WO2001079767A1 - Dispositif de refrigeration - Google Patents
Dispositif de refrigeration Download PDFInfo
- Publication number
- WO2001079767A1 WO2001079767A1 PCT/JP2001/002837 JP0102837W WO0179767A1 WO 2001079767 A1 WO2001079767 A1 WO 2001079767A1 JP 0102837 W JP0102837 W JP 0102837W WO 0179767 A1 WO0179767 A1 WO 0179767A1
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- WO
- WIPO (PCT)
- Prior art keywords
- refrigerant
- refrigeration
- inner diameter
- compressor
- side pipe
- Prior art date
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B41/00—Fluid-circulation arrangements
- F25B41/40—Fluid line arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/24—Only one single fluoro component present
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B13/00—Compression machines, plants or systems, with reversible cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/12—Inflammable refrigerants
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2500/00—Problems to be solved
- F25B2500/01—Geometry problems, e.g. for reducing size
Definitions
- the present invention relates to a refrigeration apparatus, and more particularly to a refrigeration apparatus using a single R32 refrigerant or a mixed R32 refrigerant.
- a refrigerating apparatus includes a refrigerant circuit having a compressor, a condenser, a decompression mechanism, and an evaporator, and the refrigerant circuit forms a refrigerating cycle using an HCFC system such as R22 as a refrigerant.
- the compressor plays an important role, in particular, in boosting the pressure of the refrigerant, so that refrigerating machine oil is required for smooth operation.
- an extreme pressure additive is often added to the refrigerating machine oil.
- This extreme pressure additive is hydrolyzed when the sliding surface of the compressor is in a high temperature state and in the presence of moisture, and the lubricity is reduced. Furthermore, the hydrolyzed degraded product does not dissolve in the refrigerant, but precipitates as sludge in the expansion valve or the cavity tube, which may cause blockage of the flow path of the refrigerant circuit.
- chlorine-based extreme pressure additives sometimes generate corrosive substances such as hydrochloric acid by hydrolysis.
- the present invention has been made in view of such a point, and an object of the present invention is to improve the reliability and ease of handling of an apparatus. Disclosure of the invention
- the present invention uses a resin material as an insulating material of a motor in a compressor, and uses a single refrigerant R32 or R32 which is a refrigerant having a smaller pressure loss than R22 or the like.
- a mixed refrigerant was used.
- the present invention has been made based on the following reasons.
- R32 single refrigerant or R32 mixed refrigerant has a greater refrigeration effect than R22, R407C or R410A
- the refrigerant required to obtain the same capacity The amount of circulation may be smaller than that of a refrigerant such as R22. Therefore, in the case of the R32 single refrigerant or the R32 mixed refrigerant, the pressure loss when flowing through the flow path having the same diameter is smaller than that of the refrigerant such as R22.
- the liquid side pipe is, for example, a pipe from a condenser outlet to an evaporator inlet. Even if the pressure loss increases, as long as the pressure loss is within the control range of the pressure reducing mechanism (capillary tube or expansion valve, etc.), the performance of the device does not deteriorate.
- the height difference pressure of the refrigerant circuit is about 1.6 times at the maximum as compared with the case where R22 is used. Accordingly, the allowable range of the refrigerant pressure loss increases. Therefore, when the R32 single refrigerant or the R32 mixed refrigerant is used, the diameter of the liquid side pipe can be made smaller than before without lowering the device performance.
- the discharge pipe is, for example, a pipe between a compressor discharge side and a condenser inlet
- the suction pipe is, for example, a pipe between an evaporator outlet and a compressor suction side.
- the saturation temperature difference corresponding to the refrigerant pressure loss is important as a factor that affects its performance.
- the saturation temperature difference can be made equal to the conventional one.
- the heat exchange capacity can be kept high even if the diameter of the heat transfer tube is reduced.
- the inventor of the present invention has succeeded in reducing the internal volume of the refrigerant circuit by using the R32 single refrigerant / the R32 mixed refrigerant and reducing the diameter of the refrigerant pipe and the heat transfer tube of the heat exchanger. It was found that there was no problem in terms of performance. On the other hand, the amount of air and moisture mixed into the refrigerant circuit increases in proportion to the internal volume of the refrigerant circuit. Therefore, in the present invention, the amount of air and moisture mixed into the refrigerant circuit is reduced by reducing the internal volume of the refrigerant circuit using the R32 single refrigerant / the R32 mixed refrigerant, and the extreme pressure additive is used. It was decided to prevent deterioration.
- extreme pressure additives are often added to refrigeration oil. That is, when the sliding portion of the compressor is at a high temperature and high pressure, an extreme pressure additive is added to the refrigerating machine oil to prevent abrasion and seizure.
- HFC-based refrigerants do not contain chlorine atoms
- CFC-based refrigerants ⁇ HFCFC-based refrigerants do not have an extreme pressure effect that is effectively exerted.
- the extreme pressure action means that chlorine atoms in the refrigerant react with iron in the sliding part of the compressor to form an extreme pressure film. With the above HFC-based refrigerant, this extreme pressure film is not formed.
- extreme pressure additives are high in HFC-based refrigerants.
- chlorine-based or sulfur-based ones are used in addition to phosphorus-based ones such as phosphate esters and phosphites.
- the extreme pressure additive is hydrolyzed when the sliding surface of the compressor is at a high temperature and in the presence of moisture, and the lubricity is reduced. Furthermore, the hydrolyzed degraded products do not dissolve in the refrigerant, In some cases, sludge precipitates in the expansion valve or the capillary tube, which is an expansion mechanism, which may block the flow path of the refrigerant circuit.
- chlorine-based extreme pressure additives sometimes generate corrosive substances such as hydrochloric acid by hydrolysis.
- the present invention reduces the internal volume of the refrigerant circuit by using R32 single refrigerant / R32 mixed refrigerant. This reduces the amount of air and moisture entering the refrigerant circuit. By reducing the amount of air and moisture, it was decided to prevent hydrolysis of the extreme pressure additive and prevent its deterioration.
- the first invention uses a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32, while adding an extreme pressure additive to the refrigerating machine oil.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) that has a cooling capacity of 5 kW or less.
- the liquid side pipe (32) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 4.75 mm.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) that has a cooling capacity of 5 kW or less.
- the liquid side pipe (32) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of 3.2 mm to 4.2 mm.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) that has a cooling capacity of 5 kW or less.
- the inside diameter of the liquid side pipe (32) of the refrigerant circuit (10) is 3.5mn! It is formed by piping that is ⁇ 3.9mm.
- Another invention provides a compressor (") in which a refrigeration cycle is formed using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant, and an extreme pressure additive is added to refrigeration oil.
- a refrigerant circuit (10) having a cooling capacity of 5 kW or less It is intended for refrigeration equipment.
- the liquid side pipe (32) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of 3.6 mm to 3.8 mm.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) that has a cooling capacity rating of more than 5 kW and 18 kW or less.
- the liquid side pipe (32) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 7.92 mm.
- Another invention relates to a compressor in which a refrigeration cycle is formed using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant, and an extreme-pressure additive is added to refrigerating machine oil (11)
- the liquid-side pipe (32) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 11.1 mm.
- Another invention relates to a compressor in which a refrigeration cycle is formed using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant, and an extreme-pressure additive is added to refrigerating machine oil (11)
- It is intended for refrigeration systems that have a refrigerant circuit (10) with a cooling capacity of more than 5 kW and less than 22.4 kW.
- the liquid side pipe (32) of the refrigerant circuit (10) has an inner diameter of 5.4mn! It is formed by piping that is ⁇ 7 Omm.
- Another invention relates to a compressor in which a refrigeration cycle is formed using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant, and an extreme-pressure additive is added to refrigerating machine oil (11)
- It is intended for refrigeration systems that have a refrigerant circuit (10) with a cooling capacity of more than 5 kW and 22.4 kW or less.
- the liquid side pipe (32) of the refrigerant circuit (10) has an inner diameter of 5.7mn! It is formed by piping that is ⁇ 6.7 mm.
- Another invention relates to a compressor in which a refrigeration cycle is formed using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant, and an extreme-pressure additive is added to refrigerating machine oil (11) Equipped with a refrigerant circuit (10) having a cooling capacity of more than 5 kW It is intended for refrigeration equipment with a capacity of 22.4 kW or less.
- the liquid side pipe (32) of the refrigerant circuit (10) has an inner diameter of 6. Omn! It is formed by piping that is ⁇ 6.4 mm.
- Another aspect of the present invention is a compressor that forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and adds an extreme-pressure additive to refrigerating machine oil (11)
- It is intended for refrigeration systems that are equipped with a refrigerant circuit (10) that has a cooling capacity that is designed to be greater than 22.4 kW.
- the liquid side pipe (32) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 1.88 mm.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration systems that have a refrigerant circuit (10) that has a cooling capacity rating greater than 22.4 kW. And the liquid side pipe (32) of the refrigerant circuit (10) has an inner diameter of 7.5mn! It is formed by piping that is ⁇ 9.8 mm.
- Another invention is a compressor (11) that forms a refrigeration cycle using a single refrigerant of R32 or a mixed solvent containing 75% or more of R32 as a refrigerant and adding an extreme-pressure additive to refrigerating machine oil.
- Refrigeration equipment that has a refrigerant circuit (10) with a cooling capacity of more than 22.4 kW.
- the inner diameter of the liquid side pipe (32) of the refrigerant circuit (10) is 7.8mn! It is formed by piping that is ⁇ 9.5 mm.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration systems that have a refrigerant circuit (10) that has a cooling capacity rating greater than 22.4 kW.
- the liquid side pipe (32) of the refrigerant circuit (10) has an inner diameter of 8. l mn! It is formed by piping that is up to 9.1 mm.
- Another invention relates to a method of forming a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and adding an extreme-pressure additive to refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) with a compressor (11) and a rated cooling capacity of 3.2 kW or less. And the gas side piping of the refrigerant circuit (10)
- (31) is formed by piping with an inner diameter of less than 7.92 mm.
- Another invention relates to a compressor in which a refrigeration cycle is formed using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant, and an extreme-pressure additive is added to refrigerating machine oil (11) It is intended for refrigeration systems that have a refrigerant circuit (10) with a cooling capacity of greater than 3.2 kW and less than 5 kW. And the refrigerant circuit
- the gas side pipe (31) of (10) is formed by a pipe with an inner diameter of less than 11.1 mm.
- Another invention relates to a compressor in which a refrigeration cycle is formed using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant, and an extreme-pressure additive is added to refrigerating machine oil (11)
- It is intended for refrigeration systems that have a refrigerant circuit (10) with a cooling capacity of more than 5 kW and 9 kW or less.
- the gas side pipe (31) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 1.88 mm.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) that has a cooling capacity rating of more than 9 kW and 18 kW or less.
- the gas side pipe (31) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 17.05 mm.
- Another invention relates to a compressor (11) which forms a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and in which an extreme pressure additive is added to refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) and has a rated cooling capacity of more than 18 kW and not more than 22.4 kW.
- the gas side pipe (31) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 23.4 mm.
- Another invention relates to a method of forming a refrigeration cycle using a single refrigerant of R32 or a mixed refrigerant containing 75% or more of R32 as a refrigerant and adding an extreme pressure additive to the refrigerating machine oil. It is intended for refrigeration equipment that has a refrigerant circuit (10) with a compressor (11) and is designed to have a cooling rating of greater than 22.4 kW.
- the gas side pipe (31) of the refrigerant circuit (10) is formed by a pipe having an inner diameter of less than 26.18 mm.
- another invention has a compressor (11) in which an extreme pressure additive is added to refrigerating machine oil and an indoor heat exchanger (15), and a single refrigerant of R32 or R32. It is intended for refrigeration equipment equipped with a refrigerant circuit (10) that forms a refrigeration cycle using a mixed refrigerant containing 75% or more as a refrigerant.
- the heat transfer tube of the indoor heat exchanger (15) is formed by a heat transfer tube having an inner diameter of less than 5.87 mm.
- another invention has a compressor (11) in which an extreme pressure additive is added to refrigerating machine oil and an outdoor heat exchanger (13), and a single refrigerant of R32 or R32. It is intended for refrigeration equipment equipped with a refrigerant circuit (10) that forms a refrigeration cycle using a mixed refrigerant containing 75% or more as a refrigerant.
- the heat transfer tube of the outdoor heat exchanger (13) is formed by a heat transfer tube having an inner diameter of less than 6.89 mm.
- another invention has a compressor (11) in which an extreme pressure additive is added to refrigerating machine oil and an outdoor heat exchanger (13), and a single refrigerant of R32 or R32. It is intended for refrigeration equipment equipped with a refrigerant circuit (10) that forms a refrigeration cycle using a mixed refrigerant containing 75% or more as a refrigerant.
- the heat transfer tube of the outdoor heat exchanger (13) is formed of a heat transfer tube having an inner diameter of less than 7.99 mm.
- a synthetic oil may be used as a refrigerating machine oil.
- liquid side pipe (32) may be a liquid side connection pipe connecting the indoor unit (17) and the outdoor unit (16).
- gas side pipe (31) may be a gas side connection pipe connecting the indoor unit (17) and the outdoor unit (16).
- the mixed refrigerant is preferably a mixed refrigerant of R32 and R125.
- the refrigerant may be a single refrigerant of R32. Effect of one invention— Therefore, according to the present invention, the internal volume of the refrigerant circuit (10) can be reduced, so that the amount of air, moisture, and the like mixed into the refrigerant circuit (10) can be reduced. As a result, it is possible to prevent the extreme pressure additive to be added to the refrigerating machine oil from being hydrolyzed or from having reduced lubricity. In particular, the degraded hydrolyzate does not precipitate as sludge in the expansion valve / cabinet tube, and the refrigerant circuit
- Blockage of the flow path of (10) can be reliably prevented.
- FIG. 1 is a refrigerant circuit diagram of the air conditioner.
- Figure 2 is a Mollier diagram.
- Figure 3 is a table showing the results of calculating the ratio of the inner diameter of the heat transfer tubes.
- FIG. 4 is a sectional view of a grooved tube.
- Figure 5 is a Mollier diagram.
- FIG. 6 is a table showing calculation results of the inner diameter ratio of the liquid side pipe.
- FIG. 7 is a diagram showing the pipe diameters of the gas side pipe and the liquid side pipe for R22 with respect to the rated cooling capacity.
- Fig. 8 is a diagram showing the small diameter ratio of the gas side pipe and the liquid side pipe to the cooling rated capacity. is there.
- FIG. 9 is a diagram showing the relationship between the R22 copper tube and the R32 copper tube.
- Figure 10 is a table showing global warming potential.
- the refrigeration apparatus is an air conditioner (1) formed by connecting an outdoor unit (16) as a heat source unit and an indoor unit (17) as a utilization unit. is there.
- the refrigerant circuit (10) of the air conditioner (1) uses R32 single refrigerant (hereinafter referred to as R32 single refrigerant) as a refrigerant, or 75% by weight or more and 100% by weight.
- % Of the mixed refrigerant of R32 and R125 (a mixed refrigerant of R32 composition rich, hereinafter referred to as R32 / R125 mixed refrigerant) is used as the refrigerant.
- the refrigerant circuit (10) is a refrigerant circuit forming a vapor compression refrigeration cycle, and includes a compressor (11), a four-way switching valve (12), and an outdoor heat exchanger (a heat source side heat exchanger). 13)
- the expansion valve (14), which is an expansion mechanism, and the indoor heat exchanger, which is a use side heat exchanger, 5 ) are sequentially passed through a gas side pipe (31) and a liquid side pipe (32), which are refrigerant pipes. Connected and configured.
- the discharge side of the compressor (11) and the first port (12a) of the four-way switching valve (12) are connected by a first gas side pipe (21).
- the second port of the four-way switching valve (12) (12b) outdoor heat exchanger (1 3) are connected by a second gas side pipe (22).
- the outdoor heat exchanger (13) and the expansion valve (14) are connected by the first liquid side pipe (25).
- the expansion valve (14) and the indoor heat exchanger (15) are connected by the second liquid side piping (26).
- the indoor heat exchanger (15) and the third port (12c) of the four-way switching valve (12) are connected by a third gas side pipe (23).
- the fourth port (12d) of the four-way switching valve (12) and the suction side of the compressor (11) are connected by a fourth gas side pipe (24).
- the fourth gas side pipe (24) is housed in the outdoor unit (16) together with an outdoor blower (not shown).
- the indoor heat exchanger (15) is housed in an indoor unit (17) together with an indoor blower (not shown).
- a part of the second liquid side pipe (26) and the third gas side pipe (23) constitutes a so-called communication pipe connecting the outdoor unit (16) and the indoor unit (17).
- synthetic oil is used as the refrigerating machine oil.
- synthetic oil for example, alkylbenzene oil is used in addition to ether oil and ester oil.
- An extreme pressure additive is added to the refrigerating machine oil.
- the extreme pressure additive in addition to phosphorus-based compounds such as phosphate esters and phosphite esters, chlorine-based and sulfur-based additives are used.
- an electric motor is housed in a casing.
- This motor uses insulating materials such as insulating paper, lead wires and tying cords.
- insulating material a resin material is used.
- the insulating materials include, for example, polyethylene terephthalate (PET), polyethylene naphthate (PEN), polyphenylene sulfide (PPS), polybutylene terephthalate (PBT), polyethylene terephthalate (PEEK) ), Polyamide (PAI) or polyamide.
- the above-described resin material is used for the insulating paper, the lead wire, the binding string, and the like.
- PET is used for the insulating paper
- PPS is used for the lead wire
- a plurality of types of resin materials are used for the electric motor.
- the above-mentioned ether oil and alkylbenzene oil are oxidatively degraded by air.
- the ester oil is hydrolyzed by mixing of water. Either air or moisture causes any synthetic oil to raise the total acid number.
- the strength of the resin material of the above-described electric motor decreases when the total acid value increases. In the worst case, there is a risk of burning the motor.
- the extreme pressure additive hydrolyzes, reduces lubricity, and precipitates as sludge on the expansion valve (14), Extreme pressure additives in the system can generate corrosive substances.
- the internal volume of the refrigerant circuit (10) is reduced by using R32 single refrigerant or R32 / R125 mixed refrigerant to reduce the amount of air and moisture mixed.
- R32 single refrigerant or R32 / 125 mixed refrigerant has a greater refrigeration effect per unit volume than R22
- the refrigerant circulation required to achieve the specified capacity is R 2 Less than 2 Therefore, in the case of the R32 single refrigerant or the R32 / R125 mixed refrigerant, when the inner diameter of the heat transfer tube of the heat exchanger is fixed, the refrigerant circulation amount is reduced, and the pressure loss in the tube is reduced. It is smaller than R22.
- the part of the refrigerant circuit (10) that has the largest amount of refrigerant is the outdoor heat exchanger (13). Therefore, by reducing the diameter of the heat transfer tube of the outdoor heat exchanger (13), the amount of refrigerant charged can be effectively reduced. In addition, the internal diameter of the refrigerant circuit (10) is reduced by reducing the diameter of the heat transfer tube. In addition, since the outdoor heat exchanger (13) and the indoor heat exchanger (15) are downsized by reducing the diameter of the heat transfer tubes, the outdoor unit (16) and the indoor unit (17) can be made more compact. It becomes possible.
- the diameters of the heat transfer tubes of the outdoor heat exchanger (13) and the indoor heat exchanger (15) are reduced until the pressure loss in the tubes becomes equivalent to R22.
- the heat transfer tube Considering the amount of change in the refrigerant saturation temperature corresponding to the pressure loss in the heat exchanger tubes of the outdoor heat exchanger (13) and the indoor heat exchanger (15), the temperature change is equivalent to: R22.
- the outdoor heat exchanger (13) is set so that the saturation temperature change ⁇ e corresponding to the pressure loss of the evaporated refrigerant becomes equal to the saturation temperature change of R22 in the conventional device.
- Fig. 3 shows the calculation results obtained by substituting each physical property value into the above equation (6).
- the evaporation temperature Te is assumed to be 2 ° C and the condensing temperature Tc is assumed to be 49 ° C
- the superheat SH at the evaporator outlet is 5 ° C
- the subcool SC at the condenser outlet SC 5 ° C.
- a heat transfer tube having the following inner diameter is used in comparison with the heat transfer tube for R22.
- the inside diameter of the heat transfer tube of the indoor heat exchanger (15) is 4.7mn! 5: 9mm heat transfer tube
- the inner diameter of the heat transfer tube of the outdoor heat exchanger (13) is 5.4mn! Formed with heat transfer tubes of ⁇ 6.7 mm.
- the indoor heat exchanger (15) should have a heat transfer tube with an inner diameter of 4.7 mm to 6.2 mm.
- the inner diameter of the heat transfer tube of (13) is 5.4mn! ⁇ 7.1 mm heat transfer tube was.
- the inner diameters of the heat transfer tubes of the outdoor heat exchanger (13) and the indoor heat exchanger (15) are set within the above numerical ranges in order to balance them.
- the inside diameter of the heat transfer tube of the indoor heat exchanger (15) is 4.9 mn!
- the heat transfer tube of the outdoor heat exchanger (13) has an inner diameter of 5.6mn! It may be formed of a heat transfer tube of up to 6.5 mm.
- the heat transfer tube of the indoor heat exchanger (15) is formed by a heat transfer tube with an inner diameter of 5.1 mm to 5.5 mm, and the heat transfer tube of the outdoor heat exchanger (13) is used.
- the inner diameter of the heat transfer tube is 5.8mn! It may be formed of a heat transfer tube of ⁇ 6.3 mm.
- the inside diameter of the heat transfer tube of the indoor heat exchanger (15) is 4.9 mn!
- the heat transfer tube of the outdoor heat exchanger (13) has an inner diameter of 5.6 mn! It may be formed of a heat transfer tube of up to 6.9 mm.
- the inside diameter of the heat transfer tube of the indoor heat exchanger (15) is 5.2 mn!
- the heat transfer tube of the outdoor heat exchanger (13) has an inner diameter of 5.9 mn! It may be formed of a heat transfer tube of ⁇ 6.6 mm.
- the inner diameter of the heat transfer tube means the inner diameter of the tube after expansion in the case of a smooth inner surface tube.
- Various types of heat transfer tubes such as copper tubes and aluminum tubes can be used as the heat transfer tubes.
- the external heat exchanger (13) and the indoor heat exchanger (13) according to the present embodiment are a type of air heat exchanger for performing heat exchange with air, which is a plate filter made of copper tubes and aluminum fins.
- Heat transfer tubes are made of copper tubes
- the pressure loss of the refrigerant is reduced. Therefore, even if the inside diameter of the liquid side pipe (32) of the refrigerant circuit (10) is reduced and the pressure loss in the pipe is increased to the same level as when R22 is used, the performance of the device remains the same as before. Will be maintained. Therefore, in the above air conditioner (1), the liquid side pipe (32) is reduced in diameter until the pressure loss in the pipe becomes R22, so that the contents of the refrigerant circuit (10) can be maintained while maintaining the performance of the apparatus. The product has been reduced.
- the gas side pipe (31) is the same as the conventional R22 gas side pipe.
- the liquid-side pipe (32) is occupied with a pressure drop of the refrigerant from the condenser outlet to the evaporator inlet, so that the ratio of the pressure loss of the liquid-side pipe (32) to that of R22 is equal to that of R22.
- Design (32) That is, the following equation is established using the symbols shown in FIG.
- G Refrigerant circulation amount (kg / s)
- A Channel cross-sectional area (m 2 )
- FIG. 6 shows a calculation result obtained by substituting each physical property value into the above equation (12).
- the evaporation temperature Te was 2 ° C
- the condensing temperature Tc was 49 ° C
- the superheat SH 5 ° C
- the subcool SC 5 ° C.
- the liquid side pipe (32) of the R32 single refrigerant can be reduced in diameter to about 0.76 times the liquid side pipe for R22.
- the diameter can be reduced to about 0.76 to 0.8 times.
- the same calculation was performed for other alternative refrigerants for reference, but it was found that the effect of reducing the diameter as much as R32 could not be obtained (see Fig. 6).
- FIG. 7 is a diagram showing the diameters (outer diameters) of the gas side pipe and the liquid side pipe in the conventional apparatus using R22 for each rated cooling capacity.
- the gas side pipe (31) uses the same diameter as the R22 gas side pipe, while the liquid side pipe (32) uses Use a pipe with a smaller diameter than the liquid side pipe for R22.
- liquid side piping ( 32 ) are used.
- the above inner diameter ratio is 2.1 to 3.5 (such gas side piping (31) and liquid side piping).
- the gas side piping (31) and the liquid side piping should be such that the above inner diameter ratio becomes 2.6 to 3.5.
- the rated cooling capacity When the rated cooling capacity is 5 kW or less, use a pipe with an inner diameter of 3.2 mm to 4.2 mm as the liquid side pipe (32). When the rated cooling capacity is greater than 5 kW and less than 22.4 kW, the inner diameter of the liquid side pipe (32) is 5.4mn! Use a pipe of ⁇ 7.0mm. If the rated cooling capacity is 22.4 kW or more, use piping with an inner diameter of 7.5 mm to 9.8 mm as the liquid side piping (32).
- the gas-side pipe (31) and the liquid-side pipe (32) should be set within the above numerical ranges so that the refrigerant charge can be sufficiently reduced while maintaining the performance of the apparatus. did.
- the above inner diameter ratio may be set to 2.4 to 3.2.
- the above inner diameter ratio may be 2.8 to 3.3.
- the above-mentioned inner diameter ratio may be set to 2.6 to 3.0.
- the above inner diameter ratio may be set to 2.9 to 3.1.
- the inner diameter of the liquid side pipe (32) is 3.5mn when the rated cooling capacity is 5 kW or less.
- the cooling capacity is more than 5 kW and less than 22.4 kW, 5.7 mn! Up to 6.7 mm, and 7.8 mn when the rated capacity of the cooling and broom is 22.4 kW or more! It may be up to 9.5 mm.
- the inside diameter of the liquid side pipe (32) should be 3.6 mm to 3.8 mm when the cooling capacity is 5 kW or less, and when the cooling capacity is more than 5 kW and less than 22.4 kW. 6. Omn! If the cooling capacity is 22.4 kW or more, 8. lmn! It may be 9.1 mm.
- both the liquid side pipe (32) and the gas side pipe (31) are composed of only standard products by combining standard products so as to have the above-mentioned inner diameter ratio.
- Fig. 9 shows the specifications of the copper pipe (JI SB 8607) for R22 and It is a figure which compared with the specification of the high pressure corresponding piping for R32 which was proposed by the association (Nichirei plan).
- the optimum inner diameter ratio calculated from the above calculation result is 0.76 in the case of the R32 single refrigerant, and the R32 / R125 mixed refrigerant containing 75% by weight of R32 is used. In that case it is 0.80. From FIG. 9 above, it was found that within the range of ⁇ 10% of the optimum inner diameter ratio, the inner diameter ratio can be easily realized by combining standard products.
- the present embodiment is a form that can be easily realized by combining standard products. Operation of the air conditioner
- the four-way switching valve (12) is set to the solid line side shown in Fig. 1. In other words, the four-way switching valve (12) is in a state where the first port (12a) and the second port (12b) communicate with each other, and the third port (12c) and the fourth port (12d) communicate with each other. .
- the gas refrigerant discharged from the compressor (11) flows through the first gas-side pipe (21), the four-way switching valve (12) and the second gas-side pipe (22), and passes through the outdoor heat exchanger.
- the two-phase refrigerant that has flowed out of (14) flows through the second liquid side pipe (26) and passes through the indoor heat exchanger.
- the four-way switching valve (12) is set on the broken line side shown in FIG. That is, in the four-way switching valve (12), the first port (12a) and the fourth port (12d) communicate with each other, and the second port (12b) and the third port (12c) communicate with each other.
- the gas refrigerant discharged from the compressor (11) flows through the first gas-side pipe (21), the four-way switching valve (12), and the third gas-side pipe (23), and passes through the indoor heat exchanger. (15).
- the refrigerant flowing into the indoor heat exchanger (15) exchanges heat with indoor air and condenses to heat the indoor air.
- the R32 single refrigerant or the R32 / R125 refrigerant is used as the refrigerant, and the heat transfer of the outdoor heat exchanger (13) and the indoor heat exchanger (15) is performed.
- the diameter of the pipe and the liquid side pipe (32) were made smaller than before. Therefore, according to the present embodiment, the internal volume of the refrigerant circuit (10) can be reduced while maintaining the performance of the device, and the entry of moisture and the like into the refrigerant circuit (10) can be suppressed.
- the extreme pressure additive to be added to the refrigerating machine oil from being hydrolyzed and from reducing the lubricity.
- the hydrolyzed degraded product does not precipitate as sludge in the expansion valve (14), and the flow path of the refrigerant circuit (10) can be reliably prevented from being blocked.
- the reliability of the device can be improved. In other words, despite the use of synthetic oil as the refrigerating machine oil, clogging of the circuit due to precipitation of sludge hardly occurs, and the reliability of the device is improved. In addition, since there is little possibility that moisture or the like will enter the refrigerant circuit (10), the product must be manufactured and installed. Quality control can be eased.
- the internal volume of the refrigerant circuit (10) has become smaller, it has become possible to reduce the amount of refrigerant to be charged, and to reduce the effect of global warming. Also, by reducing the diameter of the heat transfer tubes, the cost and size of the outdoor heat exchanger (13) and the indoor heat exchanger (15) can be reduced, and the indoor unit (17) and the outdoor unit ( 16) can be reduced in size.
- both the gas side pipe (31) and the liquid side pipe (32) may be reduced in diameter.
- the effect of reducing the internal volume of (10) can be obtained.
- the gas side pipes (31) to be reduced in diameter include the first gas side pipe (21), the second gas side pipe (22), the third gas side pipe (23), and the fourth gas side pipe (24). ) May not be all, or may be a part thereof.
- the liquid-side pipe (32) to be reduced in diameter may not be all of the first liquid-side pipe (25) and the second liquid-side pipe (26), and may be a part thereof. Good.
- Diameter of the liquid side pipe (32) (outer diameter or the inner diameter) is based on the values of the values different from 2 2 for liquid side pipe according to FIG. 7, it may be set smaller than those c Specifically, the liquid side pipe (32) may be formed of a pipe of less than 4.75 mm when the cooling rated capacity is 5 kW or less.
- liquid side pipe (32) may be formed of a pipe having a cooling capacity of more than 5 kW and less than 7.9 mm when the cooling capacity is not more than 18 kW.
- the liquid side pipe (32) may be formed of a pipe having a cooling capacity of more than 18 kW and less than 11.1 mm when the cooling capacity is 22.4 kW or less.
- the liquid side pipe (32) may be formed with a pipe of less than 13.88 mm when the cooling capacity is larger than 22.4 kW.
- the diameter of the gas side pipe (31) may be set to be smaller than the value of the R22 gas side pipe different from the value shown in FIG.
- the gas side pipe (31) may be formed of a pipe of less than 792 mm when the cooling capacity is 3.2 kW or less.
- gas side pipe (31) may be formed of a pipe having a cooling capacity of more than 3.2 kW and less than 5 kW and less than 11.1 mm.
- the gas side pipe (31) may be formed of a pipe with a cooling capacity of more than 5 kW and less than 13.88 mm when the cooling capacity is 9 kW or less.
- the gas side pipe (31) may be formed of a pipe having a cooling capacity rating of more than 9 kW and less than 17.05 mm when the rated cooling capacity is 18 kW or less.
- gas side pipe (31) may be formed of a pipe with a cooling capacity of more than 18 kW and less than 23.4 mm when the rated cooling capacity is 22.4 kW or less.
- gas side pipe (31) may be formed with a pipe of less than 26.18 mm when the rated cooling capacity is greater than 22.4 kW.
- the diameter of the heat transfer tubes of the indoor heat exchanger (15) and the outdoor heat exchanger (13) may be set to be smaller than the diameter of the heat transfer tubes for R22.
- the heat transfer tube of the indoor heat exchanger (15) may be formed by a heat transfer tube having an inner diameter of less than 5.87 mm.
- the heat transfer tube of the outdoor heat exchanger (13) may be formed by a heat transfer tube having an inner diameter of less than 6.89 mm.
- the heat transfer tube of the outdoor heat exchanger (13) may be formed by a heat transfer tube having an inner diameter of less than 7.99 mm.
- the so-called heat pump type air conditioner capable of selectively performing the cooling operation and the heating operation
- the application target of the present invention is not limited to the heat pump type air conditioner.
- it may be a cooling only machine.
- the liquid side piping (32) and gas side piping By setting the inner diameter of (31) or an inner diameter ratio thereof, the present invention can be applied to a heating-only machine.
- the cooling rated capacity of the present invention means the capacity of the evaporator, and is not limited to the capacity of the air conditioner at the time of cooling.
- the rated cooling capacity is based on the specified JIS conditions (indoor dry bulb temperature of 27 ° C; indoor wet bulb) when the connecting pipe length is 5 m and the height difference between the indoor unit and the outdoor unit is O m. Temperature of 19 ° C; outdoor dry bulb temperature of 35 ° C).
- the gas side pipe (31) and the liquid side pipe (32) need not necessarily be formed of copper pipes, but may be formed of other pipes such as a SUS pipe, an aluminum pipe, and an iron pipe.
- the indoor heat exchanger (15) and the outdoor heat exchanger (13) are not limited to air heat exchangers, but may be liquid-liquid heat exchangers such as double-pipe heat exchangers.
- the refrigeration apparatus of the present invention is not limited to a refrigeration apparatus in a narrow sense, and can be a refrigeration apparatus in a broad sense including a refrigeration apparatus, a dehumidifier, and the like, as well as the above-described air conditioning apparatus.
- the present invention When the present invention is applied to a refrigeration system compatible with long piping or an air conditioner equipped with a plurality of indoor units, the allowable piping length can be increased. Further, the present invention can increase the number of indoor units. Therefore, the easiness of handling the device is improved, and the merchantability can be improved.
- the refrigeration apparatus according to the present invention is useful when using an R32 single refrigerant or an R32 mixed refrigerant, and is particularly suitable for a refrigeration apparatus using an extreme pressure additive.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Compression-Type Refrigeration Machines With Reversible Cycles (AREA)
- Devices That Are Associated With Refrigeration Equipment (AREA)
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0110611-2A BR0110611B1 (pt) | 2000-04-19 | 2001-03-30 | sistema de refrigeração. |
KR1020027014017A KR100669071B1 (ko) | 2000-04-19 | 2001-03-30 | 냉동장치 |
EP01917767A EP1278026A4 (en) | 2000-04-19 | 2001-03-30 | REFRIGERATION DEVICE |
CA002402393A CA2402393C (en) | 2000-04-19 | 2001-03-30 | Refrigeration system |
US10/257,919 US6971244B2 (en) | 2000-04-19 | 2001-03-30 | Refrigerator |
AU44695/01A AU780334B2 (en) | 2000-04-19 | 2001-03-30 | Refrigerator |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000118225A JP4848576B2 (ja) | 2000-04-19 | 2000-04-19 | 冷凍装置 |
JP2000-118225 | 2000-04-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001079767A1 true WO2001079767A1 (fr) | 2001-10-25 |
Family
ID=18629406
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2001/002837 WO2001079767A1 (fr) | 2000-04-19 | 2001-03-30 | Dispositif de refrigeration |
Country Status (9)
Country | Link |
---|---|
US (1) | US6971244B2 (ja) |
EP (2) | EP1278026A4 (ja) |
JP (1) | JP4848576B2 (ja) |
KR (1) | KR100669071B1 (ja) |
CN (2) | CN1425121A (ja) |
AU (1) | AU780334B2 (ja) |
BR (1) | BR0110611B1 (ja) |
CA (1) | CA2402393C (ja) |
WO (1) | WO2001079767A1 (ja) |
Cited By (1)
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JPWO2016139737A1 (ja) * | 2015-03-02 | 2017-09-14 | 三菱電機株式会社 | 絶縁フィルム、電動機、冷媒圧縮機、及び冷凍サイクル装置 |
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JP2004257610A (ja) * | 2003-02-25 | 2004-09-16 | Sanyo Electric Co Ltd | 冷媒サイクル装置の製造方法 |
JP2008032275A (ja) * | 2006-07-27 | 2008-02-14 | Daikin Ind Ltd | 空気調和装置 |
US11214720B2 (en) | 2009-07-29 | 2022-01-04 | Honeywell International Inc. | Compositions containing difluoromethane and fluorine substituted olefins |
JP2011038729A (ja) * | 2009-08-12 | 2011-02-24 | Hoshizaki Electric Co Ltd | 冷凍装置 |
ES2906170T3 (es) | 2009-09-10 | 2022-04-13 | Mitsubishi Electric Corp | Aparato de aire acondicionado |
JP5602243B2 (ja) * | 2010-11-19 | 2014-10-08 | 三菱電機株式会社 | 空気調和機 |
US9187682B2 (en) | 2011-06-24 | 2015-11-17 | Emerson Climate Technologies, Inc. | Refrigeration compressor lubricant |
US9207002B2 (en) | 2011-10-12 | 2015-12-08 | International Business Machines Corporation | Contaminant separator for a vapor-compression refrigeration apparatus |
WO2013111176A1 (ja) * | 2012-01-23 | 2013-08-01 | 三菱電機株式会社 | 空気調和装置 |
JP2012184920A (ja) * | 2012-06-29 | 2012-09-27 | Mitsubishi Electric Corp | 空気調和機 |
JP6044238B2 (ja) * | 2012-09-28 | 2016-12-14 | ダイキン工業株式会社 | 空気調和機 |
JPWO2017154093A1 (ja) * | 2016-03-08 | 2018-08-09 | 三菱電機株式会社 | 車両用空気調和装置 |
CN110023684B (zh) * | 2016-11-30 | 2020-08-11 | 大金工业株式会社 | 配管直径的确定方法、配管直径的确定装置以及制冷装置 |
CN206361846U (zh) * | 2016-12-30 | 2017-07-28 | 广东美的暖通设备有限公司 | 用于空调器的室外机和空调器 |
JP2018115831A (ja) * | 2017-01-20 | 2018-07-26 | ダイキン工業株式会社 | 室内ユニット |
JP2020003163A (ja) * | 2018-06-29 | 2020-01-09 | 株式会社富士通ゼネラル | 空気調和機 |
EP4006449B1 (en) * | 2019-07-31 | 2024-04-10 | Daikin Industries, Ltd. | Freezing apparatus |
JP7049310B2 (ja) * | 2019-12-25 | 2022-04-06 | ダイキン工業株式会社 | 冷凍装置 |
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-
2001
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- 2001-03-30 CN CN01808346A patent/CN1425121A/zh active Pending
- 2001-03-30 KR KR1020027014017A patent/KR100669071B1/ko active IP Right Grant
- 2001-03-30 EP EP01917767A patent/EP1278026A4/en not_active Withdrawn
- 2001-03-30 WO PCT/JP2001/002837 patent/WO2001079767A1/ja active IP Right Grant
- 2001-03-30 EP EP09001186A patent/EP2051026A1/en not_active Withdrawn
- 2001-03-30 US US10/257,919 patent/US6971244B2/en not_active Expired - Lifetime
- 2001-03-30 BR BRPI0110611-2A patent/BR0110611B1/pt not_active IP Right Cessation
- 2001-03-30 CN CNA2007100855993A patent/CN101055140A/zh active Pending
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Also Published As
Publication number | Publication date |
---|---|
AU780334B2 (en) | 2005-03-17 |
CN1425121A (zh) | 2003-06-18 |
US20030167780A1 (en) | 2003-09-11 |
BR0110611A (pt) | 2003-04-29 |
KR20030009442A (ko) | 2003-01-29 |
BR0110611B1 (pt) | 2010-05-04 |
AU4469501A (en) | 2001-10-30 |
CA2402393C (en) | 2009-11-03 |
EP1278026A4 (en) | 2008-05-21 |
EP1278026A1 (en) | 2003-01-22 |
EP2051026A1 (en) | 2009-04-22 |
KR100669071B1 (ko) | 2007-01-15 |
JP4848576B2 (ja) | 2011-12-28 |
US6971244B2 (en) | 2005-12-06 |
JP2001304702A (ja) | 2001-10-31 |
CN101055140A (zh) | 2007-10-17 |
CA2402393A1 (en) | 2001-10-25 |
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