WO2004036994A1 - 水和性顆粒剤よりなる農園芸用粒状組成物 - Google Patents
水和性顆粒剤よりなる農園芸用粒状組成物 Download PDFInfo
- Publication number
- WO2004036994A1 WO2004036994A1 PCT/JP2003/013427 JP0313427W WO2004036994A1 WO 2004036994 A1 WO2004036994 A1 WO 2004036994A1 JP 0313427 W JP0313427 W JP 0313427W WO 2004036994 A1 WO2004036994 A1 WO 2004036994A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- granules
- composition
- salt
- water
- parts
- Prior art date
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
- A01N25/14—Powders or granules wettable
Definitions
- Emulsions are mostly produced by dissolving active agricultural chemicals in organic solvents and adding an emulsifier to the resulting solution. Therefore, an emulsion can be produced only when the pesticidal active ingredient is soluble in an organic solvent. In emulsions, organic solvents that are commonly used are flammable, and there is a risk of fire. Handling, transport, and storage require careful consideration. Emulsions also have problems with toxicity and chemical damage associated with the use of organic solvents.
- a surfactant having a strong wet spreading effect may be added, especially in order to improve disintegration in water and dispersibility in water.
- a surfactant having a strong wet spreading effect may be added, especially in order to improve disintegration in water and dispersibility in water.
- the present invention contains at least one solid or liquid pesticidal active ingredient (a) as an active ingredient, and further comprises a sulfonate-type surfactant, a sulfate ester-type surfactant, and phosphoric acid.
- a granular composition comprising a hydratable granule having low foamability, characterized by comprising hydratable granules containing the hydratable granules.
- insecticides include BPMC, BPPS, BRP, a crystal toxin produced by the bacterium Bacillus thuringiensis, a crystal toxin produced by the spore of Bacillus thuringiensis, CVMP, CVP, CYAP, DDVP, DEP, DMTP, ECP, EPN, ESP, MEP, MIPC, MPP, MTMC, NAC, PAP, PHCs PMP, XMCs achrinathrin, acequinosyl, acetamipride, acephtoit, amitraz, aranicarp, arethrin, isresin, isresin Imido®, cloprid, indoxacarp, ethiofencarp, ethione, ethylthiomethone, etoxazole, etofenprox, etophofos, emamectin benzoate, oxamyl,
- alkanolamine salts include polyoxyethylene alkyl ether sulfates (eg, sodium salts of polyoxyethylene lauryl ether sulfate, ammonium salts, alkanolamines), polyoxyethylene aryl ethers ⁇ acid ester salts (for example, sodium salt of polyoxyethylene nonylphenyl sulfate, ammonium salt, alkanolamine salt, sodium salt of polyoxyethylene styrylphenyl sulfate, ammonium salt, ammonium salt) Salt and alkanolamine salt).
- polyoxyethylene alkyl ether sulfates eg, sodium salts of polyoxyethylene lauryl ether sulfate, ammonium salts, alkanolamines
- polyoxyethylene aryl ethers ⁇ acid ester salts for example, sodium salt of polyoxyethylene nonylphenyl sulfate, ammonium salt, alkanolamine salt, sodium salt of polyoxyethylene st
- Examples of the phosphate ester type surfactant used in the composition of the present invention include alkyl phosphate ester salts (for example, sodium salt, ammonium salt, alkanolamine salt of lauryl phosphate ester) and polyoxyphosphate.
- alkyl phosphate ester salts for example, sodium salt, ammonium salt, alkanolamine salt of lauryl phosphate ester
- polyoxyphosphate for example, sodium salt, ammonium salt, alkanolamine salt of lauryl phosphate ester
- Ethylene alkyl ester phosphate eg, sodium salt, ammonium salt, alkanolamine salt of polyoxyethylene lauryl ester sulfate
- polyoxyethylene phosphate ester salt eg, polyoxyethylene nonylphenyl ester
- composition of the present invention other surfactants other than those described above, for example, polyoxyethylene alkyl ether, polyoxyalkylene alkyl ether, polyoxyethylenestyrylphenyl ether, 1 ter, polyoxyalkylene styrylphenyl ether, polyoxyethylene alkylaryl ether, polyoxyethylene alkyl ester, polyoxyethylene sorbitan alkyl ester, sorbitan alkyl ester, polyoxyethylene polyoxypropylene block copolymer 1.
- a nonionic surfactant such as polyoxyethylene castor oil and acetylene glycol; and an anionic surfactant such as polycarboxylate and resinate can also be added.
- examples of water-soluble fatty acid metal salts having 6 to 28 carbon atoms include sodium salts of mixed (C 6 to C 28 ) fatty acids or mixed (C 6 -C 28) potassium fatty acid salts or sodium laurate, myristic acid sodium, sodium Roh palmitic acid, sodium stearate, Orein acid sodium ⁇ beam, sodium elaidate, sodium brassidic acid, potassium force prills acid, lauric acid Potassium, potassium myristate, potassium normitate, potassium stearate or potassium oleate.
- the content of the kieselguhr in the granule is usually about 10 to 90% by weight on a weight basis.
- the proportion of the solid carrier can be changed according to the concentration of the active ingredient and the surfactant in the granules. From the viewpoint of improving granulation properties and disintegration in water, preferably, about 50 to 90% by weight of kieselguhr can be blended with the granules.
- the compounded cassot or processed cassid acts as an excipient during granulation.
- the kneaded material is usually granulated into columnar fine granules by an extrusion granulator provided with a die having a hole having a diameter of 0.1 to 5 mm, preferably 0.2 to 2 mm, and the obtained granulated material is subjected to granulation.
- the granular composition of the present invention comprising the desired granules can be obtained by a formulation method comprising drying, classifying through an appropriate sieve according to the set particle size, and obtaining granules having a desired particle size.
- the pesticidal active ingredient, surfactant and defoamer to the appropriate amount of water, add the required amount of carrier if necessary, and add the required other components in the required amount.
- the obtained mixture is subjected to a wet mill such as a ball mill, a dyno mill, a sand grinder, etc., and if necessary, other components such as a surfactant and a carrier are added in an appropriate amount to the obtained aqueous suspension and mixed.
- the mixture thus obtained is put into an extrusion-type granulator to form a granulated kneaded product, and the mixture is granulated into desired granules to obtain the granular composition of the present invention. You can also.
- the kneaded material was granulated into columnar fine particles using an extrusion granulator equipped with a screen die having a pore diameter of 0.6 mm. After drying the granulated material at 60 ° C., the dried granulated material was sieved with a set of 16 mesh sieves and a set of 48 mesh sieves placed under the sieve while shaking. The fines remaining on the 48 mesh sieve were harvested. As a result, granules having a desired particle size of 0.3 to L.Omm were obtained as a granular composition comprising the hydratable granules of the present invention.
- the mixture was pulverized using a jetizer.
- the kneaded product was granulated using an extrusion granulator equipped with a screen die having a pore diameter of 0.6 mm. After drying the granulated material at 60 ° C., the dried granulated material was sieved with a 16 mesh sieve and a 48 mesh sieve as in Example 1. The fines remaining on the 48 mesh sieve were harvested. Thereby, granules having a desired particle size of 0.3 to L. Omm were obtained as a granular composition of the hydratable granule of the present invention.
- Example 7 After drying at 60 ° C., the dried granules were sieved with a 16 mesh sieve and a 48 mesh sieve as in Example 1. The fines remaining on the 48 mesh sieve were harvested. Thus, hydratable granules having a particle size of 0.3 to 1.0 mm were obtained. This granule is a sample for comparison with the granule of Example 7.
- the present invention provides a new granular composition comprising a wettable granule containing a pesticide as an active ingredient, and this composition is useful and can be used in the agricultural field.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP03758745A EP1559319A4 (en) | 2002-10-22 | 2003-10-21 | PARTICULATE COMPOSITION CONTAINING AGGREGATE OR HORTICULTURE AGING AGENT |
AU2003275569A AU2003275569A1 (en) | 2002-10-22 | 2003-10-21 | Agricultural or horticultural particulate composition comprising wettable granular agent |
JP2004546431A JPWO2004036994A1 (ja) | 2002-10-22 | 2003-10-21 | 水和性顆粒剤よりなる農園芸用粒状組成物 |
US10/532,108 US20060013846A1 (en) | 2002-10-22 | 2003-10-21 | Agricultural or horticultural particulate composition comprising wettable granular agent |
BR0315539-0A BR0315539A (pt) | 2002-10-22 | 2003-10-21 | Composição granular para agricultura ou horticultura compreendendo grânulos disporsìveis em água |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2002306780 | 2002-10-22 | ||
JP2002-306780 | 2002-10-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004036994A1 true WO2004036994A1 (ja) | 2004-05-06 |
Family
ID=32170914
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2003/013427 WO2004036994A1 (ja) | 2002-10-22 | 2003-10-21 | 水和性顆粒剤よりなる農園芸用粒状組成物 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20060013846A1 (ja) |
EP (1) | EP1559319A4 (ja) |
JP (1) | JPWO2004036994A1 (ja) |
AU (1) | AU2003275569A1 (ja) |
BR (1) | BR0315539A (ja) |
WO (1) | WO2004036994A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1830635A2 (en) * | 2004-12-27 | 2007-09-12 | Huntsman LLC | Reduced foam dispersions and formulations therefor |
JP2008537534A (ja) * | 2004-12-27 | 2008-09-18 | ハンツマン・コーポレーシヨン・オーストラリア・ピーテイワイ・リミテツド | 泡を低減させた分散液およびこのための製剤 |
WO2014133178A1 (ja) * | 2013-02-28 | 2014-09-04 | 住友化学株式会社 | 顆粒水和剤 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090118125A1 (en) * | 2005-06-15 | 2009-05-07 | Nissan Chemical Industries, Ltd. | Water Dispersible Agricultural Chemical Granules and Method of Producing the Same |
JP5122841B2 (ja) * | 2006-03-24 | 2013-01-16 | 石原産業株式会社 | 除草組成物 |
TWI501728B (zh) | 2008-04-07 | 2015-10-01 | Bayer Cropscience Ag | 生物控制劑與殺蟲劑或殺真菌劑之組合物 |
EP2273873A4 (en) * | 2008-04-07 | 2011-09-07 | Bayer Cropscience Lp | STABLE AQUEOUS FORMULATION CONTAINING SPORES |
WO2009130910A1 (ja) * | 2008-04-25 | 2009-10-29 | 日本曹達株式会社 | 顆粒状農薬組成物及びその製造方法 |
CN101379993B (zh) * | 2008-08-06 | 2011-07-20 | 张少武 | 一种噻菌灵的杀菌水分散颗粒剂 |
MX2011005798A (es) * | 2008-12-01 | 2011-06-20 | Kumiai Chemical Industry Co | Procedimiento para producir una composicion agricola quimica particulada dispersable en agua. |
ES2603384T3 (es) * | 2012-05-25 | 2017-02-27 | Bayer Cropscience Ag | Estabilización química de sal de yodosulfuron-metil-sodio mediante hidroxiestearatos |
KR102160178B1 (ko) * | 2016-08-31 | 2020-09-28 | 마이크론 테크놀로지, 인크 | 메모리 어레이 |
EP3846624A4 (en) * | 2018-09-07 | 2022-05-11 | Rhodia Operations | SURFACTANT COMPOSITION AND USE |
US20210195894A1 (en) * | 2018-09-07 | 2021-07-01 | Rhodia Operations | Surfactant composition and use thereof |
CN113142200A (zh) * | 2021-04-20 | 2021-07-23 | 郑州先利达化工有限公司 | 吲哚丁酸-多效唑颗粒剂及制备方法 |
Citations (2)
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JPH10109905A (ja) * | 1996-10-03 | 1998-04-28 | Kumiai Chem Ind Co Ltd | 粒状農薬組成物及びその散布方法 |
EP1157612A1 (en) * | 1999-12-28 | 2001-11-28 | Nippon Soda Co., Ltd. | Granular water-dispersible agents and process for producing the same |
Family Cites Families (8)
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US2965510A (en) * | 1958-06-02 | 1960-12-20 | Phillips Petroleum Co | Carbon black slurries and method of preparation |
JPS60204701A (ja) * | 1984-03-30 | 1985-10-16 | Toho Chem Ind Co Ltd | 低起泡性農薬水和剤組成物 |
DE3627070A1 (de) * | 1986-08-09 | 1988-02-11 | Bayer Ag | Verwendung von magnesiumstearat als entschaeumer |
HUT69067A (en) * | 1992-06-16 | 1995-08-28 | Du Pont | Dry flowable agricultural compositions of glyphosate |
JP2001010915A (ja) * | 1999-07-01 | 2001-01-16 | Shionogi & Co Ltd | バチルス・チューリンゲンシス顆粒状農薬製剤 |
US6620421B1 (en) * | 1999-10-05 | 2003-09-16 | Sumitomo Chemical Company, Limited | Water dispersible granules |
JP4292657B2 (ja) * | 1999-11-12 | 2009-07-08 | 住友化学株式会社 | 顆粒状水和剤 |
US6596292B2 (en) * | 2000-06-22 | 2003-07-22 | Sumitomo Chemical Company, Limited | Solid pesticidal formulation |
-
2003
- 2003-10-21 EP EP03758745A patent/EP1559319A4/en not_active Withdrawn
- 2003-10-21 BR BR0315539-0A patent/BR0315539A/pt not_active IP Right Cessation
- 2003-10-21 US US10/532,108 patent/US20060013846A1/en not_active Abandoned
- 2003-10-21 AU AU2003275569A patent/AU2003275569A1/en not_active Abandoned
- 2003-10-21 WO PCT/JP2003/013427 patent/WO2004036994A1/ja active Application Filing
- 2003-10-21 JP JP2004546431A patent/JPWO2004036994A1/ja active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JPH10109905A (ja) * | 1996-10-03 | 1998-04-28 | Kumiai Chem Ind Co Ltd | 粒状農薬組成物及びその散布方法 |
EP1157612A1 (en) * | 1999-12-28 | 2001-11-28 | Nippon Soda Co., Ltd. | Granular water-dispersible agents and process for producing the same |
Non-Patent Citations (1)
Title |
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See also references of EP1559319A4 * |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1830635A2 (en) * | 2004-12-27 | 2007-09-12 | Huntsman LLC | Reduced foam dispersions and formulations therefor |
JP2008537534A (ja) * | 2004-12-27 | 2008-09-18 | ハンツマン・コーポレーシヨン・オーストラリア・ピーテイワイ・リミテツド | 泡を低減させた分散液およびこのための製剤 |
EP1830635A4 (en) * | 2004-12-27 | 2011-09-14 | Huntsman Llc | DISPERSIONS WITH REDUCED FOAM RATE AND ASSOCIATED FORMULATIONS |
JP4917046B2 (ja) * | 2004-12-27 | 2012-04-18 | ハンツマン・コーポレーシヨン・オーストラリア・ピーテイワイ・リミテツド | 泡を低減させた分散液およびこのための製剤 |
CN102696585A (zh) * | 2004-12-27 | 2012-10-03 | 胡茨曼澳大利亚股份有限公司 | 减少泡沫的分散体及其制剂 |
CN102696585B (zh) * | 2004-12-27 | 2015-01-14 | 胡茨曼澳大利亚股份有限公司 | 减少泡沫的分散体及其制剂 |
WO2014133178A1 (ja) * | 2013-02-28 | 2014-09-04 | 住友化学株式会社 | 顆粒水和剤 |
US20160007592A1 (en) * | 2013-02-28 | 2016-01-14 | Sumitomo Chemical Company, Limited | Water dispersible granules |
JPWO2014133178A1 (ja) * | 2013-02-28 | 2017-02-09 | 住友化学株式会社 | 顆粒水和剤 |
US9808000B2 (en) | 2013-02-28 | 2017-11-07 | Sumitomo Chemical Company, Limited | Water dispersible granules |
Also Published As
Publication number | Publication date |
---|---|
EP1559319A1 (en) | 2005-08-03 |
US20060013846A1 (en) | 2006-01-19 |
BR0315539A (pt) | 2005-08-23 |
JPWO2004036994A1 (ja) | 2006-05-18 |
EP1559319A4 (en) | 2006-12-20 |
AU2003275569A1 (en) | 2004-05-13 |
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