WO2004040666A1 - Vertikal integriertes bauelement, bauelement-anordnung und verfahren zum herstellen eines vertikal integrierten bauelements - Google Patents
Vertikal integriertes bauelement, bauelement-anordnung und verfahren zum herstellen eines vertikal integrierten bauelements Download PDFInfo
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- WO2004040666A1 WO2004040666A1 PCT/DE2003/003587 DE0303587W WO2004040666A1 WO 2004040666 A1 WO2004040666 A1 WO 2004040666A1 DE 0303587 W DE0303587 W DE 0303587W WO 2004040666 A1 WO2004040666 A1 WO 2004040666A1
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- conductive layer
- electrically conductive
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- -1 Titanium molybdenum aluminum Titanium Chemical compound 0.000 claims description 3
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- 125000006850 spacer group Chemical group 0.000 claims description 3
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- 150000004770 chalcogenides Chemical class 0.000 claims description 2
- 239000007769 metal material Substances 0.000 claims description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 2
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 claims description 2
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- DZXOZMCJXVIQOP-UHFFFAOYSA-N [Ge].[In].[Si] Chemical compound [Ge].[In].[Si] DZXOZMCJXVIQOP-UHFFFAOYSA-N 0.000 claims 1
- NAWOSTKISNSQHP-UHFFFAOYSA-N tantalum titanium Chemical compound [Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ti].[Ta].[Ta].[Ta] NAWOSTKISNSQHP-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 description 28
- 230000008569 process Effects 0.000 description 13
- 238000005229 chemical vapour deposition Methods 0.000 description 12
- 238000000151 deposition Methods 0.000 description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/78—Field effect transistors with field effect produced by an insulated gate
- H01L29/786—Thin film transistors, i.e. transistors with a channel being at least partly a thin film
- H01L29/78642—Vertical transistors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/0657—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
- H01L29/0665—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body the shape of the body defining a nanostructure
- H01L29/0669—Nanowires or nanotubes
- H01L29/0673—Nanowires or nanotubes oriented parallel to a substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/06—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
- H01L29/0657—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body
- H01L29/0665—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape of the body the shape of the body defining a nanostructure
- H01L29/0669—Nanowires or nanotubes
- H01L29/0676—Nanowires or nanotubes oriented perpendicular or at an angle to a substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66439—Unipolar field-effect transistors with a one- or zero-dimensional channel, e.g. quantum wire FET, in-plane gate transistor [IPG], single electron transistor [SET], striped channel transistor, Coulomb blockade transistor
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66742—Thin film unipolar transistors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/66007—Multistep manufacturing processes
- H01L29/66075—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
- H01L29/66227—Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
- H01L29/66409—Unipolar field-effect transistors
- H01L29/66477—Unipolar field-effect transistors with an insulated gate, i.e. MISFET
- H01L29/66787—Unipolar field-effect transistors with an insulated gate, i.e. MISFET with a gate at the side of the channel
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/66—Types of semiconductor device ; Multistep manufacturing processes therefor
- H01L29/68—Types of semiconductor device ; Multistep manufacturing processes therefor controllable by only the electric current supplied, or only the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched
- H01L29/76—Unipolar devices, e.g. field effect transistors
- H01L29/772—Field effect transistors
- H01L29/775—Field effect transistors with one dimensional charge carrier gas channel, e.g. quantum wire FET
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
- H10K10/40—Organic transistors
- H10K10/46—Field-effect transistors, e.g. organic thin-film transistors [OTFT]
- H10K10/462—Insulated gate field-effect transistors [IGFETs]
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K19/00—Integrated devices, or assemblies of multiple devices, comprising at least one organic element specially adapted for rectifying, amplifying, oscillating or switching, covered by group H10K10/00
- H10K19/10—Integrated devices, or assemblies of multiple devices, comprising at least one organic element specially adapted for rectifying, amplifying, oscillating or switching, covered by group H10K10/00 comprising field-effect transistors
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
- H10K85/221—Carbon nanotubes
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/60—Organic compounds having low molecular weight
- H10K85/615—Polycyclic condensed aromatic hydrocarbons, e.g. anthracene
Definitions
- the invention relates to a vertically integrated component, a component arrangement and a method for producing a vertically integrated component.
- Nano structures such as, for example, nanotubes, in particular carbon nanotubes, and nanorods, also called nanowires, are known as possible successors to conventional semiconductor electronics.
- Carbon nanotube is a single-walled or multi-walled tubular carbon compound.
- multi-walled nanotubes at least one inner nanotube is coaxially surrounded by an outer nanotube.
- Single-walled nanotubes typically have a diameter of Inm, the length of a nanotube can be several hundred niti. The ends of a nanotube are often terminated with half a fullerene molecule.
- Nanotubes can be produced by depositing a catalyst material layer, for example made of iron, cobalt or nickel, on a substrate and on this catalyst material layer using a chemical vapor deposition (CVD) process by introducing a carbon-containing material (for example Acetylene) are grown in the process chamber carbon nanotubes on the catalyst material layer. Because of the good electrical
- Conductivity of carbon nanotubes and due to the adjustability of this conductivity, for example by applying an external electric field or by doping the nanotubes with potassium, for example, nanotubes are suitable for a large number of applications, in particular in electrical coupling technology in integrated circuits, for components in microelectronics as well as an electron emitter.
- a carbon nanotube can be used to form such a field effect transistor, as a result of which a so-called CNT-FET (“carbon nanotube field effect transistor”) is formed.
- CNT-FET carbon nanotube field effect transistor
- a nanotube is planarly formed and contacted on a dielectric layer on a conductive substrate.
- the conductivity of the carbon nanotube is controlled via a suitable electrical voltage applied to the conductive substrate, so that the electrical current flow through the nanotube, clearly the electrical current flow between the source / drain connections of the CNT-FET, by applying a voltage to the conductive one Substrate is controllable.
- a method for forming a field effect transistor using a carbon nanotube is described, for example, in [2].
- a silicon dioxide layer is first formed on a silicon substrate and contact pads are formed thereon.
- a carbon nanotube is then applied between two contacting pads and contacted with the contacting pads, the conductivity of the carbon nanotube being controllable by applying a voltage to the silicon substrate.
- the size of the electrical current flow between the two end sections of a carbon nanotube is dependent on the conductivity of the carbon anotube at a given electrical voltage and can therefore be controlled by means of the electrical voltage on the silicon substrate.
- Carbon nanotubes, nanorods, also called nanowires, are used as nanostructures for an integrated circuit.
- free-standing zinc oxide nanowires with diameters of approximately 40 nm to 150 nm can be produced, with a density of approximately 10 3 wires per cm 2 .
- tufts of zinc oxide nanowires are used as laser components.
- Cross-formed nanowires made of p-doped silicon and n-doped gallium nitride.
- the nanowires according to [4] are only planarly formed and contacted in the horizontal direction on a substrate surface. Since the dimension of a component obtained is determined by the length of a nanostructure (on the order of micrometers), the method known from [4] runs counter to the need for progressive miniaturization.
- [7] discloses ultra-high density nanotransistors using selectively grown vertical carbon nanotubes.
- [8] discloses an electronic component with an electrically conductive connection made of carbon nanotubes and method for its production.
- the problem underlying the invention is to increase the integration density of sufficiently precisely controllable components with a nanostructure and to provide sensitive nano-structures in such a way that they are protected against mechanical damage.
- a vertically integrated component is created with a first electrically conductive layer, a middle layer partially made of dielectric material on the first electrically conductive layer and a second electrically conductive layer on the middle layer. Furthermore, a nanostructure integrated in a through-hole made in the middle layer is provided with a first end section coupled to the first electrically conductive layer and with a second end section coupled to the second electrically conductive layer.
- the middle layer has a third electrically conductive layer, the thickness of which, between two adjacent dielectric sublayers is less than the thickness of at least one of the dielectric sub-layers.
- the invention provides a component arrangement with at least two components arranged next to one another and / or with at least two components arranged one above the other with the above-mentioned features.
- a first electrically conductive layer is formed, a middle layer is partially formed from dielectric material and a through hole is made in the middle layer. Furthermore, a nanostructure having a first end section and a second end section is formed in the through hole, the first end section being coupled to the first electrically conductive layer. A second electrically conductive layer is formed on the middle layer and coupled to the second end section of the nanostructure.
- the middle layer is formed in such a way that a third electrically conductive layer is formed between two adjacent dielectric sublayers, the thickness of which is less than the thickness of at least one of the dielectric sublayers.
- a basic idea of the invention is to be seen in the fact that by means of the sufficiently thin third electrically conductive layer contained in the middle layer, the electrical conductivity of an adjacent region of the nanostructure can be controlled reliably.
- the vertically integrated component can thus be operated as a field-effect transistor-like component, the third electrically conductive layer serving in this case as a gate electrode layer, whereas the nanostructure clearly serves as a channel region.
- the third electrically conductive layer is provided sufficiently thin according to the invention, it forms when an electrical voltage is applied to the third electrically conductive layer due to an electrostatic peak effect in an adjacent surrounding area of the nanostructure, a particularly strong electric field is produced, in other words there is a field concentration. Using the field effect, the electrical conductivity in the region of the nanostructure adjacent to the third electrically conductive layer can be controlled with very high accuracy.
- the thickness of a respective layer can be set with an accuracy of up to one atomic layer, that is to say to a few angstroms.
- the desired position and thickness of the third electrically conductive layer within the middle layer can thus be defined very precisely according to the invention.
- safe blocking or safe conduction of the channel region of the field effect transistor is optionally made possible, the desired operating state in each case being adjustable by means of applying or not applying a voltage to the third electrically conductive layer.
- the adjustability of the electrical conductivity of the nanotube is clearly improved compared to the prior art in that a spatially precisely defined location of the nanostructure is influenced by means of a spatially localized electrical field of a large amplitude, instead of using a less specific and Undefined control of the conductivity of almost an entire nanostructure, as according to the prior art.
- Carbon nanotubes growing up in a through hole Carbon nanotubes growing up in a through hole.
- An advantage of the vertically integrated component according to the invention is the miniaturization of the component down to the range of lateral nanometer dimensions, since the surface requirement of a vertically integrated component is in principle only limited by the cross-sectional area of the nanostructure. Furthermore, according to the invention, the often sensitive nanostructure is incorporated in an insulating and protective matrix made of the dielectric material of the middle layer.
- the spatial arrangement of nanostructures of different vertically integrated components of a component arrangement according to the invention can be realized by specifying a spatial arrangement of through holes in which the nanostructures are grown, so that an orderly arrangement of different nanostructures is made possible. Furthermore, the presence of a crystalline substrate is unnecessary.
- Carbon nanotubes in a vertical contact hole can be technologically implemented with reasonable effort. Furthermore, the length of the nanostructure, for example a carbon nanotube, can be adjusted by dividing the thickness of the middle layer.
- the first conductive layer and the nanostructure there is preferably catalyst material for catalyzing the Forming the nanostructure arranged.
- catalyst material for catalyzing the Forming the nanostructure arranged.
- the catalyst material can, for example, be deposited locally in the through hole, alternatively a catalyst material layer can be formed between the first electrically conductive layer and the middle layer, or, in certain applications, the first conductive layer can be produced from such a material that the first electrically conductive layer can be used as a catalyst for catalyzing the formation of the nanostructure.
- the first electrically conductive layer can be made of iron material and can therefore be used as a catalyst for growing carbon nanotubes
- the third electrically conductive layer can surround the nanostructure in a surrounding area of the first or the second end section.
- the third conductive layer can be functionally split into a first and a second partial layer, the first partial layer being located in the area of the first conductive layer and the second partial layer being located in the area of the second conductive layer. With the aid of this split third conductive layer, it is possible to perform optimal gate control of the Schottky barriers formed in these areas at both end contacts of the nanostructure.
- the third electrically conductive layer surrounds the nanostructure in a surrounding area from one of the end sections of the nanostructure at which it adjoins the first or the second electrically conductive layer, an additional improvement of the
- a Schottky barrier is formed between the first electrically conductive layer and the first end section of the nanostructure, and between the second electrically conductive layer and the second end section of the nanostructure is sensitive and is very spatially localized. If the third electrically conductive layer is formed near the first or the second end section, the electrical conductivity of the nanostructure can be set particularly sensitively by applying an electrical voltage to the third electrically conductive layer.
- the thickness of the third electrically conductive layer can be less, preferably significantly less, than the thickness of both dielectric sublayers.
- the thickness ratio between the first or the second dielectric partial layer on the one hand and the third electrically conductive layer is preferably at least three, more preferably at least five, and even more preferably at least ten.
- the component according to the invention can also be designed as a field effect transistor, in which component the first end section of the nanostructure serves as the first source / drain region and the second end section of the nanostructure as the second source / drain region, and in which component in the third electrically conductive region Layer, which serves as the gate electrode of the field effect transistor, is arranged along the through hole made in the third electrically conductive layer, a ring structure made of an electrically insulating material as the gate insulating region of the field effect transistor.
- the electrical conductivity of the nanostructure can clearly be controlled by applying a suitable electrical potential to the third electrically conductive layer, since such an electrical potential characteristically influences the electrical conductivity of the nanotube due to the field effect, which thus acts as a channel region in this area of a field effect transistor can be used. Due to the ring-like structure of the gate-insulating layer, the electrical field generated as a result of the electrical potential of the third electrically conductive layer reaches the nanostructure sufficiently well, which is due to the fact that the gate electrode is electrically insulated on all sides by means of the gate-insulating layer.
- the middle layer can have an additional electrically conductive layer, which serves at least one additional electrically conductive layer as an additional gate electrode of the field effect transistor, with an additional ring structure made of an electrically insulating material as an additional along the through hole made in the additional electrically conductive layer Gate insulating region of the field effect transistor is arranged.
- the component designed as a field effect transistor can have one or more additional gate connections, as a result of which the controllability of the electrical resistance of the nanostructure is further improved.
- the possibility of providing additional electrically conductive middle layers as additional gate connections is based essentially on the fact that the electrically conductive layer or layers in the middle layer are sufficiently thin.
- the component according to the invention can have an additional field effect transistor, which is arranged above the field effect transistor.
- critical parameters such as the gate length of such a field effect transistor, are defined according to the invention not by means of a structuring process but by means of a deposition process. A much higher structural accuracy can be achieved with a deposition process than with a structuring process. For example, using the ALD method
- atomic layer deposition the thickness of a deposited layer down to the dimension of an atomic layer, ie down to a few angstroms accuracy.
- Field effect transistor of the component according to the invention can be connected to one another as an inverter circuit.
- the field effect transistor and the additional field effect transistor are designed as transistors with different conduction types, for example the field effect transistor as a transistor of the p-conduction type and the additional field effect transistor as a transistor of the n conduction type or vice versa.
- the first and / or the second electrically conductive layer of the component can have tantalum, tantalum nitride (TaN), titanium, titanium nitride (TiN), molybdenum (Mo), aluminum (Al) and / or a ferromagnetic material, or can have any layer stack from a combination of the specified materials
- the first and / or the second electrically conductive layer is made of ferromagnetic material such as iron, cobalt or nickel or of a suitable ferromagnetic alloy, in particular of a hard magnetic or a soft magnetic material
- the component for applications can be used in the "Spintronic".
- semiconductor technology is combined with magnetic effects.
- the spintronic uses, in addition to the electron charge in electricity transport, additionally or alternatively the spin of the electron.
- Applications in spintronic are particularly advantageous according to the invention if the nanostructure is designed as a carbon nanotube, since the charge transport through a carbon nanotube is spin-preserving over sufficiently large dimensions, that is to say takes place without a spin flip.
- ferromagnetic first and second electrically conductive layers for example an MRAM memory cell (“magnetic random access memory”) comes into consideration.
- MRAM memory cell magnetic random access memory
- the vertically integrated component in the embodiment of the vertically integrated component according to the invention as a field effect transistor, it can be set up, for example, as a switching transistor of a DRAM memory cell, in which case a further stack capacitor is to be formed.
- Field effect transistor is designed as a charge storage layer (e.g. as an ONO layer), the storage and deletion of information in this case being carried out by injecting electrons or holes into the charge storage layer.
- a charge storage layer e.g. as an ONO layer
- the third and / or the additional electrically conductive layer preferably has polysilicon, tantalum, titanium, niobium and / or aluminum.
- the dielectric material of the middle layer can be one or a combination of the materials silicon dioxide (Si0 2 ), silicon nitride (Si 3 N 4 ) or silicon dioxide doped with potassium ions.
- Silicon dioxide doped with potassium ions has the particular advantage that potassium ions can be expelled from such a dielectric layer by means of heating and can therefore serve as a dopant for a surrounding material.
- the nanostructure can be a nanotube, a bundle of nanotubes or a nanorod (also called nanowire).
- the nanostructure can be semiconducting.
- the nanorod can contain silicon, germanium, indium phosphide, gallium nitride, gallium arsenide, zirconium oxide and / or a metal.
- the nanotube can be a carbon nanotube, a carbon-boron nanotube, a carbon-nitrogen nanotube, a carbon-boron-nitrogen nanotube, a tungsten sulfide nanotube or a chalcogenide nanotube.
- the nanostructure is a
- Carbon nanotube, iron, cobalt and / or nickel can be used as catalyst material.
- the nanostructure is a gallium arsenide nanorod, gold is preferably used as the catalyst material.
- the portion of the through hole that is free of the nanostructure can be at least partially filled with an electrically insulating spacer structure.
- the component can be formed exclusively from dielectric material, metallic material and the material of the nanostructure. Furthermore, the component can be formed on and / or in a substrate made of polycrystalline or amorphous material.
- the component according to the invention can only consist of electrically conductive material, dielectric material and material of the nanostructure (preferably a carbon nanotube).
- the component can be manufactured without expensive semiconductor technology processes.
- Another important advantage in this connection is that a polycrystalline or amorphous material, that is to say a non-single-crystalline material, can be used as the substrate in order to produce the component. It is therefore an expensive, single-crystalline substrate for the production of the component
- any starting substrate can be used according to the invention (e.g. glass).
- the middle layer which is dielectric Partial layers and additional conductive layers (for example made of polysilicon, tantalum, titanium, niobium, aluminum) can be deposited.
- a vertical through-hole with a typical diameter between 0.4nm and 100nm and with a typical length between O.Ol ⁇ m and 3 ⁇ m can then be made in the middle layer.
- the dielectric and electrically conductive partial layers of the middle layer are structured.
- the third electrically conductive layer interspersed with the through hole is further oxidized along the circumference of the through hole, for example a third electrically conductive layer made of polysilicon material can be oxidized, so that electrically insulating silicon dioxide material is electrically in a surrounding area of the through hole in the third Is formed conductive layer, which silicon dioxide material can be used as a gate insulating layer.
- an annular, gate-insulating layer is formed using the chemical vapor deposition (CVD) method or the atomic layer deposition (ALD) method, in that the through-hole is uniformly coated with an electrically insulating wall layer is coated.
- the nanostructure can then be formed in the through hole, for example a carbon nanotube is grown on a catalyst material deposited on the first electrically conductive layer.
- the catalyst material can either be deposited as a layer on the first electrically conductive layer or, after forming the gate insulating layer using the "electroless deposition" method, can be deposited on the surface of the first electrically conductive layer in the through hole.
- an intermediate region can be sealed between the through hole and the nanostructure, for example by introducing silicon dioxide material into at least part of the through hole using a CVD or spin-on method. Excess material can optionally be etched back to expose the nanostructure, and the second electrically conductive Layer can be formed on the surface of the layer sequence and optionally structured.
- FIG. 1A shows a cross-sectional view of a component according to a first exemplary embodiment of the invention
- FIG. IB shows an enlarged cross-sectional view, taken along the section line A-A from FIG. 1A, of the component shown in FIG. 1A according to the first exemplary embodiment of the invention
- FIG. 2 shows a cross-sectional view of a component according to a second exemplary embodiment of the invention
- FIG. 3 shows a component arrangement according to a first exemplary embodiment of the invention
- FIG. 4A shows a cross-sectional view of a component arrangement according to a second exemplary embodiment of the invention
- FIG. 4B shows an equivalent circuit of the component arrangement shown in FIG. 4A according to the second exemplary embodiment of the invention
- FIG. 5 shows a cross-sectional view of a component according to a third exemplary embodiment of the invention.
- a vertically integrated component 100 according to a first exemplary embodiment of the invention is described below with reference to FIGS. 1A, 1B.
- the vertically integrated component 100 shown in FIG. 1A has a first electrically conductive layer 101, a middle layer 102 partially formed from dielectric material on the first electrically conductive layer 101 and a second electrically conductive layer 103 on the middle layer 102. Furthermore provided is a carbon nanotube 104 integrated into a through-hole 108 made in the middle layer 102, which has a first end section 104a coupled to the electrically conductive layer 101 and a second end section 104b coupled to the second electrically conductive layer 103.
- Catalyst material 107 for catalyzing the formation of the carbon nanotube 104 is arranged between the first conductive layer 101 and the carbon nanotube 104.
- the middle layer 102 is divided into two dielectric sublayers 102a, 102b arranged one above the other.
- a third electrically conductive layer 105 is arranged between the first middle sublayer 102a and the second middle sublayer 102b, the thickness of which is substantially less than the thickness of both dielectric sublayers 102a, 102b.
- the first electrically conductive layer 101 and the second electrically conductive layer 103 are made of tantalum nitride, the third electrically conductive layer 105 is made of polysilicon, the dielectric material of the middle layer 102 is silicon dioxide or silicon dioxide containing potassium ions.
- the vertically integrated Component 100 is the nanostructure a carbon nanotube 104 and the catalyst material 107 is an alloy of iron, cobalt and nickel. It is known that this combination of materials has an advantageous catalytic effect on the formation of a carbon nanotube.
- the vertically integrated component 100 is designed as a field effect transistor, in which component 100 the first end portion 104a of the carbon nanotube 104 serves as the first source / drain region and the second end portion 104b of the carbon nanotube 104 serves as the second source / drain region, and in of the third electrically conductive layer 105, which serves as the gate electrode of the field effect transistor, a ring structure 106 made of an electrically insulating material is arranged as a gate-insulating region of the field transistor along the through hole 108 made therein.
- the vertically integrated component 100 shown in FIG. 1A fulfills the functionality of a field effect transistor.
- the conductivity of the carbon nanotube 104 can be influenced characteristically by applying a suitable electrical voltage to the third electrically conductive layer 105, which has the functionality of a gate electrode.
- the conductivity of the carbon nanotube 104 can be influenced characteristically in a spatially sharply defined central region 104c.
- the central area 104c clearly functions as a channel area.
- the third electrically conductive layer 105 is provided according to the invention in a sufficiently thin manner, an electrical voltage is applied to the third electrically conductive layer 105 due to an electrostatic peak effect in an adjacent one
- the electrical conductivity of the carbon tube 104 in the central region 104c adjoining the third electrically conductive layer 105 can be controlled very precisely by means of the field effect.
- FIG. 1B shows an enlarged cross-sectional view, taken along the section line A-A from FIG. 1A, of the vertically integrated component 100 from FIG. 1A.
- the carbon nanotube 104 is contained in the through hole 108.
- the semiconducting carbon nanotube 104 is decoupled from the third electrically conductive layer 105 by means of the electrically insulating ring structure 106.
- the strength of an electrical current flow between the first and second electrically conductive layers 101, 103 functioning as source / drain connections depends on whether or not an electrical voltage is applied to the gate electrode 105.
- the vertically integrated component 100 therefore fulfills the function of a field effect transistor.
- the first electrically conductive layer 101 is formed by applying titanium nitride, for example using a CVD method (“chemical vapor deposition”).
- a first middle sub-layer 102a is formed by depositing silicon dioxide material.
- the third electrically conductive layer 105 is formed on the first middle sublayer 102a by depositing polysilicon material. Again, this can be done using a CVD process.
- second middle sub-layer 102b is formed by depositing silicon dioxide. Both the silicon dioxide material of the first middle sublayer 102a and the silicon dioxide material of the second middle sublayer 102b can be made according to a modified TEOS
- tetra-ethyl-orthosilicate are formed such that the middle sub-layers 102a, 102b can each have potassium doping atoms.
- the middle layer 102 which is at least partially formed on dielectric material, is formed.
- the through hole 108 is made in the middle layer 102. This is done using a lithography and an etching process.
- the etching method is preferably selected in such a way (in particular by specifying the etchant) that the etching process on the electrically conductive layer 101 stops.
- the electrically insulating ring structure 106 is formed from silicon dioxide by means of thermal oxidation of the third electrically conductive layer 105 made of polysilicon material.
- the catalyst material 107 made of iron, cobalt and nickel is deposited in the through hole 108 and on the first electrically conductive layer 101.
- This can be implemented using a vapor deposition, sputtering, electro or electroless deposition method.
- electroless deposition a conductive material is deposited autocatalytically from a solution containing the material to be deposited without applying an electrical current to certain surface areas of a layer sequence.
- the carbon nanotube 104 is then grown in the through hole 108, the first end section 104 a being coupled to the first conductive structure 101.
- a carbon nanotube is formed using a CVD process in which a methane / hydrogen mixture is introduced as a carbon source into the process chamber. In this way, a p-doped carbon nanotube 104 is often formed.
- the possibly introduced potassium ions from the first can be tempered
- Middle sublayer 102a and the second middle sublayer 102b are expelled, these potassium ions diffuse into the previously p-doped carbon nanotube 104 and act as an n-dopant.
- the initially p-doped carbon nanotube 104 is converted into a carbon nanotube 104 of the n-conduction type.
- the second electrically conductive layer 103 is formed on the middle layer 102 and coupled to the second end section 104b of the carbon nanotube 104, as a result of which the vertically integrated component 100 shown in FIGS. 1A, 1B is obtained.
- a vertically integrated component 200 designed as a field effect transistor is described below with reference to FIG. Only the differences between the vertically integrated component 200 and the vertically integrated component 100 are described below.
- the electrically insulating ring structure 106 from FIG. 1A is not provided.
- the through hole 108 of the vertically integrated component 200 is provided with a continuous electrically insulating edge coating 201, which perceives the functionality of a gate insulating layer.
- Component 200 from FIG. 2 has the function of a
- Voltage to the third electrically conductive layer 105 is controlled. This takes place using the field effect, for which a partial area of the electrically insulating edge coating 201 surrounding the central area 104c of the carbon nanotube 104 is essential.
- the through hole 108 is coated uniformly with an electrically insulating material using the CVD method, thereby electrically insulating edge coating 201 is formed.
- This can additionally fulfill the function of a spacer or a guide for the carbon nanotube 104.
- a component arrangement 300 according to a first exemplary embodiment of the invention is described below with reference to FIG.
- the component arrangement 300 has two components arranged one above the other, each of which is configured similarly to the vertically integrated component 100.
- the component arrangement 300 clearly has a field effect transistor, formed by the vertically integrated component 100, which is arranged above another field effect transistor.
- the additional field effect transistor which is arranged below the vertically integrated component 100, has a common electrically conductive layer 301 together with the vertically integrated component 100, in other words, in the component arrangement 300, the first electrically conductive layer 101 from FIG. lA and the upper electrically conductive layer of the underlying
- the field effect transistor additionally provided in the component arrangement 300 compared to the vertically integrated component 100 has an additional first electrically conductive layer 303, on which an additional middle layer 302 is formed. This is formed from a first middle sublayer 302a, a second middle sublayer 302b and an additional third electrically conductive layer 305, which is arranged between the middle sublayers 302a, 302b.
- the first middle sublayer 302a and the second middle sublayer 302b of the additional middle layer 302 are made of silicon dioxide material.
- the additional third electrically conductive layer 305 is designed like the electrically conductive layer 105. Furthermore, an additional through hole 308 of the lower region of the component arrangement 300 according to FIG.
- FIG. 3 is in a region in which the through hole 308 is the additional third electrically conductive layer 305 penetrates, an additional electrically insulating ring structure 306 arranged.
- An additional carbon nanotube 304 has been grown on additional catalyst material 307, the lower end section 304a of which is coupled to the additional catalyst material 307 according to FIG. 3, and the upper end section 304b of which is coupled to the common electrically conductive layer 301.
- the nanostructure in the component arrangement 300 is clearly formed from the carbon nanotube 104 and the additional carbon nanotube 304. Subareas of
- the nanostructure namely the carbon nanotube 104 on the one hand and the additional carbon nanotube 304 on the other hand, have a different electrical conductivity.
- the carbon nanotube 104 of the nanostructure is (as described above) doped with charge carriers of the n-type, and the additional carbon nanotube 304 of the nanostructure is doped with p-type charge carriers.
- the different doping of the carbon nanotubes 104, 304 is based on the fact that the carbon nanotube 104 is surrounded by silicon dioxide material 102a, 102b doped with potassium ions, whereas the additional carbon nanotube 304 is surrounded by pure silicon dioxide material 302a, 302b.
- the potassium material is driven out of the layers 102a, 102b and diffuses into the carbon nanotube 104, which is thereby n-doped.
- the upper field effect transistor of the component arrangement 300 according to FIG. 3 fulfills the functionality of an n-MOSFET, whereas the lower field effect transistor of the component arrangement 300 according to FIG. 3 fulfills the functionality of a p-MOSFET.
- the component arrangement 300 is produced by first forming the lower field-effect transistor in accordance with FIG. 3, analogously to that described above with reference to FIG. 1A.
- the first middle sublayer 302a and the second middle sublayer 302b are each made of pure potassium doping atoms Silicon dioxide manufactured. This creates the lower field-effect transistor of the component arrangement 300, which has the additional carbon nanotube 304 of the p-conduction type.
- a vertically integrated component 100, as shown in FIG. 1A, is subsequently produced on this layer sequence.
- both the first middle sublayer 102a and the second middle sublayer 102b are produced from silicon dioxide material doped with potassium material, so that the carbon nanotube 104 obtained as a p-doped carbon nanotube in the CVD production process faces upwards described annealing is n-doped.
- the component arrangement 300 provides an n-MOS transistor on a p-MOS transistor, therefore the component arrangement 300 can be used as a CMOS component.
- CMOS technology complementary metal oxide semiconductor
- alternating n-channel and p-channel MOSFETs are used as switches.
- CMOS devices are used in many highly integrated circuits, for example, many modern microprocessors are built in this technology.
- a component arrangement 400 according to a second exemplary embodiment of the invention is described below with reference to FIGS. 4A, 4B.
- a p-MOS field-effect transistor 401 formed by the lower layer sequence according to FIG. 4 A and an n-MOS field transistor 402, formed by the upper layer sequence of the component arrangement 400 according to FIG interconnected as an inverter circuit.
- Field effect transistor 402 the electrical ground potential V ss 403 created. Furthermore, the electrical potential of a supply voltage Vdd 404 is applied to the additional first electrically conductive layer 303 of the p-MOS field-effect transistor 401.
- the third electrically conductive layer 105 and the additional third electrically conductive layer 305 are coupled to an input 405 of the CMOS inverter.
- the common electrically conductive layer 301 is coupled to an output 406 of the CMOS inverter.
- FIG. 4B shows an equivalent circuit 410 of the component arrangement 400, which component arrangement 400 is connected as a CMOS inverter.
- the input 405 is coupled to the gate regions of the p-MOS field-effect transistor 401 and the n-MOS field-effect transistor 402, that is to say to the components of the component arrangement 400 functioning as the respective gate electrode, namely to the third electrically conductive layer 105 and with the additional third electrically conductive layer 305.
- the second electrically conductive layer 103 of the n-MOS field-effect transistor 402 serves as the first source / drain connection of the n-MOS field-effect transistor 402, and is to the first electrically conductive layer 103 therefore the electrical ground potential V SS 403 applied.
- a second source / drain connection of the n-MOS field-effect transistor 402 and a first source / drain connection of the p-MOS field-effect transistor 401 are jointly formed as a common electrically conductive layer 301 and connected to the output 406 as the CMOS Inverter connected component arrangement 410 coupled.
- a second source / drain connection of the p-MOS field-effect transistor 401 is formed by the additional electrically conductive layer 303, to which the electrical potential of the supply voltage V d 404 is applied.
- a vertically integrated component 500 according to a third preferred exemplary embodiment of the invention is described below with reference to FIG.
- the middle layer 501 of the vertically integrated component 500 has, in addition to the first middle sublayer 102a made of potassium-doped silicon dioxide, the second middle sublayer 102b made of potassium doped silicon dioxide, the third electrically conductive layer 105 made of polysilicon and the electrically insulating ring structure 106 a third middle sublayer 501a made of silicon nitride, which is arranged between the third electrically conductive layer 105 and a fourth electrically conductive layer 502.
- An additional electrically insulating ring structure 503 is located in a boundary area between the through hole 108 and the fourth electrically conductive layer 502 arranged.
- the fourth electrically conductive layer 502 is made of polysilicon material and the fourth electrically insulating ring structure 503 is made of silicon dioxide material.
- the vertically integrated component 500 represents a field effect transistor with two gate electrodes 105, 502.
- a field effect transistor with a plurality of gate connections can be advantageous in order to improve the electrical conductivity of the
- a vertically integrated component is created according to the invention, which is optionally available as
- CMOS component inverter and field effect transistor with multiple gate electrodes can be used.
- a large number of more complex circuits can be constructed or formed from these basic components, for example logic gates and further complex circuit arrangements. Due to the vertical orientation, the individual components of the invention can be formed one above the other in any way, and can also be formed side by side.
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Abstract
Description
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EP03778239A EP1556909A1 (de) | 2002-10-31 | 2003-10-29 | Vertikal integriertes bauelement, bauelement-anordnung und verfahren zum herstellen eines vertikal integrierten bauelements |
US10/533,550 US7709827B2 (en) | 2002-10-31 | 2003-10-29 | Vertically integrated field-effect transistor having a nanostructure therein |
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DE10250868A DE10250868B8 (de) | 2002-10-31 | 2002-10-31 | Vertikal integrierter Feldeffekttransistor, Feldeffekttransistor-Anordnung und Verfahren zum Herstellen eines vertikal integrierten Feldeffekttransistors |
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WO2005071754A1 (de) * | 2004-01-22 | 2005-08-04 | Infineon Technologies Ag | Halbleiter-leistungsschalter sowie dafür geeignetes herstellungsverfahren |
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Also Published As
Publication number | Publication date |
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US20060128088A1 (en) | 2006-06-15 |
US7709827B2 (en) | 2010-05-04 |
DE10250868A1 (de) | 2004-05-19 |
EP1556909A1 (de) | 2005-07-27 |
DE10250868B8 (de) | 2008-06-26 |
DE10250868B4 (de) | 2008-03-06 |
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