WO2001026614A1 - Composition detergente - Google Patents

Composition detergente Download PDF

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Publication number
WO2001026614A1
WO2001026614A1 PCT/JP2000/007043 JP0007043W WO0126614A1 WO 2001026614 A1 WO2001026614 A1 WO 2001026614A1 JP 0007043 W JP0007043 W JP 0007043W WO 0126614 A1 WO0126614 A1 WO 0126614A1
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WO
WIPO (PCT)
Prior art keywords
surfactant
ether
group
carbon atoms
component
Prior art date
Application number
PCT/JP2000/007043
Other languages
English (en)
Japanese (ja)
Inventor
Chikako Matsumoto
Keiko Hasebe
Hiroshi Sonohara
Nobuaki Tatsuta
Tetsuya Miyajima
Kennichi Kasuga
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from JP28988199A external-priority patent/JP4287555B2/ja
Priority claimed from JP29230099A external-priority patent/JP4287556B2/ja
Priority claimed from JP29230199A external-priority patent/JP4210399B2/ja
Priority claimed from JP29229999A external-priority patent/JP4210398B2/ja
Priority claimed from JP29230299A external-priority patent/JP4210400B2/ja
Priority claimed from JP33281899A external-priority patent/JP4275823B2/ja
Application filed by Kao Corporation filed Critical Kao Corporation
Publication of WO2001026614A1 publication Critical patent/WO2001026614A1/fr

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A61Q19/10—Washing or bathing preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/345—Alcohols containing more than one hydroxy group
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/45—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/06—Ether- or thioether carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/126—Acylisethionates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/90—Betaines
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0094—High foaming compositions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/596—Mixtures of surface active compounds

Definitions

  • the present invention relates to a detergent composition which is mild to the skin, has good foaming, and is excellent in a feeling of feeling after rinsing and stability at low temperatures.
  • Detergent compositions that come into direct contact with the skin are required to have low irritation to the skin in addition to detergency, foaming properties, and feeling of use.
  • Sulfate surfactants which are widely used as cleansing ingredients, have high foaming performance, but may seep when shampooing, and if used for a long period of time, may cause sensitive hands and skin to become rough.
  • the cleaning power is high, there is a problem that the shampoo squeezes the hair during rinsing and deteriorates the usability.
  • a conditioning component such as a cationic polymer or a silicone compound is added to improve the rinsing property, the foaming property is reduced.
  • ether carboxylic acid surfactants N-acyl amino acid surfactants, acyl isethionates, acyl taurine surfactants, polyoxyethylene fatty acid amide ether sulfate surfactants, amidoamine amphoteric surfactants
  • Surfactants with low irritation to the skin, such as agents have been developed. However, all of these surfactants have poor foaming properties. Therefore, when used in a detergent composition, it is necessary to use a large amount of a sulfate type surfactant or a betaine type surfactant. Was. When the amount of the surfactant used in combination is increased, the foaming property is improved, but the characteristic of these surfactants, which is inherently low irritation, cannot be utilized. Some of these surfactants were inferior in low-temperature stability depending on the type.
  • An object of the present invention is to provide a detergent composition that is less irritating to the skin, has good foaming, and has excellent low-temperature stability. Disclosure of the invention
  • glyceryl ether having a specific structure has the effect of increasing the foaming properties of other surfactants, and that when this glyceryl ether is used in combination with a specific surfactant, It has been found that a detergent composition which is low irritation, has good foaming, and has excellent moist feeling after rinsing and excellent low-temperature stability can be obtained.
  • the present invention provides the following components (A) and (B):
  • (A) (1) ether carboxylic acid surfactant, (2) N-acyl amino acid or a salt thereof, (3) acyl isethionate, (4) amidoamine type amphoteric surfactant,
  • acyl taurine surfactant one or more selected from an acyl taurine surfactant and (6) a polyoxyethylene fatty acid amide ether sulfate type surfactant,
  • the present invention provides a cleaning composition comprising:
  • the present invention provides a foam-enhancing agent containing the glyceryl ether as an active ingredient.
  • the present invention provides a method for increasing the foaming of the detergent composition containing the above-mentioned component (A), which contains the glyceryl ether.
  • the ether carboxylic acid-based surfactant may be represented by the general formula (1)
  • R 1 ⁇ Z— (AO) n — Y— COOX (1)
  • R 1 represents an alkyl group or an alkenyl group which may have a linear or branched hydroxyl group having 5 to 21 carbon atoms
  • Z represents —O— or —CONH—
  • A represents X represents an alkylene group having 2 or 3 carbon atoms
  • X represents a hydrogen atom, an alkali metal, an alkaline earth metal, ammonia, a mono-, di- or trialkano-l-monmonium or a basic amino acid having a total carbon number of 1 to 22
  • Y represents an alkylene group having 1 to 3 carbon atoms
  • n ′ represents a number of 2 to 15
  • R 1 when Z is —0_, R 1 preferably has 12 to 16 carbon atoms, and when Z is —CONH—, R ′ has 11 to 15 carbon atoms. It is preferred that A is preferably an ethylene group or a propylene group, particularly preferably an ethylene group.
  • X is preferably an alkali metal, particularly preferably sodium or potassium.
  • Y preferably has 1 carbon atom.
  • n 1 represents the average number of moles of alkylene oxide added, preferably 2 to 10.
  • One or more ether carboxylic acid-based surfactants (1) can be used, and 2 to 60% by weight, particularly 5 to 50% by weight, and more preferably 5 to 40% by weight in the total composition. Is preferred.
  • N-acyl amino acid examples include glutamic acid, aspartic acid, alanine, glycine and the like.
  • the acyl group preferably has 8 to 18 carbon atoms, and examples thereof include a caprinyl group, a lauroyl group, a myristyl group, and a palmitoyl group.
  • the amide nitrogen of the N-amino acid may be substituted with a lower alkyl group.
  • the lower alkyl group those having 1 to 3 carbon atoms are preferable, and examples thereof include a methyl group, an ethyl group, an n-propyl group, and an isopropyl group.
  • examples of these salts include alkyl metal salts such as sodium and potassium; alkanolamine salts such as triethanolamine; and basic amino acid salts such as arginine.
  • alkyl metal salts such as sodium and potassium
  • alkanolamine salts such as triethanolamine
  • basic amino acid salts such as arginine.
  • N-acyl amino acids include N-cocoylglycine, N-acyl-N-carboxyl tyldaricin, N-lauroylglutamic acid, and N-myristoyl.
  • Glutamic acid N-cocoyldarnic acid, N-lauroylue; 3-alanine, N-lauroylue N-isopropylglycine, N-lauroylsarcosine, N-myristoylsarcosine, N-palmitoylsarcosine, N-lauroyl-N-methyl-
  • 3-alanine and the like and further, their alkali metal salts, alkanolamine salts, basic amino acid salts and the like.
  • N-acyl amino acids or salts thereof can be used, and 2 to 70% by weight, particularly 5 to 50% by weight, and more preferably 10 to 30% by weight in the whole composition. It is preferable to contain them from the viewpoint of foaming properties.
  • R 2 represents an alkyl group or an alkenyl group which may have a hydroxyl group having 7 to 21 carbon atoms
  • M 1 represents an alkali metal, an alkaline earth metal, ammonium, alkyl ammonium or (Alkanoummonium is shown.
  • R 2 is preferably an alkyl group having 11 to 15 carbon atoms, and more preferably, an R 2 C-1 acyl group is a lauroyl group, a myristoyl group, or a cocoyl group.
  • M examples include alkali metals such as sodium and potassium; alkaline earth metals such as calcium and magnesium; ammonium; alkanol ammonium such as triethanolamine, and the like, with alkali metals and ammonium being particularly preferred.
  • acyl isethionate examples include sodium lauroyl isethionate, sodium cocoyl isethionate, and cocoyl isethionate. And the like.
  • acyl isethionates can be used, and the content in the total composition is usually 20 to 90% by weight, especially 30 to 70% by weight when the detergent composition is solid. %; Preferably 10 to 70% by weight in the case of an aqueous base; 3 to 40% by weight, particularly preferably 3 to 20% by weight in the case of an aqueous liquid. .
  • amidoamine type amphoteric surfactant the general formula (3) or (4)
  • R and R 5 represent an alkyl group or an alkenyl group having 7 to 19 carbon atoms
  • R 4 and R 6 are - CH 2 COOM 2, -CH 2 CH 2 COOM 2 or - CH 2
  • OH alkali metal represents an alkaline earth metal, shows a Anmoniumu or alkanol ⁇ Min
  • R is a hydrogen atom, -CH, COOM 2, -CH 2 CH 2 COOM 2 or - CH 2 CHCH 2 S0 3 M 2 (M 2 before
  • R 3 and R 5 are preferably an alkyl group having 11 to 15 carbon atoms, and an acyl group of R 3 CO— or R 5 CO— is a lauroyl group, a myristoyl group, or a palmitoyl. And cocoyl groups.
  • M 2 examples include a hydrogen atom; an alkali metal such as sodium and potassium; an alkaline earth metal such as potassium and magnesium; an ammonium; an alkanolamine such as triethanolamine; Luamine is preferred.
  • the compound represented by the general formula (3) include, for example, N-lautyl-N'-potoxymethyl-N '-(2-hydroxyethyl) ethylenediamine, N-lauroylu N'-carboxyethyl — N '— (2-Hydroxyethyl) Ethylenediamine, N—Myristoyl—N′—Caproloxymethyl—N ′ — (2-Hydroxyethyl) Ethylenediamine, N—Myristoyl—N′—Carboxixethyl—N ′ — (2— Hydroxyethyl) Ethylenediamine, N-cocoyl- — '—Carpoxymethyl_ ⁇ '-(2-hydroxyethyl) ethylenediamine, ⁇ -cocoyl—N'—Power-l-poxyshethyl-N '-(2-hydroxyethyl) ethylenediamine, ⁇ —palmitoy
  • the compound represented by the general formula (4) include, for example, ⁇ -lauroylu ⁇ ⁇ -(2-hydroxyethyl) -1-N'-carboxymethylethylenediamine, ⁇ -lauroylu ⁇ - (2-hydroxyethyl) diamine Chill) — N ', ⁇ ' — screw
  • the amidoamine-type amphoteric surfactant (4) is a surfactant obtained by reacting 1 to 2 mol of monochloroacetic acid or acrylic acid with 1 mol of an imidazoline derivative, for example. It was called surfactant or imidazolini emubein, etc.In the 5th edition of the CTFA Dictionary, SODIUM COCOAMPHOACETATE, SODIUM COCOAMPHOPROPIONATE, SODIUM Corresponds to what is described as I ACETATE and is widely known under the trademark "Miranol".
  • amidoamine-type amphoteric surfactants (4) can be used, and it is preferable to contain 2 to 60% by weight, particularly 5 to 50% by weight, and more preferably 5 to 40% by weight in the whole composition.
  • R 8 represents an alkyl group having 1 to 19 carbon atoms, a hydroxyalkyl group or an alkenyl group
  • R 9 represents a hydrogen atom or an alkyl group having 1 to 3 carbon atoms
  • M 3 hydrogen atom , Alkali metal, alkaline earth metal, ammonium or alkanol ammonium
  • R 8 is preferably an alkyl group having 9 to 17 carbon atoms, and particularly preferably an alkyl group having 9 to 13 carbon atoms.
  • R 9 is a methyl group, an ethyl group, n— Examples thereof include a propyl group and an isopropyl group, and a methyl group is particularly preferable.
  • M 3 examples include a hydrogen atom; an alkali metal such as sodium and potassium; an alkaline earth metal such as potassium and magnesium; an ammonium; an alkanol ammonium such as triethanolamine; and the like, particularly an alkali metal and a hydrogen atom. Also preferred is sodium.
  • acyl-taurine-based surfactant examples include N-lauroyl-N-methyltaurine, N-cocoyl-N-methyltaurine, N-myristoyl N-methylsulfuric acid, and these metal salts. And the like.
  • One or more of the acyl-taurine-based surfactants (5) can be used, and it is preferable that the surfactant be contained in the entire composition in an amount of 1 to 50% by weight, particularly 2 to 30% by weight, and more preferably 3 to 20% by weight. .
  • R 'Q is an alkyl or alkenyl group of 7 to 2 1 carbon atoms
  • R 11 represents a water atom or an alkyl group having 1 to 3 carbon atoms
  • M 4 a hydrogen atom, an alkali metal, ⁇ alkaline earth metal, shows a Anmoniumu or alkanol ammonium Niu beam
  • n 2 is a number of 2-2 0
  • R l () is preferably an alkyl group or alkenyl group having 9 to 17 carbon atoms, particularly preferably an alkyl group or alkenyl group having 9 to 13 carbon atoms.
  • R include a hydrogen atom, a methyl group, and an ethyl group, and a hydrogen atom is particularly preferable.
  • a hydrogen atom As the M 4, a hydrogen atom; alkali metals such as sodium and potassium; force Rushiumu, alkaline earth metals such as magnesium metal; Anmoniumu; triethanolamine And alkali metals, particularly sodium, are preferred in terms of foaming property.
  • n 2 represents the average number of moles of ethylene oxide added, preferably 2 to 10, particularly preferably 2 to 5.
  • polyoxyethylene fatty acid amide ester sulfate type surfactant examples include polyoxyethylene (3) sodium lauric acid ester sodium sulfate, polyoxyethylene (3) coconut oil fatty acid amide ester sulfate Thorium and the like.
  • One or more polyoxyethylene fatty acid amide ether sulfate type surfactants can be used, and from the viewpoint of detergency and irritation, 1 to 50% by weight, especially 2 to 30% by weight in the whole composition. % By weight, more preferably 3 to 20% by weight.
  • the component (A) includes (1) an ether carboxylic acid-based surfactant, (4) an amidoamine-type amphoteric surfactant, (5) an acyltaurin-based surfactant, and (6) a poly (polyurethane) surfactant.
  • an ether carboxylic acid-based surfactant (4) an amidoamine-type amphoteric surfactant, (5) an acyltaurin-based surfactant, and (6) a poly (polyurethane) surfactant.
  • One or more selected from oxyethylene fatty acid amide ether sulfate type surfactants are more preferable, and (1) an ether carboxylic acid type surfactant is particularly preferable.
  • the glyceryl ether of the component (B) is a glycerin mono-, di-, or triether, preferably a glycerin mono- or ether, and particularly preferably a monoether.
  • the glyceryl ether has a linear or branched alkyl or alkenyl group having 4 to 12 carbon atoms. Among them, a glyceryl ether having a linear alkyl or alkenyl group is preferable.
  • n-butyl isobutyl, tert-butyl, n-pentyl, isopentyl, n-hexyl, isohexyl, n-heptyl, n-octyl, 2-ethylhexyl, n
  • carbon number 4-11 more carbon number 6-10, especially carbon number Mono- or diglyceryl ethers having an alkyl group of 8, especially monoglyceryl ether, are preferred.
  • One or more glyceryl ethers of component (B) can be used, and 0.1 to 30% by weight, particularly 0.5 to 15% by weight, and more preferably 1 to 10% by weight in the total composition. preferable.
  • the weight ratio [(A) / (B)] of the component (A) to the component (B) in the composition of the present invention is 99Z1 to 30Z70, particularly 95Z5 to 50Z50, and more preferably 90Z10 to 60/40. preferable.
  • the cleaning composition of the present invention may contain (C) an anionic or nonionic water-soluble polymer for the purpose of improving foam quality.
  • the component (C) may be any of natural and synthetic ones.
  • those having an average molecular weight of 10,000 to 100,000, and more preferably 10,000 to 3,000,000 (measured by a light scattering method) are preferable in terms of foaming power and fineness of foam.
  • polyvinyl alcohol, hydroxypropyl methylcellulose, Polyethylene oxide is preferred.
  • the component (C) can be used in combination of two or more kinds.
  • the content of the component (C) in the detergent composition of the present invention varies depending on the type of the detergent and the like, but is preferably 0.01 to 5% by weight, more preferably 0.05 to 3% by weight in the total composition. Further, when the content is 0.1 to 1% by weight, the foam quality becomes fine, which is preferable.
  • the cleaning composition of the present invention further includes components used in ordinary cleaning compositions, for example, humectants such as propylene glycol, glycerin, diethylene glycol monoethyl ester, sorbitol, and panthenol; cationic polymers Conditioning agents such as silicone compounds and derivatives thereof; pearling agents such as ethylene glycol stearic acid ester; nonionic surfactants such as polyoxyethylene alkyl ether and alkyl polidaricoside; amphoteric surfactants such as alkylamidopropyl betaine Anionic surfactants other than component (A); cationic surfactants such as cetyltrimethylammonium salt; coloring agents such as dyes and pigments; viscosity modifiers such as methylcellulose, polyethylene glycol and ethanol; citric acid, and water oxidation Power PH adjusters such as gum; salts such as sodium chloride, plant extracts, preservatives, bactericides, chelating agents, vitamins, anti-inflammatory agents
  • the detergent composition of the present invention can be produced according to a conventional method, and can be applied to a detergent composition such as a shampoo, a whole body detergent, a facial cleanser, a body detergent such as a hand detergent, and the like.
  • a detergent composition such as a shampoo, a whole body detergent, a facial cleanser, a body detergent such as a hand detergent, and the like.
  • a cleaning composition having the composition shown in Table 1 was produced by an ordinary method, and evaluated for foaming power, feeling of feeling after rinsing, irritation and low-temperature stability. The results are shown in Table 1. (Evaluation method)
  • a body wash having the following composition was produced by a conventional method.
  • the resulting body wash was mild to the skin, had good foaming, and was excellent in moist feeling after rinsing and low-temperature stability.
  • a cleaning composition having the composition shown in Table 2 was produced by a conventional method, and evaluated for foaming power, irritation and squeaky feeling during rinsing. The results are shown in Table 2.
  • A Foaming amount 20 OmL or more.
  • Ten expert panelists used 2 g of each detergent composition and an appropriate amount of tap water to wash the upper arm with the palm, and sensuously evaluated the squeaky feeling when rinsed with tap water for 1 minute according to the following criteria. .
  • the average point was determined, and the average was 1.5 or more as ⁇ , 0.5 or more and less than 1.5 as ⁇ , and less than 0.5 as X.
  • a shampoo having the following composition was produced by a conventional method.
  • the resulting shampoo was less irritating to the skin, had good foaming, and did not irritate during rinsing.
  • a detergent composition having the composition shown in Table 3 was produced by a conventional method, and evaluated for foaming power and irritation in the same manner as in Example 1. The results are shown in Table 3.
  • a solid stone having the following composition was produced by a conventional method.
  • a shampoo having the following composition was produced by a conventional method.
  • a body having the following composition was manufactured by a conventional method.
  • a cleaning composition having the composition shown in Table 4 was produced by a conventional method, and evaluated for foaming power, irritation, and low-temperature stability in the same manner as in Example 1. The results are shown in Table 4.
  • a body wash having the following composition was produced by a conventional method.
  • the obtained body wash had low irritation to the skin, and was excellent in foaming power and low-temperature stability.
  • a cleaning composition having the composition shown in Table 5 was produced by a conventional method, and the foaming power, the feeling of feeling after rinsing, the irritation, and the low-temperature stability were evaluated in the same manner as in Example 1. The results are shown in Table 5.
  • a shampoo having the following composition was produced by a conventional method.
  • the resulting shampoo was mild to the skin, had good foaming, and was excellent in moist feeling after rinsing and low-temperature stability.
  • a cleaning composition having the composition shown in Table 6 was produced by a conventional method, and evaluated for foaming power and irritation in the same manner as in Example 1. The results are shown in Table 6.
  • a body wash having the following composition was produced by a conventional method.
  • the resulting body wash was mild to the skin and showed good foaming.
  • a shampoo having the following composition was produced by a conventional method.
  • the resulting shampoo was mild to the skin and showed good foaming.
  • cleaning composition which is less irritating to skin, foams well, is excellent in moist feeling after rinsing, and is excellent in low-temperature stability is obtained.

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  • Life Sciences & Earth Sciences (AREA)
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  • Engineering & Computer Science (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
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  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
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Abstract

L'invention se rapporte à une composition détergente contenant (A) au moins un élément sélectionné parmi (1) des tensioactifs à base d'acide carboxylique-éther, des acides N-acylamino et des sels de ces derniers, (3) des sels acylisethionate, (4) des tensioactifs amphotères à base d'amidoamines, (5) des tensioactifs à base d'acyltaurine et (6) des tensioactifs sulfate-éther-amide-acide gras-polyoxyéthylène et (B) un éther de glycéryle ayant des groupes alkyle ou alcényle de 4 à 12 atomes. Cette composition s'avère peu irritante pour la peau et excellente s'agissant de son aptitude à mousser et de sa stabilité à basse température.
PCT/JP2000/007043 1999-10-12 2000-10-11 Composition detergente WO2001026614A1 (fr)

Applications Claiming Priority (12)

Application Number Priority Date Filing Date Title
JP28988199A JP4287555B2 (ja) 1999-10-12 1999-10-12 洗浄剤組成物
JP11/289881 1999-10-12
JP29230099A JP4287556B2 (ja) 1999-10-14 1999-10-14 洗浄剤組成物
JP11/292299 1999-10-14
JP11/292301 1999-10-14
JP29230199A JP4210399B2 (ja) 1999-10-14 1999-10-14 洗浄剤組成物
JP29229999A JP4210398B2 (ja) 1999-10-14 1999-10-14 洗浄剤組成物
JP29230299A JP4210400B2 (ja) 1999-10-14 1999-10-14 洗浄剤組成物
JP11/292300 1999-10-14
JP11/292302 1999-10-14
JP33281899A JP4275823B2 (ja) 1999-11-24 1999-11-24 洗浄剤組成物
JP11/332818 1999-11-24

Publications (1)

Publication Number Publication Date
WO2001026614A1 true WO2001026614A1 (fr) 2001-04-19

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2000/007043 WO2001026614A1 (fr) 1999-10-12 2000-10-11 Composition detergente

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Country Link
WO (1) WO2001026614A1 (fr)

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57119998A (en) * 1981-01-20 1982-07-26 Kao Corp Shampoo composition
EP0269939A2 (fr) * 1986-11-18 1988-06-08 Kao Corporation Composition détergente
WO1990012960A1 (fr) * 1989-04-18 1990-11-01 Pharmacia Biosensor Ab Appareil de pompage et de dosage
JPH0415298A (ja) * 1990-05-09 1992-01-20 Kao Corp 洗浄剤組成物
JPH05339597A (ja) * 1992-06-08 1993-12-21 Kawaken Fine Chem Co Ltd 洗浄剤組成物
JPH06279228A (ja) * 1993-03-30 1994-10-04 Kao Corp 発泡性組成物
WO1995014073A1 (fr) * 1993-11-18 1995-05-26 Henkel Kommanditgesellschaft Auf Aktien Octylethers de glycerine utilises dans des melanges tensioactifs
JPH08134494A (ja) * 1994-11-07 1996-05-28 Ajinomoto Co Inc 洗浄剤組成物
JPH10245590A (ja) * 1997-02-28 1998-09-14 Kanebo Ltd 洗浄剤組成物

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57119998A (en) * 1981-01-20 1982-07-26 Kao Corp Shampoo composition
EP0269939A2 (fr) * 1986-11-18 1988-06-08 Kao Corporation Composition détergente
WO1990012960A1 (fr) * 1989-04-18 1990-11-01 Pharmacia Biosensor Ab Appareil de pompage et de dosage
JPH0415298A (ja) * 1990-05-09 1992-01-20 Kao Corp 洗浄剤組成物
JPH05339597A (ja) * 1992-06-08 1993-12-21 Kawaken Fine Chem Co Ltd 洗浄剤組成物
JPH06279228A (ja) * 1993-03-30 1994-10-04 Kao Corp 発泡性組成物
WO1995014073A1 (fr) * 1993-11-18 1995-05-26 Henkel Kommanditgesellschaft Auf Aktien Octylethers de glycerine utilises dans des melanges tensioactifs
JPH08134494A (ja) * 1994-11-07 1996-05-28 Ajinomoto Co Inc 洗浄剤組成物
JPH10245590A (ja) * 1997-02-28 1998-09-14 Kanebo Ltd 洗浄剤組成物

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