WO2001024925A1 - Verfahren zur aktivierung von passiviertem eisen - Google Patents
Verfahren zur aktivierung von passiviertem eisen Download PDFInfo
- Publication number
- WO2001024925A1 WO2001024925A1 PCT/EP2000/009020 EP0009020W WO0124925A1 WO 2001024925 A1 WO2001024925 A1 WO 2001024925A1 EP 0009020 W EP0009020 W EP 0009020W WO 0124925 A1 WO0124925 A1 WO 0124925A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- iron
- activation
- component
- nitrile
- catalyst
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/16—Reducing
- B01J37/18—Reducing with gases containing free hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C211/00—Compounds containing amino groups bound to a carbon skeleton
- C07C211/01—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms
- C07C211/02—Compounds containing amino groups bound to a carbon skeleton having amino groups bound to acyclic carbon atoms of an acyclic saturated carbon skeleton
- C07C211/09—Diamines
Definitions
- the present invention relates to a method for activating passivated iron, which is suitable as a catalytically active component after activation, with hydrogen at elevated temperature and pressure, characterized in that the activation is carried out in the presence of a nitrile.
- the present invention further relates to the use of nitriles in such processes, iron obtainable by this process, use of iron in heterogeneous catalysts and processes for hydrogenation using such catalysts.
- Catalysts consisting entirely or largely of elemental iron are of great importance, e.g. B. for the synthesis of ammonia from nitrogen and hydrogen, for the production of hydrocarbons from synthesis gas (Fischer-Tropsch synthesis) and for the hydrogenation of nitriles to amines (JW Geus, Applied Catalysis 25, pages 313 to 333 (1986 ).
- Such catalysts are usually produced by reducing iron oxides with hydrogen.
- the iron oxide is reduced at high temperatures in the hydrogen stream, the oxide oxygen being converted into water and being discharged in this form.
- DP-PS 855.263 describes the reduction of molten and subsequently crushed iron oxide at 400 ° C in a stream of hydrogen.
- No. 3,758,584, column 1, lines 47 to 65 shows that the reduction of the iron oxides is carried out at 300 to 600 ° C. in the presence of 0.01 to 10 percent by volume of ammonia. A temperature of 350 to 420 ° C. is preferred, the hydrogen containing 0.25 to 3 percent by volume of ammonia (column 2, lines 12 to 18). Such iron catalysts are used for. B. used for the hydrogenation of adiponitrile to hexamethylenediamine.
- the reduction can also be carried out in three stages by reducing the iron oxide with hydrogen or mixtures of hydrogen and ammonia in a first step, then treating the elemental iron formed in a second step with an oxygen-containing gas and then in a third step Reduction analogous to the first step - repeated.
- the reduced iron catalyst produced by the processes mentioned is pyrophoric. If the reduction of the iron oxide was carried out directly in the synthesis reactor intended for the subsequent reaction, the catalyst can then be used for the intended chemical conversion.
- the reduction in the synthesis reactor has disadvantages: since the reduction takes many hours together with heating and cooling, the reactor is not available for production during this time.
- the reduction temperature can be significantly higher than the later synthesis temperature. This means additional equipment expenditure on the reactor, which is only required for the reduction.
- the pyrophoric catalyst must be passivated by treatment with air.
- This passivation can according to WO 98/11/05 at temperatures in the range of 20 to 80 ° C, preferably 25 to 60 ° C, z. B. with nitrogen-oxygen mixtures.
- the activation of such catalysts (“reduced / passivated”) is then carried out in the synthesis reactor at a temperature in the range from 180 to 500 ° C., preferably from 200 to 400 ° C., in a hydrogen-containing atmosphere.
- activation is understood to mean the conversion of a reduced / passivated iron into a catalytically active form.
- DE-A-3, 524, 330 describes the activation of passivated iron in the presence of a redox system, e.g. Ketone / alcohol, at temperatures of around 200 ° C.
- a redox system e.g. Ketone / alcohol
- the present invention was therefore based on the object of providing a process which enables the activation of passivated iron, which is suitable as a catalytically active component after activation, with hydrogen at elevated temperature and increased pressure in a technically simple and economical manner, while avoiding it of the disadvantages mentioned.
- the passivated iron used in the process according to the invention and suitable as a catalytically active component after activation can be obtained by processes known per se.
- iron oxides, iron hydroxides, iron oxyhydroxides or mixtures thereof can be used as precursors of such iron (component a).
- iron (III) oxide, iron (II, III) oxide, iron (II) oxide, iron (II) hydroxide, iron (III) hydroxide or iron oxyhydroxide such as FeOOH come in consideration.
- Such compounds can be used for the production of iron-containing supported catalysts, preferably for the production of iron-containing unsupported catalysts.
- readily water-soluble salts of iron such as nitrates, chlorides, acetates, formates or sulfates, preferably nitrates, or mixtures thereof, and mixtures of such salts with the iron oxides, iron hydroxides or iron oxyhydroxides already mentioned can be used as component a) become.
- Such compounds can be used for the production of iron-containing unsupported catalysts, preferably for the production of iron-containing supported catalysts.
- the passivated iron used in the process according to the invention which is suitable as a catalytically active component after activation, can contain further components, such as promoters.
- component (c) one or more compounds based on one or more alkali or alkaline earth metals are advantageous.
- the precursor of component (a) may already contain part or all of component (b) or its precursor.
- the precursor of component (a) may already contain part or all of component (c) or its precursor.
- Suitable precursors of component (b) are preferably readily water-soluble salts or complex salts of the elements mentioned, such as nitrates, chlorides, acetates, formates, sulfates, preferably nitrates.
- Suitable precursors of component (c) are preferably readily water-soluble salts or complex salts of the elements mentioned, such as hydroxides, carbonates, nitrates, chlorides, acetates, formates, sulfates, preferably hydroxides and carbonates.
- Such supported catalysts can contain support materials known per se, preferably aluminum oxide, silicon oxide, aluminum silicates, lanthanum oxide, titanium dioxide, zirconium dioxide, magnesium oxide, zinc oxide, zeolites or activated carbon and mixtures thereof.
- the catalyst precursors can generally be prepared by, if desired, precursors of component (a) together with precursors of component (b) and, if desired, with precursors of component (c) in the absence, or in the case of supported catalysts, in the presence of support materials precipitates, if desired, the catalyst precursor thus obtained is processed into strands or tablets, dried and then calcined.
- the precipitation can generally be carried out from aqueous solutions in a manner known per se, for example by adding precipitation reagents, by changing the pH or by changing the temperature.
- Supported catalysts are generally also obtainable by impregnating a support material with a solution of component (a), if desired component (b) and if desired component (c), it being possible to add the individual components simultaneously or in succession, or by adding the components ( a), if desired component (b) and, if desired, component (c) sprayed onto a carrier material by methods known per se.
- the catalyst precursor composition thus obtained can generally be predried at temperatures in the range from 80 to 150, preferably from 80 to 120 ° C. This is usually followed by a calcination.
- the calcination is usually carried out at temperatures in the range from 150 to 500 ° C., preferably from 200 to 450 ° C. in a gas stream, for example from air or nitrogen. 5
- the catalyst precursors containing passivated iron which is suitable as a catalytically active component after activation, can also be obtained by melting iron-containing oxides, hydroxides or oxide hydroxides or mixtures of such compounds at temperatures
- iron-containing starting compounds can already contain component (b) or component (c). It is also possible, if desired, to add component (b) or component (c) or components (b) and (c).
- the catalyst precursor mass obtained is generally exposed to a reducing atmosphere.
- the catalyst precursor composition is preferably set at a temperature in the range from 200 to 500 ° C., preferably from 250 to
- the reaction times are generally 2 to 72 hours.
- the load on the catalyst precursor is preferably 100 to 500 Nl / 1 catalyst precursor x hour, for
- the passivation of the catalyst precursor containing metallic iron is generally carried out at 20 to 100 ° C., preferably 25 30 to 60 ° C.
- the catalyst precursors can advantageously be brought into contact with an oxidizing gas, preferably with a molecular oxygen-containing gas, in particular with a mixture of nitrogen and oxygen.
- the catalyst precursor is activated according to the invention with hydrogen at elevated temperature and pressure in the presence of a nitrile.
- the hydrogen can be used as a pure gas or as a gas containing further constituents, such as inert gas, for example nitrogen or argon, in particular nitrogen.
- inert gas for example nitrogen or argon, in particular nitrogen.
- the activation of the catalyst precursor can advantageously be carried out in the reactor in which the catalyst is used after the activation.
- the catalyst precursor can do this as Fixed bed arranged in the reactor or suspended in the reactor in a solvent.
- all nitriles, ie organic compounds which have at least one, preferably several, such as two, three or four nitrile groups reactive in the process according to the invention can be used individually or in a mixture, such as aromatic nitriles, ie nitriles , in which the nitrile group is directly linked to an aromatic or arylaliphate, for example benzonitrile, o-aminobenzonitrile or phthalonitrile, or aliphatic nitriles, ie nitriles, in which the nitrile group is linked to an aliphatic system or the aliphatic part of an arylaliphate is directly linked.
- the aromatic or aliphatic nitriles can carry one or more, such as two, three or four further identical or different functional groups, such as amino groups or ester groups.
- Suitable aliphatic nitriles are those with 1 to 20 carbon atoms, calculated without the nitrile group or nitrile groups, where the aliphatic system can be linear, branched or cyclic, such as linear nitriles with a nitrile group, for example acetonitrile or propionitrile , Cyclic nitriles with a nitrile group, for example cyclohexyl nitrile, linear nitriles with a nitrile group and a further functional group, for example cyanoacetic acid esters or 6-aminocapronitrile, such as linear nitriles with two nitrile groups, for example 2-methylglutaronitrile or adiponitrile or Succinonitrile.
- the activation can be carried out continuously or batchwise in a trickle or bottoms procedure.
- the temperature should advantageously be in the range between 20 and 180 ° C., in particular 30 to 150 ° C.
- the pressure should advantageously be in the range between 2 and 40 MPa, in particular 3 to 30 MPa.
- the activation can preferably be carried out in the presence of an inorganic solvent, such as ammonia, or an organic solvent
- Solvents such as an amine, diamine or triamine, preferably with 1 to 6 carbon atoms, for example trimethylamine, triethylamine, Perform tri-n-propylamine, tri-i-propylamine, tributylamine, such as an alcohol, for example methanol, ethanol, n-propanol, i-propanol, n-butanol, i-butanol, s-butanol, preferably ammonia.
- an amine, diamine or triamine preferably with 1 to 6 carbon atoms, for example trimethylamine, triethylamine
- 1 to 10 g, preferably 2 to 6 g of solvent, in particular ammonia, can be used per g of nitrile.
- the activation can be carried out batchwise or preferably continuously, in particular in the liquid phase.
- the temperature should advantageously be in the range between 20 and 180 ° C., preferably 40 and 150 ° C., in particular 50 to 100 ° C.
- the pressure should advantageously be in the range between 2 and 40 MPa, preferably 2 and 30 MPa, particularly preferably 3 to 30 MPa, in particular 4 to 9 MPa.
- the residence time should advantageously be in the range between 50 and 275 min, preferably 70 to 200 min.
- the activation can preferably be carried out in the presence of an inorganic solvent, such as ammonia, or an organic solvent, such as an amine, diamine or triamine, preferably having 1 to 6 carbon atoms, for example trimethylamine, triethylamine, tri-n-propylamine, tri-i -Propylamine, tributylamine, such as an alcohol, for example methanol, ethanol, n-propanol, i-propanol, n-butanol, i-butanol, s-butanol, preferably ammonia.
- an inorganic solvent such as ammonia
- an organic solvent such as an amine, diamine or triamine, preferably having 1 to 6 carbon atoms, for example trimethylamine, triethylamine, tri-n-propylamine, tri-i -Propylamine, tributylamine, such as an alcohol, for example methanol, ethanol, n-propanol
- the amount of catalyst precursor, based on the amount of nitrile is in the range from 1 to 50% by weight, in particular 5 to 20% by weight.
- the nitriles used in the process according to the invention are generally obtained partly as amines and partly as carboxamides.
- the course of the activation can be followed in a manner known per se, for example by gas-chromatographic analysis of the reaction output in the case of a continuous reaction procedure or gas-chromatographic analysis of samples of the reaction mixture in the case of a discontinuous reaction procedure.
- Particularly advantageous catalytically active iron obtainable by the process according to the invention has a content of 0 to 10 25% by weight of component (b), based on component (a), and a content of 0 to 10% by weight of component ( c), based on component (a).
- the optimal parameters for producing the desired composition can easily be determined in a few preliminary tests.
- the iron obtainable by the process according to the invention can be used in numerous chemical processes, for example the synthesis of ammonia from nitrogen and hydrogen, the production of 20 hydrocarbons from synthesis gas (Fischer-Tropsch synthesis) or in hydrogenations, such as the hydrogenation of nitriles, in particular alpha, omega-dinitriles to alpha, omega-aminonitriles or alpha, omega-diamines, are used as catalytically active components in heterogeneous catalysts.
- heterogeneous catalysts is the hydrogenation of adiponitrile to hexamethylene diamine and the partial hydrogenation of adiponitrile to 6-aminocapronitrile and hexamethylene diamine.
- the heterogeneous catalyst can advantageously after activation with solvents such as alcohols, hydrocarbons, amines, ammonia or Washed ether and optionally dried.
- the nitrile 0 to be reacted on the activated catalyst can advantageously be used during the activation in the process according to the invention.
- T he catalyst precursor was made by melting a magnetite ore above 1550 ° C in air.
- the magnetite ore used had the following composition:
- the cooled melting block was crushed in the jaw crusher. A sieve fraction of 1.5 to 3 mm was sieved out and reduced within 72 hours at 450 ° C. in a hydrogen / nitrogen stream. After cooling under nitrogen, the catalyst was passivated with a mixture of 1% air with nitrogen within 24 hours, taking care that the temperature of the hot spot in the bed did not exceed 45 ° C.
- ACN 6-aminocapronitrile
- HMD hexamethylenediamine
- ACSA 6-aminocaproic acid amide
- ADN adiponitrile
- Table 1 shows that the water formed reacts with ACN to ACSA. b) hydrogenation of adiponitrile to hexamethylenediamine
- the catalyst prepared according to 1 a) by activating reduced-passivated iron catalyst was used in the same reactor for the hydrogenation of adiponitrile to hexamethylenediamine. In contrast to la), the reactor was operated continuously. Was hydrogenated at 135 ° C, 250 * 10 5 Pa and a catalyst load of 1.0 kg ADN / 1 cat. X h. A mixture of ammonia and ADN in a weight ratio of 2: 1 was fed continuously to the reactor. Samples were taken over a period of 100 hours and analyzed by gas chromatography. With complete ADN conversion, the hexamethylene diamine yield was 99%.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR0014456-8A BR0014456A (pt) | 1999-10-01 | 2000-09-15 | Processos para ativação por hidrogênio em alta temperatupa e alta pressão de ferro passivado, e para hidrogenação na presença d um catalizador heterogênio, métodos para uso de nitrilas, e para uso de ferro, e, ferro catalìtico |
DE50006521T DE50006521D1 (de) | 1999-10-01 | 2000-09-15 | Verfahren zur aktivierung von passiviertem eisen |
CA002385597A CA2385597A1 (en) | 1999-10-01 | 2000-09-15 | Method for activating passivated iron |
AT00966020T ATE267044T1 (de) | 1999-10-01 | 2000-09-15 | Verfahren zur aktivierung von passiviertem eisen |
KR1020027004184A KR20020040827A (ko) | 1999-10-01 | 2000-09-15 | 패시베이션된 철의 활성화 방법 |
EP00966020A EP1216095B1 (de) | 1999-10-01 | 2000-09-15 | Verfahren zur aktivierung von passiviertem eisen |
JP2001527914A JP2003511219A (ja) | 1999-10-01 | 2000-09-15 | 不動態化された鉄の活性化 |
AU76565/00A AU7656500A (en) | 1999-10-01 | 2000-09-15 | Method for activating passivated iron |
US10/088,406 US6815388B1 (en) | 1999-10-01 | 2000-09-15 | Method for activating passivated iron |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19947508A DE19947508A1 (de) | 1999-10-01 | 1999-10-01 | Verfahren zur Aktivierung von passiviertem Eisen |
DE19947508.3 | 1999-10-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001024925A1 true WO2001024925A1 (de) | 2001-04-12 |
Family
ID=7924288
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2000/009020 WO2001024925A1 (de) | 1999-10-01 | 2000-09-15 | Verfahren zur aktivierung von passiviertem eisen |
Country Status (15)
Country | Link |
---|---|
US (1) | US6815388B1 (de) |
EP (1) | EP1216095B1 (de) |
JP (1) | JP2003511219A (de) |
KR (1) | KR20020040827A (de) |
CN (1) | CN1134299C (de) |
AR (1) | AR025905A1 (de) |
AT (1) | ATE267044T1 (de) |
AU (1) | AU7656500A (de) |
BR (1) | BR0014456A (de) |
CA (1) | CA2385597A1 (de) |
DE (2) | DE19947508A1 (de) |
ES (1) | ES2221858T3 (de) |
MY (1) | MY122747A (de) |
TW (1) | TW592809B (de) |
WO (1) | WO2001024925A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2004225908B2 (en) * | 2003-04-02 | 2009-05-28 | Adelaide Research & Innovation Pty Ltd | Comparative genomic hybridization |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BRPI0405847B1 (pt) * | 2004-12-21 | 2015-04-22 | Petroleo Brasileiro Sa | Processo para a oxidação extrativa de contaminantes presentes em correntes brutas de combustíveis catalisada por óxidos de ferro |
FR2892118B1 (fr) | 2005-10-18 | 2010-12-10 | Rhodia Recherches & Tech | Procede de fabrication d'hexamethylene diamine et d'aminocapronitrile. |
GB0704003D0 (en) * | 2007-03-01 | 2007-04-11 | Oxford Catalysts | Promoted carbide-based fischer-tropsch catalyst, method for its preparation and uses thereof |
US8614158B2 (en) | 2008-02-29 | 2013-12-24 | Schlumberger Technology Corporation | Fischer-trospch and oxygenate synthesis catalyst activation/regeneration in a micro scale process |
US7939953B2 (en) * | 2008-04-16 | 2011-05-10 | Schlumberger Technology Corporation | Micro scale fischer-tropsch and oxygenate synthesis process startup unit |
CN105531254A (zh) | 2013-09-13 | 2016-04-27 | 因温斯特技术公司 | 从二腈制造二胺的氢化方法 |
CN105555753A (zh) | 2013-09-13 | 2016-05-04 | 因温斯特技术公司 | 从二腈制备二胺的氢化方法 |
WO2015038679A1 (en) | 2013-09-13 | 2015-03-19 | Invista Technologies S.A R.L. | Catalyst preparation and hydrogenation process |
CN105658617A (zh) | 2013-09-13 | 2016-06-08 | 因温斯特技术公司 | 使二腈氢化以便制备二胺 |
WO2015038673A1 (en) | 2013-09-13 | 2015-03-19 | Invista Technologies S.À R.L. | Hydrogenation of dinitriles for the preparation of diamines |
JP6355226B2 (ja) * | 2013-09-26 | 2018-07-11 | 住友化学株式会社 | アンモニア合成触媒及びアンモニアの製造方法 |
CN106536476B (zh) | 2014-04-25 | 2018-11-13 | 英威达纺织(英国)有限公司 | 通过使二腈氢化来制备二胺 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19742221A1 (de) * | 1997-09-24 | 1999-03-25 | Basf Ag | Verfahren zur Herstellung von aliphatischen alpha,omega-Aminonitrilen |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE855263C (de) | 1943-10-19 | 1952-11-10 | Basf Ag | Verfahren zur Herstellung aliphatischer Diamine |
US3758584A (en) * | 1970-12-23 | 1973-09-11 | Du Pont | Hydrogenation of adiponitrile |
US4064172A (en) * | 1973-09-12 | 1977-12-20 | Imperial Chemical Industries Limited | Hexamethylene diamine by hydrogenation of adiponitrile in presence of an activated iron oxide catalyst |
US4480051A (en) | 1983-08-03 | 1984-10-30 | E. I. Du Pont De Nemours And Company | Activated iron hydrogenation catalyst |
DE3524330A1 (de) | 1985-07-08 | 1987-01-08 | Basf Ag | Verfahren zur herstellung von katalysatoren und ihre verwendung bei hydrier- und aminierreaktionen |
CA2017985A1 (en) * | 1989-06-16 | 1990-12-16 | Otto Immel | Process for the preparation of an iron catalyst and a process for the preparation of primary amines by the hydrogenation of nitriles using said iron catalyst |
FR2743010B1 (fr) * | 1995-12-29 | 1998-02-20 | Rhone Poulenc Fibres | Procede de preparation par hydrogenation de catalyseurs a base de metal de transition et de phosphine |
AU4300497A (en) | 1996-09-10 | 1998-04-02 | Basf Aktiengesellschaft | Process for the manufacture of aliphatic alpha, omega amino nitriles |
-
1999
- 1999-10-01 DE DE19947508A patent/DE19947508A1/de not_active Withdrawn
-
2000
- 2000-09-08 TW TW089118451A patent/TW592809B/zh not_active IP Right Cessation
- 2000-09-13 MY MYPI20004260 patent/MY122747A/en unknown
- 2000-09-15 BR BR0014456-8A patent/BR0014456A/pt not_active IP Right Cessation
- 2000-09-15 WO PCT/EP2000/009020 patent/WO2001024925A1/de active IP Right Grant
- 2000-09-15 AU AU76565/00A patent/AU7656500A/en not_active Abandoned
- 2000-09-15 ES ES00966020T patent/ES2221858T3/es not_active Expired - Lifetime
- 2000-09-15 CN CNB008137196A patent/CN1134299C/zh not_active Expired - Fee Related
- 2000-09-15 CA CA002385597A patent/CA2385597A1/en not_active Abandoned
- 2000-09-15 KR KR1020027004184A patent/KR20020040827A/ko active IP Right Grant
- 2000-09-15 JP JP2001527914A patent/JP2003511219A/ja not_active Withdrawn
- 2000-09-15 US US10/088,406 patent/US6815388B1/en not_active Expired - Fee Related
- 2000-09-15 AT AT00966020T patent/ATE267044T1/de not_active IP Right Cessation
- 2000-09-15 EP EP00966020A patent/EP1216095B1/de not_active Expired - Lifetime
- 2000-09-15 DE DE50006521T patent/DE50006521D1/de not_active Expired - Fee Related
- 2000-09-28 AR ARP000105134A patent/AR025905A1/es unknown
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19742221A1 (de) * | 1997-09-24 | 1999-03-25 | Basf Ag | Verfahren zur Herstellung von aliphatischen alpha,omega-Aminonitrilen |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2004225908B2 (en) * | 2003-04-02 | 2009-05-28 | Adelaide Research & Innovation Pty Ltd | Comparative genomic hybridization |
Also Published As
Publication number | Publication date |
---|---|
DE19947508A1 (de) | 2001-04-05 |
US6815388B1 (en) | 2004-11-09 |
ATE267044T1 (de) | 2004-06-15 |
CA2385597A1 (en) | 2001-04-12 |
DE50006521D1 (de) | 2004-06-24 |
JP2003511219A (ja) | 2003-03-25 |
AU7656500A (en) | 2001-05-10 |
CN1134299C (zh) | 2004-01-14 |
AR025905A1 (es) | 2002-12-18 |
MY122747A (en) | 2006-05-31 |
EP1216095B1 (de) | 2004-05-19 |
EP1216095A1 (de) | 2002-06-26 |
CN1377298A (zh) | 2002-10-30 |
TW592809B (en) | 2004-06-21 |
ES2221858T3 (es) | 2005-01-16 |
KR20020040827A (ko) | 2002-05-30 |
BR0014456A (pt) | 2002-06-11 |
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