WO2003002670A1 - Nouveau materiau a base de silicone, son procede de preparation et son utilisation - Google Patents

Nouveau materiau a base de silicone, son procede de preparation et son utilisation Download PDF

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Publication number
WO2003002670A1
WO2003002670A1 PCT/CN2001/001064 CN0101064W WO03002670A1 WO 2003002670 A1 WO2003002670 A1 WO 2003002670A1 CN 0101064 W CN0101064 W CN 0101064W WO 03002670 A1 WO03002670 A1 WO 03002670A1
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Prior art keywords
product
silicone rubber
weight
cross
linking agent
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Application number
PCT/CN2001/001064
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English (en)
French (fr)
Inventor
K. C. Ricky Yeung
Original Assignee
Sar Holdings International Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Sar Holdings International Limited filed Critical Sar Holdings International Limited
Priority to EP01980123A priority Critical patent/EP1408088B1/en
Priority to CNB018235824A priority patent/CN100369975C/zh
Priority to DE60126436T priority patent/DE60126436T2/de
Priority to ES01980123T priority patent/ES2281448T3/es
Priority to AU2002212049A priority patent/AU2002212049B2/en
Priority to US10/482,638 priority patent/US7169884B2/en
Priority to PCT/CN2001/001064 priority patent/WO2003002670A1/zh
Priority to AT01980123T priority patent/ATE353091T1/de
Publication of WO2003002670A1 publication Critical patent/WO2003002670A1/zh
Priority to HK05103780A priority patent/HK1070914A1/xx

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/003—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor characterised by the choice of material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2021/00—Use of unspecified rubbers as moulding material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/0097—Glues or adhesives, e.g. hot melts or thermofusible adhesives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/011—Crosslinking or vulcanising agents, e.g. accelerators

Definitions

  • the present invention relates to a new silicone rubber material, which is solid and highly viscous.
  • the invention also relates to a method for preparing the silicone rubber material and its application in non-slip automatic pasting. Background technique
  • pressure-sensitive adhesive silicone resins which are fluid or liquid are disclosed. Such an adhesive is inconvenient to handle and it is difficult to maintain the same thickness.
  • a method of applying a pressure-sensitive adhesive silicone resin to a substrate is disclosed in Japanese Patent 62225580.
  • U.S. Patent No. 5023288 a method of applying a pressure-sensitive adhesive silicone resin to a substrate is further disclosed. This method aims to improve the tensile strength of the pressure-sensitive adhesive silicone resin to obtain a thinner thickness.
  • Pressure-sensitive adhesive silicone resin film material From the above prior art, it can be seen that the application of pressure-sensitive adhesive silicone resin adhesive is limited to the method of applying pressure-sensitive adhesive silicone resin to a substrate to make an adhesive tape. The pressure-sensitive adhesive silicone adhesive itself has been limited to liquid use alone.
  • a method of joining a silicone rubber-coated fabric using a pressure-sensitive adhesive silicone resin is disclosed in US4889576.
  • the silicone rubber-coated fabric can be formed by calendering, knife coating or dip coating the silicone rubber composition, followed by thermal curing or standing at room temperature.
  • the pressure-sensitive adhesive silicone resin is composed of a diorganopolysiloxane, an organohydrogenpolysiloxane, a Pt-type catalyst, and a reinforcing agent filler that can be connected to silicon; or a diorganopolysiloxane, Organic peroxide and enhancer composition.
  • a silicone rubber-coated fiber is laminated with a pressure-sensitive adhesive silicone resin, followed by pressure bonding and heat curing.
  • Another object of the present invention is to provide a method for preparing the silicone rubber material.
  • Another object of the present invention is to provide the application of the silicone rubber material product prepared by the method of the present invention in the non-slip automatic pasting.
  • the present invention uses a commercially available siloxane silica gel raw material, and by mixing and reacting it with a methylsiloxane resin and a crosslinking agent, a solid silicone rubber material having a high viscosity is unexpectedly obtained.
  • the inventors also found that the silicone rubber prepared according to the method of the present invention has a non-slip, self-adhesive property, and can place objects that need to be prevented from moving on it and prevent it from sliding. Invention details
  • the invention relates to a new silicone rubber.
  • the raw material for preparing the silicone rubber includes a diorganopolysiloxane having an alkenyl group which can be connected to silicon, a methylsiloxane resin, and a peroxide crosslinking agent or a Pt and an organohydrogenpolysiloxane crosslinking agent. .
  • a solid silicone rubber material having a high viscosity was unexpectedly obtained.
  • the diorganopolysiloxane having an alkenyl group which can be connected to silicon is preferably a dimethyl vinyl siloxane silica gel, and preferably has a polymerization degree of 7000 to 8000.
  • organohydrogen polysiloxane crosslinking agents are:
  • the organohydrogenpolysiloxane preferably has the following structure:
  • the methylsiloxane resin of the present invention is commercially available.
  • Pt-based catalysts are platinum black, chlorochloric acid, platinum tetrachloride, chloroplatinic acid-olefin complexes, chloroplatinic acid-methylethylene! ⁇ Guyane complexes, etc.
  • the peroxide includes benzoyl peroxide, di 2,4-dichlorobenzoyl peroxide, dicumyl peroxide, di-t-butyl peroxide, p-monochlorobutyl peroxide, 2, 5 -Dimethyl-2,5-di-tert-butylperoxyhexane, di-tert-butylperoxyperoxide, 2,5-dimethyl-2,5-bis (tert-butylperoxy ) Hexane and tert-butylcumyl peroxide.
  • a preferred crosslinking agent is 2,5-dimethyl-2,5-di-tert-butylperoxyhexane, and a more preferred crosslinking agent is commercially available from Shin-Etsu Silicone. Trade names are C-8, C_8A or C-8B crosslinkers.
  • the amount of the cross-linking agent is 0.3 to 4% by weight based on the weight of other raw materials. .
  • the method for preparing the compound of the present invention is as follows: Reaction scheme A: dimethyl vinyl oxane silica gel + peroxide + methyl ⁇ oxane resin — _ product reaction scheme B: dimethyl vinyl siloxane silica gel + organic hydrogen Polysiloxane + methylsiloxane Pt
  • Resin 1 product The molding method of the silicone rubber of the present invention is as follows:
  • Compression molding method refers to the general hydraulic press, the molding pressure is 150 ⁇ 220 tons, the clamping temperature is 120 ° C ⁇ 280'C :. Due to the different size of the cloth, the clamping time is about 200 ⁇ 2000 seconds, and the formula is formed.
  • Injection molding refers to molding with an injection machine, the pressure is 20kg ⁇ 200kg, the temperature is 150 ° C ⁇ 280 ° C, and the time is about 100 ⁇ 1000 seconds.
  • Hot air hardening After being kneaded by multiple rollers, it is fed into the oven at 100 ° C ⁇ 300 ° C with a certain thickness and formed in 100-600 seconds. After the conventional silicone rubber and the cross-linking agent are molded by one of the methods described above, the temperature is 200 ° C. Baking at C for 4 hours gave the product of the present invention.
  • the silicone rubber prepared by the compound of the present invention prepared by the above method has a non-slip, self-adhesive property, and an object that needs to be prevented from moving can be placed on it to prevent it from sliding. It can be close to general mobile phones, sunglasses, cosmetics, papers, letters, photos, or photo frames, etc. It can be placed on the surface of the cabin, ice door, computer screen or toilet wall. Examples
  • Example 3 100 parts by weight of dimethyl ethylene 1-oxane silica gel, 0.5 parts by weight of C-8A, and 10 parts by weight of methylsiloxane resin were uniformly mixed, and then the conventional compression molding method was used at 165. The product was vulcanized under pressure at C for 10 minutes, and baked at 200'C for 4 hours to obtain the product of the present invention.
  • Example 3 100 parts by weight of dimethyl ethylene 1-oxane silica gel, 0.5 parts by weight of C-8A, and 10 parts by weight of methylsiloxane resin were uniformly mixed, and then the conventional compression molding method was used at 165. The product was vulcanized under pressure at C for 10 minutes, and baked at 200'C for 4 hours to obtain the product of the present invention.
  • Example 3 100 parts by weight of dimethyl ethylene 1-oxane silica gel, 0.5 parts by weight of C-8A, and 10 parts by weight of methylsiloxane resin were uniformly mixed, and then the conventional compression molding method was
  • Example 4 100 parts by weight of dimethylethylene ⁇ guaxane silica gel, 1 part by weight of C-8B and 10 parts by weight of methylsiloxane resin are uniformly mixed, and then pressurized at 165 ° C by a conventional compression molding method It was vulcanized for 10 minutes and baked at 200 ° C for 4 hours to obtain the product of the present invention.
  • Example 4 100 parts by weight of dimethylethylene ⁇ guaxane silica gel, 1 part by weight of C-8B and 10 parts by weight of methylsiloxane resin are uniformly mixed, and then pressurized at 165 ° C by a conventional compression molding method It was vulcanized for 10 minutes and baked at 200 ° C for 4 hours to obtain the product of the present invention.
  • Example 4 100 parts by weight of dimethylethylene ⁇ guaxane silica gel, 1 part by weight of C-8B and 10 parts by weight of methylsiloxane resin are uniformly mixed, and then pressurized at 165
  • Example 6 100 parts by weight of dimethyl vinyloxane silica gel, 2 parts by weight of C-8, and 10 parts by weight of methylsiloxane resin are uniformly mixed, and then press-vulcanized at 165 ° C by a conventional injection molding method for 10 minutes. Minutes, at 200. Bake at C for 4 hours to obtain the product of the present invention.
  • Example 6 100 parts by weight of dimethyl vinyloxane silica gel, 2 parts by weight of C-8, and 10 parts by weight of methylsiloxane resin are uniformly mixed, and then press-vulcanized at 165 ° C by a conventional injection molding method for 10 minutes. Minutes, at 200. Bake at C for 4 hours to obtain the product of the present invention.
  • Example 6 100 parts by weight of dimethyl vinyloxane silica gel, 2 parts by weight of C-8, and 10 parts by weight of methylsiloxane resin are uniformly mixed, and then press-vulcanized at 165 ° C by a conventional injection molding method for 10
  • silicone rubber material of the present invention has unexpectedly strong stickiness.
  • the silicone rubber material of the present invention will have different superior properties depending on the hardness of the selected raw materials, as shown in Table 1 (based on Shore A 30 degrees):

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Polymers (AREA)
  • Medicinal Preparation (AREA)

Description

新的硅橡胶材料、 其制备方法及用途
技术领域
本发明涉及一种新的硅橡胶材料， 该材料为固态， 并具有高度的粘性。 本发明还涉及所述硅橡胶材料的制备方法及其在防滑自动粘贴方面的应 用。 背景技术
在先有技术中， 均是只公开了流动的或液态的压敏粘合剂硅树脂。 这 种粘合剂操作不方便， 而且厚度难以保持不变。 在日本专利 62225580中公 开了将压敏粘合剂硅树脂涂于基材上的方法。 而在美国专利 5023288 中则 进一步公开了压敏粘合剂硅树脂'涂于基材上的方法， 这种方法致力于提高 压敏粘合剂硅树脂的拉伸强度， 以得到具有更薄厚度的压敏粘合剂硅树脂 涂膜材料。 从以上的先有技术中可看出， 人们对压敏粘合剂硅树脂粘合剂 的应用仅限于将压敏粘合剂硅树脂涂于基材上而制成胶带的方法。 而压敏 粘合剂硅树脂粘合剂本身的单独使用则一直局限于液态。
在 US4889576中公开了使用压敏粘合剂硅树脂接合硅橡胶涂布的织物 的方法。 其中， 硅橡胶涂布的织物可通过将硅橡胶组合物压延、 刮涂（knife coating ) 或浸涂然后热固化或在室温下静置而成。 而压敏粘合剂硅树脂则 由具有可与硅连接的二有机基聚硅氧烷、 有机氢聚硅氧烷、 Pt型催化剂及 增强剂填料組成； 或由二有机基聚硅氧烷、 有机过氧化物及增强剂组成。 在该篇专利中， 将硅橡胶涂布的纤维与压敏粘合剂硅树脂叠合， 然后进行 压粘和热固化。
总之， 在先有技术中， 还没有自粘性固态硅橡胶的报道。 而本发明则 开辟了全新的领域， 通过本发明的技术解决方案制得的硅橡胶呈固态， 具 有自粘性。 这样的硅橡胶由于其具有黏性， 又呈固态， 具有广泛的应用前 景。 发明目的
本发明的一个目的是提供一种具有高度粘性的固态硅橡胶材料。
本发明的另一个目的是提供所述硅橡胶材料的制备方法。
本发明的再一个目的是提供由本发明的方法制备的硅橡胶材料产品在 防滑自动粘贴方面的应用。 发明概述
本发明使用市售的硅氧烷硅胶原材料， 通过将其与甲基硅氧烷树脂 和交联剂混合并反应， 出乎意料地得到了具有高度黏性的固态硅橡胶材料。 本发明人还发现， 按照本发明方法制得的硅橡胶具有防滑自动粘贴的性能, 可将需要防止走动的物件置于其上而防止其滑动。 发明详迷
本发明涉及一种新的硅橡胶。
制备该硅橡胶的原料包含具有可与硅连接链烯基的二有机基聚硅氧 烷， 甲基硅氧烷树脂， 及过氧化物交联剂或 Pt与有机氢聚硅氧烷交联剂。 通过将上面所述原料混合并反应， 出乎意料地得到了具有高度黏性的固态 硅橡胶材料。
下面将详细解释本发明。
所述具有可与硅连接链烯基的二有机基聚硅氧烷 优选为二甲基乙烯 基硅氧烷硅胶， 优选具有 7000 - 8000的聚合度。
有机氢聚硅氧烷交联剂的例子有：
三甲基硅氧基封端的甲基氢聚硅氧烷，
三甲基硅氧基封端的二甲基硅氧烷-甲基氢硅氧烷共聚物，
二甲基苯基硅氧基封端的甲基苯基硅氧烷甲基氢硅氧烷共聚物。
有机氢聚硅氧烷优选具有以下的结构：
Figure imgf000004_0001
本发明的甲基硅氧烷树脂可从市场上买到。 本发明优选使用具有如下 的网状结构的甲基佳氧烷树脂， 其聚合度优选为 7000-8000，
Figure imgf000004_0002
Pt性催化剂的例子有铂黑、 氯舶酸、 四氯化铂、 氯铂酸-烯烃配合物、 氯铂酸 -甲基乙烯！ ^圭氧烷配合物等。
所述过氧化物包括过氧化苯甲酰、 过氧化二 2, 4 -二氯苯甲酰， 过氧 化二枯基， 过氧化二叔丁基， 过氧化对-一氯丁基， 2, 5-二甲基 -2, 5-二- 叔丁基过氧基己烷， 二叔丁基过氧基过氧化物， 2， 5 -二甲基 - 2, 5 -双 (叔丁基过氧基） 己烷及叔丁基枯基过氧化物。 优选的交联剂为 2， 5-二 甲基 -2, 5-二-叔丁基过氧基己烷， 更优选的交联剂为市售的日本信越公司 (Shin-Etsu Silicone)生产的商品名为 C - 8、 C _ 8A或 C - 8B交联剂。 交联 剂的用量为基于其它原料的重量计 0.3 - 4重量 °/。。 制备本发明化合物的方法如下: 反应路线 A: 二甲基乙烯基 氧烷硅胶 +过氧化物 +甲羞^氧烷树脂— _ 产品 反应路线 B: 二甲基乙烯基硅氧烷硅胶 +有机氢聚硅氧烷 +甲基硅氧垸 Pt
树脂一" 产品 本发明硅橡胶的成型方法具体如下：
压縮成型方法-指一般油压机， 成型压力为 150 ~ 220吨， 锁模温度 为 120°C ~ 280'C：。 因反应不同尺布码， 锁模时间在大约为 200 ~ 2000秒不 等， 配方成型。
射出成型： 指用射出机成型， 压力为 20kg ~ 200kg, 温度 150 °C ~ 280 °C , 时间大约为 100 ~ 1000秒。
热风硬化： 经多重辊轮捏合后， 以一定厚度送入 100 °C ~ 300 °C烤箱中， 经 100 - 600秒成型。 将常规硅橡胶和交联剂经上述方法之一成型后， 在 200。C下烘烤 4 小 时， 得到本发明的产品。 采用以上方法制得的本发明化合物制得的硅橡胶具有防滑自动粘贴的 性能， 可将需要防止走动的物件置于其上而防止其滑动。 可紧贴一般手提 电话， 太阳眼镜， 化妆品， 纸条， 信件， 相片， 或相架等， 可放在车厢内 的表板上， 冰拒门、 电脑屏幕上或洗手间的墙壁上。 实施例
实施例 1
将 100重量份的二甲基乙烯 氧烷硅胶、 2重量份的 C - 8和 10重 量份的甲基硅氧烷树脂均匀混合， 然后用常规的压缩成型方法在 165。C下 加压硫化 10分钟， 在 200。C下烘烤 4小时， 得到本发明的产品。 实施例 2
将 100重量份的二甲基乙烯 1 ^氧烷硅胶、 0.5重量份的 C - 8A和 10 重量份的甲基硅氧烷树脂均匀混合， 然后用常规的压缩成型方法在 165。C 下加压硫化 10分钟， 在 200'C下烘烤 4小时， 得到本发明的产品。 实施例 3
将 100重量份的二甲基乙烯^圭氧烷硅胶、 1重量份的 C - 8B和 10 重量份的甲基硅氧烷树脂均匀混合, 然后用常规的压缩成型方法在 165 °C 下加压硫化 10分钟， 在 200°C下烘烤 4小时， 得到本发明的产品。 实施例 4
将 100重量份的二甲基乙烯^氧烷硅胶、 ' 3重量份的 C - 8和 10重 量份的甲基硅氧烷树脂均匀混合， 然后用常规的压缩成型方法在 165°C下 加压硫化 5分钟, 在 200。C下烘烤 4小时， 得到本发明的产品。 实施例 5
将 100重量份的二甲基乙烯 氧烷硅胶、 2重量份的 C - 8和 10重 量份的甲基硅氧烷树脂均匀混合， 然后用常规的射出成型方法在 165 °C下 加压硫化 10分钟， 在 200。C下烘烤 4小时， 得到本发明的产品。 实施例 6
将 100重量份的二甲基乙烯 M氧烷硅胶、 2重量份的 C - 8和 10重 量份的甲基硅氧烷树脂均匀混合， 然后用热风硬化方法在 165 °C下加压硫 化 10分钟， 在 200。C下烘烤 4小时， 得到本发明的产品。 将 100重量份的二甲基乙烯基硅氧烷硅胶、 1.5重量份的 C - 3和 10 重量份的甲基硅氧烷树脂均匀混合， 然后用常规的热风硬化方法在 155 °C 下加压硫化 10分钟， 在 200°C下烘烤 4小时， 得到本发明的产品。 实施例 8
将 100 重量份的二甲基乙烯 氧烷硅胶、 0.5 重量份的有机氢聚硅 氧烷和 Pt、 2.5 重量份的 C - 19 (含 HC≡C 化合物抑制剂， 结构式为 1C≡CR2, Rl与 R2为反应性自由基， 购自曰本信越公司）和 10重量份 的甲基硅氧烷树脂均匀混合， 然后用常规的压缩成型方法在 120°C下加压 硫化 10分钟， 在 200。C下烘烤 4小时， 得到本发明的产品。 本发明的硅橡胶材料出乎意料地具有很强的粘性。 并且， 本发明的硅 橡胶材料依所选择原料的不同硬度会有不同的优越性能， 如表 1 所示的性 能 (以硬度 Shore A 30度计)：
实验项目 规格
比重 (23±2 ) 1.05 - 1.15 硬度 (硬度计 A) 30+10
拉伸强度 (MPa) >1
延伸率 (％) ≥400
撕裂强度 (Crescent A KN/m) >2

Claims

权 利 要 求 书
1、 一种硅橡胶材料产品， 是通过将包括具有可与硅连接链烯基的二 有机基聚硅氧烷、 甲基硅氧烷树脂及交联剂在内的原料进行混合并反应成 型而制得的。
2、 权利要求 1 的产品， 其中所迷的可与硅连接链烯基的二有机基聚 硅氧烷为二甲基乙烯基硅氧烷硅胶。
3、 权利要求 1的产品， 其中甲基硅氧烷树脂具有如下的网状结构：
Figure imgf000008_0001
4、 权利要求 1 - 3之任一项的产品， 其中交联剂为一种过氧化物。
5、 权利要求 4的产品， 其中交联剂为 2, 5-二甲基 -2, 5-二-叔丁基过 氧基己烷。
6、 权利要求 1 - 3之任何一项的产品， 其中交联剂为有机氢聚硅氧烷， 并使用 Pt作催化剂。
7、 杈利要求 1 - 5之任一项的产品， 其中交联剂的用量为基于其它原 料的重量计 0.3 - 4重量。 /。。
8、 权利要求 1 - 7之任一项所述的产品， 其为防滑自动粘贴物。
9、 权利要求 8 的产品， 其为用于紧贴一般手提电话， 太阳眼镜， 化 妆品， 紙条， 信件， 相片， 或相架等， 可放在车厢内的表板上， 冰柜门、 电脑屏幕上或洗手间的墙壁上的物件。
10、 权利要求 1 - 9之任一项的产品的反应成型方法， 其中的成型方 法包括 压缩成型方法、 射出成型方法或热风硬化方法成型。
11. 权利要求 10的反应成型方法， 包括加压硫化及烘烤步骤。
PCT/CN2001/001064 2001-06-28 2001-06-28 Nouveau materiau a base de silicone, son procede de preparation et son utilisation WO2003002670A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
EP01980123A EP1408088B1 (en) 2001-06-28 2001-06-28 Novel silicone material, its preparation method and the use thereof
CNB018235824A CN100369975C (zh) 2001-06-28 2001-06-28 新的硅橡胶材料、其制备方法及用途
DE60126436T DE60126436T2 (de) 2001-06-28 2001-06-28 Neues silikonmaterial, verfahren zu dessen herstellung und dessen verwendung
ES01980123T ES2281448T3 (es) 2001-06-28 2001-06-28 Nuevo material de silicona, su metodo de preparacion y utilizacion del mismo.
AU2002212049A AU2002212049B2 (en) 2001-06-28 2001-06-28 Novel silicone material, its preparation method and the use thereof
US10/482,638 US7169884B2 (en) 2001-06-28 2001-06-28 Silicone material, its preparation method and use thereof
PCT/CN2001/001064 WO2003002670A1 (fr) 2001-06-28 2001-06-28 Nouveau materiau a base de silicone, son procede de preparation et son utilisation
AT01980123T ATE353091T1 (de) 2001-06-28 2001-06-28 Neues silikonmaterial, verfahren zu dessen herstellung und dessen verwendung
HK05103780A HK1070914A1 (en) 2001-06-28 2005-05-04 Novel silicone material, its preparation method and the use thereof

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WO2012116193A1 (en) * 2011-02-25 2012-08-30 Carey & Co. Dry adhesive
US20130005843A1 (en) * 2011-06-30 2013-01-03 Yeung K C Ricky Self-adhesive silicone rubber compositions and articles comprising same
US20130005844A1 (en) * 2011-06-30 2013-01-03 Yeung K C Ricky Self-adhesive silicone rubber compositions and articles comprising same
CN102899000B (zh) * 2012-11-05 2014-12-31 江苏天辰新材料有限公司 一种具有金属自粘性的硅橡胶混合料及其制备方法
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CN103923596B (zh) * 2014-03-25 2016-01-27 安徽神舟飞船胶业有限公司 阳光板专用胶
CN104059242B (zh) * 2014-06-18 2017-05-10 中国科学院宁波材料技术与工程研究所 一种自粘性硅橡胶泡沫材料的制备方法
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CN100369975C (zh) 2008-02-20
EP1408088B1 (en) 2007-01-31
ATE353091T1 (de) 2007-02-15
EP1408088A4 (en) 2004-11-03
AU2002212049B2 (en) 2007-09-06
CN1545537A (zh) 2004-11-10
US7169884B2 (en) 2007-01-30
DE60126436T2 (de) 2007-11-15
HK1070914A1 (en) 2005-06-30
ES2281448T3 (es) 2007-10-01
US20040249089A1 (en) 2004-12-09
DE60126436D1 (de) 2007-03-22
EP1408088A1 (en) 2004-04-14

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