WO2003004715A1 - Fine feuille d'alliage a faible dilatation thermique, et masque perfore faisant intervenir son utilisation - Google Patents
Fine feuille d'alliage a faible dilatation thermique, et masque perfore faisant intervenir son utilisation Download PDFInfo
- Publication number
- WO2003004715A1 WO2003004715A1 PCT/JP2002/006785 JP0206785W WO03004715A1 WO 2003004715 A1 WO2003004715 A1 WO 2003004715A1 JP 0206785 W JP0206785 W JP 0206785W WO 03004715 A1 WO03004715 A1 WO 03004715A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- thermal expansion
- alloy sheet
- present
- shadow mask
- coefficient
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J29/00—Details of cathode-ray tubes or of electron-beam tubes of the types covered by group H01J31/00
- H01J29/02—Electrodes; Screens; Mounting, supporting, spacing or insulating thereof
- H01J29/06—Screens for shielding; Masks interposed in the electron stream
- H01J29/07—Shadow masks for colour television tubes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0205—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips of ferrous alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01J—ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
- H01J2229/00—Details of cathode ray tubes or electron beam tubes
- H01J2229/07—Shadow masks
- H01J2229/0727—Aperture plate
- H01J2229/0733—Aperture plate characterised by the material
Definitions
- the present invention is a low thermal expansion alloy sheet, in particular, be used in the CRT of the shadow mask or the like, 1.0 X 10- 6 IK excellent in productivity and etching property
- the present invention relates to a low-thermal-expansion alloy sheet having an average thermal expansion coefficient of 20 to 100 ° C. and a shadow mask using the same. Background art
- Fe-Ni alloys containing approximately 36% Ni have an extremely low coefficient of thermal expansion near room temperature, so they can be used in precision equipment, pi-metals, shadow masks for computer and television bran tubes, etc. Widely used.
- Japanese Patent No. 2694864 discloses that the content of Ni is 34% or more, Mn is 0.1% or less, C is less than 0.009%, the balance is Fe and unavoidable impurities, and the average thermal expansion from around room temperature to 100 ° C. coefficient lower low thermal ⁇ nickel alloy full 1 X 10- 6 I has been proposed for the shadow mask.
- FIG. 1 is a diagram showing the relationship between Mn + Si + Al and the average thermal expansion coefficient at 20-100 ° C.
- Embodiment the present inventors of the implementation of the invention the cracking and breakage during production, or no flaw occurred, stable 1.0 average thermal expansion coefficient of the X 10- 6 / K or less of 20-100 is obtained and, The following findings were obtained as a result of a study on low thermal expansion alloy sheets that provide good etching properties and dimensional accuracy during shadow mask production.
- Ni is an essential element for obtaining a low coefficient of thermal expansion. 20-100 The average thermal expansion coefficient of ° C to less 1.0 X 10- 6 / K is the amount and 35.0-37.0%.
- Mn, Si, A1 break in hot rolling and cold rolling, cracks, and prevent the occurrence of flaws, the Netsu ⁇ Choritsu below 1.0 X 10- 6 / K, the defective etching and dimensional accuracy defect of the shadow mask
- fine oxides are formed on the surface of the thin plate during heat treatment in the manufacturing process to deteriorate the etching properties, and to prevent electron beam scattering and increase heat dissipation as in the case of shadow masks. In some cases, the formation of a dense and high-black film is hindered, and the coefficient of thermal expansion is further increased.
- the respective amounts of Mn and Si must be 0.09%, 0.04% or less, and 0.04% or less. Further, as shown in FIG. 1, in order to stably obtain a coefficient of thermal expansion of 1.0 ⁇ 10 ′′ 6 / K or less, it is necessary to set Mn + Si + A1 ⁇ 0.15%.
- Mn is a strong sulfide-forming element, and fixes S, which causes grain boundary embrittlement during hot working, as a sulfide to improve hot workability and cracks in bulk rolling, forging, hot rolling, etc. And work to prevent breakage.
- Mn I S needs to be 20 or more.
- Mn / S exceeds 300, the Mn amount becomes excessive even if Mn is 0.09% or less, causing the above-mentioned problem.
- 0 0 is not only a cause of cracking during hot rolling, flaws during cold rolling, and poor etching during the formation of oxidized products, but also inhibits the growth of crystal grains during heat treatment and leads to the formation of fiber bundles. Since it may have an effect and it may be difficult to stably secure a low coefficient of thermal expansion, the content is preferably set to 0.005% or less.
- S Since S causes grain boundary embrittlement during hot working, it causes cracks and fractures in spreading, forging, and hot rolling, and segregation occurs when S that cannot be completely fixed by Mn increases. Since the hot workability and the etching property are greatly reduced in a strong portion, the content is preferably 0.002% or less.
- the low-thermal-expansion alloy sheet of the present invention can be produced by melting, sintering, hot rolling, It can be manufactured by cold rolling and annealing.
- a slab having a thickness of 100 to 400 mm is produced by melting an alloy having the above-mentioned composition and forming it by a continuous forming method or an ingot forming method.
- hot rolling is performed at 800 ° C or higher to obtain a sheet having a thickness of 2 to 4 mm, and cold rolling and annealing are performed once or more times to obtain a desired thin sheet.
- Fe-Ni alloy No. 1-21 with the component composition shown in Table 1 was melted, formed into a hot rolled sheet by slab rolling and hot rolling, pickled, cold rolled and annealed, if necessary Tension leveler treatment and strain relief annealing were performed to produce 0.1 mm and 0.2 mm thin sheets.
- “ ⁇ ” indicates that it could be manufactured without any problem
- “X” indicates that it had a fracture or a flaw.
- the thin plate thus obtained was subjected to a heat treatment at 850 ° C for 15 min, and then the average thermal expansion coefficient at 20-100 ° C was measured by an optical interference thermal dilatometer.
- the determining the maximum value, as the difference between the maximum value and the minimum value is more than 0.5 X 10- 6 / K is the lack of stability of the preparation X as measured by 10 for each alloy did. Furthermore, a resist film having a large number of circular holes with an opening diameter of 90 m is formed on the surface of the obtained thin plate, and a ferric chloride solution having a solution temperature of 40 ° C or more and a concentration of 40% or more is applied at 30 to 50 MPa.
- a hole with a diameter of 100-200 m was drilled in the thin plate by etching at a pressure of, and the presence or absence of abnormalities in the hole shape of 100 holes, and the dimensional accuracy with respect to the average diameter, that is, the variation of the hole diameter were investigated.
- a hole having a high roundness and a dimensional accuracy of ⁇ 3% or less was indicated by “ ⁇ ”, and a hole having a low roundness and a dimensional accuracy exceeding ⁇ 3% was indicated by “X”.
- Alloy Nos. 1-10 of the present invention exhibited good manufacturability without cracking or breakage in hot rolling or cold rolling.
- the etching property was good and an extremely low coefficient of thermal expansion was obtained.
- alloy No. 11-21 of the comparative example was inferior in either property. That is, in No.ll, the value of Mn + Si + A1 is out of the range of the present invention, so that a low coefficient of thermal expansion cannot be obtained. In No. 12, a low coefficient of thermal expansion cannot be obtained because the amount of Mn, the amount of Si, the value of Mn + Si + Al, and the value of Mn / S are out of the range of the present invention. In the case of N0.13, the values of Mn amount and Mn / S are out of the range of the present invention, so that they are cracked or broken by hot rolling, resulting in poor productivity.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Electrodes For Cathode-Ray Tubes (AREA)
- Heat Treatment Of Steel (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP02745824A EP1403393A4 (en) | 2001-07-05 | 2002-07-04 | FINE ALLOY SHEET WITH LOW THERMAL EXPANSION, AND PERFORATED MASK USING THE USE THEREOF |
KR10-2003-7002951A KR100519615B1 (ko) | 2001-07-05 | 2002-07-04 | 저열팽창 합금박판 및 이를 이용한 새도우 마스크 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001204212 | 2001-07-05 | ||
JP2001-204212 | 2001-07-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2003004715A1 true WO2003004715A1 (fr) | 2003-01-16 |
Family
ID=19040715
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2002/006785 WO2003004715A1 (fr) | 2001-07-05 | 2002-07-04 | Fine feuille d'alliage a faible dilatation thermique, et masque perfore faisant intervenir son utilisation |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1403393A4 (ja) |
KR (1) | KR100519615B1 (ja) |
CN (1) | CN1200130C (ja) |
WO (1) | WO2003004715A1 (ja) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3854121B2 (ja) * | 2001-10-22 | 2006-12-06 | 日本冶金工業株式会社 | 耐食性に優れるシャドウマスク素材用Fe−Ni系合金およびシャドウマスク材料 |
CN105648323A (zh) * | 2016-01-13 | 2016-06-08 | 铜陵百荣新型材料铸件有限公司 | 一种镍铁合金材料及其制备工艺 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4402684A1 (de) * | 1993-05-27 | 1994-12-01 | Krupp Vdm Gmbh | Ausdehnungsarme Eisen-Nickel-Legierung |
JPH09176797A (ja) * | 1995-12-27 | 1997-07-08 | Nikko Kinzoku Kk | シャドウマスク用Fe−Ni−Cr系合金素材およびそれから作製したシャドウマスク |
JP2001192775A (ja) * | 2000-01-05 | 2001-07-17 | Nisshin Steel Co Ltd | 架張方式のシャドウマスク用Fe−Ni合金薄板 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19920144C1 (de) * | 1999-05-03 | 2000-08-03 | Krupp Vdm Gmbh | Eisen-Nickel-Legierung |
-
2002
- 2002-07-04 EP EP02745824A patent/EP1403393A4/en not_active Withdrawn
- 2002-07-04 WO PCT/JP2002/006785 patent/WO2003004715A1/ja not_active Application Discontinuation
- 2002-07-04 CN CNB028022955A patent/CN1200130C/zh not_active Expired - Fee Related
- 2002-07-04 KR KR10-2003-7002951A patent/KR100519615B1/ko not_active IP Right Cessation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4402684A1 (de) * | 1993-05-27 | 1994-12-01 | Krupp Vdm Gmbh | Ausdehnungsarme Eisen-Nickel-Legierung |
JPH09176797A (ja) * | 1995-12-27 | 1997-07-08 | Nikko Kinzoku Kk | シャドウマスク用Fe−Ni−Cr系合金素材およびそれから作製したシャドウマスク |
JP2001192775A (ja) * | 2000-01-05 | 2001-07-17 | Nisshin Steel Co Ltd | 架張方式のシャドウマスク用Fe−Ni合金薄板 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1403393A4 * |
Also Published As
Publication number | Publication date |
---|---|
CN1200130C (zh) | 2005-05-04 |
KR20030024922A (ko) | 2003-03-26 |
EP1403393A1 (en) | 2004-03-31 |
CN1464915A (zh) | 2003-12-31 |
KR100519615B1 (ko) | 2005-10-07 |
EP1403393A4 (en) | 2005-01-05 |
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