WO2005097055A2 - O/w-gel-zusammensetzungen mit estern des pentaerythrits oder dessen oligomeren - Google Patents
O/w-gel-zusammensetzungen mit estern des pentaerythrits oder dessen oligomeren Download PDFInfo
- Publication number
- WO2005097055A2 WO2005097055A2 PCT/EP2005/003232 EP2005003232W WO2005097055A2 WO 2005097055 A2 WO2005097055 A2 WO 2005097055A2 EP 2005003232 W EP2005003232 W EP 2005003232W WO 2005097055 A2 WO2005097055 A2 WO 2005097055A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- esters
- gel
- composition according
- gel composition
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/003—Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/266—Esters or carbonates
Definitions
- the invention relates to specific O / W gel formulations, their use as skin care products and a process for their preparation.
- Gel formulations based on polyacrylate have long been known to the person skilled in the art. Many of these gel formulations relate to surfactants that are used for body cleansing. For example, WO 96/17591 and WO 96/17592 describe surfactant-containing formulations for skin cleansing which are stabilized by polymeric gel formers. 0 pale gels give a sensorially very light and pleasantly cooling impression, they are usually not used for the formulation of skin care products because they have insufficient care effects. In particular, gel formulations based on polyacrylate do not show any lasting care effects. Gel formulations are also sensitive to salt, so they often break when applied to the skin due to the presence of salts.
- the object of the present invention was to provide gel formulations which have a pleasant, light-weight profile and good care effects and do not break when applied to the skin. Another aspect of the task was to provide formulations that were as free from irritation as possible.
- the invention therefore relates to an O / W gel composition (a) 0.05-5% by weight of at least one polymeric gelling agent selected from the group of homopolymers or copolymers of acrylic acid and / or acrylamide and their derivatives, (b) 0.1-10% by weight of at least one wax component a melting point of at least 30 ° C. selected from the group consisting of the pentaerythritol esters, the dipentaerythritol esters and / or the tripentaerythritol esters (c) 1-30% by weight of at least one oil component which is liquid at 25 ° C and (d) 60-95% by weight Water.
- a polymeric gelling agent selected from the group of homopolymers or copolymers of acrylic acid and / or acrylamide and their derivatives
- at least one wax component a melting point of at least 30 ° C. selected from the group consisting of the pentaerythritol esters, the dipentaerythritol
- compositions of this type are considerably more stable than the salt content on the skin and leave a smooth and soft feeling with very good care properties. They are easy to distribute, absorb well on the skin, leave a relatively low oily or greasy, but rather velvety feeling on the skin.
- compositions according to the invention contain no additional anionic and cationic surfactants / emulsifiers. As a result, the compositions have a low potential for irritation.
- the O / W gel compositions according to the invention preferably have a viscosity of 50,000 to 500,000 mPa.s at 20 ° C., measured with a Brookfield RVF viscometer, spindle TE with Helipath at 4 revolutions per minute.
- the gelling agents are selected from the group of homopolymers or copolymers of acrylic acid and / or acrylamide and their derivatives or from any mixture of these substances.
- the commercially available polymers often also contain a nonionic surfactant / emulsifier.
- the gel formers which can be used according to the invention include commercially available substances, such as, for example, Sepigel® 305, INCI: polyacrylamide (and) C13-14 isoparaffin (and) Laureth-7; Sepigel® 501, INCI: acrylamide copolymer (and) mineral oil (and) C13-14 isoparaffin (and) polysorbate 85; Sepigel® 502, INCI: C13-14 isoparaffin (and) isostearyl isostearate (and) sodium polyacrylate (and) polyacrylamide (and) polysorbate 60; Simulgel® 600, INCI: acrylamide / sodium acryloyldimethyl taurate copolymer (and) isohexadecane (and) polysorbate 80; Simulgel® 800, INCI: sodium polyacryloyldimethyl taurate (and) isohexadecane (and) sorbitan oleate; Simulgel® EG, INCI: sodium Acrylate / acrylo
- the polymers can be cross-linked or uncross-linked. Crosslinked polymers are preferably used. Polyacrylates and polyacrylamides are preferred according to the invention. Polyacrylates, especially their sodium salts, are particularly preferred. A polymer which is particularly preferred according to the invention is commercially available under the names Cosmedia® SP and Cosmedia® SPL. According to the invention, the polymers are used in amounts of 0.05-5% by weight, based on the overall composition. Quantities of 0.1-4% by weight, in particular 0.5-3% by weight and very particularly preferably 0.5-2% by weight, based on the overall composition, are preferred.
- wax is usually understood to mean all natural or artificially obtained substances and mixtures of substances with the following properties: they have a solid to fragile hard consistency, coarse to fine crystalline, translucent to cloudy and melt above 30 ° C without decomposition. They are low viscosity and not stringy a little above the melting point and show a strongly temperature-dependent consistency and solubility.
- a wax component or a mixture of wax components which can be used at 30 ° C. or above can be used according to the invention melt and are selected from the group of esters of pentaerythritol, dipentaerythritol or tripentaerythritol. They are contained in the compositions according to the invention in a total amount of 0.1-10% by weight.
- the content of the wax component is 0.2-5% by weight, based on the overall composition. Amounts of 0.5-4% by weight and in particular 0.5-2% by weight, based on the total composition, are particularly preferred. A content of 0.5 to 1.5% by weight of the wax component (s), based on the overall composition, is very particularly preferred, since the overall sensory profile is optimal in this area.
- a further preferred embodiment of the O / W gel composition is characterized in that the wax component or the mixture of wax components (b) has a melting point between 40 ° C and 80 ° C, preferably between 40 and 60 ° C, because in this range give the best sensory effects.
- the wax component (b) is selected from the group of the esters of saturated or unsaturated and / or branched or unbranched C6-C24 fatty acids, preferably C14-C22 fatty acids of pentaerythritol, dipentaerythritol and / or tripentaerythritol, with less than 0.3% by weight of C17 fatty acid ester.
- the esters must have a melting point of at least 30 ° C. It can also be mixed esters, for example long-chain and short-chain fatty acids, as long as they have the required melting point.
- a further preferred embodiment of the O / W gel composition is characterized in that the wax component (b) is selected from the group of the esters which are obtained by reacting the pentaerythritol or dipentaerythritol with a fatty acid mixture containing 40-50% by weight of C16 fatty acid and 45-55% by weight of C18 fatty acid. Esters of linear, unbranched C16 / C18 fatty acids are particularly preferred.
- a further preferred embodiment of the O / W gel composition contains at least one wax component (b) selected from the group of the esters of pentaerythritol with a proportion of (a) 5-35% by weight monoester, (b) 20-50% by weight.
- esters which are obtained by reacting the pentaerythritol with a fatty acid mixture containing 40-50% by weight of C16 fatty acid and 45-55% by weight of C18 fatty acid and which have the following ester distribution are very particularly preferred: (a) 12-19 % By weight of monoesters, (b) 25-35% by weight of diester and (c) 30-40% by weight of triester, and 6-11% by weight of tetraester. oil body
- the O / W gels according to the invention contain 1-30% by weight, based on the total composition, of an oil component which is liquid at 25 ° C. or any mixture of these oil components.
- the oil component (s) are preferably present in a total amount of 3-20% by weight, in particular 5-15% by weight and particularly preferably 7-12% by weight.
- the oil classes listed below are suitable, for example, as long as they are liquid at 25 ° C.
- Guerbet alcohols based on fatty alcohols with 6 to 18, preferably 8 to 10 carbon atoms esters of linear or branched, saturated or unsaturated Ce-C 22 fatty acids with linear or branched, saturated or unsaturated C6-C22 fatty alcohols , especially 2-ethylhexanol.
- esters are, for example, esters of Ci8-C38-alkylhydroxycarboxylic acids with linear or branched, saturated or unsaturated C 6 -C 22 fatty alcohols, esters of linear and / or branched, saturated or unsaturated fatty acids with polyhydric alcohols (such as propylene glycol , Dimer diol or trimer triol) and / or Guerbet alcohols
- B. Cetiol® AB linear or branched, symmetrical or asymmetrical dialkyl ethers having 6 to 22 carbon atoms per alkyl group, such as.
- Dialkyl carbonates and esters of C8-C24 fatty acids and C8-C24 fatty alcohols or a mixture of these substances are preferred according to the invention as oil bodies.
- the dialkyl carbonates can be symmetrical or asymmetrical, branched or unbranched, saturated or unsaturated and can be prepared by transesterification reactions which are well known from the prior art.
- Dialkyl carbonates with alkyl chains which have 6 to 24 carbon atoms, in particular di-n-octyl carbonate or di (2-ethylhexyl) carbonate or a mixture of these substances, are particularly suitable according to the invention. Among these is the di-n-octyl carbonate. prefers.
- the hydrocarbons which can be used according to the invention have a chain length of preferably 8 to 40 carbon atoms. They can be branched or unbranched, saturated or unsaturated. Among them, branched, saturated C8-C40 alkanes are preferred. Both pure substances and mixtures of substances can be used. Usually it is a matter of mixtures of substances of different isomeric compounds.
- Compositions which have alkanes with 10 to 30, preferably 12 to 20, and particularly preferably 16 to 20 carbon atoms are particularly suitable, and among them a mixture of alkanes which contains at least 10% by weight of branched alkanes, based on the total amount of the alkanes contains. They are preferably branched, saturated alkanes. Mixtures of alkanes which contain more than 1% by weight of 5,8-diethyldodecane and / or more than 1% by weight of didecene are particularly suitable.
- a preferred embodiment of the O / W gel composition according to the invention contains (a) 0.05-5% by weight of at least one polyacrylate, (b) 0.1-10% by weight of at least one C16 / C18 ester of pentaerythritol and / or dipentaerythritol, (c) 1-30% by weight of at least one oil component and (d) 60-95% by weight of water.
- the polyacrylate (a) is preferably a sodium polyacrylate.
- the oil components are preferably selected from the fatty acid esters or dialkyl carbonates or any mixture of these substances.
- a further preferred embodiment is an O / W gel composition containing (a) 0.5-2% by weight of at least one sodium polyacrylate, (b) 0.5-2% by weight of at least one ester, which is passed through Reaction of the pentaerythritol and / or the dipentaerythritol with a fatty acid mixture containing 40-50% by weight of C16 fatty acid and 45-55% by weight of C18 fatty acid, (c) 7-12% by weight of at least one oil component selected from fatty acid esters, trigylcerides, dialkyl carbonates, hydrocarbons, dialkyl ethers or any mixture of these substances which are liquid at 25 ° C. and (d) 60-95% by weight of water.
- esters mentioned under (b) are preferably pentaerythritol esters with the following ester distribution: 12-19% by weight monoesters, 25-35% by weight diesters, 30-40% by weight triester and 6-11% by weight tetraesters.
- the application also relates to a process for the preparation of the O / W gel composition according to the invention, wherein either a) the gel former or a mixture of the gel formers (a) dispersed in the liquid oil phase containing the wax and oil components and then emulsifying them with the aqueous phase, or b) swelling the gel former or a mixture of the gel formers in the aqueous phase and mixing them with the liquid oil phase or c) a swelling of the gelling agent or a mixture of the gelling agents in a low molecular weight polyol or polyol mixture with a molecular weight of ⁇ 1000 daltons is processed with the aqueous phase and with the liquid oil phase.
- the invention also relates to the use of the O / W gel composition according to the invention for body care.
- Another object of the invention is the use of esters of pentaerythritol, dipentaerythritol and / or tripentaerythritol to improve the salt tolerance of gel compositions according to claim 1.
- the cosmetic formulations contain a number of other auxiliaries and additives such as, for example, emulsifiers / surfactants, further wax or lipid components, further thickeners, superfatting agents, stabilizers, polymers, lecithins, phospholipids, biogenic active ingredients, UV light protection factors, antioxidants, deodorants, Film formers, swelling agents, insect repellents, hydrotropes, solubilizers, preservatives, perfume oils, dyes etc., which are listed below as examples.
- the amounts of the respective additives depend on the intended use.
- Fats and fat-like substances with a wax-like consistency can be used as further waxes / lipid components. These include Fats (triglycerides), mono- and diglycerides, natural and synthetic waxes, fatty and wax alcohols, fatty acids, esters of fatty alcohols and fatty acids as well as fatty acid amides or any mixtures of these substances.
- Fats are triacylglycerols, i.e. the triple esters of fatty acids with glycerin. They preferably contain saturated, unbranched and unsubstituted fatty acid residues. This can also be mixed esters, i.e. triple esters of glycerol with various fatty acids. So-called hardened fats and oils, which are obtained by partial hydrogenation, can be used according to the invention and are particularly well suited as a consistency agent. Vegetable hardened fats and oils are preferred, e.g. B.
- hardened castor oil peanut oil, soybean oil, rapeseed oil, rape seed oil, cottonseed oil, Soybean oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, corn oil, olive oil, sesame oil, cocoa butter and coconut oil.
- triple esters of glycerol with Ci2-C6o fatty acids and especially C12-C36 fatty acids include hardened castor oil, a triple ester of glycerin and a hydroxystearic acid, which is commercially available, for example, under the name Cutina® HR.
- Glycerol tristearate, glycerol tribehenate (e.g. Syncrowax® HRC), glycerol tripalmitate or the triglyceride mixtures known under the name Syncrowax® HGLC are also suitable.
- glyceride mixtures which can be used according to the invention include the products Novata® AB and Novata® B (mixture of Ci2-Ci8 mono-, di- and triglycerides) marketed by Cognis GmbH & Co. KG as well as Cutina® MD or Cutina® GMS (glyceryl stearate) ).
- Mixed esters and mixtures of mono-, di- and triglycerides are preferably suitable according to the invention because they show a lower tendency to crystallize and thus improve the performance of the composition according to the invention.
- the fatty alcohols which can be used according to the invention include the Ci2-C5o fatty alcohols, in particular the Ci2-C24 fatty alcohols, which are obtained from natural fats, oils and waxes, such as, for example, myristyl alcohol, i-pentadecanol, cetyl alcohol, 1-heptadecanol, stearyl alcohol, 1- Nonadecanol, arachidyl alcohol, 1-heneicosanol, behenyl alcohol, brassidyl alcohol, lignoceryl alcohol, ceryl alcohol or myricyl alcohol. Saturated unbranched fatty alcohols are preferred according to the invention. Fatty alcohol cuts, such as those used in the reduction of naturally occurring fats and oils such as e.g.
- B beef tallow, peanut oil, rape oil, cottonseed oil, soybean oil, sunflower oil, palm kernel oil, linseed oil, castor oil, corn oil, rapeseed oil, sesame oil, cocoa butter and coconut oil.
- synthetic alcohols e.g. B. the linear, even-numbered fatty alcohols of Ziegler synthesis (Alfole®) or the partially branched alcohols from oxosynthesis (Dobanole®) can be used.
- C- ⁇ -cis fatty alcohols for example those from Cognis Deutschland GmbH under the name Lanette® 16 (Ci6 alcohol), Lanette® 14 (C14 alcohol), Lanette® 0 (C Ci ⁇ alcohol) and Lanette® 22 (C Ca alcohol) are marketed.
- Fatty alcohols give the compositions a drier skin feel than triglycerides and are therefore preferred over the latter.
- C 4 -C 40 fatty acids or mixtures thereof can also be used as additional wax components.
- B. beeswax, shellac wax, walrus, wool wax and pretzel fat In the sense of the invention it can be advantageous to use hydrogenated or hardened waxes.
- the natural waxes that can be used according to the invention also include the mineral waxes, such as, for. B.
- the ceresin and ozokerite or the petrochemical waxes such as. B. petrolatum, paraffin waxes and micro waxes.
- Chemically modified waxes, in particular the hard waxes, such as, for. B. Montanester waxes, Sasol waxes and hydrogenated jojoba waxes can be used.
- the synthetic waxes which can be used according to the invention include, for example, wax-like polyalkylene waxes and polyethylene glycol waxes. Vegetable waxes are preferred according to the invention. -
- the additional wax component can also be selected from the group of wax esters from saturated and / or unsaturated, branched and / or unbranched alkane carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols, from the group of esters from aromatic carboxylic acids, dicarboxylic acids, Tricarboxylic acids or hydroxycarboxylic acids (e.g.
- 12-hydroxystearic acid and saturated and / or unsaturated, branched and / or unbranched alcohols, from the group of polyols esterified with carboxylic acids (other than pentaerythritol, dipentaerythritol or tripentaerythritol), and also from the group the lactides of long-chain hydroxycarboxylic acids.
- esters are the C 4 Ci6-o-alkyl stearates, C2o-C4o-alkyl stearates (eg. B.
- Kesterwachs® K82H C2o-C4o-dialkyl esters of dimer acids, C18-C38- or C2o-C4o-Alkylhydroxystearoylstearate Alkylerucate.
- Anionic, nonionic, cationic and / or amphoteric or zwitterionic surfactants or emulsifiers or any mixture of these surfactants / emulsifiers can be present as surface-active substances.
- the content of surface-active substances depends on the type of formulation, but usually does not exceed 10% by weight.
- a preferred embodiment of the invention contains no anionic or cationic surfactants, but has a content of nonionic surfactants.
- the nonionic surfactants can include also be contained in the commercially available gel formers.
- the preferred content of nonionic surfactants is between 0-5% by weight, in particular 0.1-3% by weight, based on the total composition of the gel.
- anionic surfactants are soaps, alkylbenzene sulfonates, alkane sulfonates, olefin sulfonates, alkyl ether sulfonates, glycerol ether sulfonates, ⁇ -methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, fatty acid ethate sulfate monomers (hydroxymate ether sulfate) and dialkyl sulfosuccinates, mono- and dialkyl sulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts, fatty acid isethionates, fatty acid sarcosinates, fatty acid taurides, N-acyl
- anionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
- Typical examples of nonionic surfactants are fatty alcohol polyglycol ethers, polyglycerol esters, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide-polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, alk (en) yl oligoglycosides or glucoronic acid glucide acid amide derivatives (G) especially vegetable products based on wheat), polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides.
- nonionic surfactants contain polyglycol ether chains, they can have a conventional, but preferably a narrow, homolog distribution.
- cationic surfactants are quaternary ammonium compounds, such as, for example, dimethyldistearylammonium chloride, and esterquats, in particular quaternized fatty acid trialkanolamine ester salts.
- amphoteric or zwitterionic surfactants are alkyl betaines, alkyl amido betaines, aminopropionates, aminoglycinates, imidazolinium betaines and sulfobetaines. The surfactants mentioned are exclusively known compounds.
- Typical examples of particularly suitable mild, ie particularly skin-compatible, surfactants are fatty alcohol polyglycol ether sulfates, monoglyceride sulfates, mono- and / or dialkyl sulfosuccinates, fatty acid taurides, fatty acid glutamates, ⁇ -olefin sulfonates, ethercarboxylic acids, alkyl oligoglucosides, fatty acid glucamides, alkylamidobetaines, amphoacetals and / or protein fatty acid condensates, preferably based on wheat proteins.
- Suitable thickeners are, for example, Aerosil types (hydrophilic silicas), polysaccharides, in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl and hydroxypropyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone and bentonites such as.
- Aerosil types hydrophilic silicas
- polysaccharides in particular xanthan gum, guar guar, agar agar, alginates and tyloses, carboxymethyl cellulose and hydroxyethyl and hydroxypropyl cellulose, polyvinyl alcohol, polyvinyl pyrrolidone and bentonites such as.
- Bentone ® Gel VS-5PC Rheox
- UV light protection factors are to be understood, for example, liquid or crystalline organic substances (light protection filters) at room temperature which are able to absorb ultraviolet rays and absorb the energy in the form of longer-wave radiation, e.g. B. to release heat again.
- UV-B filters can be oil-soluble or water-soluble.
- Derivatives of benzoylmethane are particularly suitable as typical UV-A filters.
- the UV-A and UV-B filters can of course also be used in mixtures, for example combinations of the derivatives of benzoylmethane, e.g. B.
- insoluble light-protection pigments namely finely dispersed metal oxides
- suitable metal oxides are, in particular, zinc oxide and titanium dioxide.
- biogenic active substances include tocopherol, tocopherol acetate, tocopherol palmitate, ascorbic acid, (deoxy) ribonucleic acid and its fragmentation products, ß-glucans, retinol, bisabolol, allantoin, phytantriol, panthenol, AHA acids, amino acids, ceramides, pseudocleamides, plant extracts, extracts of essential oils such as B. Prunus extract, Bambaranus extract and vitamin complexes to understand.
- Deodorising agents counteract, mask or eliminate body odors.
- Body odors arise from the action of skin bacteria on apocrine sweat, whereby unpleasant smelling breakdown products are formed.
- suitable deodorising agents include germ inhibitors, enzyme inhibitors, odor absorbers or odor maskers.
- Suitable insect repellents are, for example, include N, N-diethyl-m-toluamide, 1,2-pentanediol or 3- (N-n-butyl-N-acetyl-amino) -propionic acid ethyl ester) which lent as Insect Repel- ® 3535 is marketed by Merck KGaA, as well as butylacetylaminopropionate.
- Dihydroxyacetone is suitable as a self-tanner.
- Arbutin, ferulic acid, kojic acid, coumaric acid and ascorbic acid (vitamin C) can be used as tyrosine inhibitors, which prevent the formation of melanin and are used in depigmenting agents.
- Hydrotropes such as, for example, ethanoi, isopropyl alcohol, or polyols can also be used to improve the flow behavior.
- Polyols that come into consideration here preferably have 2 to 15 carbon atoms and at least two hydroxyl groups.
- Suitable preservatives are, for example, phenoxyethanol, formaldehyde solution, parabens, pentanediol or sorbic acid as well as the silver complexes known under the name Surfacine® and the other classes of substances listed in Appendix 6, Parts A and B of the Cosmetics Ordinance.
- Perfume oils include mixtures of natural and synthetic fragrances. Natural fragrances are extracts of flowers, stems and leaves, fruits, fruit peels, roots, woods, herbs and grasses, needles and branches, resins and balms. Animal raw materials such as civet and castoreum and synthetic fragrance compounds of the ester, ether, aldehyde, ketone, alcohol and hydrocarbon type are also suitable. The dyes which can be used are those which are suitable and approved for cosmetic purposes.
- Examples are Kochillerot A (Cl 16255), Patent Blue V (C.1.42051), Indigotine (C.1.73015), Chlorophyllin (C.1.75810), Quinoline Yellow (CI47005), Titanium Dioxide (C.1.77891), Indanthrene Blue RS (Cl, 69800) and madder varnish (CI58000). These dyes are usually used in concentrations of 0.001 to 0.1% by weight, based on the mixture as a whole.
- the stated amounts relate to% by weight of the commercially available substance in the overall composition.
- the pentaerythrityl distearate is an ester mixture which, by reacting pentaerythritol with a fatty acid mixture containing 42-48% by weight of C16 fatty acid and 50-56% by weight of C18 fatty acid (remaining amounts: ⁇ C14 fatty acids and> C18 Fatty acids) is obtained and has the following ester distribution: 12-19% by weight monoester, (b) 25-35% by weight diester, (c) 30-40% by weight triester and (d) 6-11% by weight .-% Tetraester and less than 0.3 wt .-% C17 fatty acyl groups contains.
- 10 ⁇ l of the above Compositions were applied to the hairless side of the test subjects' forearms using a micropipette and rubbed with the fingers of the hands on the contralateral side.
- the sensors were assessed during and after absorption.
- the sensor test was carried out on 10 subjects, as described in the book "Cosmetic Lipids and the Skin Barrier” (Marcel Dekker Verlag New York, 2002, Ed. Thomas Förster, pp. 319-352).
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Dispersion Chemistry (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020067020585A KR101308835B1 (ko) | 2004-04-05 | 2005-03-26 | 펜타에리트리톨 에스테르 또는 그의 올리고머를 가진 o/w겔 조성물 |
JP2007506690A JP5627836B2 (ja) | 2004-04-05 | 2005-03-26 | ペンタエリスリトールエステルまたはそのオリゴマーを含むo/wゲル組成物 |
US11/547,599 US9149420B2 (en) | 2004-04-05 | 2005-03-26 | O/W-gel-compositions having pentaerythritol esters or oligomers thereof |
EP05716399A EP1742607B1 (de) | 2004-04-05 | 2005-03-26 | O/w-gel-zusammensetzungen mit estern des pentaerythrits oder dessen oligomeren |
CN2005800096338A CN1976673B (zh) | 2004-04-05 | 2005-03-26 | 含有季戊四醇酯或其低聚物的o/w-凝胶组合物 |
DE502005007621T DE502005007621D1 (de) | 2004-04-05 | 2005-03-26 | O/w-gel-zusammensetzungen mit estern des pentaerythrits oder dessen oligomeren |
KR1020137011332A KR20130064816A (ko) | 2004-04-05 | 2005-03-26 | 펜타에리트리톨 에스테르 또는 그의 올리고머를 가진 o/w 겔 조성물 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004017221A DE102004017221A1 (de) | 2004-04-05 | 2004-04-05 | O/W-Gel-Zusammensetzungen mit Estern des Pentaerythrits oder dessen Oligomeren |
DE102004017221.8 | 2004-04-05 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2005097055A2 true WO2005097055A2 (de) | 2005-10-20 |
WO2005097055A3 WO2005097055A3 (de) | 2006-11-30 |
Family
ID=34962383
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2005/003232 WO2005097055A2 (de) | 2004-04-05 | 2005-03-26 | O/w-gel-zusammensetzungen mit estern des pentaerythrits oder dessen oligomeren |
Country Status (8)
Country | Link |
---|---|
US (1) | US9149420B2 (de) |
EP (1) | EP1742607B1 (de) |
JP (1) | JP5627836B2 (de) |
KR (2) | KR20130064816A (de) |
CN (1) | CN1976673B (de) |
DE (2) | DE102004017221A1 (de) |
ES (1) | ES2329386T3 (de) |
WO (1) | WO2005097055A2 (de) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008104215A1 (de) | 2007-02-28 | 2008-09-04 | Henkel Ag & Co. Kgaa | Wirkstoff-stabilisierte o/w-emulsionen ii |
WO2008104214A1 (de) * | 2007-02-28 | 2008-09-04 | Henkel Ag & Co. Kgaa | Reinigende öi-in-wasser-emulsionen |
DE102012221227A1 (de) | 2012-11-20 | 2014-05-22 | Beiersdorf Ag | Sensorisch attraktive Hydrodispersion mit Wachsen |
DE102012221224A1 (de) | 2012-11-20 | 2014-05-22 | Beiersdorf Ag | Hydrodispersion mit verbesserter Leistung |
DE102017201948A1 (de) | 2017-02-08 | 2018-08-09 | Beiersdorf Ag | Sensorisch attraktive Hydrodispersion mit UV-Schutzfiltern |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1964540A3 (de) | 2007-02-28 | 2009-11-25 | Henkel AG & Co. KGaA | Wirkstoff-stabilisierte O/W-Emulsion |
US10512796B2 (en) | 2009-12-31 | 2019-12-24 | Sol-Gel Technologies Ltd. | Core stabilized microcapsules, method of their preparation and uses thereof |
US10653899B2 (en) | 2009-12-31 | 2020-05-19 | Sol-Gel Technologies Ltd. | Core stabilized microcapsules, method of their preparation and uses thereof |
US11071878B2 (en) | 2009-12-31 | 2021-07-27 | Sol-Gel Technologies Ltd. | Core stabilized microcapsules, method of their preparation and uses thereof |
JP5674353B2 (ja) * | 2010-06-29 | 2015-02-25 | 花王株式会社 | 皮膚外用剤 |
EP3698778B1 (de) | 2011-06-29 | 2021-10-13 | Sol-Gel Technologies Ltd. | Stabilisierte topische formulierungen mit kern-hüllen-mikrokapseln |
JP5506106B2 (ja) * | 2011-12-01 | 2014-05-28 | 株式会社 資生堂 | 水中油型乳化皮膚化粧料 |
KR101467740B1 (ko) | 2011-12-01 | 2014-12-01 | 가부시키가이샤 시세이도 | 수성 피부 화장료 |
FR3002444B1 (fr) | 2013-02-25 | 2015-03-13 | Oreal | Composition cosmetique de type gel |
FR3002449B1 (fr) | 2013-02-25 | 2015-04-03 | Oreal | Composition cosmetique de type gel |
FR3002448B1 (fr) * | 2013-02-25 | 2015-04-03 | Oreal | Composition cosmetique de type gel |
FR3025100B1 (fr) | 2014-08-28 | 2016-12-09 | Oreal | Composition cosmetique de type gel a tenue amelioree |
DE102015207624A1 (de) | 2015-04-27 | 2016-10-27 | Beiersdorf Ag | Hautpflegezubereitung |
GB2547685A (en) * | 2016-02-26 | 2017-08-30 | Reckitt Benckiser Laundry Detergents | Composition |
JP7010615B2 (ja) * | 2017-07-26 | 2022-01-26 | 株式会社コーセー | 皮膚貼付用ゲル組成物及び積層物 |
FR3080766B1 (fr) * | 2018-05-02 | 2020-10-23 | Gattefosse Sas | Composition capillaire comprenant des cires vegetales modifiees |
EP4066903A4 (de) * | 2019-11-25 | 2024-01-03 | Kao Corporation | Hautreinigungsmittel |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3976789A (en) * | 1974-02-01 | 1976-08-24 | Shiseido Co., Ltd. | Cosmetic composition |
EP0179416A2 (de) * | 1984-10-22 | 1986-04-30 | PLOUGH, INC. (a Delaware corporation) | Kosmetika für langen Gebrauch |
WO1999062468A1 (en) * | 1998-06-04 | 1999-12-09 | The Procter & Gamble Company | Hair conditioning composition comprising primary oil and secondary oil |
EP1216685A2 (de) * | 2000-12-21 | 2002-06-26 | Johnson & Johnson Consumer Companies, Inc. | Körperpflegezusammensetzungen |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1951593A (en) * | 1930-09-06 | 1934-03-20 | American Cyanamid Co | Long chain esters and compositions thereof |
US2427255A (en) * | 1942-07-28 | 1947-09-09 | Hayden Chemical Corp | Artificial waxes comprising reaction products of maleic anhydride and partial esters of stearic acid and polyhydric alcohols of the pentaerythritol series, methods for preparing, and compositions containing the same |
US2441555A (en) * | 1943-10-12 | 1948-05-18 | Heyden Chemical Corp | Mixed esters of polyhydric alcohols |
US2705722A (en) * | 1951-02-24 | 1955-04-05 | Drew & Co Inc E F | Refining and bleaching fatty acid esters |
BE566621A (de) * | 1957-04-09 | |||
US4113635A (en) * | 1971-12-13 | 1978-09-12 | Nippon Steel Corporation | Rust-proof lubricant compositions |
US4290337A (en) * | 1977-01-03 | 1981-09-22 | Nittetsu Bolten Kabushiki Kaisha | Fastener set |
US4400295A (en) * | 1979-03-24 | 1983-08-23 | Loire Cosmetics Co., Ltd. | Emulsifier composition |
US4332702A (en) * | 1981-01-12 | 1982-06-01 | Henkel Corporation | Polyvinyl chloride compositions and processing |
EP0163806B1 (de) * | 1984-05-07 | 1990-08-29 | Miranol Inc. | Mischungen von Oligomeren von partiell verestertem Pentaerythrit, ihre Herstellung und Verwendung |
DE3723826A1 (de) * | 1987-07-18 | 1989-01-26 | Henkel Kgaa | Verfahren zur herstellung von alkylglykosiden |
DE3833780A1 (de) | 1988-10-05 | 1990-04-12 | Henkel Kgaa | Verfahren zur direkten herstellung von alkylglykosiden |
US5576425A (en) * | 1988-10-05 | 1996-11-19 | Henkel Kommanditgesellschaft Auf Aktien | Process for the direct production of alkyl glycosides |
DE4010393A1 (de) | 1990-03-30 | 1991-10-02 | Henkel Kgaa | Verfahren zur herstellung von oel-in-wasser-cremes |
JP3442101B2 (ja) * | 1992-07-27 | 2003-09-02 | 日清オイリオ株式会社 | ラノリン様合成油剤及びこれを配合してなる化粧品、外用剤 |
US5304665A (en) * | 1993-04-05 | 1994-04-19 | Arco Chemical Technology, L.P. | Process for the preparation of highly esterified alkoxylated polyol compositions |
FR2722116B1 (fr) * | 1994-07-11 | 1996-08-23 | Oreal | Emulsion huile-dans-eau sans tensioactif, stabilisee par des particules thermoplastiques creuses |
EP0796083A1 (de) | 1994-12-06 | 1997-09-24 | The Procter & Gamble Company | Lagerstabile, flüssige, gelbildende hautreinungspolymer und lipid |
WO1996017592A2 (en) | 1994-12-06 | 1996-06-13 | The Procter & Gamble Company | Shelf stable skin cleansing liquid with gel forming polymer, lipid and crystalline ethylene glycol fatty acid ester |
US5741919A (en) * | 1995-08-17 | 1998-04-21 | Fan Tech Ltd. | Complex meadowfoam esters |
DE19623383C2 (de) * | 1996-06-12 | 1999-07-01 | Henkel Kgaa | Verwendung von Fettstoffen als Siliconersatz zur Herstellung von kosmetischen und/oder pharmazeutischen Zubereitungen |
JP3496132B2 (ja) * | 1996-09-20 | 2004-02-09 | 株式会社コーセー | 水中油型化粧料 |
JP3556781B2 (ja) * | 1996-09-29 | 2004-08-25 | 株式会社資生堂 | 脂溶性ビタミンを含有する乳化組成物 |
US6881776B2 (en) * | 1998-10-29 | 2005-04-19 | Penreco | Gel compositions |
JP3756042B2 (ja) * | 2000-06-30 | 2006-03-15 | 花王株式会社 | 皮膚化粧料 |
US6939980B2 (en) * | 2000-09-11 | 2005-09-06 | Nof Corporation | Process for producing ester |
JP2002138014A (ja) * | 2000-10-31 | 2002-05-14 | Noevir Co Ltd | 微細エマルション組成物 |
DE10143960A1 (de) | 2001-09-07 | 2003-03-27 | Basf Ag | Kosmetische und dermatologische Zubereitungen in Stiftform, enthaltend ein aminosubstituiertes Hydroxybenzophenon |
EP1434562B1 (de) | 2001-09-29 | 2017-08-16 | Beiersdorf AG | Kosmetische und dermatologische stifte |
-
2004
- 2004-04-05 DE DE102004017221A patent/DE102004017221A1/de not_active Withdrawn
-
2005
- 2005-03-26 KR KR1020137011332A patent/KR20130064816A/ko not_active Application Discontinuation
- 2005-03-26 WO PCT/EP2005/003232 patent/WO2005097055A2/de active Application Filing
- 2005-03-26 KR KR1020067020585A patent/KR101308835B1/ko active IP Right Grant
- 2005-03-26 CN CN2005800096338A patent/CN1976673B/zh not_active Expired - Fee Related
- 2005-03-26 DE DE502005007621T patent/DE502005007621D1/de active Active
- 2005-03-26 ES ES05716399T patent/ES2329386T3/es active Active
- 2005-03-26 US US11/547,599 patent/US9149420B2/en not_active Expired - Fee Related
- 2005-03-26 JP JP2007506690A patent/JP5627836B2/ja not_active Expired - Fee Related
- 2005-03-26 EP EP05716399A patent/EP1742607B1/de active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3976789A (en) * | 1974-02-01 | 1976-08-24 | Shiseido Co., Ltd. | Cosmetic composition |
EP0179416A2 (de) * | 1984-10-22 | 1986-04-30 | PLOUGH, INC. (a Delaware corporation) | Kosmetika für langen Gebrauch |
WO1999062468A1 (en) * | 1998-06-04 | 1999-12-09 | The Procter & Gamble Company | Hair conditioning composition comprising primary oil and secondary oil |
EP1216685A2 (de) * | 2000-12-21 | 2002-06-26 | Johnson & Johnson Consumer Companies, Inc. | Körperpflegezusammensetzungen |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2008104215A1 (de) | 2007-02-28 | 2008-09-04 | Henkel Ag & Co. Kgaa | Wirkstoff-stabilisierte o/w-emulsionen ii |
WO2008104214A1 (de) * | 2007-02-28 | 2008-09-04 | Henkel Ag & Co. Kgaa | Reinigende öi-in-wasser-emulsionen |
DE102012221227A1 (de) | 2012-11-20 | 2014-05-22 | Beiersdorf Ag | Sensorisch attraktive Hydrodispersion mit Wachsen |
DE102012221224A1 (de) | 2012-11-20 | 2014-05-22 | Beiersdorf Ag | Hydrodispersion mit verbesserter Leistung |
WO2014079734A1 (de) * | 2012-11-20 | 2014-05-30 | Beiersdorf Ag | Sensorisch attraktive hydrodispersion mit wachsen |
US20150290117A1 (en) * | 2012-11-20 | 2015-10-15 | Beiersdorf Ag | Sensorily attractive hydrodispersion comprising waxes |
EP2922598B1 (de) | 2012-11-20 | 2019-01-09 | Beiersdorf AG | Sensorisch attraktive hydrodispersion mit wachsen |
DE102017201948A1 (de) | 2017-02-08 | 2018-08-09 | Beiersdorf Ag | Sensorisch attraktive Hydrodispersion mit UV-Schutzfiltern |
WO2018145831A1 (de) | 2017-02-08 | 2018-08-16 | Beiersdorf Ag | Sensorisch attraktive hydrodispersion mit uv-schutzfiltern 2-ethylhexylsalicylat und 4-tert-butyl-4'-methoxy dibenzoylmethan |
Also Published As
Publication number | Publication date |
---|---|
CN1976673B (zh) | 2012-05-16 |
US20080064761A1 (en) | 2008-03-13 |
JP2007531776A (ja) | 2007-11-08 |
KR20070001214A (ko) | 2007-01-03 |
ES2329386T3 (es) | 2009-11-25 |
KR101308835B1 (ko) | 2013-09-13 |
DE502005007621D1 (de) | 2009-08-13 |
US9149420B2 (en) | 2015-10-06 |
JP5627836B2 (ja) | 2014-11-19 |
EP1742607B1 (de) | 2009-07-01 |
KR20130064816A (ko) | 2013-06-18 |
DE102004017221A1 (de) | 2005-10-20 |
CN1976673A (zh) | 2007-06-06 |
EP1742607A2 (de) | 2007-01-17 |
WO2005097055A3 (de) | 2006-11-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP1742607B1 (de) | O/w-gel-zusammensetzungen mit estern des pentaerythrits oder dessen oligomeren | |
EP1732877B1 (de) | Sensorische wachse für kosmetische und/oder pharmazeutische formulierungen | |
EP1853219B1 (de) | Emollients und kosmetische zusammensetzungen auf basis spezieller verzweigter kohlenwasserstoffe | |
WO2005097057A1 (de) | O/w-gel-zusammensetzungen mit wachsen | |
EP2349495A1 (de) | Ethylenoxid-freie antiperspirant/desodorant-zubereitungen | |
WO2005097056A1 (de) | Wachmischung auf basis von partialglyceriden und pentaerythritestern | |
EP2144597B1 (de) | Wirkstoff-stabilisierende o/w-emulsionen ii | |
EP1740528A1 (de) | Emulgatorkonzentrat für kosmetische zusammensetzung | |
EP2150230B1 (de) | Reinigende öi-in-wasser-emulsionen | |
DE102005061239A1 (de) | Emollient Mischung für kosmetische und pharmazeutische Formulierungen | |
WO2008135187A1 (de) | Kosmetische zusammensetzungen enthaltend ester auf basis von 2-propylheptansäure | |
DE102005009853A1 (de) | Emollients und kosmetische Zusammensetzungen auf Basis spezieller verzweigter Kohlenwasserstoffe | |
EP2229932A1 (de) | Antitranspiration in Form einer Mikroemulstion und Doppelemulsion | |
EP1964540A2 (de) | Wirkstoff-stabilisierte O/W-Emulsion | |
DE102007059679A1 (de) | Wirkstoff-stabilisierte O/W-Emulsionen I | |
DE102005012300A1 (de) | Kosmetische Zusammensetzungen enthaltend Ester auf Basis von 2-Propylheptanol | |
EP3302714A1 (de) | Kombination von isosorbiddiestern mit nichtionischen tensiden als perlglanzmittel | |
DE102005011691A1 (de) | Emollients und kosmetische Zusammensetzungen auf Basis spezieller verzweigter Kohlenwasserstoffe |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SM SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): BW GH GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 200580009633.8 Country of ref document: CN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2005716399 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020067020585 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007506690 Country of ref document: JP |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWW | Wipo information: withdrawn in national office |
Country of ref document: DE |
|
WWP | Wipo information: published in national office |
Ref document number: 1020067020585 Country of ref document: KR |
|
WWP | Wipo information: published in national office |
Ref document number: 2005716399 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 11547599 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 11547599 Country of ref document: US |