WO2003063812A1 - Preparation pour coloration capillaire - Google Patents

Preparation pour coloration capillaire Download PDF

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Publication number
WO2003063812A1
WO2003063812A1 PCT/JP2002/000586 JP0200586W WO03063812A1 WO 2003063812 A1 WO2003063812 A1 WO 2003063812A1 JP 0200586 W JP0200586 W JP 0200586W WO 03063812 A1 WO03063812 A1 WO 03063812A1
Authority
WO
WIPO (PCT)
Prior art keywords
acid
hair dye
hair
component
alcohol
Prior art date
Application number
PCT/JP2002/000586
Other languages
English (en)
Japanese (ja)
Inventor
Katsunori Yoshida
Haruhiko Inoue
Koichi Kinoshita
Masatoshi Ochiai
Katsuo Hashimoto
Yasunari Nakama
Original Assignee
Shiseido Company, Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to JP2001000973A priority Critical patent/JP4079597B2/ja
Application filed by Shiseido Company, Ltd. filed Critical Shiseido Company, Ltd.
Priority to PCT/JP2002/000586 priority patent/WO2003063812A1/fr
Priority to KR10-2004-7011549A priority patent/KR20040074132A/ko
Priority to US10/502,356 priority patent/US7166136B2/en
Publication of WO2003063812A1 publication Critical patent/WO2003063812A1/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair

Definitions

  • the present invention relates to a hair dye.
  • it is excellent in stability, feeling in use (smoothness), and dyeability, and it also relates to a hair acid hair dye that does not require much time and effort after washing.
  • Hair dyes for dyeing hair are widely used, for example, as “white hair dye” and “fashionable dye”.
  • This hair dye naturally contains a coloring agent for coloring the hair to a desired color, and as such a coloring agent, an “acid dye” which exhibits the best hair dyeing effect in the acidic region is used. It is mentioned as one of the most suitable because of its excellent safety.
  • azo-based acid dyes are mainly used as coloring agents of “semi-permanent hair dyes” intended to sustain the hair coloring effect semi-permanently, and the need for acid dyes in hair dyes is great.
  • the "acid hair dye” which is a hair dye using such an acid dye as a coloring agent, needs to adjust the pH range to a strongly acidic range of 1.5 to 4.5 at the time of use.
  • natural dyes are also used in terms of dyeability and color, but when natural dyes are blended, their use in the acidic region is desirable in terms of mildness to hair and the like. Those which can exhibit a dyeing effect in such an acidic region are preferably used. In such an acidic region, it is generally practiced to add a thickener so that the strongly acidic hair dye does not sag during use and does not come in contact with the hair dye.
  • thickeners usable in p H of the strong acid region is rather limited, yet even thickeners are said to be used in a strongly acidic region, thickeners you formulated hair dye Are not always completely satisfactory. That is, xanthan gum can be mentioned as the main slimming agent currently used for acid-based hair dye (Japanese Patent Publication No. 2-32253), and in addition to xanthan gum, Ben as a improver. A system in which tonite and z or a crosslinkable sodium polyacrylate are used in combination has been used (Japanese Patent Application Laid-Open No. 5-51099).
  • the hair dye containing xanthan gum which has been known to date, is stable at pH 4.5 or higher, but exerts a dyeing effect, but its viscosity is strong in the strongly acidic region of pH 1.5 to 4.5. Changed significantly and there was a problem with stability. In addition, it can not be denied that it has poor fluidity, and when applied from the hand to the head, it tends to be clumped down and difficult to stretch in the hair. Furthermore, it was accompanied by a sticky feeling of use, and it was not satisfactory for the feeling of use.
  • the present invention has been made in view of the above circumstances, and is stable even in a strongly acidic region (p H 1 .5 to 4.5) that exerts the coloring effect of an acid dye, and has an appropriate viscosity, Furthermore, it aims to provide a hair dye that is excellent in feel on use and does not require time-consuming washing after use. Disclosure of the invention
  • CO— represents a saturated or unsaturated fatty acid residue (asyl group) having an average of 10 to 22 carbon atoms
  • a represents one — or one NR — (wherein R represents a hydrogen atom, or Represents an alkyl group having 1 to 3 carbon atoms)
  • Mi represents a hydrogen atom, an alkali metal, an alkaline earth metal, an ammonium or an organic amine
  • n represents an integer of 1 to 3
  • Ashirusuruhon acid salt anionic Ion surfactant represented 0 / o, 25-25 0.
  • B a fatty alcohol. 0 weight 0/0, and
  • C A hair dye comprising an acid dye and Z or a natural dye is provided. .
  • (A) component: (B) component 1: 2.5 to 1:50 (weight ratio).
  • the long chain acid sulfonate type anionic surfactant as the component (A) is represented by the following general formula (I).
  • I ⁇ CO- represents a saturated or unsaturated fatty acid residue (asyl group) having an average of 10 to 22 carbon atoms.
  • I ⁇ CO CuH CC C 12 H 25 CO, C 13 H 27 CO, C 14 H 29 CO, C 15 H 31 CO, C 16 H 33 CO, C 17 H 35 CO, coconut fatty acid residue, palm palm Fatty acid residues and the like are exemplified.
  • I ⁇ CO preferably has an average carbon atom number of 12 to 22.
  • a represents one 0- or one NR- (wherein R represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms). These are electron donating groups. As a, one hundred, one NH, one N (CH 3 ), one strength s is preferable.
  • IV ⁇ is a hydrogen atom, an alkali metal, an alkaline earth metal, an ammonium or Represents organic amines.
  • M include lithium, potassium, sodium, calcium, magnesium, ammonium, monoethanolamine, diethanolamine, triethanolamine, sodium taurine, N-methyltaurine sodium and the like.
  • a compound in which a is — that is, a long-chain isethionate type anionic surfactant, cocoyl isethionate, stearoyl isethionate, lauryl Examples include isethionate, myristoyl isethionate and the like.
  • a compound in which a represents —NH— that is, a long chain sodium taurate salt type anionic surfactant, N-lauroyl taurine salt, N-cococy taurine salt, N-myristoyl taurine salt , N-stearoyl taurine salt and the like are exemplified.
  • a compound in which a represents one N (CH 3 ) one, that is, as a long chain acyl methyl taurine salt type anionic surfactant, N-lauroyl-N-methyltaurine salt, N -Palmitoyl mono-N-methyl taurine salt, N-stearoyl mono-N-methyl taurine salt, N-cocoyl mono-N-methyl taurine salt etc. are illustrated.
  • N-stearoyl-N-methyl taurine salt is particularly preferable as the component (A).
  • the component (A) can be used alone or in combination of two or more.
  • the amount of the component in hair dyes total amount from 0.1 to 1 0. 0 weight 0/0, the preferred properly is from 0.5 to 5.0 weight 0/0. 0. If it is less than 1 wt 0/0, the crystallization of the aliphatic alcohols Ichiru as the component (B), the stability is lowered, and a smooth feeling can not be obtained at the time of rinsing, whereas, 1 0. 0 weight If it is more than 10%, stability and safety are reduced due to low viscosity. 3 ⁇ 4: Produce.
  • component (B) for example, linear alcohol such as lauryl alcohol, cetyl alcohol, stearyl alcohol, phenyl alcohol, myristyl alcohol, oleyl alcohol, cetosaryl alcohol, hardened rapeseed oil alcohol, jojoba alcohol etc.
  • branched alcohols such as monostearylglycerin ether (batyl alcohol), 2-decyl tetrate radinol, lanolin alcohol, cholesterol, phytosterol, hexidodecanol, isostearyl alcohol, octotridodecanol, and the like.
  • linear alcohols are preferred.
  • the component (B) can be used alone or in combination of two or more.
  • the blending amount of the component (B) is 0.2 to 55.0% by weight based on the total amount of the hair dye. If it is less than 0.5% by weight, the stability is lowered due to the low viscosity, while if it is more than 25.0% by weight, no smooth feeling is obtained at the time of rinsing, and the dyeing effect on the hair is reduced.
  • the component (A) and the component (B) form a gel, which is a conventional trimethyl ammonium type cationic surfactant and a long chain alkyl alcohol.
  • the gel formed by the component (A) and the component (B) is anionic, it does not form a complex with the acid dye or natural pigment which is the component (C) described later. ) It can coexist stably with the ingredients. As a result, it has become possible to prepare a hair dye which is excellent in stability (especially viscosity stability) and excellent in dyeability with an unprecedented feeling of smooth use.
  • the acid dye is not particularly limited as long as it can be used for a hair dye, and it is not limited thereto, and it is a nitroto dye, azo dye, nitroso dye, trifenylmethane dye, xanthene dye, quinoline dye, Anthraquinone dyes, indigo dyes and the like can be mentioned. Specifically, for example, Red No. 2, Red No. 3, Red No. 102, Red No. 104, Red No. 105, Red No. 106, Red No. 201, Red No. 220, Red 2 7, Red 2 3 0, Red 2 3 1, Red 2 3 2, Red 4 0 1, Red 5 0 2, Red 5 0 3, Red 5 0 4, Red 5 No.
  • oil-based dyes include, for example, Red No. 215, Red No. 218, Red No. 225, Orange No. 201, Orange No. 206, Yellow No. 201, Yellow No. 204 , Green 202, Purple 201, Red 501, Red 505, Orange 400, Yellow 400, Yellow 405, Blue 400 .
  • the natural pigment is not particularly limited as long as it can be used as a hair dye, and examples thereof include carotenoids, anthraquinones, flavonoids (anthocyanins, chalcones, flavones), porphyrins, and diketones. And betasyphanin type, azophyllone type etc.
  • one or more of acid dyes and natural dyes can be used.
  • the blending amount of the component (C) is preferably 0.01 to 20.0% by weight based on the total amount of the hair dye. 0. 0 0 is less than 1 wt% not sufficient dyeing effect to the hair, while 2. And degree force great-of stain adhesion to hands at 0 weight 0/0 greater, also causes a reduction in the safety bee Become.
  • a low pH region which exerts the effect of the component (C) component force, for example, about pH 1.5 to 4.5. Even in the low pH region, gel formation by the (A) component and the (B) component can maintain an extremely stable viscosity, and it is excellent in usability and dyeing with excellent hair dyeability. T / JP 02/00586 Hair is provided.
  • the hair dye of the present invention has a low viscosity change rate and is excellent in viscosity stability. Specifically, for example, with respect to the viscosity after storing the hair dye of the present invention at a temperature of 45 ° C. for 28 days, when the long-term stability of viscosity is evaluated by the change rate of viscosity shown in the following formula A hair dye excellent in long-term viscosity stability of 0.8 to 1 can be obtained.
  • Rate of change of viscosity 2 (45 ° C., viscosity after storage for 28 days) / (viscosity after 1 hour of production)
  • the viscosity can be measured with a B-type viscometer.
  • the viscosity of the systems of hair family of the present invention, 2000 ⁇ 50000m 'P as (25T :) about what is preferred force s, 50000 m - may P the as greater even.
  • optional additional components can be optionally blended.
  • an organic acid, an inorganic acid or a salt thereof can be suitably blended as a pH regulator to adjust the pH of the hair dye of the present invention to a strongly acidic region.
  • organic acids or salts thereof include propanoic acid, butanoic acid, butanedioic acid, pentanic acid, hexanoic acid, citric acid, lactic acid, tartaric acid, phthalic acid, L-glutamic acid, glycolic acid, DL-glutamic acid, taurine, N- methyl taurine, Kuen trisodium, lactated Natoriumu equipotent s.
  • inorganic acid or salt thereof carbonic acid, hydrochloric acid, sulfuric acid, phosphoric acid, salts Ihinatoriumu, and s potassium chloride force.
  • lactic acid, citric acid, tartaric acid, glycolic acid, and salts of these, which are widely used in cosmetics, are preferably used.
  • R 2 represents a hydrogen atom, a methyl group or a methoxy group
  • Show
  • aromatic alcohols monohydric aliphatic alcohols, polyhydric aliphatic alcohols and the like.
  • aromatic alcohol examples include benzyl alcohol, phenethyl alcohol, y-phenylpropyl alcohol, key peel alcohol, anice alcohol, p-methylbenzyl alcohol, dimethyldimethyl ethyl alcohol, ⁇ -phenylethanol And hydroxyethanol and the like.
  • benzyl alcohol is preferable in view of the dyeability effect and the like.
  • monohydric aliphatic alcohols include ⁇ , ethanol, butanol, isopropanol, cyclohexanol, etc.
  • polyhydric aliphatic alcohols include ethylene glycol, propylene glycol, butylene glycol, dipropylene glycol, hexylene glycol, isoprene glycol, glycerin etc. '
  • ⁇ -methyl pyrrolidone methyl cellosolve
  • acetyl cellulose methyl carbitol
  • acetyl carbitol methyl carbitol
  • These hair dye assistants can be blended 1 type or 2 types or more. Distribution total amount of hair dye auxiliaries, in hair dye based on the total amount of 0.5 to 15 wt% strength 5 'weight, more preferably from 1 to 1 0% by weight.
  • non-volatile silicone-based conditioning components may be blended in order to further improve the usability.
  • components for example, in addition to dimethylpolysiloxane, methylphenylpolysiloxane, amino-modified primary polysiloxane, polyether silicone, etc. are preferably used.
  • the non-volatile silicone is usually blended into the hair dye as an oil, but may be blended as a component to be prepared as an emulsion.
  • silicone When added as an emulsion, it may be either mechanically dispersed or emulsion polymerized, and the particle size may be used without particular limitation, but it is preferably about 10 nm to 1 mm.
  • the properties of silicone may be any of oil, rubber, resin, and powder, and may be linear or cross-linked, and its viscosity is also particularly limited. Not
  • other components generally used in the hair dye can be used as long as the effects of the present invention are not impaired, if necessary.
  • components include cationic surfactants, lanolin derivatives, protein derivatives, oil components, humectant components, plant extracts such as herbal medicines, and cationic 'anion' non-ionic water These include molecules, sequestering agents, preservatives, bactericides, ultraviolet absorbers, antioxidants, colorants, and perfumes.
  • the buffer capacity of the hair dye of the present invention is preferably 0.01 to 2.0 g equivalent / 1.
  • the term “buffering capacity” as used herein refers to a value determined by the following formula using the concentration of the base required to increase the pH of a 10% aqueous solution of a hair dye at 25 ° C. by 1 from the initial value. It is.
  • Buffering capacity d C s / dp H-(wherein, C s represents the ion concentration of base ( ⁇ equivalent 1))
  • the hair dye of the present invention is suitably used as a one-component hair dye, and can be applied to hair nail polish and force rinse.
  • the present invention will be described in more detail based on examples given below, but the invention is in no way limited thereby.
  • the compounding amount is% by weight.
  • “Dimethylpolysiloxane emulsion polymer (1)” has a silicone particle diameter of 200 nm, a viscosity of 100, OOO cs (25 ° C.) , it was used for the active component 4 0 wt 0/0.
  • the viscosity (30 ° C.) after 1 hour of sample production was measured by a B-type viscometer (12 rpm / min). .
  • the rate of change in viscosity was calculated by the following equation, and evaluated according to the following evaluation criteria.
  • the state of the sample after production was stored for 28 days in a thermostat at each temperature of 45 ° C., 25 ° C., and 15 ° C. was visually observed and evaluated according to the following evaluation criteria.
  • the hair dye of the present invention shows little or no decrease in viscosity when stored for a long period of time, even in a strongly acidic region that exhibits the dyeing effect of an acid dye, In addition, it is turbid, does not have the ability to cause precipitation and separation, has excellent stability, has no hair squeezing upon rinsing, it does not feel well after drying, and has an excellent feeling in use. Furthermore, the hair dye of the present invention is within the allowable range of adhesion to the skin during use, and it does not take time and effort to wash it off after use. (Example 1 7)
  • the hair dye manufactured by the above-mentioned method according to the conventional method is excellent in stability, high in dyeability and leveling ability, good in color and lack of sticky feeling in use, and after washing and after drying. There was no squeaky feeling, and the degree of stain on the hand was also acceptable. In addition, p H was 2.5.
  • Bentonite 1 7 Dipropylene glycol 2.0 citric acid 1.0
  • the hair dye manufactured by the above-mentioned method according to the conventional method is excellent in stability, high in dyeability and leveling ability, good in color and lack of sticky feeling in use, and after washing and after drying. There was no squeaky feeling, and the degree of stain on the hand was also acceptable. In addition, p H was 2.2.
  • the hair dye manufactured by the above-mentioned method according to the conventional method is excellent in stability, is excellent in dyeability and leveling ability, good in color and lack of sticky feeling in use, and is further washed off and dry. There was no squeaky feeling behind, and the degree of stain on the hand was also within the acceptable range.
  • the pH was 2.1. .
  • composition component (% by weight)
  • the hair dye manufactured by the above-mentioned method according to the conventional method is excellent in stability, high in dyeability and leveling ability, good in color and lack of sticky feeling in use, and after washing and after drying. There was no squeaky feeling, and the degree of stain on the hand was also acceptable.
  • the pH was 1.8.
  • composition component (% by weight)
  • the hair dye manufactured by the above-mentioned method according to the conventional method is excellent in stability, high in dyeability and leveling ability, good in color and lack of sticky feeling in use, and after washing and after drying. There was no squeaky feeling, and the degree of stain on the hand was also acceptable.
  • the pH was 2.5.
  • composition component (% by weight)
  • the hair dye produced by the above method according to the conventional method is excellent in stability, is excellent in dyeability and leveling ability, good in color, and has no feeling of uselessness, and further, There was no feeling of squeaking at the time of washing and after drying, and the degree of stain on the hand was also within the allowable range.
  • the pH was 4.0.
  • the hair dye manufactured by the above-mentioned method according to the conventional method is excellent in stability, high in dyeability and leveling ability, good in color and lack of sticky feeling in use, and after washing and after drying. There was no squeaky feeling, and the degree of stain on the hand was also acceptable. PH was 3.8.
  • the hair dye manufactured by the above-mentioned method according to the conventional method is excellent in stability, high in dyeability and leveling ability, good in color and lack of sticky feeling in use, and after washing and after drying. There was no squeaky feeling, and the degree of stain on the hand was also acceptable.
  • the pH was 4.2. Industrial applicability

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une préparation pour coloration capillaire contenant (A) 0,1 à 10,0 % en poids d'un tensioactif anionique spécifique de type sel d'acide acylsulfonique à longue chaîne, (B) 0,25 à 25,0 % en poids d'alcool aliphatique, et (C) un colorant acide et/ou un pigment naturel. Cette préparation pour coloration capillaire est stable même lorsqu'elle se trouve dans une zone fortement acide (pH compris entre 1,5 et 4,5) où elle présente un effet colorant. Cette préparation possède une viscosité moyenne et est agréable à utiliser. En outre, une fois utilisée, cette préparation s'enlève facilement.
PCT/JP2002/000586 2001-01-09 2002-01-28 Preparation pour coloration capillaire WO2003063812A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2001000973A JP4079597B2 (ja) 2001-01-09 2001-01-09 染毛料
PCT/JP2002/000586 WO2003063812A1 (fr) 2001-01-09 2002-01-28 Preparation pour coloration capillaire
KR10-2004-7011549A KR20040074132A (ko) 2002-01-28 2002-01-28 염모제
US10/502,356 US7166136B2 (en) 2001-01-09 2002-01-28 Hairdye preparation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2001000973A JP4079597B2 (ja) 2001-01-09 2001-01-09 染毛料
PCT/JP2002/000586 WO2003063812A1 (fr) 2001-01-09 2002-01-28 Preparation pour coloration capillaire

Publications (1)

Publication Number Publication Date
WO2003063812A1 true WO2003063812A1 (fr) 2003-08-07

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PCT/JP2002/000586 WO2003063812A1 (fr) 2001-01-09 2002-01-28 Preparation pour coloration capillaire

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JP (1) JP4079597B2 (fr)
WO (1) WO2003063812A1 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017222138A (ja) * 2016-06-17 2017-12-21 共同印刷株式会社 積層体及びチューブ容器

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JP4731109B2 (ja) * 2003-10-31 2011-07-20 株式会社 資生堂 ゲル状組成物およびそれを用いたクリーム組成物
JP4968774B2 (ja) * 2006-08-11 2012-07-04 株式会社 資生堂 クリーム組成物
JP4982858B2 (ja) * 2007-06-08 2012-07-25 国立大学法人京都工芸繊維大学 酸化染毛剤の製造方法
DE102008046883A1 (de) * 2008-09-11 2010-03-18 Henkel Ag & Co. Kgaa Haarbehandlungsmittel mit Spirulina-Extrakt
MX2019002587A (es) * 2016-09-28 2019-07-01 Unilever Nv Mezclas de defi y taurato amida y procesos de las mismas.
RU187816U1 (ru) * 2018-04-02 2019-03-19 Федеральное государственное казенное военное образовательное учреждение высшего образования "Военная академия материально-технического обеспечения имени генерала армии А.В. Хрулёва" Оптико-электронный модуль переносного пассивного прибора разведки

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KR0123072B1 (ko) * 1993-12-02 1997-11-13 성재갑 헤어컨디셔너 조성물
JP2001089335A (ja) * 1999-09-24 2001-04-03 Sanei Kagaku Kk 毛髪用染毛料組成物
JP2001213739A (ja) * 2001-03-12 2001-08-07 Sanei Kagaku Kk 毛髪処理剤配合用組成物及び毛髪処理剤
JP2001213737A (ja) * 2001-03-12 2001-08-07 Sanei Kagaku Kk 毛髪処理剤配合用組成物及び毛髪処理剤
JP2001213738A (ja) * 2001-03-12 2001-08-07 Sanei Kagaku Kk 毛髪処理剤配合用組成物及び毛髪処理剤

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR0123072B1 (ko) * 1993-12-02 1997-11-13 성재갑 헤어컨디셔너 조성물
JP2001089335A (ja) * 1999-09-24 2001-04-03 Sanei Kagaku Kk 毛髪用染毛料組成物
JP2001213739A (ja) * 2001-03-12 2001-08-07 Sanei Kagaku Kk 毛髪処理剤配合用組成物及び毛髪処理剤
JP2001213737A (ja) * 2001-03-12 2001-08-07 Sanei Kagaku Kk 毛髪処理剤配合用組成物及び毛髪処理剤
JP2001213738A (ja) * 2001-03-12 2001-08-07 Sanei Kagaku Kk 毛髪処理剤配合用組成物及び毛髪処理剤

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2017222138A (ja) * 2016-06-17 2017-12-21 共同印刷株式会社 積層体及びチューブ容器

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JP2002205923A (ja) 2002-07-23

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