane resin particles, polyethylene resin particles, benzoguanamine resin particles, epoxy resin particles, and particle-based waxes such as hydrocarbon wax, fatty acid wax, and fatty acid amide wax. Can be used.
  • the average particle diameter of such particles can be 1 ⁇ m or more and 10 ⁇ m or less.
  • the mixture power of particles having an average particle diameter of 1 ⁇ m or more and less than 5 ⁇ m, preferably 4 ⁇ m or less, and particles having an average particle diameter of 5 ⁇ m or more, preferably 6 ⁇ m or more and 10 ⁇ m or less is also high.
  • the mixing ratio of the particles to 100 parts by weight of the binder resin is a total of 1 part by weight or more, preferably 2 parts by weight or more and 10 parts by weight or less, preferably 8 parts by weight or less.
  • the amount is preferably 0.5 parts by weight or more, preferably 1 part by weight or more and 9.5 parts by weight or less, and more preferably 7 parts by weight or less.
  • the smooth surfaces 14, 15 of the light diffusing film 2 or the prism sheet 3 include at least a comb-shaped polymer containing at least a comb-shaped polymer so as not to be damaged even when they come into contact with the opposing uneven surfaces 13, 12.
  • Smooth layers 23 and 33 are provided.
  • the comb polymer is a polymer having a trunk portion and a branch portion. Since the comb-shaped polymer is easily entangled with each other and other polymer molecules due to the presence of the branch portion, the strength of the formed layer is higher than that of a normal polymer. Therefore, by forming the smooth layers 23 and 33 with a material containing the comb polymer, The scratch resistance of the layers 23 and 33 can be improved.
  • a monomer for polymerizing the polymer constituting each of the trunk portion and the branch portion various types of monomers can be used.
  • the types of the monomer are different between the trunk portion and the branch portion. This is preferable because the branch portion causes micro-layer separation with respect to the trunk portion, and the branch portion has a shape spread to the trunk portion and is easily entangled soon.
  • the trunk portion is made of acrylic and the branch portion is made of non-acrylic.
  • the comb polymer does not necessarily require the trunk and branch to be of different types, the effect of being easily entangled is obtained compared to a polymer that does not have such a shape, and the scratch resistance is improved. I do.
  • the trunk portion is excellent in coatability.
  • the branches are preferably those having good adhesion to the transparent polymer films 21 and 31 and those having good compatibility with other resins blended with the comb polymer, but the trunk is preferably made of a transparent polymer. If the adhesiveness with the films 21 and 31 and the compatibility with the resin to be blended are excellent, the branch portions do not necessarily have to have such properties.
  • the comb polymer is preferably a copolymer obtained by copolymerizing a monomer serving as a trunk portion and a macromonomer serving as a branch portion.
  • the comb polymer obtained by such a macromonomer method is suitable because it can be produced in a one-step reaction, and the target molecule can be easily obtained.
  • the main component of the trunk monomer is an acrylic monomer, and the polymer has a monoethylene unsaturated group as a polymerizable functional group at the terminal of the macromonomer which serves as a branch.
  • the skeleton component is formed by polymerizing a non-acrylic monomer as a main component.
  • the main component is preferably at least 50% by weight, preferably at least 60% by weight as a monomer component to be polymerized.
  • the acrylic monomer includes methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, amyl acrylate, 2-ethylhexyl acrylate, octyl acrylate, cyclohexyl acrylate, Acrylic ester monomers such as benzyl acrylate; methacrylic ester monomers such as butyl methacrylate, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, and benzyl methacrylate; and acrylic acid and methacrylic acid Carboxyl group-containing acrylic monomer, 2-hydroxyethyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 4-hydroxybutyrate (meth) acrylate Hydroxy-containing acrylic monomers such as tyl and N-methylol acrylamide, tertiary amino group-containing acrylic monomers such as dimethylaminoethyl
  • Non-acrylic monomers such as butyl acetate, butyl propionate, butyl ether, and styrene can be polymerized together with the acrylic monomer as auxiliary components.
  • the macromonomer which is a component of the branch portion has a monoethylenically unsaturated group as a polymerizable functional group at the terminal, and has a skeleton component obtained by polymerizing a non-acrylic monomer as a main component. It can be suitably used.
  • the polymerizable functional group is graft-polymerized to the trunk portion when the monomer in the trunk portion is polymerized. Can be synthesized.
  • non-acrylic monomer which is the main component of the skeleton component of the macromonomer
  • examples of the non-acrylic monomer which is the main component of the skeleton component of the macromonomer include the above-mentioned butyl propionate, butyl ether, and styrene.
  • a styrene monomer as the non-acrylic monomer, the refractive index difference between the transparent polymer films 21 and 31 and the smooth layers 23 and 33 when a polyethylene terephthalate film is used as the transparent polymer films 21 and 31. Can be reduced, and the total light transmittance can be improved.
  • the proportion of the macromonomer of the branch component to be copolymerized with the monomer of the trunk component is 1 part by weight or more, preferably 2 parts by weight or more, and 30 parts by weight or less based on 100 parts by weight of the monomer of the trunk component. , Preferably 15 parts by weight or less.
  • the smoothing layers 23 and 33 preferably contain 40% by weight or more, preferably 50% by weight or more of the comb polymer in the components of the smoothing layers 23 and 33.
  • the uneven layers 22 and 32 are formed by blending with such a comb polymer. It is also possible to include the resins exemplified as Noinder resins.
  • the shape of the light diffusing surface 11 of the light diffusing film 2 is not particularly limited as long as the surface of the light diffusing film 2 has a light diffusing function! /.
  • the film when the light diffusing surface 11 is formed directly on the surface of the transparent polymer film 21, the film may be in an uncured or semi-cured state during the manufacturing process of the transparent polymer film 21, and may have a specific surface shape.
  • the light diffusing surface 11 can be formed by transferring a shape that irregularly refracts light onto the surface by contacting with a shaping film or the like having the following.
  • a resin is applied to the transparent polymer film 21 so that the applied layer has a specific surface shape in an uncured or semi-cured state.
  • the light diffusing layer 24 having the light diffusing surface 11 can be formed by transferring a shape that irregularly refracts light onto the surface by making contact with a shaped film or the like. Further, from the viewpoint of ease of manufacturing because the surface shape can be easily adjusted, it is preferable that the light diffusion layer 24 is also formed of a material containing a noinder resin and light diffusion particles. Here, the optical characteristics of the light diffusion layer 24 can be adjusted by factors such as the thickness of the layer, the mixing ratio of the binder resin and the light diffusion particles, the particle diameter, the number of particles per unit area, and the like.
  • the binder resin and the light diffusing particles forming the light diffusing layer 24 the same binder resin and particles as those exemplified as the binder resin forming the concave and convex layers 22 and 32 may be used. Can be.
  • the light diffusing particles forming the light diffusing layer 24 are not less than 30 parts by weight, preferably not less than 40 parts by weight, and not more than 80 parts by weight, and preferably not more than 70 parts by weight, based on 100 parts by weight of the binder resin. Is desirably mixed at a ratio of When the light control sheet 1 is used as a surface light source, a good viewing angle can be easily obtained when the light control sheet 1 is used as a surface light source, and when the light control sheet is used as a surface light source, when the light control sheet 1 is used below 80 parts by weight. It becomes easy to obtain good front luminance.
  • the thickness of the light diffusion layer is preferably 1 ⁇ m or more, preferably 5 ⁇ m or more, and is 18 ⁇ m or less, preferably 15 ⁇ m or less.
  • additives such as a dispersant, an antistatic agent, and a leveling agent may be added to the uneven layers 22, 32, the smooth layers 23, 33, and the light diffusion layer 24 according to the present invention.
  • Light control sheet function It can be appropriately contained within the range not to be described.
  • the uneven layers 22, 32, the smooth layers 23, 33, and the light diffusion layer 24 are prepared as a coating liquid by appropriately mixing particles, additives, and a diluting solvent with a binder resin or the like as necessary. It can be formed by applying the coating solution to the surfaces of the polymer films 21 and 31 by a conventionally known coating method.
  • the shape of the prism surface 16 is such that when the prism surface 16 of the light control sheet 1 of the present invention is disposed so as to face the light exit surface of the light guide plate, the exit light having the light exit surface of the light guide plate enters, There is no particular limitation as long as it has a function of causing the light to rise in a substantially normal direction of the light guide plate, but a cross-sectional shape having a substantially V-shaped continuous shape is preferable.
  • an ultraviolet curable resin solution is filled in a rotary roll intaglio having a concave portion having an inverse shape to the prism shape, and then a base sheet is formed thereon.
  • the transparent polymer film 31 is supplied and pressed onto the roll intaglio from above the resin solution on the plate surface, and while the resin is pressed, the resin solution is cured by irradiating with ultraviolet light, and then the solidified ultraviolet-cured resin is transparentized. It can be formed by a method in which a rotating roll intaglio force is peeled off together with the molecular film 31.
  • the light control sheet 1 of the present invention in which the light diffusing film 2 and the prism sheet 3 as described above are laminated with the uneven surfaces 12, 13 and the smooth surfaces 14, 15 facing each other is used as a surface light source.
  • a surface light source In order to eliminate the problem of rainbow-like ring-shaped patterns without impairing the frontal brightness and viewing angle when adopted as a component member, and also to solve the problem of damage between component members.
  • the surface light source is combined with a liquid crystal display panel or the like, the display quality in a liquid crystal display device or the like caused by such damage does not occur.
  • the surface light source 6 of the present invention has at least a light guide plate 4 having a light source 5 disposed at an end thereof and a light control sheet 1 of the present invention disposed on a light emitting surface of the light guide plate 4.
  • the prism surface 16 of the prism sheet 3 in the light control sheet 1 is arranged so as to face the light exit surface of the light guide plate 4 (FIGS. 3 and 4).
  • the light source 5 disposed at the end of the light guide plate 4 for example, a lamp such as a cold cathode tube can be used.
  • the light guide plate 4 at least one side surface is used as a light incident surface.
  • the light guide plate 4 may have a prism shape on the surface on the light emitting surface side or the surface on the opposite side, or may be formed by mixing light diffusing particles in the light guide plate 4. You may.
  • the surface light source 6 of the present invention includes a light reflecting member ⁇ called a lamp reflector 7 that covers the light source 5, and a light reflecting sheet 8 called a light reflecting sheet 8 on a surface opposite to the light emitting surface of the light guide plate 4. It is preferable to dispose members.
  • a surface light source 6 of the present invention can form a liquid crystal display device 10 or the like by being laminated with a liquid crystal display panel 9 (FIG. 5).
  • the surface light source of the present invention as described above is configured using the light control sheet of the present invention, thereby eliminating the occurrence of a rainbow-like ring-shaped pattern without impairing the front luminance and the viewing angle.
  • the problem of damage caused by the constituent members can be solved, it is possible to prevent a decrease in display quality caused by such damage when combined with a liquid crystal display panel or the like.
  • a reaction vessel equipped with a stirrer, condenser, thermometer and nitrogen inlet tube, 60 g of ethyl acetate, 60 g of toluene, 60 g of methyl ethyl ketone, 95 g of methyl methacrylate monomer, and a monoethylenically unsaturated group as a polymerizable functional group at the end.
  • 5 g of styrene macromonomer AS-6: Toa Gosei Co., Ltd.
  • Another vessel benzo I peroxide 50 weight 0/0 flakes (Nyper FF: NOF Corporation) dissolved the 0.
  • a transparent polymer film 21 As a transparent polymer film 21, a transparent polyethylene terephthalate film (Cosmoshine A4300: Toyobo Co., Ltd.) having a thickness of 50 ⁇ m was prepared, and one surface was coated with a coating solution a for an uneven layer having the following composition.
  • An uneven layer 22 having a thickness of about 4 m is formed by heating, drying and curing, and then a coating liquid b for a light diffusion layer having the following composition is applied to the surface opposite to the uneven layer 22, and dried by heating.
  • a light diffusion layer 24 having a thickness of about 12 m was formed, and a light diffusion film 2 having the structure shown in FIG. 1 as a constituent member of the light control sheet 1 shown in FIG. 1 of the present invention was produced.
  • a coating solution c for a smoothing layer having the following composition was applied to a surface of a commercially available downward-facing prism sheet (Diaart S168: Mitsubishi Rayon Co., Ltd.) opposite to the prism surface to obtain a smooth layer having a thickness of about 3 ⁇ m.
  • a coating solution c for a smoothing layer having the following composition was applied to a surface of a commercially available downward-facing prism sheet (Diaart S168: Mitsubishi Rayon Co., Ltd.) opposite to the prism surface to obtain a smooth layer having a thickness of about 3 ⁇ m.
  • the downward prism sheet 3 in FIG. 1 which is a constituent member of the light control sheet 1 in FIG. 1 of the present invention was produced.
  • the light diffusing film 2 and the downward prism sheet 3 are combined with the surface 12 having the uneven layer 22 of the light diffusing film 2 and the surface 15 having the smooth layer 33 of the downward prism sheet 3. Were laminated so as to face each other to produce the light control sheet 1 of FIG. 1 of the present invention.
  • Example 1 in producing the light diffusing film 2, the smooth polymer layer (the polyethylene terephthalate film) 21 was replaced with the uneven layer coating solution “a” and the smooth layer coating solution “c” was used. 23, and use the uneven layer coating solution a instead of the smooth layer coating solution c to be applied to the surface opposite to the prism surface 16 of the prism sheet.
  • the layer 32 is formed. Except for this, in the same manner as in Example 1, a light diffusing film 2 and a downward prism sheet 3, which are components of the light control sheet 1 of FIG. 2 of the present invention, were produced.
  • the light-diffusing film 2 and the downward prism sheet 3 face each other, and the surface 14 of the light-diffusing film 2 having the smooth layer and the surface 13 of the downward prism sheet 3 having the uneven layer 32 face each other.
  • the light control sheet 1 having the structure shown in FIG. 2 was produced.
  • Example 1 a smooth layer 33 was formed using a smooth layer coating solution d having the following composition, which did not include a comb-shaped polymer instead of the smooth layer coating solution c applied to the surface opposite to the prism surface of the prism sheet.
  • a light diffusing film and a downward-facing prism sheet of Comparative Example 1 were produced in the same manner as in Example 1 except for the above.
  • the light-diffusing film of Comparative Example 1 and the downward prism sheet are set so that the surface of the light-diffusing film having the uneven layer and the surface of the downward prism sheet having the smooth layer 23 face each other. Then, the light control sheet of Comparative Example 1 having the same structure as that of FIG. 1 was produced.
  • Comparative Example 2 was made in the same manner as in Example 2 except that the smooth layer 23 was not formed on one surface of the transparent polymer film (polyethylene terephthalate film) 21 in the production of the light diffusing film 2.
  • a light diffusing film and a downward prism sheet were prepared.
  • the light-diffusing film of Comparative Example 2 and the downward prism sheet are combined with the surface of the light-diffusing film opposite to the surface having the light diffusion layer 24 and the concave / convex layer 32 of the downward prism sheet.
  • the light control sheet of Comparative Example 2 was produced by laminating the surfaces so as to face each other.
  • Example 3 In Example 1, in the same manner as in Example 1 except that the uneven layer 22 was not formed and the smooth layer 33 of the prism sheet 3 was not formed in producing the light diffusing film 2, A light diffusing film and a downward prism sheet were produced.
  • the light-diffusing film of Comparative Example 3 and the downward prism sheet are combined with a surface opposite to the diffusion surface 11 of the light diffusion film and a surface opposite to the prism surface 16 of the downward prism sheet. Were laminated so as to face each other to produce a light control sheet of Comparative Example 3.
  • Example 2 a smooth layer 23 was formed by using a smooth layer coating solution e having the following composition instead of the smooth layer coating solution c applied to the surface of the light diffusion film 2 opposite to the light diffusion layer 24.
  • a light diffusing film and a downward prism sheet of Comparative Example 4 were produced in the same manner as in Example 2 except for performing the above.
  • the light-diffusing film of Comparative Example 4 and the downward prism sheet are set so that the surface of the light-diffusing film having the smooth layer 23 and the surface of the downward prism sheet having the uneven layer 32 face each other.
  • the light control sheet of Comparative Example 4 was produced.
  • the light control sheet 1 obtained in Example 1 was disposed on the light exit surface of the light guide plate 4 with the prism surface 16 of the prism sheet 3 and the light exit surface of the light guide plate 4 facing each other.
  • a light reflecting member (not shown in FIG. 3) was disposed on the surface of the light guide plate 4 opposite to the light exit surface, to produce a surface light source having the structure of FIG. 3 of the present embodiment.
  • the prism sheet 3 constituting the light control sheet 1 The one subjected to the following rubbing test for rubbing the uneven surface of the light diffusing film 2 with the smooth surface of the prism sheet was used.
  • a 8.4-inch diagonal prism sheet 3 is fixed to the moving table of the surface property measuring instrument (HEIDON-14: Shinto Kagaku) so that the prism surface faces the moving table, and the smooth surface 15 of the prism sheet 3 is fixed. and a light diffusion film 2 so that the contact area between the uneven surface 12 of the light-diffusing film 2 is approximately 40 cm 2 attached to surface contact jig, the moving table by putting a weight of lkg on the surface contact jig By moving at a speed of lmZmin, the uneven surface 12 of the light diffusing film 2 and the smooth surface 15 of the prism sheet 3 were rubbed.
  • HEIDON-14 Shinto Kagaku
  • one end face of the light guide plate 4 with a diagonal of 8.4 inches (1 inch 25.4 mm) is used as the light incident surface, and the cold cathode tube (light source) covered by the lamp reflector 7 is used. 5) was arranged.
  • the light control sheet 1 obtained in Example 2 was disposed on the light exit surface of the light guide plate 4 with the prism surface 16 of the prism sheet 3 and the light exit surface of the light guide plate 4 facing each other.
  • a light-reflecting member (light-reflecting sheet) 8 was arranged on the surface of the light guide plate 4 opposite to the light-emitting surface to produce a surface light source having the structure shown in FIGS. 4 and 5 according to the embodiment of the present invention. .
  • the one subjected to a rubbing test in which the uneven surface 13 of the prism sheet 3 and the smooth surface 14 of the light diffusing film 2 were rubbed was used as the light diffusing film 2 constituting the light control sheet 1.
  • the rubbing test was performed in the same manner as the rubbing test used in Example 3, except that the place where the prism sheet 3 and the light diffusing film 2 were attached was changed. Otherwise, in the same manner as in Example 3, the uneven surface 13 of the prism sheet 3 and the smooth surface 14 of the light diffusing film 2 were rubbed.
  • one end face of the light guide plate 4 with a diagonal of 8.4 inches (1 inch 25.4mm) is used as a light incident surface, and a cold cathode tube (light source 5) covered with a lamp reflector is used. ) was placed.
  • the light control sheets obtained in Comparative Examples 1 to 4 were arranged on the light exit surface of the light guide plate 4 with the prism surface of the prism sheet and the light exit surface of the light guide plate 4 facing each other.
  • a light reflecting member was disposed on the surface of the light guide plate 4 opposite to the light exit surface, and surface light sources of Comparative Examples 5 to 8 were produced.
  • the prism sheets constituting the light control sheets of Comparative Examples 1 and 3 were the same as in Example 3.
  • a light-diffusing film constituting the light control sheet of Comparative Examples 2 and 4 was subjected to a rubbing test in the same manner as in Example 4 and used.
  • the cold-cathode tubes (light source 5) of the surface light sources obtained in Examples 3 and 4 and Comparative Examples 5 to 8 were turned on as described above to obtain a front luminance, a viewing angle, and a rainbow-like ring-shaped pattern. The occurrence was visually evaluated, and a liquid crystal display panel was arranged on the surface light source to visually evaluate whether or not the display quality of the liquid crystal display device deteriorated due to the problem of scratches between the components of the light control sheet. . Table 1 shows the results.
  • the surface light source (Comparative Example 7) configured using the light control sheet obtained in Comparative Example 3, the front luminance and the viewing angle were not impaired, and the light control sheet was damaged A rainbow-like ring-shaped pattern was generated because the opposing surfaces of the light diffusing film of the light control sheet and the prism sheet were both smooth surfaces. For this reason, the display quality of the liquid crystal display device caused by the damage was not reduced, but the display quality was reduced by the rainbow-like ring-shaped pattern.
  • FIG. 1 is a cross-sectional view showing one embodiment of the light control sheet of the present invention.
  • FIG. 2 is a cross-sectional view showing another embodiment of the light control sheet of the present invention.
  • FIG. 3 is a cross-sectional view showing one embodiment of the surface light source of the present invention.
  • FIG. 4 is a cross-sectional view showing another embodiment of the surface light source of the present invention.
  • FIG. 5 is a cross-sectional view showing one embodiment of a liquid crystal display device combined with a surface light source according to the present invention.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Liquid Crystal (AREA)
  • Planar Illumination Modules (AREA)
  • Laminated Bodies (AREA)
PCT/JP2005/006458 2004-04-09 2005-04-01 光制御シート及びそれを用いた面光源 Ceased WO2005098485A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2006512056A JP4695071B2 (ja) 2004-04-09 2005-04-01 光制御シート及びそれを用いた面光源
EP05727520A EP1734384A4 (en) 2004-04-09 2005-04-01 LIGHT CONTROL SHEET AND LIGHT SURFACE SOURCE USING THE SAME
US10/594,723 US7535642B2 (en) 2004-04-09 2005-04-01 Light control sheet and surface light source using the same
KR1020067023075A KR101072036B1 (ko) 2004-04-09 2006-11-03 광제어 시트 및 그것을 사용한 면광원

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2004115443 2004-04-09
JP2004-115443 2004-04-09

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US (1) US7535642B2 (https=)
EP (1) EP1734384A4 (https=)
JP (1) JP4695071B2 (https=)
KR (1) KR101072036B1 (https=)
CN (1) CN100472242C (https=)
TW (1) TW200609618A (https=)
WO (1) WO2005098485A1 (https=)

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JP2017097150A (ja) * 2015-11-24 2017-06-01 スタンレー電気株式会社 下向きプリズム光学シート及びこれを用いたサイドエッジ型面発光装置、並びに製造方法

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US20100265739A1 (en) * 2008-01-24 2010-10-21 Yohei Funabashi Light-diffusing sheet and backlight device using same
JP2009223198A (ja) * 2008-03-18 2009-10-01 Sumitomo Chemical Co Ltd 輝度向上フィルム積層光拡散板及びその製造方法
KR101084186B1 (ko) * 2010-01-14 2011-11-17 삼성모바일디스플레이주식회사 백라이트 유니트 및 이를 채용한 디스플레이 모듈
US8469573B2 (en) * 2010-02-12 2013-06-25 Chi Lin Optoelectronics Co., Ltd. Light guide plate and back light module having the same
KR101090495B1 (ko) 2010-12-09 2011-12-06 도레이첨단소재 주식회사 발광다이오드용 광확산 필름
JP5635451B2 (ja) * 2011-05-25 2014-12-03 富士フイルム株式会社 導光板、面状照明装置および導光板の製造方法
US10126485B2 (en) 2014-05-21 2018-11-13 Samsung Electronics Co., Ltd. Optical film and lighting and display products including same
KR20200103816A (ko) * 2018-01-08 2020-09-02 쓰리엠 이노베이티브 프로퍼티즈 컴파니 광학 필름 조립체

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WO2009041278A1 (ja) * 2007-09-26 2009-04-02 Kimoto Co., Ltd. 光拡散フィルムおよびそれを用いた光源装置
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EP1734384A1 (en) 2006-12-20
KR101072036B1 (ko) 2011-10-10
EP1734384A4 (en) 2010-10-20
JP4695071B2 (ja) 2011-06-08
JPWO2005098485A1 (ja) 2008-02-28
TW200609618A (en) 2006-03-16
TWI366718B (https=) 2012-06-21
US7535642B2 (en) 2009-05-19
KR20070015419A (ko) 2007-02-02
US20070273975A1 (en) 2007-11-29
CN1947038A (zh) 2007-04-11
CN100472242C (zh) 2009-03-25

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