WO2004014631A1 - Verfahren und vorrichtung zur herstellung einer vorformlings aus kunststoff - Google Patents
Verfahren und vorrichtung zur herstellung einer vorformlings aus kunststoff Download PDFInfo
- Publication number
- WO2004014631A1 WO2004014631A1 PCT/DE2003/002620 DE0302620W WO2004014631A1 WO 2004014631 A1 WO2004014631 A1 WO 2004014631A1 DE 0302620 W DE0302620 W DE 0302620W WO 2004014631 A1 WO2004014631 A1 WO 2004014631A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- molded part
- cylindrical
- preform
- blank
- stage
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/36—Moulds for making articles of definite length, i.e. discrete articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/36—Moulds for making articles of definite length, i.e. discrete articles
- B29C43/42—Moulds for making articles of definite length, i.e. discrete articles for undercut articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/06—Making preforms by moulding the material
- B29B11/12—Compression moulding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B11/00—Making preforms
- B29B11/14—Making preforms characterised by structure or composition
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/36—Moulds for making articles of definite length, i.e. discrete articles
- B29C43/361—Moulds for making articles of definite length, i.e. discrete articles with pressing members independently movable of the parts for opening or closing the mould, e.g. movable pistons
- B29C2043/3615—Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices
- B29C2043/3631—Forming elements, e.g. mandrels or rams or stampers or pistons or plungers or punching devices moving in a frame for pressing and stretching; material being subjected to compressing stretching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/0715—Preforms or parisons characterised by their configuration the preform having one end closed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/07—Preforms or parisons characterised by their configuration
- B29C2949/072—Preforms or parisons characterised by their configuration having variable wall thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/20—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
- B29C2949/22—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at neck portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/20—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
- B29C2949/24—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at flange portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/20—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
- B29C2949/26—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at body portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/20—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer
- B29C2949/28—Preforms or parisons whereby a specific part is made of only one component, e.g. only one layer at bottom portion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3024—Preforms or parisons made of several components characterised by the number of components or by the manufacturing technique
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2949/00—Indexing scheme relating to blow-moulding
- B29C2949/30—Preforms or parisons made of several components
- B29C2949/3056—Preforms or parisons made of several components having components being compression moulded
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/02—Combined blow-moulding and manufacture of the preform or the parison
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C49/00—Blow-moulding, i.e. blowing a preform or parison to a desired shape within a mould; Apparatus therefor
- B29C49/071—Preforms or parisons characterised by their configuration, e.g. geometry, dimensions or physical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/25—Solid
- B29K2105/253—Preform
- B29K2105/258—Tubular
Definitions
- the invention relates to a method and a device for producing a preform according to the preamble of claim 1.
- preforms are also referred to as preforms. It is a tubular part with a thread in the mouth area. Preforms consist of a thermoplastic material. To produce a container, for example a bottle, the preform is heated and blown into a predetermined shape.
- Injection molding processes are known from the prior art for producing preforms.
- the material is heated so much that it is in liquid form. Temperatures between 250 and 300 degrees Celsius are typically necessary for this.
- the liquefied material is injected into a mold through a nozzle. Since the preforms and thus the injection molds are relatively long, especially for larger containers, the liquefied material in the injection mold must travel a relatively long way. This is only possible if the material is heated to the high temperature mentioned above and working with a high injection pressure.
- a disadvantage of these known methods is that a high amount of energy has to be applied for the heating.
- acetaldehyde is produced at these high temperatures.
- the amount of acetaldehyde in the preform depends on the temperature at which the preform is manufactured. A reduction in the amount of acetaldehyde is therefore only possible through a lower temperature during production. In the case of injection molding processes, the temperature cannot be reduced for the reasons stated above. The high injection pressure also creates shear forces, which lead to additional heating of the material. In addition, it proves to be disadvantageous that, in the injection molding process, the heated material has to displace the air from the entire mold. The volume of this air to be displaced is relatively large.
- the shape of the preform is at least partially determined by the injection molding process. For example, the bottom of the preform can only be curved, since otherwise it cannot be guaranteed that the material will fill the entire mold during injection molding.
- the inventive method and the inventive device for producing preforms according to claim 1 have the advantage that the preform is not produced by injection molding but by the action of pressure and the occurrence of a suction effect.
- compression molding is referred to as compression molding.
- This technical term has also become established in the German-speaking world.
- the above-mentioned disadvantages of the injection molding process do not occur with compression molding.
- the material is introduced into an outer molded part in the form of a round block. In this form, the material is also called pellet.
- an inner molded part exerts pressure on the pellet by a driven relative axial movement of the two molded parts.
- the pellet is formed into a blank between the inner and the outer molded part. In the first stage, the pellet turns into a blank.
- This blank already shows the Mouth area and the bottom of the preform.
- a relatively short cylindrical section extends in between. Due to the inner and outer molded part, this has a larger diameter and a larger wall thickness and a shorter length than the cylindrical section of the preform.
- all of the air is displaced from the space between the inner and the outer molded part. Since the volume of the space in the first stage of production is smaller than the volume of the preform, a smaller volume of air is displaced in the method according to the invention than in the injection molding method.
- the blank is transferred to the preform.
- the inner molded part exerts additional pressure on the blank, the bottom of the outer molded part being lowered relative to the side walls.
- the cylindrical area of the blank lengthens.
- the short cylindrical section of the blank with a large wall thickness merges into a long cylindrical section of the preform with a small wall thickness.
- a bead remains between the mouth region and the cylindrical section, the diameter of which corresponds to the diameter of the cylindrical region of the blank.
- the blank and the preform match.
- the mouth area and the bottom no longer change in this second stage.
- the thickness of the soil is specified in the first stage of the manufacturing process. When the desired thickness is reached in the first stage, the second stage begins and the inner molded part and the bottom of the outer molded part move downwards at the same time, so that the distance between the two molded parts in the region of the floor no longer changes in the second stage changed.
- the tool for producing the preform essentially consists of an inner and an outer molded part.
- the inner molded part is designed as a cylindrical mandrel.
- the outer molded part has a bottom and cylindrical side walls.
- the cylindrical side walls have two sections: a first section with a larger diameter and a second section with a smaller diameter.
- a drive ensures a relative axial movement of the two molded parts.
- thermoplastic material under pressure lower temperatures are necessary than with injection molding, since the material does not have to be liquefied as much. Temperatures between 100 and 200 degrees Celsius are usually sufficient. This temperature is about 100 degrees Celsius lower than the temperature in the injection molding process. This has the advantage that acetaldehyde is produced in a much smaller amount, that less energy is required during production and that the temperature of approx. 60 to 80 degrees Celsius, at which the finished preform can be removed from the molded parts, is reached more quickly. Since the material does not cool down during the molding process like in injection molding, the molding process can be designed individually.
- the shape of the floor is not determined by the manufacturing process and can therefore be chosen almost arbitrarily. In addition to a spherical base as in the injection molding process, angular shapes are also possible.
- the inner and outer molded part are moved in opposite directions. So that the preform is not damaged, it must be cooled to a temperature of approx. 80 degrees Celsius.
- the inner and / or the outer molded part are supported by springs.
- springs can be mechanical springs, for example helical springs, or pneumatic or hydropneumatic pressure boosters. Other spring-like devices are also possible.
- rods are provided which are seated on the outer molded part in a first stage, in which a blank is formed from the material present as a pellet. It is thereby achieved that in the second stage of manufacture the cylindrical side walls of the outer molded part no longer change their position, while the inner molded part and the bottom of the outer molded part simultaneously lower.
- Receptacles for the rods can be provided on the outer molding. Instead of the rods and receptacles, other devices are possible which achieve the same effect.
- FIG. 1 different stages of the method according to the invention
- FIG. 2 different positions of the tool in the method according to FIG. 1,
- Figure 3 arrangement of several tools in a circle.
- FIGS. 1 and 2 Various stages of the method and the device according to the invention are shown in FIGS. 1 and 2.
- the left part of FIG. 1 shows the insertion of a pellet 1 in the direction of the arrow into an outer molded part 2.
- the outer molded part 2 has a bottom 3 with a spherical shape and cylindrical side walls 4.
- the central part of FIG. 1 shows the first stage of production.
- the inner molded part 5 which is designed as a cylindrical mandrel, has been moved in the direction of the arrow by a drive which cannot be seen in the drawing. Since the outer molded part 2 has not changed its position, the pellet 1 is deformed by pressure and merges into a blank 6.
- the base 7 and the mouth region 8 of the preform are already formed.
- a threaded molded part 9 is provided on the inner molded part 5.
- a cylindrical region 10 is created between the bottom 7 and the mouth region 8.
- the blank 6 is tightly enclosed on all sides by the inner and outer molded parts 2 and 5. All the air is thus displaced from the space between the inner and the outer molded part.
- the inner molded part 5 is moved further in the direction of the arrow. This is shown in the right part of Figure 1.
- the bottom 3 of the outer molded part 2 lowers.
- the blank 6 deforms into the preform 11.
- the cylindrical region 10 of the blank 6 is elongated.
- the amount of material in the cylindrical region 10 of the blank 6 must be such that it is sufficient to form the cylindrical region 12 of the preform 11.
- the cylindrical side walls 4 of the outer molded part have a first section 13 with a larger diameter and a second section 14 with a smaller diameter.
- a bead 15 remains at the transition between the mouth area 8 and the cylindrical area 12. This bead is formed on the step-shaped transition 16 between the first and the second section 13, 14 of the cylindrical side walls 4.
- the threaded molded part 9 presses against the bead 15 from above ,
- FIG. 2 shows the various stages of manufacture, together with the device.
- I shows the tool before the pellet 1 is introduced.
- the pellet 1 is already in the outer molded part 2.
- IM corresponds to the first stage of production, in which the pellet 1 has already been pre-compressed into a blank 6.
- IV shows the second stage of production, in which the blank 6 is formed into a preform 11.
- V the finished preform 11 is removed from the tool.
- the coil spring 17 can be seen, over which the inner molded part 5 is mounted.
- FIG. 2 also shows the rods 18, with which the part of the tool surrounding the inner molded part 5 is supported on the outer molded part 2.
- receptacles 19 are provided on the outer molded part.
- III does not move the inner molded part downwards but the outer molded part upwards. The effect is the same, however, because the relative movement of the two molded parts is important.
- Several devices for producing a preform can either be arranged linearly in a row as in FIG. 2 or in a circle as in FIG. 3. This means that several preforms can be produced at the same time.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU2003258479A AU2003258479A1 (en) | 2002-08-05 | 2003-08-04 | Method and device for producing a plastic preform |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10235845A DE10235845A1 (de) | 2002-08-05 | 2002-08-05 | Verfahren und Vorrichtung zur Herstellung einer Preform aus thermoplastischem Werkstoff zur Fertigung eines Behälters |
DE10235845.1 | 2002-08-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2004014631A1 true WO2004014631A1 (de) | 2004-02-19 |
Family
ID=30775019
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/DE2003/002620 WO2004014631A1 (de) | 2002-08-05 | 2003-08-04 | Verfahren und vorrichtung zur herstellung einer vorformlings aus kunststoff |
Country Status (3)
Country | Link |
---|---|
AU (1) | AU2003258479A1 (de) |
DE (1) | DE10235845A1 (de) |
WO (1) | WO2004014631A1 (de) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IT201800010919A1 (it) | 2018-12-10 | 2020-06-10 | Sacmi | Apparato e metodo per formare un oggetto concavo. |
MX2023001547A (es) * | 2020-08-05 | 2023-03-08 | Sacmi | Metodo y aparato de moldeo por compresion. |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1335219A (fr) * | 1961-07-28 | 1963-08-16 | Ici Ltd | Procédé de fabrication d'objets façonnés par moulage par compression de matières plastiques |
GB1232684A (de) * | 1967-06-01 | 1971-05-19 | ||
US3757718A (en) * | 1966-12-13 | 1973-09-11 | Shell Oil Co | Method for forming hollow articles of work-stengthenable plastic materials |
US4122147A (en) * | 1978-03-23 | 1978-10-24 | The Continental Group, Inc. | Method of making multilayer containers |
US4512735A (en) * | 1981-11-26 | 1985-04-23 | Plm Ab | Apparatus for blow molding a container having an upward bulged bottom |
US4649013A (en) * | 1982-07-08 | 1987-03-10 | Toyo Seikan Kaisha, Limited | Method of making a plastic cap |
EP0506872A1 (de) * | 1989-12-26 | 1992-10-07 | Dow Chemical Co | Verfahren und vorrichtung zur herstellung von mehrschichtigen kunststoffgegenständen. |
US6349838B1 (en) * | 1998-12-25 | 2002-02-26 | Toyo Seikan Kaisha, Ltd. | Plastic bottle and method of producing the same |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1704022C3 (de) * | 1967-08-08 | 1975-10-09 | Enzinger-Union-Werke Ag, 6800 Mannheim | Verfahren und Vorrichtung zum Herstellen und anschließenden Füllen und Verschließen von flaschenförmigen Hohlkörpern aus Kunststoff |
US4419320A (en) * | 1980-10-22 | 1983-12-06 | The Goodyear Tire & Rubber Company | Novel process for deep stretch forming of polyesters |
JPS6071207A (ja) * | 1983-09-29 | 1985-04-23 | Toyo Seikan Kaisha Ltd | 延伸ブロー成形用多層プリフォームの製造方法 |
JPH0635147B2 (ja) * | 1990-11-28 | 1994-05-11 | 東洋製罐株式会社 | 耐圧容器用プリフォーム及び耐圧容器の製造方法 |
US5971740A (en) * | 1998-02-03 | 1999-10-26 | The Elizabeth And Sandor Valyi Foundation, Inc. | Process and apparatus for producing a container |
-
2002
- 2002-08-05 DE DE10235845A patent/DE10235845A1/de not_active Withdrawn
-
2003
- 2003-08-04 WO PCT/DE2003/002620 patent/WO2004014631A1/de not_active Application Discontinuation
- 2003-08-04 AU AU2003258479A patent/AU2003258479A1/en not_active Abandoned
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1335219A (fr) * | 1961-07-28 | 1963-08-16 | Ici Ltd | Procédé de fabrication d'objets façonnés par moulage par compression de matières plastiques |
US3757718A (en) * | 1966-12-13 | 1973-09-11 | Shell Oil Co | Method for forming hollow articles of work-stengthenable plastic materials |
GB1232684A (de) * | 1967-06-01 | 1971-05-19 | ||
US4122147A (en) * | 1978-03-23 | 1978-10-24 | The Continental Group, Inc. | Method of making multilayer containers |
US4512735A (en) * | 1981-11-26 | 1985-04-23 | Plm Ab | Apparatus for blow molding a container having an upward bulged bottom |
US4649013A (en) * | 1982-07-08 | 1987-03-10 | Toyo Seikan Kaisha, Limited | Method of making a plastic cap |
EP0506872A1 (de) * | 1989-12-26 | 1992-10-07 | Dow Chemical Co | Verfahren und vorrichtung zur herstellung von mehrschichtigen kunststoffgegenständen. |
US6349838B1 (en) * | 1998-12-25 | 2002-02-26 | Toyo Seikan Kaisha, Ltd. | Plastic bottle and method of producing the same |
Also Published As
Publication number | Publication date |
---|---|
DE10235845A1 (de) | 2004-02-26 |
AU2003258479A1 (en) | 2004-02-25 |
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