WO2000011231A1 - Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung - Google Patents
Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung Download PDFInfo
- Publication number
- WO2000011231A1 WO2000011231A1 PCT/DE1999/002491 DE9902491W WO0011231A1 WO 2000011231 A1 WO2000011231 A1 WO 2000011231A1 DE 9902491 W DE9902491 W DE 9902491W WO 0011231 A1 WO0011231 A1 WO 0011231A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- magnesium
- weight
- scandium
- aluminum
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
Definitions
- New weldable, corrosion-resistant, high-magnesium aluminum-aluminum alloy especially for automotive applications
- the invention relates to a weldable, corrosion-resistant, high-magnesium aluminum-magnesium alloy, which contains a ternary aluminum-scandium-zirconium phase as an essential component.
- a weldable, corrosion-resistant, high-magnesium aluminum-magnesium alloy which contains a ternary aluminum-scandium-zirconium phase as an essential component.
- Such an alloy is known, for example, from US Pat. No. 5,624,632 and, due to its low density, high strength and corrosion resistance, is of interest above all for applications in aviation.
- By adding rare earth elements or elements similar to rare earths, 0 in the aluminum-magnesium alloy dispersoids are generated, which according to the above. US patent produce higher strength and corrosion resistance.
- the weldability of such an alloy the above-mentioned. No information can be found in US patent.
- This object is achieved by an aluminum-magnesium alloy according to claim 1.
- this new alloy is particularly suitable for body panels and has an addition of titanium and cerium over the known alloy.
- An alloy in which the ratio of manganese to scandium is less than two exhibits particularly favorable corrosion behavior.
- the titanium content in contrast to the known alloy, contributes to the increase in strength, in addition to its effect as a grain refining agent, since titanium can replace the zirconium in the ternary Al-Sc-Zr phase, although the solubility of titanium is lower than that of zirconium.
- the cerium additive also contributes to increasing the strength and further increasing the yield strength and thermal stability.
- a particularly strong and corrosion-resistant alloy contains at least 0.15% by weight of scandium.
- the addition of lanthanides advantageously ranges between 0.05 and 0.35% by weight, this range relating to the total mixture when a lanthanide mixture is used.
- the alloy tolerates silicon impurities up to 0.2% by weight; above all, the dynamic properties deteriorate.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Powder Metallurgy (AREA)
- Prevention Of Electric Corrosion (AREA)
- Arc Welding In General (AREA)
- Forging (AREA)
- Conductive Materials (AREA)
- Extrusion Of Metal (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT99952346T ATE216735T1 (de) | 1998-08-21 | 1999-08-10 | Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium- legierung, insbesondere für die automobilanwendung |
| JP2000566481A JP2002523621A (ja) | 1998-08-21 | 1999-08-10 | 新規な腐食耐性を有する溶接可能な、特に自動車用の高マグネシウム含量アルミニウム−マグネシウム合金 |
| US09/530,067 US6315948B1 (en) | 1998-08-21 | 1999-08-10 | Weldable anti-corrosive aluminum-magnesium alloy containing a high amount of magnesium, especially for use in automobiles |
| CA002306726A CA2306726C (en) | 1998-08-21 | 1999-08-10 | Novel weldable anti-corrosive aluminium-magnesium alloy containing a high amount of magnesium, especially for use in automobiles |
| EP99952346A EP1025270B1 (de) | 1998-08-21 | 1999-08-10 | Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung |
| DE59901293T DE59901293D1 (de) | 1998-08-21 | 1999-08-10 | Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19838015A DE19838015C2 (de) | 1998-08-21 | 1998-08-21 | Gewalztes, stranggepreßtes, geschweißtes oder geschmiedetes Bauteil aus einer schweißbaren, korrosionsbeständigen hochmagnesiumhaltigen Aluminium-Magnesium-Legierung |
| DE19838015.1 | 1998-08-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000011231A1 true WO2000011231A1 (de) | 2000-03-02 |
Family
ID=7878284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/DE1999/002491 Ceased WO2000011231A1 (de) | 1998-08-21 | 1999-08-10 | Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6315948B1 (enExample) |
| EP (1) | EP1025270B1 (enExample) |
| JP (1) | JP2002523621A (enExample) |
| CN (1) | CN1107120C (enExample) |
| AT (1) | ATE216735T1 (enExample) |
| CA (1) | CA2306726C (enExample) |
| DE (2) | DE19838015C2 (enExample) |
| ES (1) | ES2173759T3 (enExample) |
| RU (1) | RU2226567C2 (enExample) |
| WO (1) | WO2000011231A1 (enExample) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10248594B4 (de) * | 2001-12-14 | 2006-04-27 | Eads Deutschland Gmbh | Verfahren zum Herstellen eines Scandium (Sc)- legierten Aluminiumblechmaterials mit hoher Risszähigkeit |
| US20040156739A1 (en) | 2002-02-01 | 2004-08-12 | Song Shihong Gary | Castable high temperature aluminum alloy |
| AT501867B1 (de) * | 2005-05-19 | 2009-07-15 | Aluminium Lend Gmbh & Co Kg | Aluminiumlegierung |
| US7875132B2 (en) * | 2005-05-31 | 2011-01-25 | United Technologies Corporation | High temperature aluminum alloys |
| US7584778B2 (en) * | 2005-09-21 | 2009-09-08 | United Technologies Corporation | Method of producing a castable high temperature aluminum alloy by controlled solidification |
| CN100445019C (zh) * | 2006-09-14 | 2008-12-24 | 中国航空工业第一集团公司北京航空材料研究院 | Al-Mg-Sc系焊丝 |
| WO2009062866A1 (en) | 2007-11-15 | 2009-05-22 | Aleris Aluminum Koblenz Gmbh | Al-mg-zn wrought alloy product and method of its manufacture |
| US7875131B2 (en) * | 2008-04-18 | 2011-01-25 | United Technologies Corporation | L12 strengthened amorphous aluminum alloys |
| US8409373B2 (en) * | 2008-04-18 | 2013-04-02 | United Technologies Corporation | L12 aluminum alloys with bimodal and trimodal distribution |
| US20090263273A1 (en) * | 2008-04-18 | 2009-10-22 | United Technologies Corporation | High strength L12 aluminum alloys |
| US7811395B2 (en) * | 2008-04-18 | 2010-10-12 | United Technologies Corporation | High strength L12 aluminum alloys |
| US7879162B2 (en) * | 2008-04-18 | 2011-02-01 | United Technologies Corporation | High strength aluminum alloys with L12 precipitates |
| US7875133B2 (en) | 2008-04-18 | 2011-01-25 | United Technologies Corporation | Heat treatable L12 aluminum alloys |
| US8002912B2 (en) * | 2008-04-18 | 2011-08-23 | United Technologies Corporation | High strength L12 aluminum alloys |
| US20090260724A1 (en) * | 2008-04-18 | 2009-10-22 | United Technologies Corporation | Heat treatable L12 aluminum alloys |
| US8017072B2 (en) * | 2008-04-18 | 2011-09-13 | United Technologies Corporation | Dispersion strengthened L12 aluminum alloys |
| US7871477B2 (en) * | 2008-04-18 | 2011-01-18 | United Technologies Corporation | High strength L12 aluminum alloys |
| US8778099B2 (en) * | 2008-12-09 | 2014-07-15 | United Technologies Corporation | Conversion process for heat treatable L12 aluminum alloys |
| US20100143177A1 (en) * | 2008-12-09 | 2010-06-10 | United Technologies Corporation | Method for forming high strength aluminum alloys containing L12 intermetallic dispersoids |
| US8778098B2 (en) * | 2008-12-09 | 2014-07-15 | United Technologies Corporation | Method for producing high strength aluminum alloy powder containing L12 intermetallic dispersoids |
| US20100226817A1 (en) * | 2009-03-05 | 2010-09-09 | United Technologies Corporation | High strength l12 aluminum alloys produced by cryomilling |
| RU2393073C1 (ru) * | 2009-03-17 | 2010-06-27 | Федеральное Государственное Унитарное Предприятие "Центральный Научно-Исследовательский Институт Конструкционных Материалов "Прометей" (Фгуп "Цнии Км "Прометей") | Состав сварочной проволоки на основе алюминия |
| US20100252148A1 (en) * | 2009-04-07 | 2010-10-07 | United Technologies Corporation | Heat treatable l12 aluminum alloys |
| US20100254850A1 (en) * | 2009-04-07 | 2010-10-07 | United Technologies Corporation | Ceracon forging of l12 aluminum alloys |
| US9611522B2 (en) * | 2009-05-06 | 2017-04-04 | United Technologies Corporation | Spray deposition of L12 aluminum alloys |
| US9127334B2 (en) * | 2009-05-07 | 2015-09-08 | United Technologies Corporation | Direct forging and rolling of L12 aluminum alloys for armor applications |
| DE102010020268A1 (de) | 2009-05-12 | 2010-11-18 | Aleris Aluminum Duffel Bvba | Aluminium-Magnesium-Legierungsprodukt für geformte Autmobilteile |
| US20110044844A1 (en) * | 2009-08-19 | 2011-02-24 | United Technologies Corporation | Hot compaction and extrusion of l12 aluminum alloys |
| US8728389B2 (en) * | 2009-09-01 | 2014-05-20 | United Technologies Corporation | Fabrication of L12 aluminum alloy tanks and other vessels by roll forming, spin forming, and friction stir welding |
| US8409496B2 (en) * | 2009-09-14 | 2013-04-02 | United Technologies Corporation | Superplastic forming high strength L12 aluminum alloys |
| US20110064599A1 (en) * | 2009-09-15 | 2011-03-17 | United Technologies Corporation | Direct extrusion of shapes with l12 aluminum alloys |
| US9194027B2 (en) * | 2009-10-14 | 2015-11-24 | United Technologies Corporation | Method of forming high strength aluminum alloy parts containing L12 intermetallic dispersoids by ring rolling |
| US8409497B2 (en) * | 2009-10-16 | 2013-04-02 | United Technologies Corporation | Hot and cold rolling high strength L12 aluminum alloys |
| US20110091346A1 (en) * | 2009-10-16 | 2011-04-21 | United Technologies Corporation | Forging deformation of L12 aluminum alloys |
| US20110091345A1 (en) * | 2009-10-16 | 2011-04-21 | United Technologies Corporation | Method for fabrication of tubes using rolling and extrusion |
| CN102699564B (zh) * | 2012-04-27 | 2015-04-22 | 浙江宇光铝材有限公司 | 铝合金自动焊丝 |
| AU2016218269B2 (en) | 2015-02-11 | 2019-10-03 | Scandium International Mining Corporation | Scandium-containing master alloys and methods for making the same |
| CN105499832A (zh) * | 2016-01-28 | 2016-04-20 | 东北大学 | 一种铝镁铈焊丝及其制备方法 |
| CN106624428A (zh) * | 2016-12-16 | 2017-05-10 | 吴中区穹窿山天仲高分子材料技术研究所 | 一种环保型焊接合金材料及其制备方法 |
| CN107363122B (zh) * | 2017-06-14 | 2018-12-14 | 飞龙精工科技(苏州)有限公司 | 铝镁合金丝的制备工艺 |
| RU2663446C1 (ru) * | 2017-12-06 | 2018-08-06 | Общество с ограниченной ответственностью "Опытный завод "Авиаль" (ООО "ОЗА") | Сплав на основе алюминия для сварочной проволоки |
| CN111378878B (zh) * | 2018-12-29 | 2021-10-26 | 嘉丰工业科技(惠州)有限公司 | 一种高延展性非热处理压铸铝合金及其制备方法 |
| CN110029252B (zh) * | 2019-04-12 | 2021-08-24 | 范卫忠 | 一种5g手机中板用高强高韧抗氧化铝镁合金材料及其制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5055257A (en) * | 1986-03-20 | 1991-10-08 | Aluminum Company Of America | Superplastic aluminum products and alloys |
| FR2717827A1 (fr) * | 1994-03-28 | 1995-09-29 | Collin Jean Pierre | Alliage d'aluminium à hautes teneurs en Scandium et procédé de fabrication de cet alliage. |
| US5624632A (en) * | 1995-01-31 | 1997-04-29 | Aluminum Company Of America | Aluminum magnesium alloy product containing dispersoids |
| RU2082809C1 (ru) * | 1995-07-25 | 1997-06-27 | Акционерное общество открытого типа "Всероссийский институт легких сплавов" | Деформируемый термически неупрочняемый сплав на основе алюминия |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU439535A1 (ru) * | 1972-07-04 | 1974-08-15 | Предприятие П/Я Р-6209 | Сплав на основе алюмини |
| SU480513A1 (ru) * | 1973-04-28 | 1975-08-15 | Предприятие П/Я М-5539 | Сплав дл сварочной проволоки на основе алюмини |
| JPS59159961A (ja) * | 1983-02-28 | 1984-09-10 | Mitsubishi Alum Co Ltd | 超塑性Al合金 |
| JPS63179040A (ja) | 1987-01-20 | 1988-07-23 | Showa Alum Corp | 表面平滑性に優れたシリンダ用アルミニウム合金 |
| JPS63248593A (ja) * | 1987-03-31 | 1988-10-14 | Showa Alum Corp | アルミニウム合金溶加材 |
| JP3286982B2 (ja) * | 1990-04-25 | 2002-05-27 | 菱化マックス株式会社 | 金型素材 |
| JPH07145441A (ja) * | 1993-01-27 | 1995-06-06 | Toyota Motor Corp | 超塑性アルミニウム合金およびその製造方法 |
| KR100469929B1 (ko) * | 1997-02-10 | 2005-02-02 | 알코아 인코포레이티드 | 알루미늄 합금 및 그로부터 제조된 항공기 부품 |
| PT918095E (pt) * | 1997-11-20 | 2003-06-30 | Alcan Tech & Man Ag | Processo para a obtencao de um componente estrutural a partir de uma liga de aluminio de moldagem sob pressao |
-
1998
- 1998-08-21 DE DE19838015A patent/DE19838015C2/de not_active Expired - Fee Related
-
1999
- 1999-08-10 EP EP99952346A patent/EP1025270B1/de not_active Expired - Lifetime
- 1999-08-10 US US09/530,067 patent/US6315948B1/en not_active Expired - Lifetime
- 1999-08-10 CN CN99801195A patent/CN1107120C/zh not_active Expired - Lifetime
- 1999-08-10 RU RU2000112645/02A patent/RU2226567C2/ru not_active IP Right Cessation
- 1999-08-10 DE DE59901293T patent/DE59901293D1/de not_active Expired - Lifetime
- 1999-08-10 ES ES99952346T patent/ES2173759T3/es not_active Expired - Lifetime
- 1999-08-10 CA CA002306726A patent/CA2306726C/en not_active Expired - Lifetime
- 1999-08-10 JP JP2000566481A patent/JP2002523621A/ja active Pending
- 1999-08-10 WO PCT/DE1999/002491 patent/WO2000011231A1/de not_active Ceased
- 1999-08-10 AT AT99952346T patent/ATE216735T1/de active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5055257A (en) * | 1986-03-20 | 1991-10-08 | Aluminum Company Of America | Superplastic aluminum products and alloys |
| FR2717827A1 (fr) * | 1994-03-28 | 1995-09-29 | Collin Jean Pierre | Alliage d'aluminium à hautes teneurs en Scandium et procédé de fabrication de cet alliage. |
| US5624632A (en) * | 1995-01-31 | 1997-04-29 | Aluminum Company Of America | Aluminum magnesium alloy product containing dispersoids |
| RU2082809C1 (ru) * | 1995-07-25 | 1997-06-27 | Акционерное общество открытого типа "Всероссийский институт легких сплавов" | Деформируемый термически неупрочняемый сплав на основе алюминия |
Non-Patent Citations (3)
| Title |
|---|
| CHEMICAL ABSTRACTS, vol. 84, no. 18, 3 May 1976, Columbus, Ohio, US; abstract no. 125606, KAZAKOV, V. A. ET AL: "Aluminum alloy for welding wire" XP002125482 * |
| DATABASE WPI Section Ch Week 199805, Derwent World Patents Index; Class M, Page 26, AN 1998-050644, XP002125483 * |
| LUKIN V I: "EFFECT OF ALLOYING ELEMENTS SC, MN AND ZR ON WELDABILITY OF ALLOYS OF THE AL-MGG-SC-MN-ZR SYSTEM", WELDING INTERNATIONAL,GB,WELDING INSTITUTE. ABINGTON, vol. 10, no. 12, pages 987-989, XP000639339, ISSN: 0950-7116 * |
Also Published As
| Publication number | Publication date |
|---|---|
| DE19838015C2 (de) | 2002-10-17 |
| CA2306726A1 (en) | 2000-03-02 |
| CN1274391A (zh) | 2000-11-22 |
| JP2002523621A (ja) | 2002-07-30 |
| US6315948B1 (en) | 2001-11-13 |
| CA2306726C (en) | 2008-07-29 |
| ES2173759T3 (es) | 2002-10-16 |
| DE59901293D1 (de) | 2002-05-29 |
| RU2226567C2 (ru) | 2004-04-10 |
| EP1025270B1 (de) | 2002-04-24 |
| CN1107120C (zh) | 2003-04-30 |
| EP1025270A1 (de) | 2000-08-09 |
| DE19838015A1 (de) | 2000-03-02 |
| ATE216735T1 (de) | 2002-05-15 |
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