WO2004079021A1 - Procede de fabrication de toles d’acier lamine a chaud et a froid a tres haute resistance et tole obtenue - Google Patents
Procede de fabrication de toles d’acier lamine a chaud et a froid a tres haute resistance et tole obtenue Download PDFInfo
- Publication number
- WO2004079021A1 WO2004079021A1 PCT/FR2004/000136 FR2004000136W WO2004079021A1 WO 2004079021 A1 WO2004079021 A1 WO 2004079021A1 FR 2004000136 W FR2004000136 W FR 2004000136W WO 2004079021 A1 WO2004079021 A1 WO 2004079021A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- sheet
- hot
- rolled
- equal
- mpa
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/34—Methods of heating
- C21D1/44—Methods of heating in heat-treatment baths
- C21D1/48—Metal baths
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0278—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips involving a particular surface treatment
Definitions
- the present invention relates to a process for manufacturing hot-rolled, then cold-rolled steel sheets, with very high resistance, and to the cold-rolled sheet thus obtained.
- Very high strength steels have been developed in recent years, in particular to meet the specific needs of the automotive industry, which are in particular the reduction of the weight and therefore of the thickness of the parts, and the improvement of safety. which involves increasing the resistance to fatigue and the impact resistance of the parts. These improvements must not further deteriorate the formability of the sheets used for the manufacture of the parts. This aptitude for shaping supposes in particular that the steel has a significant elongation.
- the fatigue resistance of the parts defines their service life according to the stresses undergone, and can be improved by increasing the tensile strength Rm of the steel.
- the increase in strength deteriorates the formability of the steel, thus limiting the workpieces, in particular as regards their thickness.
- a first family of very high strength steels is known, which are steels alloyed with manganese, containing high proportions of carbon and manganese (more than 1.2%) and the structure of which is ferritocarbonitic. They have a maximum tensile strength of 800 MPa, and can only be obtained by hot rolling to a minimum thickness of 2.3 mm, because the addition of manganese increases the hardness when hot and limits the capacity reduction in rolling.
- a second family of very high strength steels are HLE steels with high yield strength, which are micro-alloyed steels having a yield strength of between 315 and 700 MPa. They cannot be obtained by hot rolling to a thickness less than 1.8 mm, because the addition of element such as niobium increases hot hardness and limits the rolling reduction capacity.
- a third family of very high strength steels are multiphase steels, the structure of which is composed of ferrite and / or bainite and / or martensite in variable proportions, and which cannot be obtained by hot rolling to a thickness less than 1.5 mrn, because the addition of addition elements such as manganese, chromium, molybdenum increase the hardness when hot and limit the reduction capacity during rolling, even if for these grades the choice of elements is optimized to achieve the smallest possible thicknesses.
- the object of the present invention is to remedy the drawbacks of the steels of the prior art by proposing a method making it possible to obtain steel strips having mechanical characteristics similar to those obtained after hot rolling, but at thicknesses less than those currently accessible with the steels of the prior art.
- the first object of the invention is a method of manufacturing a high-strength steel sheet, hot-rolled then cold-rolled having a tensile strength Rm greater than or equal to 450 MPa, comprising the steps whereby :
- the high-strength steel is chosen from three-phase steels, micro-alloyed HLE steels and manganese alloyed steels with a ferrito-bainitic structure.
- the high strength steel has a tensile strength Rm greater than or equal to 600 MPa, preferably greater than or equal to 800 MPa.
- the restorative heat treatment is an annealing carried out at a temperature below Ad.
- the restorative heat treatment is an annealing carried out at a temperature above Ad and below Ac3.
- the strip is coated, after the restoration heat treatment, by passage through a bath of liquid metal, such as for example a bath comprising zinc or a zinc alloy.
- the second object of the invention is also a cold-rolled high-strength steel sheet, obtainable by the method according to the invention, having a tensile strength Rm greater than or equal to 450 MPa, and a thickness less than or equal to 1.5 mm, preferably less than or equal to 1.4 mm and more particularly preferably less than or equal to 1.3 mm.
- the sheet according to the invention can also have the following characteristics, alone or in combination:
- the high-strength steel is chosen from multi-phase steels, micro-alloyed HLE steels and manganese-alloyed steels with ferrito-bainitic structure, - sheet steel has a tensile strength Rm greater than or equal to 600 MPa, preferably greater than or equal to 800 MPa, - the sheet has a metallic coating,
- the method according to the invention consists first of all in hot rolling a high-strength steel, until a hot strip is obtained whose thickness is generally less than or equal to 2.5 mm.
- the purpose of this rolling is to obtain a homogeneous structure.
- the process then consists of a cold rolling of the hot strip with a reduction rate of between 10 and 20%.
- This rolling is carried out at this low reduction rate so as not to modify the properties of the base metal excessively and irreversibly.
- This reduction rate can be achieved on a conventional re-rolling line with the advantage of being carried out in a single pass, saving production time. It can also be carried out by a rolling pass on a cage at the entry of a galvanizing line, which makes it possible to carry out the reduction and the subsequent heat treatment of restoration on a single line.
- conventional cold-rolled steels are never rolled with such a low rate, since it is desired to obtain a recrystallized structure after annealing heat treatment, and a reduction rate that is too low does not allow this.
- the strip undergoes a restorative heat treatment at a temperature below Ac3.
- the restoration heat treatment may comprise a first phase of rapid heating at a speed V1, then a second phase of slower heating, at a speed V2, until the target holding temperature is reached.
- This holding temperature depends on the nature of the steel treated.
- the strip is cooled at a cooling rate V3, to ambient temperature.
- the strip can also be cooled to a temperature close to that of a metal bath liquid, such as a zinc bath, and soak it in such a bath, before cooling it to room temperature at a cooling rate V4.
- the different parameters of this cycle are defined to allow the restoration of the structure, that is to say, to rearrange the dislocations generated during cold rolling, in order to obtain grain sub-joints.
- the speed V1 is between 10 and 40 ° C / s
- V2 is between 5 and 25 ° C / s
- the holding temperature is between 650 ° C and 750 ° C
- the holding time is between 10 and 30 seconds.
- the cooling rate V3 is between 10 and 60 ° C / s
- the strip is cooled until it reaches approximately 470 ° C before immersing it in a galvanizing bath, then cooling it at a speed V4 between 10 and 20 ° C / s.
- a grade of multiphase steel is cast in the form of slabs which are hot rolled until they reach a thickness of 1.6 mm.
- the hot sheets are then cold rolled with a reduction rate of 10%, then three samples A, B and C are subjected to a restorative heat treatment, which will be described and the specific conditions of which are given in Table 2 .
- This treatment consists of a first heating phase at a speed V1 of 38 ° C / s until reaching a preheating temperature varying between 500 and 700 ° C, then in a second phase at a speed V2 of 10 ° C / s until reaching a holding temperature varying between 650 and 750 ° C. Heating at this temperature is carried out for 20 seconds.
- the sheet is then cooled at a speed V3 of 20 ° C / s, until it reaches 470 ° C, then galvanized by passing through a bath of liquid zinc.
- the sheet is finally cooled at a speed V4 of 15 ° C / s to room temperature.
- a multi-phase steel grade is used, the composition of which is identical to that of test 1, which is poured in the form of slabs which are hot rolled until a thickness of 1.6 mm is reached.
- the hot sheets are then cold rolled with a reduction rate of 20%, then two samples F and G are subjected to a restorative heat treatment similar to that of the test and the specific conditions of which are given in table 3 .
- the mechanical characteristics of samples F and G are then measured and collated in table 3, as well as the mechanical characteristics of a sample H from the same slab, then hot rolled, but not cold rolled, and that the mechanical characteristics of a sample I from the same slab, hot rolled, then cold rolled with a reduction rate of 20%, but not having undergone a heat treatment for restoration.
- the method according to the invention has many advantages, and in particular an improvement in the surface appearance in terms of roughness, as well as an improvement in dimensional tolerances compared to hot-rolled steel sheets.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Coating With Molten Metal (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006505658A JP2006522221A (ja) | 2003-01-28 | 2004-01-22 | 熱間圧延および冷間圧延された超高強度鋼板の製造方法および得られる超高強度鋼板 |
CA002513065A CA2513065A1 (fr) | 2003-01-28 | 2004-01-22 | Procede de fabrication de toles d'acier lamine a chaud et a froid a tres haute resistance et tole obtenue |
EP04704249A EP1590493A1 (fr) | 2003-01-28 | 2004-01-22 | Procede de fabrication de toles d'acier lamine a chaud et a froid a tres haute resistance et tole obtenue |
BR0407043-7A BRPI0407043A (pt) | 2003-01-28 | 2004-01-22 | Processo de fabricação de chapas de aço laminado a quente e a frio com elevada resistência e chapa obtida |
MXPA05007986A MXPA05007986A (es) | 2003-01-28 | 2004-01-22 | Procedimiento de fabricacion de chapas de acero laminadas en caliente y en frio de muy alta resistencia y chapa obtenida. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR03/00893 | 2003-01-28 | ||
FR0300893A FR2850398B1 (fr) | 2003-01-28 | 2003-01-28 | Procede de fabrication de toles d'acier lamine a chaud et a froid a tres haute resistance et tole obtenue |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004079021A1 true WO2004079021A1 (fr) | 2004-09-16 |
Family
ID=32669254
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2004/000136 WO2004079021A1 (fr) | 2003-01-28 | 2004-01-22 | Procede de fabrication de toles d’acier lamine a chaud et a froid a tres haute resistance et tole obtenue |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP1590493A1 (fr) |
JP (1) | JP2006522221A (fr) |
KR (1) | KR20050095776A (fr) |
CN (1) | CN1742103A (fr) |
BR (1) | BRPI0407043A (fr) |
CA (1) | CA2513065A1 (fr) |
FR (1) | FR2850398B1 (fr) |
MX (1) | MXPA05007986A (fr) |
RU (1) | RU2005127041A (fr) |
WO (1) | WO2004079021A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3126539B1 (fr) | 2014-03-31 | 2020-11-25 | Primetals Technologies Austria GmbH | Installation et procédé de décapage et de revêtement métallique d'une bande métallique |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7288158B2 (en) | 2004-03-10 | 2007-10-30 | Algoma Steel Inc. | Manufacturing process for producing high strength steel product with improved formability |
DE102009049398C5 (de) * | 2009-10-14 | 2015-05-07 | Benteler Automobiltechnik Gmbh | Verfahren zur Herstellung eines Strukturbauteils für ein Kraftfahrzeug und Strukturbauteil |
KR101652081B1 (ko) | 2014-12-30 | 2016-08-30 | 김인호 | 전극보일러 급탕시스템 |
KR20170001494A (ko) | 2015-06-26 | 2017-01-04 | 김인호 | 전극보일러 전류제어시스템 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63100134A (ja) * | 1986-10-15 | 1988-05-02 | Kawasaki Steel Corp | 厚物超深絞り用冷延鋼板の製造方法 |
JPS63125618A (ja) * | 1986-11-14 | 1988-05-28 | Kawasaki Steel Corp | 低温靭性の優れた非調質高張力鋼板の製造方法 |
JPS63195221A (ja) * | 1987-02-09 | 1988-08-12 | Nippon Steel Corp | 延性に富む高強度鋼板の製造方法 |
JPH04147946A (ja) * | 1990-10-09 | 1992-05-21 | Nippon Steel Corp | 強度、延性の優れたステンレス鋼 |
JPH11335779A (ja) * | 1998-05-26 | 1999-12-07 | Nippon Steel Corp | 一次加工後の耐しわ性に優れた容器用鋼板およびその製造方法 |
-
2003
- 2003-01-28 FR FR0300893A patent/FR2850398B1/fr not_active Expired - Fee Related
-
2004
- 2004-01-22 MX MXPA05007986A patent/MXPA05007986A/es unknown
- 2004-01-22 JP JP2006505658A patent/JP2006522221A/ja active Pending
- 2004-01-22 WO PCT/FR2004/000136 patent/WO2004079021A1/fr not_active Application Discontinuation
- 2004-01-22 CN CNA2004800025427A patent/CN1742103A/zh active Pending
- 2004-01-22 EP EP04704249A patent/EP1590493A1/fr not_active Withdrawn
- 2004-01-22 BR BR0407043-7A patent/BRPI0407043A/pt not_active Application Discontinuation
- 2004-01-22 CA CA002513065A patent/CA2513065A1/fr not_active Abandoned
- 2004-01-22 KR KR1020057013885A patent/KR20050095776A/ko not_active Application Discontinuation
- 2004-01-22 RU RU2005127041/02A patent/RU2005127041A/ru not_active Application Discontinuation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS63100134A (ja) * | 1986-10-15 | 1988-05-02 | Kawasaki Steel Corp | 厚物超深絞り用冷延鋼板の製造方法 |
JPS63125618A (ja) * | 1986-11-14 | 1988-05-28 | Kawasaki Steel Corp | 低温靭性の優れた非調質高張力鋼板の製造方法 |
JPS63195221A (ja) * | 1987-02-09 | 1988-08-12 | Nippon Steel Corp | 延性に富む高強度鋼板の製造方法 |
JPH04147946A (ja) * | 1990-10-09 | 1992-05-21 | Nippon Steel Corp | 強度、延性の優れたステンレス鋼 |
JPH11335779A (ja) * | 1998-05-26 | 1999-12-07 | Nippon Steel Corp | 一次加工後の耐しわ性に優れた容器用鋼板およびその製造方法 |
Non-Patent Citations (5)
Title |
---|
DATABASE WPI Section Ch Week 200014, Derwent World Patents Index; Class M, Page 27, AN 2000-150053, XP002256481 * |
PATENT ABSTRACTS OF JAPAN vol. 012, no. 344 (C - 528) 16 September 1988 (1988-09-16) * |
PATENT ABSTRACTS OF JAPAN vol. 012, no. 373 (C - 534) 6 October 1988 (1988-10-06) * |
PATENT ABSTRACTS OF JAPAN vol. 012, no. 479 (C - 552) 14 December 1988 (1988-12-14) * |
PATENT ABSTRACTS OF JAPAN vol. 016, no. 431 (C - 0983) 9 September 1992 (1992-09-09) * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3126539B1 (fr) | 2014-03-31 | 2020-11-25 | Primetals Technologies Austria GmbH | Installation et procédé de décapage et de revêtement métallique d'une bande métallique |
Also Published As
Publication number | Publication date |
---|---|
CN1742103A (zh) | 2006-03-01 |
EP1590493A1 (fr) | 2005-11-02 |
JP2006522221A (ja) | 2006-09-28 |
RU2005127041A (ru) | 2006-02-10 |
KR20050095776A (ko) | 2005-09-30 |
FR2850398A1 (fr) | 2004-07-30 |
MXPA05007986A (es) | 2005-09-21 |
CA2513065A1 (fr) | 2004-09-16 |
FR2850398B1 (fr) | 2005-02-25 |
BRPI0407043A (pt) | 2006-01-17 |
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