WO2000056550A1 - Procede de fabrication d'une tete thermique - Google Patents
Procede de fabrication d'une tete thermique Download PDFInfo
- Publication number
- WO2000056550A1 WO2000056550A1 PCT/JP2000/001517 JP0001517W WO0056550A1 WO 2000056550 A1 WO2000056550 A1 WO 2000056550A1 JP 0001517 W JP0001517 W JP 0001517W WO 0056550 A1 WO0056550 A1 WO 0056550A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- protective film
- thermal head
- heating resistor
- wiring electrode
- inorganic paste
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/315—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
- B41J2/32—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
- B41J2/335—Structure of thermal heads
- B41J2/33505—Constructional details
- B41J2/3353—Protective layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/315—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
- B41J2/32—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
- B41J2/335—Structure of thermal heads
- B41J2/3355—Structure of thermal heads characterised by materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/315—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
- B41J2/32—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
- B41J2/335—Structure of thermal heads
- B41J2/33555—Structure of thermal heads characterised by type
- B41J2/3357—Surface type resistors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- B41J2/00—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed
- B41J2/315—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material
- B41J2/32—Typewriters or selective printing mechanisms characterised by the printing or marking process for which they are designed characterised by selective application of heat to a heat sensitive printing or impression-transfer material using thermal heads
- B41J2/335—Structure of thermal heads
- B41J2/3359—Manufacturing processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49082—Resistor making
- Y10T29/49083—Heater type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49082—Resistor making
- Y10T29/49101—Applying terminal
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49789—Obtaining plural product pieces from unitary workpiece
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49789—Obtaining plural product pieces from unitary workpiece
- Y10T29/4979—Breaking through weakened portion
Definitions
- the present invention relates to a method for manufacturing a thermal head used for thermal recording such as a facsimile or a printer.
- a glaze layer 2 is provided as a heat storage layer on an insulating substrate 1 such as a ceramic substrate, and a Ta-based / silicide-based, Ni-Cr-based And other electrode materials such as A1, Cr-Cu, Au, etc. are formed into a film by a sputtering / evaporation method and the like, and the heating resistor 3, the common electrode, and the like are formed by patterning in a photolithography process.
- the wiring electrodes 4 of the individual electrodes are formed, and thereafter, for preventing oxidation of the heating resistor 3 and abrasion resistance, Sio2, Ta205, SiA1ON, Si3N4, SiC, etc.
- the protective film 6 is formed by sputtering, ion plating, and CVD to produce a thermal head.
- a protective film 6 is selectively formed on the heating resistor portion to prevent oxidation and abrasion resistance, and a driver IC for sending an image signal to the heating resistor via an electrode.
- the protection film unnecessary portion 4a such as a wire bonding portion with the like must be formed so that the protection film 6 does not adhere.
- the first method is to perform physical masking.
- One of the methods is to overlay a metal mask 7 on the substrate as shown in Fig. 2 (a). It is.
- the positional accuracy of the protective film 6 cannot be expected to be improved.
- the film is peeled off from the metal mask 7 and the yield is reduced.
- a gap must be provided between the metal mask and the substrate so that the wiring electrode 4 is not scratched.
- the protective film 6 wraps around the gap between the metal mask 7 and the substrate, and a protective film wraparound portion 6a is generated, and the protective film 6 adheres to the unnecessary portion 4a of the protective film.
- the design was made to allow the protective film wraparound portion 6a at the design stage, and this was a factor that hindered the reduction in the size of the board and the increase in the number of boards to be taken.
- Another method is to stack the substrates in a tile pattern.
- the wiring electrodes 4 are scratched due to the contact because the substrates are overlapped in a tile shape.
- a gap must be provided between the substrates, and there is a disadvantage that the protective film 6 adheres to the unnecessary portion 4a of the protective film.
- the substrate must be divided from a wafer shape to a long shape in order to overlap the substrates. It takes time to divide the board and stack the boards, which increases production man-hours and is a factor of cost increase.
- the process in the process after the protective film 6, the process must flow in a divided state, so that there is a disadvantage that the production tooling is deteriorated.
- a second method is to selectively form the protective film 6 by chemically etching the protective film 6.
- the protective film 6 used for the thermal head uses an inorganic ceramic film that is chemically and physically stable. For this reason, hydrogen fluoride chemicals are used for etching, but the etching rate is extremely slow, leading to a decrease in productivity. This is true not only for chemical etching but also for dry etching using a vapor phase method. In addition, when etching with chemicals, metal is Since it is used, the etching selectivity with the protective film 6 cannot be secured and the wiring electrode 4 is etched, which is not practical in the field of thermal head.
- the conventional selective method of the protective film by lift-off has been performed using a photo-resist as a masking agent.
- the protective film is formed at high temperature and high vacuum. This results in the photoresist being exposed to high temperatures and high vacuum. Since the photoresist is a resin, it does not withstand the conditions for forming the protective film, and generates gas in the vacuum chamber. These gases not only contaminate the inside of the vacuum vessel, but also lower the adhesion and quality of the protective film, leading to a decrease in the reliability of the thermal head.
- polyimide-based masking agents that have better heat resistance than these photoresists are also used.
- Polyimide has heat resistance, but once cured, its peelability is extremely reduced. At that time, the masking agent slightly remains on the wiring electrode. If the masking agent remains, the strength of the wire bonding for connecting to the driver IC for sending image signals to the heating resistor via the electrodes cannot be secured, and the bonding reliability may be released, such as disconnection of the bonding. And reduce productivity Factors. Therefore, in order to forcibly perform peeling, a polar solvent such as NMP which dissolves polyimide must be used. The use of polar solvents has an adverse effect on workers and the working environment. Furthermore, in recent years, awareness of protecting the global environment has been increasing, and there has been a problem that it is not possible to use extremely strong chemicals.
- an object of the present invention is to solve such a conventional problem by using an inorganic paste as a masking agent to cope with miniaturization of a substrate and multi-cavity production, and to achieve a protective film position accuracy
- An object of the present invention is to provide a method of manufacturing a thermal head that can selectively form a protective film having high adhesion and high reliability of the protective film. Disclosure of the invention
- the present invention provides a method of manufacturing a thermal head having at least a heating resistor, a wiring electrode for supplying power to the heating resistor, and a protective film covering the heating element and wiring electrodes therearound on an insulating substrate.
- a thermal head having at least a heating resistor, a wiring electrode for supplying power to the heating resistor, and a protective film covering the heating element and wiring electrodes therearound on an insulating substrate.
- At least a heating resistor and a wiring electrode for supplying power to the heating resistor are formed on the insulating substrate, and a dry cell IC for transmitting an image signal to the heating resistor via the electrode and a thermal IC.
- the protective film unnecessary portion of the wiring electrode for connecting the head by wire bonding is masked using an inorganic paste, and a protective film is formed on the entire surface.After that, the protective film of the unnecessary portion of the protective film is formed together with the inorganic paste. After peeling off, a protective film is selectively formed on the heat-generating body and the heat-generating part of the wiring electrodes around it.
- the unnecessary portion of the protective film is masked using an inorganic paste, and since the protective film is formed, the masking agent does not contain any resin component, so the heat resistance is low. Extremely high, no gas is generated even in a vacuum vessel at high temperature and high vacuum. Therefore, vacuum volume o High film adhesion and film reliability can be obtained without contamination of the chamber. Furthermore, since it has extremely high heat resistance and does not contain a resin component, there is no phenomenon such as carbonization or seizure, so that the releasability is easy. Therefore, the masking agent does not remain on the wiring electrodes, so that the strength of wire bonding is improved. Furthermore, since a masking agent can be used at any position, a protective film can be selectively formed, thereby reducing the substrate size, increasing the number of substrates to be taken, and improving productivity. . BRIEF DESCRIPTION OF THE FIGURES
- FIG. 1 is an explanatory diagram showing a method for manufacturing a thermal head according to the present invention.
- FIG. 2 is an explanatory view showing a conventional method for manufacturing a thermal head.
- FIG. 1 is a view showing a process of a method for manufacturing a thermal head according to the present invention. The steps of the manufacturing method of the present invention will be described in order.
- a glaze 2 is formed on an insulating substrate 1 made of, for example, alumina ceramics for heat storage.
- a heating resistor material a Ta-N, Ta-Si02 film or the like containing Ta as a main component is formed to a thickness of about 0.1 ⁇ m by sputtering, and then the heating resistor is formed by photolithography.
- Form 3 is a view showing a process of a method for manufacturing a thermal head according to the present invention. The steps of the manufacturing method of the present invention will be described in order.
- a glaze 2 is formed on an insulating substrate 1 made of, for example, alumina ceramics for heat storage.
- a heating resistor material a Ta-N, Ta-Si02 film or the like containing Ta as a main component is formed to a thickness of about 0.1 ⁇
- the wiring electrode 4 is formed by photolithography. Further, the wiring electrode 4 is provided with a protective film unnecessary portion 4a for connection by wire bonding or the like to a driver IC for sending an image signal to the heating resistor via the electrode later.
- the inorganic paste 5 is composed of a ceramic powder mainly composed of pure water and alumina silica, and bentonite as a binder component. These are mixed to form a paste and used as an inorganic paste 5.
- the ceramic powder used here has a particle size of about 1 to 5 m. If the particle size of the ceramic powder is larger than 5 m, it may not be practical because it may cause problems such as poor printability.
- bentonite which is a binder component
- bentonite is a hydrous layered silicate mainly composed of montmorillonite, which is a clay mineral, and has the property of swelling and sticking with water. Therefore, it is ideal for printing inorganic substances in paste form, and because it does not contain organic substances, it has excellent heat resistance and does not generate gas even at high temperatures or high vacuum.
- the best method for applying is a screen printing method.
- Screen printing has high productivity and high printing accuracy, and since various patterns can be formed by changing the shape of the screen mask, the inorganic material list 5 is selectively used as the protective film unnecessary portion 4 a of the wiring electrode 4. It is effective to apply to the surface, and about 10 to 30 inorganic pastes 5 are printed by screen printing. Since the film thickness to be printed depends on the film thickness of the protective film 6 to be formed later, at least twice the film thickness of the protective film 6 is necessary. If the thickness is equal to or smaller than the thickness of the protective film, the peelability in a later step will be reduced.
- coating methods there are a coating method using a dispenser, an offset printing method using a mouthpiece, and a flexographic printing method, which can be selected according to a shape to be coated.
- the water in the inorganic paste 5 evaporates.
- the inorganic paste 5 is hardened by the evaporation of the water, and the unnecessary portion 4 a of the wiring electrode 4 is masked.
- Si 3N4 and Si 02 should be covered so as to cover all of the heating resistor 3, wiring electrode 4, and inorganic paste 5.
- a protective film 6 is formed on the entire surface of the substrate by sputtering or the like to a thickness of about 3 to 6 ⁇ m by sputtering or the like.
- the substrate on which the protective film 6 is formed over the entire surface is immersed in water such as pure water, so that the inorganic paste 5 swells and the portion formed on the unnecessary portion 4a of the protective film is formed.
- the protective film 6 is peeled off together with the inorganic paste 5.
- ultrasonic cleaning is effective as a means for increasing the peelability and improving the productivity, or as a means for removing the residue of the inorganic paste 5 on the wiring electrode 4 and increasing the strength of the wire bonding to obtain reliability.
- a low frequency band such as 2 8 ⁇ 4 5 k H Z is valid.
- a cleaning method using a high frequency band of 100 kHz or more is more effective.
- a running water washing method using high pressure water such as a water jet is also effective.
- the size of the substrate is reduced by selectively forming the protective film of the thermal head using the inorganic base, thereby increasing the number of substrates to be obtained and improving the productivity. Is improved. Also, since selective formation is possible, it is possible to form complicated protective films such as through-holes and multilayer wiring electrode structures that were not possible in the past, improving the flexibility of thermal head design. I do.
- the inorganic paste does not generate gas even in a vacuum vessel, high reliability of the protective film can be obtained and the life of the thermal head can be extended. Sa Furthermore, since the inside of the vacuum vessel is not contaminated, the maintenance cycle of the equipment can be improved.
- the protective film can be selectively formed easily without using any chemicals, it has no effect on workers and working environment, and has no effect on the natural environment of the earth. .
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Electronic Switches (AREA)
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00908043A EP1080925B1 (en) | 1999-03-19 | 2000-03-13 | Method of manufacturing thermal head |
KR1020007012696A KR20010025016A (ko) | 1999-03-19 | 2000-03-13 | 서멀 헤드의 제조방법 |
DE60004143T DE60004143T2 (de) | 1999-03-19 | 2000-03-13 | Verfahren zur herstellung eines thermokopfes |
US09/674,391 US6560855B1 (en) | 1999-03-19 | 2000-03-13 | Method of manufacturing thermal head |
JP2000606428A JP3989684B2 (ja) | 1999-03-19 | 2000-03-13 | サーマルヘッドの製造方法 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11/75989 | 1999-03-19 | ||
JP7598999 | 1999-03-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000056550A1 true WO2000056550A1 (fr) | 2000-09-28 |
Family
ID=13592202
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2000/001517 WO2000056550A1 (fr) | 1999-03-19 | 2000-03-13 | Procede de fabrication d'une tete thermique |
Country Status (6)
Country | Link |
---|---|
US (1) | US6560855B1 (ja) |
EP (1) | EP1080925B1 (ja) |
JP (1) | JP3989684B2 (ja) |
KR (1) | KR20010025016A (ja) |
DE (1) | DE60004143T2 (ja) |
WO (1) | WO2000056550A1 (ja) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006150758A (ja) * | 2004-10-27 | 2006-06-15 | Kyocera Corp | サーマルヘッド及びサーマルヘッドの製造方法並びにサーマルプリンタ |
JP2009133589A (ja) * | 2007-11-30 | 2009-06-18 | Toyota Central R&D Labs Inc | 蓄熱装置及びその製造方法 |
JP2009133590A (ja) * | 2007-11-30 | 2009-06-18 | Toyota Central R&D Labs Inc | 蓄熱装置及びその製造方法 |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2004319881A (ja) * | 2003-04-18 | 2004-11-11 | Alps Electric Co Ltd | 配線基材およびそれを備えた電気機器およびスイッチ装置 |
JP2009137284A (ja) * | 2007-11-13 | 2009-06-25 | Tdk Corp | サーマルヘッド、サーマルヘッドの製造方法及び印画装置 |
US8861317B1 (en) | 2013-04-02 | 2014-10-14 | Western Digital (Fremont), Llc | Heat assisted magnetic recording transducer having protective pads |
US9343098B1 (en) | 2013-08-23 | 2016-05-17 | Western Digital (Fremont), Llc | Method for providing a heat assisted magnetic recording transducer having protective pads |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62164558A (ja) * | 1986-01-16 | 1987-07-21 | Alps Electric Co Ltd | サ−マルヘツドの製造方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4612433A (en) * | 1983-12-28 | 1986-09-16 | Pentel Kabushiki Kaisha | Thermal head and manufacturing method thereof |
JPS6154954A (ja) * | 1984-08-28 | 1986-03-19 | Alps Electric Co Ltd | サ−マルヘツド及びその製造方法 |
JPS61167574A (ja) * | 1985-01-21 | 1986-07-29 | Nippon Telegr & Teleph Corp <Ntt> | サ−マルヘツド及びその製造方法 |
JPH03218856A (ja) * | 1989-11-20 | 1991-09-26 | Ricoh Co Ltd | サーマルヘッド |
JPH03268952A (ja) * | 1990-03-19 | 1991-11-29 | Toshiba Corp | サーマルヘッド |
US5373625A (en) * | 1991-10-15 | 1994-12-20 | Rohm Co., Ltd. | Method for making thermal heads |
JP3218417B2 (ja) * | 1993-12-28 | 2001-10-15 | ローム株式会社 | サーマルプリントヘッドおよびその製造方法 |
JP2844051B2 (ja) * | 1994-10-31 | 1999-01-06 | セイコーインスツルメンツ株式会社 | サーマルヘッド |
JP3912430B2 (ja) * | 1996-12-19 | 2007-05-09 | Tdk株式会社 | サーマルヘッドおよびその製造方法 |
JP2000033724A (ja) * | 1998-07-17 | 2000-02-02 | Fuji Photo Film Co Ltd | サーマルヘッドの製造方法 |
JP3603997B2 (ja) * | 1999-05-31 | 2004-12-22 | アオイ電子株式会社 | サーマルヘッド及びサーマルヘッドの製造方法 |
JP2001063117A (ja) * | 1999-08-31 | 2001-03-13 | Riso Kagaku Corp | 厚膜式サーマルヘッドおよびその製造方法 |
-
2000
- 2000-03-13 DE DE60004143T patent/DE60004143T2/de not_active Expired - Lifetime
- 2000-03-13 JP JP2000606428A patent/JP3989684B2/ja not_active Expired - Fee Related
- 2000-03-13 US US09/674,391 patent/US6560855B1/en not_active Expired - Fee Related
- 2000-03-13 KR KR1020007012696A patent/KR20010025016A/ko not_active Application Discontinuation
- 2000-03-13 EP EP00908043A patent/EP1080925B1/en not_active Expired - Lifetime
- 2000-03-13 WO PCT/JP2000/001517 patent/WO2000056550A1/ja not_active Application Discontinuation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62164558A (ja) * | 1986-01-16 | 1987-07-21 | Alps Electric Co Ltd | サ−マルヘツドの製造方法 |
Non-Patent Citations (1)
Title |
---|
See also references of EP1080925A4 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006150758A (ja) * | 2004-10-27 | 2006-06-15 | Kyocera Corp | サーマルヘッド及びサーマルヘッドの製造方法並びにサーマルプリンタ |
JP4619102B2 (ja) * | 2004-10-27 | 2011-01-26 | 京セラ株式会社 | サーマルヘッド及びサーマルプリンタ |
JP2009133589A (ja) * | 2007-11-30 | 2009-06-18 | Toyota Central R&D Labs Inc | 蓄熱装置及びその製造方法 |
JP2009133590A (ja) * | 2007-11-30 | 2009-06-18 | Toyota Central R&D Labs Inc | 蓄熱装置及びその製造方法 |
Also Published As
Publication number | Publication date |
---|---|
DE60004143T2 (de) | 2004-03-04 |
DE60004143D1 (de) | 2003-09-04 |
KR20010025016A (ko) | 2001-03-26 |
EP1080925A1 (en) | 2001-03-07 |
US6560855B1 (en) | 2003-05-13 |
EP1080925B1 (en) | 2003-07-30 |
EP1080925A4 (en) | 2002-05-29 |
JP3989684B2 (ja) | 2007-10-10 |
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