WO2002034388A1 - Compose catalytique purifiant les gaz d'echappement, catalyseur comprenant ledit compose et procede de preparation du compose - Google Patents
Compose catalytique purifiant les gaz d'echappement, catalyseur comprenant ledit compose et procede de preparation du compose Download PDFInfo
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- WO2002034388A1 WO2002034388A1 PCT/JP2000/007506 JP0007506W WO0234388A1 WO 2002034388 A1 WO2002034388 A1 WO 2002034388A1 JP 0007506 W JP0007506 W JP 0007506W WO 0234388 A1 WO0234388 A1 WO 0234388A1
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
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- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
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- B01D—SEPARATION
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- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
- B01D53/8646—Simultaneous elimination of the components
- B01D53/865—Simultaneous elimination of the components characterised by a specific catalyst
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- B01J21/063—Titanium; Oxides or hydroxides thereof
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
- B01J23/22—Vanadium
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- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
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- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0213—Preparation of the impregnating solution
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G39/00—Compounds of molybdenum
- C01G39/006—Compounds containing, besides molybdenum, two or more other elements, with the exception of oxygen or hydrogen
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- B01D2255/207—Transition metals
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- B01D2255/20769—Molybdenum
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- B—PERFORMING OPERATIONS; TRANSPORTING
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- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
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- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
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- C01P2006/82—Compositional purity water content
Definitions
- the present invention relates to an exhaust gas purifying catalyst, and particularly to a catalyst exhibiting high activity in ammonia (NH 3 ) reduction reaction of nitrogen oxide (NO x) and dioxin oxidative decomposition reaction excellent in low-temperature activity and SO x resistance, and its catalyst. It relates to a manufacturing method.
- NH 3 ammonia
- NO x nitrogen oxide
- SO x resistance dioxin oxidative decomposition reaction excellent in low-temperature activity and SO x resistance
- NOx in flue gas emitted from power plants, various factories, automobiles, etc. is a cause of photochemical smog and acid rain.
- Flue gas denitration by selective catalytic reduction using H 3 ) as a reducing agent is widely used mainly in thermal power plants.
- the catalyst vanadium (V), molybdenum (M o) or are used titanium oxide (T i 0 2) catalysts in which the tungsten (W) to the active ingredient, particularly vanadium as one of the active ingredients
- Ti 0 2 catalysts titanium oxide (T i 0 2) catalysts in which the tungsten (W) to the active ingredient, particularly vanadium as one of the active ingredients
- W titanium oxide
- the catalyst is usually used after being formed into a honeycomb shape or a plate shape, and various production methods have been invented.
- the inclusion of highly toxic dioxins in garbage combustion exhaust gas and industrial exhaust gas has become a social problem, and catalysts have been invented that simultaneously perform denitration reactions and oxidatively decompose dioxin.
- catalysts consist of a method of kneading titanium oxide and salts of catalytically active components such as V, Mo and W together with water, followed by molding and firing (kneading method). It is usually prepared by a method of impregnating a mixed solution of salts (impregnation method) (Japanese Patent Application Laid-Open No. 50-128681, Japanese Patent Publication No. 53-341195). etc) .
- the above-mentioned conventional method of preparing a catalyst by a kneading method or an impregnation method is not always the best production method from the viewpoint of the activity of the catalyst, especially when a catalyst having a high low-temperature activity as described above is obtained. There were many aspects that were not suitable.
- Titanium oxide particles and active ingredient salts or oxide particles such as V, Mo, W, etc. are mixed once and then calcined to form a composite, so that the combined effect of V and Mo, W, etc. Not enough, the effect of improving durability by Mo and W is small, and the catalyst has low SO x resistance.
- the compounding of the active ingredient is easier than with the kneading method.
- the active components in the impregnating solution are adsorbed on the titanium oxide during the impregnation process, the active component concentration differs between the inside and the surface of the catalyst, and a plurality of active components can be maintained at a constant ratio in the catalyst. It is difficult, and the optimal combined effect cannot be expected.
- a combination of a kneading method and an impregnation method such as a method of impregnating a titanium oxide molybdenum monoxide carrier with vanadium salts, a method of sequentially impregnating a titanium oxide carrier with W, V, and the like, Attempts have been made to improve the impregnation method, but it is hard to say that a sufficient effect can be obtained.
- An object of the present invention is to provide a catalyst which does not require activation by calcination, which is a hindrance to obtaining a highly active catalyst in the above-mentioned conventional technology, and which sufficiently achieves a complex with V and Mo.
- An object of the present invention is to provide a catalyst having significantly improved activity, especially low-temperature activity and durability.
- the method adopted in the present invention uses a Mo-V composite compound having a specific composition, which does not need to be activated by firing, as an active ingredient, and uses this as a carrier mainly composed of titanium oxide. It is a method of impregnating or kneading after adding to titanium oxide powder. 'That is, the invention claimed in the present application is as follows. (1) rational formula atomic ratio V / Mo of vanadium and molybdenum are 3/2 (NH 4
- An exhaust gas purifying catalyst comprising the water-soluble compound according to (1) supported on a carrier.
- An exhaust gas purifying catalyst characterized by impregnating the water-soluble compound according to (1) into a titanium oxide carrier or kneading it with titanium oxide powder.
- a composition for an exhaust gas purifying catalyst comprising the water-soluble compound according to (1) and a sol such as silica sol.
- An exhaust gas purifying catalyst comprising the composition according to (6) supported on a carrier.
- a catalyst for purifying exhaust gas which is characterized in that the water-soluble compound described in (1) and a sol such as silica sol are mixed in advance and then supported on a titanium oxide carrier or mixed with titanium oxide powder. Manufacturing method.
- the Mo—V composite compound used herein has been found by the present inventors as a result of intensive studies for solving the above-mentioned prior art, and includes ammonium metavanadate (NH 4 VO 3) and molybdenum trioxide (MoO 3 ).
- NH 4 VO 3 ammonium metavanadate
- MoO 3 molybdenum trioxide
- the present inventors have attempted to determine the structure of this compound, but at the present stage, it is formed by adding ammonium monvanadate and molybdenum trioxide, which are hardly soluble in water, to water and stirring for a long time.
- the / 1 / ⁇ 10 ratio is close to 3/2, and only red-brown compounds with high solubility are known. Further, the compound Mo 0 3 - V 2 0 5 , NH 4 V0 3 one molybdate ammonium ((NH 4) 6 ⁇ ⁇ 7 0 24 ⁇ 4 ⁇ 2 0), ⁇ paratungstate ammonium (( ⁇ 4) ⁇ 10 ⁇ Wi 2 0 4 6 - 6 H 2 0) and NH 4 V 0 3, was tried the preparation of NH 4 V 0 3 and similar compounds in combination of a WO 3. From these, the generation of the above high solubility compound unfilled.
- the Mo-V compound referred to in the present invention means a red-brown, highly soluble and stable compound formed by stirring ammonium metavanadate and molybdenum oxide with water.
- the compound itself has high activity, and when it is added to titanium oxide, it does not need to be calcined and activated again, and since Mo and V form a stable compound and are complexed. It provides a highly durable catalyst that is not easily attacked by SOx in exhaust gas.
- the preparation of the catalyst according to the present invention an operation of impregnating the previously prepared titanium oxide carrier at a predetermined concentration with a titanium oxide carrier and then drying is performed. Since the above Mo-V compound does not require activation by firing, it exhibits high activity only by drying, but a firing step may be added if necessary.
- the catalyst using the Mo-V compound of the present invention can be obtained not only by the impregnation method but also by a method of adding the compound to the titanium oxide powder, followed by molding, drying, and, if necessary, firing. Is possible.
- the Mo-V compound used in the catalyst of the present invention is very stable, it does not decompose even when mixed with a sol such as a silicic sol, and the resulting mixed solution is made of titanium oxide.
- a catalyst having both high activity and strength can be obtained.
- the essence of the present invention lies in the use of the novel Mo-V composition that the present inventors have found, and the use of inorganic fibers, other catalyst components, inorganic or organic bonds in a catalyst or titanium oxide. It is not subject to restrictions due to the inclusion of agents.
- the activation is not performed by firing, the highest activity and high durability can be obtained.
- the firing may be performed at 500 ° C. or lower depending on the catalyst strength and the use conditions.
- the amount of the Mo—V compound to be impregnated or added to the titanium oxide is not limited, but is usually not more than 20% (by weight, the same applies hereinafter) of the titanium oxide, and preferably not more than 10%. It is easy to give good results.
- Figure 2 (A) shows the catalyst obtained by the conventional kneading method.
- 1 schematically shows a cross section of a surface layer before firing.
- V compound 1 and M 0 compound 2 each compound particle is formed and mixed with titanium oxide 3.
- the active component be calcined to form an oxide.
- Fig. 2 (B) shows a similar schematic diagram of the stage of drying the catalyst by the conventional impregnation method.
- titanium oxide (T i 0 2 ) It is deposited on the surface of 3 and it is needless to say that activation and compounding by firing are required.
- the difference in affinity between the components and the T i 0 2 in the mixed solution of the impregnated active ingredient (suction force) the distribution of each component in the catalyst appear. Therefore, it is extremely difficult to maintain a uniform ratio of active components throughout the catalyst, and it is difficult to obtain high durability by combining active components.
- FIG. 1 is a schematic diagram of a cross section of the surface layer of the catalyst according to the present invention.
- M 0—V compound 4 having high stability was used. for supporting the catalyst, it is in the state on the surface of T i 0 2 3 M 0 and V already is an active ingredient in the drying completion stage complexed, there is no need to re conjugating Te cowpea firing. Not only that, the supported Mo—V compound itself has high activity and does not require activation by firing.
- a calcination step for causing the active component and the titanium oxide to generate a thin ring is unnecessary, and accordingly, a catalyst having an extremely high activity, particularly a low surface activity that requires a high surface area can be obtained. Even if a calcination step is introduced for reasons other than activation and compounding, the temperature may be as low as possible and a highly active catalyst can be easily obtained.
- the added active ingredient maintains a specific ratio of Mo-V everywhere in the catalyst, which not only does not require special complex treatment, but also always It is possible to obtain a highly active and highly durable catalyst.
- Mo- V compound discovered is extremely stable, shea Rikazoru, T i 0 2 and without even being destroyed by mixing, impregnating a mixed solution of both, used for kneading That you can do it.
- This makes it possible to impregnate or knead the active ingredient with colloidal silica at a time, which has a large strength improving effect, and also makes it possible to greatly simplify the production process.
- the Mo—V compound used in the present invention has a feature that it has a small affinity for Tio 2 and is uniformly supported inside the catalyst.
- denitration 2 0 0 ° C near side such as waste incinerators exhaust gas
- the active sites of the entire catalyst is utilized and c becomes advantageous in this respect, there tends to be remarkably deteriorated by S Ox at low temperatures
- the supported Mo—V compound is stable and does not easily react with S 0 X, so that it is possible to obtain a catalyst having high SOx resistance, which cannot be considered conventionally.
- the catalyst of the present invention exhibits high performance in the oxidative decomposition of organic chlorine compounds, and it is necessary to have a combination of durability and oxidation activity of chlorine-containing compounds such as dioxin around 200 ° C. Denitration of exhaust gas from incinerators-ideal as a catalyst for dioxin removal ⁇ ) o
- FIG. 1 is a schematic diagram of a cross section of a surface layer of a catalyst showing a distribution state of active components of the catalyst according to the present invention.
- FIG. 2 is a similar schematic supplementary diagram showing the distribution of active components of a catalyst according to the prior art.
- FIG. 3 is a diagram comparing the performances of the catalysts in the example of the present invention and the comparative example.
- a slurry obtained by adding 49.8 g of ammonium molybdate ((NH 4 ) 6 ⁇ ⁇ 7 0 24 ⁇ 4 ⁇ 20 ) and 49.4 g of ammonium metavanadate (NH 4 V 0 3 ) to 41 g of water was added to the slurry.
- the mixture was gently stirred at room temperature for 20 hours.
- the solid content concentration in the slurry was about 18 wt%, and the VZMo atomic ratio was 3/2, which was the same as in Example 1.
- ammonium metavanadate did not dissolve, and no red-brown product was obtained.
- Example 1 and Comparative Examples 1 to 3 the production of a red-brown substance having a high solubility, which is considered to be the specific compound having a V / Mo ratio of 3/2, is caused by the formation of ammonium metavanadate and molybdenum trioxide. It is considered to be a specific substance that can be reacted in water. It was found that their formation did not occur if the starting materials were different, and that they did not form even with the oxides of W that were homologous to Mo.
- the catalyst base material was impregnated with 1% of slurry and dried at 150 ° C. to give rigidity to obtain a catalyst base material.
- 1.5 kg of titanium oxide having a specific surface area of about 230 m 2 / and 75 g of oxalic acid were added to water to form a paste, and silica-alumina fiber was further treated with 30 Og. The mixture was added and kneaded until uniform.
- the obtained paste was sandwiched between the catalyst base materials prepared above and passed through a rolling roller to form titania to a thickness of 0.7. After drying at room temperature, it was calcined at 400 ° C. for 2 hours to obtain titania.
- the titania carrier was immersed in the Mo—V compound solution synthesized in Example 1 to support the Mo—V compound, and dried at 80 ° C. for 2 hours.
- Mo 0 3 and V 2 0 5 content in the resultant catalyst was 4. 8 wt% and 4. 5 wt% with respect to T i 0 2. Comparative Example 4
- the catalyst was impregnated and dried at 150 ° C. to give rigidity to obtain a catalyst substrate.
- 1.5 kg of titanium oxide having a specific surface area of about 230 m 2 / g, 86.7 g of ammonium metavanadate, 88.3 g of ammonium molybdate, and 75 g of oxalic acid were added to water.
- Mo 0 3 and V 2 0 5 content in the catalyst was 4. 8 wt% and 4. 5 wt% with respect to T i 0 2.
- the catalyst obtained in Example 2 was calcined at 200, 300, 400, and 500, respectively, for 2 hours to prepare a catalyst.
- Example 4 The catalyst obtained in Example 4 was used in the same manner as in Comparative Examples 2 to 5, 200, 300,
- Calcination was performed at 400 and 500 ° C. to obtain a catalyst.
- Example 2 8.67 g of ammonium metavanadate and 8.83 g of ammonium molybdate It was dissolved in 1 cm 3 of a 10% aqueous solution of monomethylamine.
- the titania carrier used in Example 2 was immersed and impregnated in the obtained solution, and then dried at room temperature and 80 ° C. to obtain a catalyst of Comparative Example 9.
- the catalyst was further calcined at 500 ° C. for 2 hours to obtain a catalyst of Comparative Example 10.
- Each catalyst of Examples 2 to 6 and Comparative Examples 4 to 10 was cut into 20 mm x 100 mm, and then subjected to a denitration test under the conditions shown in Table 1. The obtained results are shown in FIG. 3 as the relationship between the firing temperature and the denitration rate.
- the drying temperature was also considered as the calcination temperature, and the data for the catalyst only for drying was also included.
- the catalyst of the present invention has extremely high activity. Not only that, the comparative example catalyst cannot obtain high activity unless calcined at 400 ° C. or higher, whereas the catalyst of the present invention has the same properties as the calcined catalyst even in the catalyst of Example 2 in which calcining is not performed at all. High performance was obtained. From this, it is clear that the catalyst of the present invention does not need to be subjected to an activation treatment such as calcination, and it can be seen that the catalyst has an extremely large effect in terms of activity and production cost.
- each of the comparative example catalysts was significantly reduced by being exposed to the SO 2 -containing gas, whereas the activity of the example catalyst was extremely small.
- the catalyst of Example 2 has the smallest decrease in activity as compared with the other catalysts. This is presumably because by supporting the compound in the form of a Mo—V compound in the catalyst, the compounding of the two is sufficient, and it is not easily violated by S 0 X.
- a catalyst was prepared in the same manner as in Comparative Example 4, except that the M0-V compound solution prepared in Example 1 was used instead of ammonium molybdate and ammonium metavanadate.
- Example 2 To M o-V solution prepared in Example 1, S i 0 2 to 2 0 wt% containing colloidal silica (manufactured by Nissan Chemical Industries, Ltd., Shirikazoru 0) to 5 0 O g was added to obtain a mixed solution of both. Using this solution, a catalyst was prepared in the same manner as in Example 2.
- Example 9 The same catalyst as in Comparative Example 9 was prepared by using a mixed solution prepared by adding 5 g of silicic acid sol-o to the mixed monomethylamine solution of Mo and V salts used in Comparative Example 9, and using the mixed solution.
- Example 9
- Example 7 The results of performance tests of the catalyst obtained in Example 7 in the same manner as in Example 2 are shown in Table 3 together with the results of Example 2. As shown in Example 7, it can be seen that high performance can be obtained as in the case of the impregnation method, even when the MOV material is used as the raw material for the kneading method. Table 3
- Example 8 The catalyst of Comparative Example has not only low activity but also bending strength. The value is extremely lower than that of Example 8. This is presumed to be because the silica sol and vanadium salt were changed into a gel state by the mixing of the monomethylamine solution of Mo and V salts with the silica sol, and were not impregnated in the titania carrier.
- the M0-V compound of the present invention can be arbitrarily mixed with the silicic acid sol, the strength improving agent and the active ingredient can be supported at the same time, and the operation is simple. A catalyst having high strength and high activity can be obtained.
- the catalyst of the present invention can obtain a high value of 80% or more as the oxidative decomposition activity of black benzene.
- the catalyst of the present invention is not only excellent in activity at a low temperature of 200 ° C., but also hardly degraded by S 0 X contained in exhaust gas from a refuse incinerator, and also contains chlorine-containing organic compounds which are simulated dioxins. Also has excellent oxidation activity. Simultaneous treatment of dioxin and denitration is desired in waste incinerators and the like, which have been increasing in recent years.
- the catalyst of the present invention is an extremely excellent catalyst that meets such social needs.
- a catalytically active compound that does not require an activation step by calcination is obtained, and a catalyst loaded or kneaded with the compound has excellent low-temperature activity, durability, and dioxin decomposition activity. It is possible to increase the efficiency of devices and the like.
- firing as an activation treatment is not required, not only can the manufacturing process be simplified, but also the catalyst can be designed with an emphasis on catalytic activity, and various improvements can be made in performance and economy. Will be possible.
- the Mo-V compound used in the present catalyst is not only stable when mixed with a sol-like substance such as a silicic acid sol, but also does not cause gelation of the sol. Therefore, the active component can be simultaneously supported in the silica sol impregnation step for improving the strength. It is possible to obtain a high-strength, high-activity catalyst in a simple step.
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Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12050199A JP3765942B2 (ja) | 1999-04-27 | 1999-04-27 | 排ガス浄化触媒化合物、該化合物を含む触媒、およびその製法 |
CNB008199973A CN1209196C (zh) | 1999-04-27 | 2000-10-26 | 用于净化废气的催化剂化合物、包含所述化合物的催化剂及其制备方法 |
KR1020037005525A KR100714031B1 (ko) | 2000-10-26 | 2000-10-26 | 배가스 정화촉매 화합물, 이 화합물을 함유한 촉매 및 그 제조방법 |
DE60039922T DE60039922D1 (de) | 1999-04-27 | 2000-10-26 | Abgasreinigende katalysatorverbindung, diese verbindung enthaltender katalysator und verfahren zur herstellung der verbindung |
US10/415,320 US7005402B1 (en) | 1999-04-27 | 2000-10-26 | Exhaust gas purifying catalyst compound, catalyst comprising said compound and method for preparing the compound |
CA002427081A CA2427081C (en) | 1999-04-27 | 2000-10-26 | Catalyst compound for purifying exhaust gas, catalyst comprising the compound, and processes for producing them |
AU2000279589A AU2000279589A1 (en) | 1999-04-27 | 2000-10-26 | Exhaust gas purifying catalyst compound, catalyst comprising said compound and method for preparing the compound |
PCT/JP2000/007506 WO2002034388A1 (fr) | 1999-04-27 | 2000-10-26 | Compose catalytique purifiant les gaz d'echappement, catalyseur comprenant ledit compose et procede de preparation du compose |
EP00970100A EP1340539B1 (en) | 1999-04-27 | 2000-10-26 | Exhaust gas purifying catalyst compound, catalyst comprising said compound and method for preparing the compound |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP12050199A JP3765942B2 (ja) | 1999-04-27 | 1999-04-27 | 排ガス浄化触媒化合物、該化合物を含む触媒、およびその製法 |
PCT/JP2000/007506 WO2002034388A1 (fr) | 1999-04-27 | 2000-10-26 | Compose catalytique purifiant les gaz d'echappement, catalyseur comprenant ledit compose et procede de preparation du compose |
Publications (1)
Publication Number | Publication Date |
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WO2002034388A1 true WO2002034388A1 (fr) | 2002-05-02 |
Family
ID=26344962
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2000/007506 WO2002034388A1 (fr) | 1999-04-27 | 2000-10-26 | Compose catalytique purifiant les gaz d'echappement, catalyseur comprenant ledit compose et procede de preparation du compose |
Country Status (8)
Country | Link |
---|---|
US (1) | US7005402B1 (ja) |
EP (1) | EP1340539B1 (ja) |
JP (1) | JP3765942B2 (ja) |
CN (1) | CN1209196C (ja) |
AU (1) | AU2000279589A1 (ja) |
CA (1) | CA2427081C (ja) |
DE (1) | DE60039922D1 (ja) |
WO (1) | WO2002034388A1 (ja) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3765942B2 (ja) * | 1999-04-27 | 2006-04-12 | バブコック日立株式会社 | 排ガス浄化触媒化合物、該化合物を含む触媒、およびその製法 |
KR100549778B1 (ko) * | 2003-09-27 | 2006-02-08 | 한국전력기술 주식회사 | 저온 탈질 특성을 갖는 바나듐/티타니아계 질소산화물제거용 촉매, 이의 사용방법 및 이의 탈질방법 |
JP4277226B2 (ja) * | 2006-02-09 | 2009-06-10 | バブコック日立株式会社 | 金属水銀酸化用触媒及び金属水銀酸化用触媒を備えた排ガス浄化用触媒とその製造方法 |
JP2008221203A (ja) | 2007-02-13 | 2008-09-25 | Babcock Hitachi Kk | 窒素酸化物除去用触媒及び窒素酸化物除去方法 |
JP5495001B2 (ja) | 2007-06-27 | 2014-05-21 | バブコック日立株式会社 | 触媒の再生方法 |
JP5490074B2 (ja) * | 2010-12-28 | 2014-05-14 | トヨタ自動車株式会社 | 三酸化硫黄分解用触媒、及び水素生成方法 |
JP5497688B2 (ja) | 2011-05-25 | 2014-05-21 | トヨタ自動車株式会社 | 三酸化硫黄分解用触媒、及び水素生成方法 |
US8623781B2 (en) * | 2011-06-28 | 2014-01-07 | King Fahd University of Pretroleum and Minerals | Oxidative dehydrogenation of propane |
CN111714964B (zh) * | 2020-06-29 | 2021-08-17 | 浙江严牌过滤技术股份有限公司 | 一种除尘脱二噁英一体化滤料及其制备方法 |
Citations (2)
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JPS58210849A (ja) * | 1982-06-03 | 1983-12-08 | Babcock Hitachi Kk | アンモニア接触還元用脱硝触媒 |
JP2000308832A (ja) * | 1999-04-27 | 2000-11-07 | Babcock Hitachi Kk | 排ガス浄化触媒化合物、該化合物を含む触媒、およびその製法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3678091A (en) * | 1969-05-13 | 1972-07-18 | Aquitaine Petrole | Process for the preparation of unsaturated alphatic nitriles by the oxidation of olefins |
JPS49126616A (ja) * | 1973-04-13 | 1974-12-04 | ||
US4001316A (en) * | 1973-06-15 | 1977-01-04 | Nippon Kayaku Kabushiki Kaisha | Method for manufacture of methacrylic acid |
US5166122A (en) * | 1988-09-19 | 1992-11-24 | Babcock-Hitachi Kabushiki Kaisha | Process for producing a denitration catalyst |
DE68913020T3 (de) * | 1988-12-21 | 1998-03-05 | Babcock Hitachi Kk | Katalysator zur Entfernung von Stickoxiden und sein Herstellungsverfahren. |
JP3101821B2 (ja) * | 1990-02-15 | 2000-10-23 | 三菱レイヨン株式会社 | メタクリル酸製造用触媒の調製法 |
EP0762925B1 (de) * | 1994-05-30 | 1999-08-11 | Siemens Aktiengesellschaft | Katalysator zur stickoxidminderung in einem strömungsmedium und verfahren zu seiner herstellung |
JP2000026123A (ja) * | 1998-07-08 | 2000-01-25 | Mitsubishi Chemicals Corp | 複合酸化物および複合酸化物の製造方法 |
WO2004099081A1 (de) * | 2003-05-12 | 2004-11-18 | Basf Aktiengesellschaft | In reiner i-phase vorliegende, mo, v und alkalimetall enthaltende multimetalloxidmassen |
-
1999
- 1999-04-27 JP JP12050199A patent/JP3765942B2/ja not_active Expired - Fee Related
-
2000
- 2000-10-26 US US10/415,320 patent/US7005402B1/en not_active Expired - Lifetime
- 2000-10-26 AU AU2000279589A patent/AU2000279589A1/en not_active Abandoned
- 2000-10-26 EP EP00970100A patent/EP1340539B1/en not_active Expired - Lifetime
- 2000-10-26 DE DE60039922T patent/DE60039922D1/de not_active Expired - Lifetime
- 2000-10-26 WO PCT/JP2000/007506 patent/WO2002034388A1/ja active IP Right Grant
- 2000-10-26 CA CA002427081A patent/CA2427081C/en not_active Expired - Fee Related
- 2000-10-26 CN CNB008199973A patent/CN1209196C/zh not_active Expired - Lifetime
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS58210849A (ja) * | 1982-06-03 | 1983-12-08 | Babcock Hitachi Kk | アンモニア接触還元用脱硝触媒 |
JP2000308832A (ja) * | 1999-04-27 | 2000-11-07 | Babcock Hitachi Kk | 排ガス浄化触媒化合物、該化合物を含む触媒、およびその製法 |
Non-Patent Citations (1)
Title |
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See also references of EP1340539A4 * |
Also Published As
Publication number | Publication date |
---|---|
CN1209196C (zh) | 2005-07-06 |
JP3765942B2 (ja) | 2006-04-12 |
EP1340539A4 (en) | 2006-06-21 |
AU2000279589A1 (en) | 2002-05-06 |
EP1340539A1 (en) | 2003-09-03 |
JP2000308832A (ja) | 2000-11-07 |
CN1455700A (zh) | 2003-11-12 |
CA2427081C (en) | 2007-06-26 |
CA2427081A1 (en) | 2003-04-14 |
EP1340539B1 (en) | 2008-08-13 |
DE60039922D1 (de) | 2008-09-25 |
US7005402B1 (en) | 2006-02-28 |
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