WO2001075186A1 - Barre a fil ou barre d'acier laminee a chaud pour utilisation dans des structures de machine pouvant se dispenser de recuit, et procede de fabrication associe - Google Patents
Barre a fil ou barre d'acier laminee a chaud pour utilisation dans des structures de machine pouvant se dispenser de recuit, et procede de fabrication associe Download PDFInfo
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- WO2001075186A1 WO2001075186A1 PCT/JP2001/002930 JP0102930W WO0175186A1 WO 2001075186 A1 WO2001075186 A1 WO 2001075186A1 JP 0102930 W JP0102930 W JP 0102930W WO 0175186 A1 WO0175186 A1 WO 0175186A1
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- rolled wire
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Classifications
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/06—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/003—Cementite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D7/00—Modifying the physical properties of iron or steel by deformation
- C21D7/13—Modifying the physical properties of iron or steel by deformation by hot working
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/573—Continuous furnaces for strip or wire with cooling
- C21D9/5732—Continuous furnaces for strip or wire with cooling of wires; of rods
Definitions
- Hot-rolled wire rods for machine structures that can be omitted for annealing
- the present invention relates to a hot wire and a steel bar for a machine structure and a method for producing the same, and more particularly, to a production of an automobile part, a construction part, etc., which is indispensable in a secondary working step following a hot rolling.
- the present invention relates to a soft wire rod and a steel bar capable of achieving mechanical properties such as strength and deformability obtained by a soft annealing treatment while hot rolling, and a method for producing the same.
- parts for automobiles, parts for construction machinery, etc. are formed by cold working such as drawing and cold forming after softening annealing the hot-rolled wire and steel bars to ensure cold workability. It is manufactured by quenching and tempering.
- soft annealing process for example, when manufacturing bolts, one of the mechanical parts, from hot-rolled wire rods, low-temperature annealing at about 650 ° C for 2 hours is performed for hexagonal
- a normal annealing at about 700 ° C for 3 hours is performed, and a spheroidizing annealing at about 720 ° C for about 20 hours is performed for a bolt with a large amount of cold working at a flange for securing cold workability. ing.
- JP-A-57-73123 which is a method for producing low alloy steel having excellent cold workability
- JP-A-58-58235 which is a method for directly softening structural steel wires
- Japanese Patent Application Laid-Open No. 2-185920 which is a method for manufacturing a softened wire rod
- Japanese Patent Application Laid-Open No. 8-209236 which is a method for manufacturing steel for machine structures suitable for cold working
- the present invention provides a wire rod subjected to soft annealing after conventional hot rolling, a wire rod for a machine structure as hot rolled having the same cold workability as a steel bar, a steel bar, and a method for producing the same.
- the challenge is
- the present inventor paid attention to the structure and reduction value (deformability) of the wire rod and the steel bar obtained by the soft annealing, and decided to obtain the structure and the reduction value (deformability) equivalent to that of the soft annealing while hot rolling. We studied to ensure more cold workability.
- Fig. 1 is a photomicrograph (4000x) of a hot-rolled CH45K steel rod subjected to normal softening treatment (700 ° C x 3 hr).
- the microstructure of steel is composed of ferrite 1 and lamellar perlite, and is a carbide in which part of the plate-like cementite in the lamellar perlite is divided.
- the softening of steel depends on the amount of ferrite in the steel structure.
- the cold workability of the wire is ensured due to the G fraction and the separation of the cementite in the lamella perlite.
- the present inventor has conducted a hot rough rolling process on a steel slab having a predetermined steel composition in a temperature range of 850 ° C to 1000 ° C or less, and a finish rolling in a temperature range of 700 ° C or more and 1000 ° C or less. Cooling to a temperature of not less than C and not more than 650 ° C, and cooling at a cooling rate of not less than O.rCZS. Immediately thereafter, maintain the furnace atmosphere temperature of not less than 650 ° C and not more than 720 ° C for not less than 15 minutes and not more than 90 minutes, and let it cool. As shown in the micrographs in Fig. 2 (a) and the micrograph in Fig.
- the ferrite 1 fraction of ferrite 1 in the structure was high, and the However, as shown in the spheroidized granular carbides 4 and the granular carbides precipitated at the grain boundaries, a new steel structure in which part of the cementite in the lamella perlite 3 is spheroidized is obtained, and The present invention was completed by finding that cold workability can be ensured because a high drawing value is obtained as hot rolled.
- the gist of the present invention is as follows.
- Item 1 The hot-rolled wire rod or steel bar for a machine structure according to the above item (1), wherein one or two or more types are contained.
- V 0.03% to 0.3%
- the hot-rolled wire rod or bar for machine structure according to the above (1) or (2) characterized in that it contains one or more of the following.
- the steel having the steel composition described in any of the above (1) to (3) is hot-rolled in a temperature range of 850 ° C to: After finishing rolling at a temperature range of 1000 ° C or less, cool at a cooling rate of 0.1 ° CZS or more to a temperature of 550 ° C or more and 650 ° C or less, and then cool at a temperature of 650 ° C or more and 720 ° C or less.
- a method for producing a hot-rolled wire or a steel bar for a machine structure which can be annealed without holding the furnace at an atmosphere temperature of 15 minutes to 90 minutes and then allowing it to cool.
- the microstructure is composed of ferrite and pearlite, the ferrite crystal grain size number specified in JIS G0552 is 11 or more, the circle equivalent diameter is 2 ⁇ or less, and the aspect ratio is A heat for mechanical structure characterized by containing 5 to 40% of granular carbide of 3 or less in terms of area, and having a tensile strength and a drawing value defined by the following formulas (1) and (2). Between rolled wire and steel bars. TS ⁇ 573XCeq +257 (1)
- a steel having a steel component according to any one of claims 1 to 3 is hot rough-rolled in a temperature range of 700 ° C or more and 1200 ° C or less, and 700 ° C or more and 1000 ° C or less. After finish rolling in the temperature range, cool down to a temperature of 200 ° C or more and 650 ° C or less, cool at a rate of 0.1 ° CZ S or more, and then immediately 600 ° C or more
- a method of manufacturing a hot-rolled wire rod for machine structure capable of omitting annealing wherein the steel sheet is kept at a furnace atmosphere temperature of 850 ° C or less for 15 minutes to 240 minutes and then cooled.
- a method for producing a hot-rolled wire rod or a steel bar for a machine structure which is maintained at a furnace atmosphere temperature of 600 ° C or more and 850 ° C or less for 15 minutes or more and 240 minutes or less, and then cooled.
- a method for producing a hot-rolled wire or a steel bar for a machine structure wherein the furnace is maintained at a furnace atmosphere temperature of 650 ° C or more and 720 ° C or less for 15 minutes to 90 minutes, and then cooled.
- a hot-rolled wire / bar for a machine structure which has a tensile strength and a drawing value defined by the following formulas (1) and (2).
- Figure 1 is a micrograph (X4000) of a steel structure obtained by normal annealing (700 ° C x 3 hours) a hot-rolled wire made of CH45K steel.
- FIGS. 2 (a) and 2 (b) are micrographs (X4000) of the steel structure of the as-heated wire rod according to the present invention.
- FIG. 3 is a diagram showing a comparison of strength between a conventional hot-rolled wire, a wire after normal annealing, and a hot-rolled wire of the present invention.
- FIG. 4 is a diagram showing a comparison of the drawing value of the conventional hot-rolled wire, the wire after normal annealing, and the hot-rolled wire of the present invention.
- FIG. 3 is a diagram showing a comparison of strength between a conventional hot-rolled wire, a wire after normal annealing, and a hot-rolled wire of the present invention.
- 1 is the conventional hot-rolled wire
- 2 is the wire that is normally annealed after hot rolling
- 3 is the strength of the hot-rolled wire of the present invention.
- the wire 3 as hot-rolled as in the present invention is the same as the conventional wire as-rolled irrespective of the wire having a different C content (0.25 to 0.45%).
- FIG. 4 is a diagram showing a comparison of the reduction values of the wire rod (1) normally annealed after the hot rolling and the wire rod (3) of the present invention as-hot rolled. It can be seen that the wire 3 as-is hot-rolled according to the present invention achieves softening and an improvement in the reduction value as well as the wire annealed after hot rolling.
- the steel material cracked under severe cold forging conditions, but the hot-rolled wire rod 3 of the present invention was confirmed not to crack even at a compression ratio of 80% or more. ing. (More than 80% may not be tested due to the risk of measuring instrument die damage)
- the ferrite grains present in the microstructure become finer and have a grain size number of 11 or more specified by JI SG 0552. Ferrite grains If the degree number is less than 11, the granulation of the cementite in the perlite becomes insufficient and the desired softening cannot be achieved.
- the amount of the granular carbide is required to be 5 to 40% in area ratio, but it is preferable to be 10% or more.
- Hot as-rolled material is formed into a molded part by cold forming using a mold.
- the strength of the material decreases (softens)
- C is an element necessary to increase the strength as a component for mechanical structures, but if it is less than 0.1%, the strength of the final product will be insufficient, and if it exceeds 0.5%, the toughness of the final product will deteriorate rather. Therefore, the C content was set to 0.1 to 0.5%.
- Si is added as a deoxidizing element and for the purpose of increasing the strength of the final product by solid solution hardening.However, if the content is less than 0.01%, the hardening of these is insufficient, while if it exceeds 0.5%, the content is increased. Since these hardenings are saturated and rather cause deterioration of toughness, the Si content is set to 0.01 to 0.5%.
- A1 deoxidation is used in addition to Si deoxidation. In particular, strong A1 deoxidation is desirable to lower the oxygen content. In such a case, less than 0.2% of A1 may remain in the steel, but the present invention can tolerate such A1.
- Mn is an effective element for increasing the strength of the final product through improvement of hardenability, but if it is less than 0.3%, this effect is insufficient. On the other hand, when the content exceeds 1.5%, this effect is saturated, and rather, the toughness is deteriorated. Therefore, the Mn content is set to 0.3 to 1.5%.
- S is an unavoidable portion contained in steel, and exists as MnS in steel, and contributes to improvement of machinability and refining of microstructure. 0.1% or less is acceptable. However, since S is a harmful element for cold forming, it is preferable to control the content to 0.035% or less when machinability is not required.
- P is a component inevitably contained in steel, but since P causes grain boundary segregation in the steel and causes deterioration of toughness, it is preferable to suppress P to 0.035% or less.
- the above are the basic components of the steel targeted by the present invention.
- one or more of Cr, Mo, Ni, Cu, and B can be further contained. These elements are added to increase the strength of the final product by increasing the hardenability. However, the multiple addition of these elements causes the formation of a bainite or martensite structure during hot rolling and causes an increase in hardness, and is not preferable in terms of economic efficiency. 2.0%, Mo: 0.1 ⁇ 1.0%, Ni: 0.3 ⁇ 1.5%, Cu: 1.0% or less, B: 0.005% or less.
- one or more of Ti, Nb, and V can be contained for the purpose of adjusting the particle size.
- the Ti content is less than 0.005%, the Nb content is less than 0.005%, and the V content is less than 0.03%, the effect is insufficient, while the Ti content is more than 0.04% and the Nb content is
- these contents are set as follows: Ti: 0.005 to 0.04%, Nb: 0.005 to 0.1% , V: 0.03 to 0.3%.
- the steel according to any one of claims 1 to 3 is subjected to hot rolling, austenite grains are refined, and then the ferrite-perillat transformation is completed by cooling.
- reheating By continuing heating (reheating), it is possible to obtain wires and bars with a new steel structure. Since the obtained wire and bar have softness and a high drawing value as they are hot-rolled, they can be used as cold-workable wires and bars for machine structural use.
- the slab is hot rough-rolled in a temperature range of 850 ° C to 1000 ° C or less, and after finish rolling in a temperature range of 700 ° C or more and 1000 ° C or less, 550 ° C or more and 650 ° C or less. Cooling to a temperature of 0.1 ⁇ S or more to complete the ferrite-per-light transformation and maintaining the furnace atmosphere temperature of 650 to 720 ° C for 15 to 90 minutes And let it cool down.
- Hot rough rolling 850 ° C or less The reason why the temperature is set to less than 1000 ° C is that if it is less than 850 ° C, rolling becomes difficult from the viewpoint of rolling mill load, and if it exceeds 1000 ° C, austenite crystal grains become coarse. This is because a ferrite grain size number of 11 or more after rolling cannot be obtained. When the finish rolling is performed at a temperature of 1000 ° C. or more, a ferrite grain size number of 11 or more cannot be obtained. Therefore, the allowable upper limit is set to 1000 ° C. in the present invention.
- finish rolling is performed in the temperature range of 700 ° C or more and 1000 ° C or less.
- cooling at a cooling speed of ⁇ ⁇ czs or more completes the ferrite-perillat transformation, but if the cooling speed is outside the range of o.rc z S or more, the time to transformation becomes longer and industrial It stipulates that production cannot be carried out. Desirably, the range is from 0. rc / S to 50 ° CZS. further, After finish rolling, set the temperature range to complete the fly perlite transformation.
- the steel temperature at the end of the pearlite transformation is lower than 550 ° C, it takes a long time (90 minutes or more) for the steel temperature inside the coil to reach the temperature range of 650 ° C or higher, which is difficult to raise in subsequent heating.
- the lower limit temperature is set to 550 ° C, because it is not preferable because it causes cost increase due to a remarkable decrease in productivity, and because some steels form a hard veneite structure when cooled to 550 ° C or less. If the temperature of the steel at the end of the pearlite transformation is 650 ° C or more, it takes a long time to complete the pearlite transformation. Therefore, the upper limit temperature is 650 ° C.
- the reason for setting the heating temperature range and heating time after completion of ferrite-perlite transformation to 650 ° C or more and 720 ° C or less and 15 minutes or more and 90 minutes, respectively, is that at temperatures lower than 650 ° C. This is because granulation of cementite and increase in the fraction of ferrite cannot be achieved, and softening and a high aperture value cannot be obtained. At a temperature higher than 720 ° C, part of the ferrite-palite structure becomes austenitized again, and then the strength is increased by cooling. Therefore, the heating temperature range should be between 650 ° C and 720 ° C.
- the heating time is shorter than 15 minutes, the temperature does not rise sufficiently to the inside of the coil, and the desired softening and reduction value cannot be obtained. If the heating time is more than 90 minutes, the cost will rise due to a remarkable decrease in productivity from the viewpoint of facilities.
- the mouth structure becomes ferrite and perliteka
- the ferrite grain size number specified in JI SG 0552 is 11 or more
- the circle equivalent diameter is 2 ⁇ or less
- Table 1 also shows the chemical components of the test materials. All of these were manufactured in a continuous process after converter melting. After slab rolling to a 162 mm square slab, it was rolled into a 11 mm warp rod under the rolling conditions shown in Table 2.
- Rolling level ⁇ in the method of the present invention is as follows: hot rough rolling at 950 ° C, finish rolling at 900 ° C which is a temperature range of 700 ° C or more and 1000 ° C or less, winding in a ring shape, and immediately Cooling to 600 ° C, a temperature range of 550 ° C or more and 650 ° C or less, by immersing in a coil, then immediately forming into a coil, heating at 700 ° C for 30 minutes while moving the coil in the furnace Then, it was allowed to cool outside the furnace.
- the finish rolling temperature was 1050 ° C, which is higher than the temperature range of 700 ° C or more and 1000 ° C or less, and the other conditions were the same as the rolling level ⁇ of the method of the present invention.
- the wire indicated by the symbol (3, 12, 21) in Table 3 was obtained.
- the cooling end point temperature was cooled to 660 ° C, which is higher than 550 ° C or higher and higher than 650 ° C, and the other conditions were treated in the same manner as in Rolling Level II of the present invention, and the results are shown in Table 3.
- the wire indicated by the symbol (4, 13, 22) was obtained.
- Comparative example level 600 is 600 ° C, which is lower than the furnace atmosphere temperature of 650 ° C or more and 720 ° C or less
- comparative example level ⁇ is a furnace atmosphere temperature of 650 ° C or more and 720 ° C or less.
- the wire was heated at 730 ° C, which was higher than the above, and treated under the same conditions as the rolling level 1 in the present invention to obtain the wire indicated by the symbol (5, 6, 14, 15, 23, 24) in Table 3. Was.
- the comparative example 7 was held for 10 minutes shorter than the range of 15 minutes or more and 90 minutes or less, and the other conditions were treated in the same manner as the rolling level ⁇ of the present invention, and the symbols (7, 16, 25 ) Was obtained.
- Comparative Example Level II hot rough rolling was performed at 900 ° C, finish rolling was performed at 750 ° C, and then gradually cooled copper was placed on the transport line. After that, it was allowed to cool, and the wire indicated by the symbol (8, 17, 26) in Table 3 was obtained. Comparative Example In Level II, hot rough rolling was performed at 1000 ° C, and after finish rolling at 900 ° C, the cooling was adjusted by applying a slow cooling cover to the coil transport line, and then allowed to cool. Furthermore, the coil after cooling was softened and annealed under the condition of standing at 700 ° C for 4 hours and then allowed to cool, obtaining the wire indicated by the symbols (9, 18, 27) in Table 3.
- the hot-rolled wire rods for machine structures of the present invention have a softened and high drawing value as they are hot-rolled without softening and annealing. Equal or better softness, aperture value, and critical compression ratio are obtained. Therefore, it is not necessary to perform soft annealing before cold working as in the past, so that productivity and energy saving can be achieved, and the life of the mold used for cold working can be greatly improved. It works.
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/240,952 US6896746B2 (en) | 2000-04-04 | 2001-04-04 | Hot-rolled steel wire rods and bars usable for machine structural use without annealing and method for producing the same |
JP2001573058A JP4018905B2 (ja) | 2000-04-04 | 2001-04-04 | 機械構造用熱間圧延線材・棒鋼およびその製造方法 |
DE60130755T DE60130755T2 (de) | 2000-04-04 | 2001-04-04 | Warmgewalzter draht oder stahlblock, die wärmebandelbar und verwendbar im maschinenbau sind und herstellungsverfahren dafür |
EP01919778A EP1281782B1 (en) | 2000-04-04 | 2001-04-04 | Hot rolled wire or steel bar for machine structural use capable of dispensing with annealing, and method for producing the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2000-102721 | 2000-04-04 | ||
JP2000102721 | 2000-04-04 |
Publications (1)
Publication Number | Publication Date |
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WO2001075186A1 true WO2001075186A1 (fr) | 2001-10-11 |
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ID=18616548
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/JP2001/002930 WO2001075186A1 (fr) | 2000-04-04 | 2001-04-04 | Barre a fil ou barre d'acier laminee a chaud pour utilisation dans des structures de machine pouvant se dispenser de recuit, et procede de fabrication associe |
Country Status (7)
Country | Link |
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US (1) | US6896746B2 (ja) |
EP (1) | EP1281782B1 (ja) |
JP (1) | JP4018905B2 (ja) |
KR (1) | KR100517674B1 (ja) |
DE (1) | DE60130755T2 (ja) |
TW (1) | TW512175B (ja) |
WO (1) | WO2001075186A1 (ja) |
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JP2010202913A (ja) * | 2009-03-02 | 2010-09-16 | Nippon Steel Corp | 高強度鋼線用線材、高強度鋼線及びこれらの製造方法 |
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KR102131529B1 (ko) * | 2018-11-27 | 2020-07-08 | 주식회사 포스코 | 구상화 열처리성이 우수한 선재 및 그 제조방법 |
CN110129675B (zh) * | 2019-05-23 | 2020-08-28 | 江苏省沙钢钢铁研究院有限公司 | 高强钢筋及其生产方法 |
CN111778441A (zh) * | 2020-07-09 | 2020-10-16 | 兰州理工大学 | 一种超高强度和塑性1045钢的制备方法 |
CN113275405B (zh) * | 2021-04-23 | 2024-02-06 | 中国科学院合肥物质科学研究院 | 一种twip钢丝直接拉拔成形的方法 |
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US6475306B1 (en) * | 2001-04-10 | 2002-11-05 | Nippon Steel Corporation | Hot rolled steel wire rod or bar for machine structural use and method for producing the same |
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- 2001-04-04 DE DE60130755T patent/DE60130755T2/de not_active Expired - Lifetime
- 2001-04-04 EP EP01919778A patent/EP1281782B1/en not_active Expired - Lifetime
- 2001-04-04 WO PCT/JP2001/002930 patent/WO2001075186A1/ja active IP Right Grant
- 2001-04-04 KR KR10-2002-7013237A patent/KR100517674B1/ko active IP Right Grant
- 2001-04-04 US US10/240,952 patent/US6896746B2/en not_active Expired - Lifetime
- 2001-04-04 TW TW090108190A patent/TW512175B/zh not_active IP Right Cessation
- 2001-04-04 JP JP2001573058A patent/JP4018905B2/ja not_active Expired - Fee Related
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JPH02213416A (ja) * | 1989-02-14 | 1990-08-24 | Toa Steel Co Ltd | 高延性棒鋼の製造方法 |
JPH11124655A (ja) * | 1997-10-22 | 1999-05-11 | Kawasaki Steel Corp | 超微細粒を有する鋼線、線材及び棒鋼並びにそれらの製造方法 |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2010053426A (ja) * | 2008-08-29 | 2010-03-11 | National Institute For Materials Science | 熱間圧延棒鋼線材とその製造方法 |
JP2010202913A (ja) * | 2009-03-02 | 2010-09-16 | Nippon Steel Corp | 高強度鋼線用線材、高強度鋼線及びこれらの製造方法 |
JP2010202920A (ja) * | 2009-03-02 | 2010-09-16 | Nippon Steel Corp | 高強度鋼線用線材、高強度鋼線及びこれらの製造方法 |
JP2010202954A (ja) * | 2009-03-05 | 2010-09-16 | Nippon Steel Corp | 高強度極細鋼線用線材、高強度極細鋼線、及び、これらの製造方法 |
JP2013007088A (ja) * | 2011-06-23 | 2013-01-10 | Kobe Steel Ltd | 冷間加工用機械構造用鋼およびその製造方法 |
US9845519B2 (en) | 2012-03-26 | 2017-12-19 | Kobe Steel, Ltd. | Boron-added high strength steel for bolt and high strength bolt having excellent delayed fracture resistance |
JP2013237903A (ja) * | 2012-05-16 | 2013-11-28 | Nippon Steel & Sumitomo Metal Corp | ボルト用鋼材 |
CN116043094A (zh) * | 2023-01-09 | 2023-05-02 | 鞍钢股份有限公司 | 一种改善中间丝热处理性能的铜包钢丝制造方法 |
Also Published As
Publication number | Publication date |
---|---|
DE60130755D1 (de) | 2007-11-15 |
EP1281782B1 (en) | 2007-10-03 |
JP4018905B2 (ja) | 2007-12-05 |
EP1281782A4 (en) | 2005-01-26 |
KR20020088425A (ko) | 2002-11-27 |
TW512175B (en) | 2002-12-01 |
KR100517674B1 (ko) | 2005-09-29 |
US6896746B2 (en) | 2005-05-24 |
US20030098104A1 (en) | 2003-05-29 |
EP1281782A1 (en) | 2003-02-05 |
DE60130755T2 (de) | 2008-07-17 |
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