EP1025270B1 - Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung - Google Patents
Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung Download PDFInfo
- Publication number
- EP1025270B1 EP1025270B1 EP99952346A EP99952346A EP1025270B1 EP 1025270 B1 EP1025270 B1 EP 1025270B1 EP 99952346 A EP99952346 A EP 99952346A EP 99952346 A EP99952346 A EP 99952346A EP 1025270 B1 EP1025270 B1 EP 1025270B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- magnesium
- weight
- scandium
- magnesium alloy
- automobiles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000011777 magnesium Substances 0.000 title claims abstract description 8
- 229910000861 Mg alloy Inorganic materials 0.000 title claims abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 title claims abstract description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 title claims abstract 4
- GANNOFFDYMSBSZ-UHFFFAOYSA-N [AlH3].[Mg] Chemical compound [AlH3].[Mg] GANNOFFDYMSBSZ-UHFFFAOYSA-N 0.000 title claims 2
- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical group [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052706 scandium Inorganic materials 0.000 claims abstract description 8
- 239000010936 titanium Substances 0.000 claims abstract description 8
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011572 manganese Substances 0.000 claims abstract description 6
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 5
- 229910052771 Terbium Inorganic materials 0.000 claims abstract description 5
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- GZCRRIHWUXGPOV-UHFFFAOYSA-N terbium atom Chemical compound [Tb] GZCRRIHWUXGPOV-UHFFFAOYSA-N 0.000 claims abstract description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052747 lanthanoid Inorganic materials 0.000 claims abstract description 4
- 150000002602 lanthanoids Chemical class 0.000 claims abstract description 4
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 3
- 239000010703 silicon Substances 0.000 claims abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052782 aluminium Inorganic materials 0.000 claims abstract 2
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910045601 alloy Inorganic materials 0.000 claims description 13
- 239000000956 alloy Substances 0.000 claims description 13
- 239000012535 impurity Substances 0.000 claims description 2
- 229910052692 Dysprosium Inorganic materials 0.000 claims 1
- 229910052691 Erbium Inorganic materials 0.000 claims 1
- 229910052693 Europium Inorganic materials 0.000 claims 1
- 229910052688 Gadolinium Inorganic materials 0.000 claims 1
- 229910052689 Holmium Inorganic materials 0.000 claims 1
- 229910052779 Neodymium Inorganic materials 0.000 claims 1
- 239000004411 aluminium Substances 0.000 claims 1
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims 1
- UYAHIZSMUZPPFV-UHFFFAOYSA-N erbium Chemical compound [Er] UYAHIZSMUZPPFV-UHFFFAOYSA-N 0.000 claims 1
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims 1
- UIWYJDYFSGRHKR-UHFFFAOYSA-N gadolinium atom Chemical compound [Gd] UIWYJDYFSGRHKR-UHFFFAOYSA-N 0.000 claims 1
- KJZYNXUDTRRSPN-UHFFFAOYSA-N holmium atom Chemical compound [Ho] KJZYNXUDTRRSPN-UHFFFAOYSA-N 0.000 claims 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims 1
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000356 contaminant Substances 0.000 abstract 1
- 230000000737 periodic effect Effects 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 description 7
- 238000005260 corrosion Methods 0.000 description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- -1 aluminum-scandium-zirconium Chemical compound 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/06—Alloys based on aluminium with magnesium as the next major constituent
Definitions
- the invention relates to a weldable, corrosion-resistant, high-magnesium aluminum-magnesium alloy, which is an essential component of a ternary aluminum-scandium-zirconium phase contains.
- a weldable, corrosion-resistant, high-magnesium aluminum-magnesium alloy which is an essential component of a ternary aluminum-scandium-zirconium phase contains.
- Such an alloy is for example from the US 5,624,632 and is known for its low density, high strength and Corrosion resistance is of particular interest for aerospace applications.
- US Patent generate higher strength and corrosion resistance. In terms of weldability such an alloy can the above. No indication can be found in U.S. patent
- this new alloy is particularly suitable for Body panels suitable and has an addition of the known alloy Titanium as well as cerium.
- An alloy shows a particularly favorable corrosion behavior the ratio of manganese to scandium is less than two.
- known alloy contains titanium, in addition to acting as a grain refining agent, to increase the strength since titanium replaces the zirconium in the ternary Al-Sc-Zr phase can, but the solubility of titanium is lower than that of zirconium.
- the cerium additive carries also to increase strength and continue to increase the yield strength as well as thermal stability.
- a particularly strong and corrosion-resistant alloy contains at least 0.15% by weight Scandium.
- the addition of lanthanides is advantageously in a weight% range between 0.05 and 0.35, this range being different when using a lanthanide mixture relates to the total mixture.
- the alloy tolerates silicon impurities up to 0.2% by weight; above all, the dynamic properties deteriorate.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Powder Metallurgy (AREA)
- Prevention Of Electric Corrosion (AREA)
- Arc Welding In General (AREA)
- Conductive Materials (AREA)
- Extrusion Of Metal (AREA)
- Pressure Welding/Diffusion-Bonding (AREA)
- Forging (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19838015A DE19838015C2 (de) | 1998-08-21 | 1998-08-21 | Gewalztes, stranggepreßtes, geschweißtes oder geschmiedetes Bauteil aus einer schweißbaren, korrosionsbeständigen hochmagnesiumhaltigen Aluminium-Magnesium-Legierung |
| DE19838015 | 1998-08-21 | ||
| PCT/DE1999/002491 WO2000011231A1 (de) | 1998-08-21 | 1999-08-10 | Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1025270A1 EP1025270A1 (de) | 2000-08-09 |
| EP1025270B1 true EP1025270B1 (de) | 2002-04-24 |
Family
ID=7878284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99952346A Expired - Lifetime EP1025270B1 (de) | 1998-08-21 | 1999-08-10 | Neue schweissbare, korrosionsbeständige hochmagnesiumhaltige aluminium-magnesium-legierung, insbesondere für die automobilanwendung |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6315948B1 (enExample) |
| EP (1) | EP1025270B1 (enExample) |
| JP (1) | JP2002523621A (enExample) |
| CN (1) | CN1107120C (enExample) |
| AT (1) | ATE216735T1 (enExample) |
| CA (1) | CA2306726C (enExample) |
| DE (2) | DE19838015C2 (enExample) |
| ES (1) | ES2173759T3 (enExample) |
| RU (1) | RU2226567C2 (enExample) |
| WO (1) | WO2000011231A1 (enExample) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE10248594B4 (de) * | 2001-12-14 | 2006-04-27 | Eads Deutschland Gmbh | Verfahren zum Herstellen eines Scandium (Sc)- legierten Aluminiumblechmaterials mit hoher Risszähigkeit |
| US20040156739A1 (en) | 2002-02-01 | 2004-08-12 | Song Shihong Gary | Castable high temperature aluminum alloy |
| AT501867B1 (de) * | 2005-05-19 | 2009-07-15 | Aluminium Lend Gmbh & Co Kg | Aluminiumlegierung |
| US7875132B2 (en) * | 2005-05-31 | 2011-01-25 | United Technologies Corporation | High temperature aluminum alloys |
| US7584778B2 (en) * | 2005-09-21 | 2009-09-08 | United Technologies Corporation | Method of producing a castable high temperature aluminum alloy by controlled solidification |
| CN100445019C (zh) * | 2006-09-14 | 2008-12-24 | 中国航空工业第一集团公司北京航空材料研究院 | Al-Mg-Sc系焊丝 |
| DE112008003052T5 (de) | 2007-11-15 | 2010-12-16 | Aleris Aluminum Koblenz Gmbh | Produkt aus Al-Mg-Zn-Knetlegierung und Herstellungsverfahren dafür |
| US7879162B2 (en) * | 2008-04-18 | 2011-02-01 | United Technologies Corporation | High strength aluminum alloys with L12 precipitates |
| US7875131B2 (en) * | 2008-04-18 | 2011-01-25 | United Technologies Corporation | L12 strengthened amorphous aluminum alloys |
| US8017072B2 (en) * | 2008-04-18 | 2011-09-13 | United Technologies Corporation | Dispersion strengthened L12 aluminum alloys |
| US8002912B2 (en) * | 2008-04-18 | 2011-08-23 | United Technologies Corporation | High strength L12 aluminum alloys |
| US7811395B2 (en) * | 2008-04-18 | 2010-10-12 | United Technologies Corporation | High strength L12 aluminum alloys |
| US7875133B2 (en) * | 2008-04-18 | 2011-01-25 | United Technologies Corporation | Heat treatable L12 aluminum alloys |
| US8409373B2 (en) * | 2008-04-18 | 2013-04-02 | United Technologies Corporation | L12 aluminum alloys with bimodal and trimodal distribution |
| US20090263273A1 (en) * | 2008-04-18 | 2009-10-22 | United Technologies Corporation | High strength L12 aluminum alloys |
| US20090260724A1 (en) * | 2008-04-18 | 2009-10-22 | United Technologies Corporation | Heat treatable L12 aluminum alloys |
| US7871477B2 (en) * | 2008-04-18 | 2011-01-18 | United Technologies Corporation | High strength L12 aluminum alloys |
| US8778099B2 (en) * | 2008-12-09 | 2014-07-15 | United Technologies Corporation | Conversion process for heat treatable L12 aluminum alloys |
| US20100143177A1 (en) * | 2008-12-09 | 2010-06-10 | United Technologies Corporation | Method for forming high strength aluminum alloys containing L12 intermetallic dispersoids |
| US8778098B2 (en) * | 2008-12-09 | 2014-07-15 | United Technologies Corporation | Method for producing high strength aluminum alloy powder containing L12 intermetallic dispersoids |
| US20100226817A1 (en) * | 2009-03-05 | 2010-09-09 | United Technologies Corporation | High strength l12 aluminum alloys produced by cryomilling |
| RU2393073C1 (ru) * | 2009-03-17 | 2010-06-27 | Федеральное Государственное Унитарное Предприятие "Центральный Научно-Исследовательский Институт Конструкционных Материалов "Прометей" (Фгуп "Цнии Км "Прометей") | Состав сварочной проволоки на основе алюминия |
| US20100252148A1 (en) * | 2009-04-07 | 2010-10-07 | United Technologies Corporation | Heat treatable l12 aluminum alloys |
| US20100254850A1 (en) * | 2009-04-07 | 2010-10-07 | United Technologies Corporation | Ceracon forging of l12 aluminum alloys |
| US9611522B2 (en) * | 2009-05-06 | 2017-04-04 | United Technologies Corporation | Spray deposition of L12 aluminum alloys |
| US9127334B2 (en) * | 2009-05-07 | 2015-09-08 | United Technologies Corporation | Direct forging and rolling of L12 aluminum alloys for armor applications |
| DE102010020268A1 (de) | 2009-05-12 | 2010-11-18 | Aleris Aluminum Duffel Bvba | Aluminium-Magnesium-Legierungsprodukt für geformte Autmobilteile |
| US20110044844A1 (en) * | 2009-08-19 | 2011-02-24 | United Technologies Corporation | Hot compaction and extrusion of l12 aluminum alloys |
| US8728389B2 (en) * | 2009-09-01 | 2014-05-20 | United Technologies Corporation | Fabrication of L12 aluminum alloy tanks and other vessels by roll forming, spin forming, and friction stir welding |
| US8409496B2 (en) * | 2009-09-14 | 2013-04-02 | United Technologies Corporation | Superplastic forming high strength L12 aluminum alloys |
| US20110064599A1 (en) * | 2009-09-15 | 2011-03-17 | United Technologies Corporation | Direct extrusion of shapes with l12 aluminum alloys |
| US9194027B2 (en) * | 2009-10-14 | 2015-11-24 | United Technologies Corporation | Method of forming high strength aluminum alloy parts containing L12 intermetallic dispersoids by ring rolling |
| US20110091345A1 (en) * | 2009-10-16 | 2011-04-21 | United Technologies Corporation | Method for fabrication of tubes using rolling and extrusion |
| US20110091346A1 (en) * | 2009-10-16 | 2011-04-21 | United Technologies Corporation | Forging deformation of L12 aluminum alloys |
| US8409497B2 (en) * | 2009-10-16 | 2013-04-02 | United Technologies Corporation | Hot and cold rolling high strength L12 aluminum alloys |
| CN102699564B (zh) * | 2012-04-27 | 2015-04-22 | 浙江宇光铝材有限公司 | 铝合金自动焊丝 |
| WO2016130426A1 (en) | 2015-02-11 | 2016-08-18 | Scandium International Mining Corporation | Scandium-containing master alloys and methods for making the same |
| CN105499832A (zh) * | 2016-01-28 | 2016-04-20 | 东北大学 | 一种铝镁铈焊丝及其制备方法 |
| CN106624428A (zh) * | 2016-12-16 | 2017-05-10 | 吴中区穹窿山天仲高分子材料技术研究所 | 一种环保型焊接合金材料及其制备方法 |
| CN107363122B (zh) * | 2017-06-14 | 2018-12-14 | 飞龙精工科技(苏州)有限公司 | 铝镁合金丝的制备工艺 |
| RU2663446C1 (ru) * | 2017-12-06 | 2018-08-06 | Общество с ограниченной ответственностью "Опытный завод "Авиаль" (ООО "ОЗА") | Сплав на основе алюминия для сварочной проволоки |
| CN111378878B (zh) * | 2018-12-29 | 2021-10-26 | 嘉丰工业科技(惠州)有限公司 | 一种高延展性非热处理压铸铝合金及其制备方法 |
| CN110029252B (zh) * | 2019-04-12 | 2021-08-24 | 范卫忠 | 一种5g手机中板用高强高韧抗氧化铝镁合金材料及其制备方法 |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU439535A1 (ru) * | 1972-07-04 | 1974-08-15 | Предприятие П/Я Р-6209 | Сплав на основе алюмини |
| SU480513A1 (ru) * | 1973-04-28 | 1975-08-15 | Предприятие П/Я М-5539 | Сплав дл сварочной проволоки на основе алюмини |
| JPS59159961A (ja) * | 1983-02-28 | 1984-09-10 | Mitsubishi Alum Co Ltd | 超塑性Al合金 |
| US5055257A (en) * | 1986-03-20 | 1991-10-08 | Aluminum Company Of America | Superplastic aluminum products and alloys |
| JPS63179040A (ja) | 1987-01-20 | 1988-07-23 | Showa Alum Corp | 表面平滑性に優れたシリンダ用アルミニウム合金 |
| JPS63248593A (ja) * | 1987-03-31 | 1988-10-14 | Showa Alum Corp | アルミニウム合金溶加材 |
| JP3286982B2 (ja) * | 1990-04-25 | 2002-05-27 | 菱化マックス株式会社 | 金型素材 |
| JPH07145441A (ja) * | 1993-01-27 | 1995-06-06 | Toyota Motor Corp | 超塑性アルミニウム合金およびその製造方法 |
| FR2717827B1 (fr) * | 1994-03-28 | 1996-04-26 | Jean Pierre Collin | Alliage d'aluminium à hautes teneurs en Scandium et procédé de fabrication de cet alliage. |
| US5624632A (en) * | 1995-01-31 | 1997-04-29 | Aluminum Company Of America | Aluminum magnesium alloy product containing dispersoids |
| RU2082809C1 (ru) * | 1995-07-25 | 1997-06-27 | Акционерное общество открытого типа "Всероссийский институт легких сплавов" | Деформируемый термически неупрочняемый сплав на основе алюминия |
| KR100469929B1 (ko) * | 1997-02-10 | 2005-02-02 | 알코아 인코포레이티드 | 알루미늄 합금 및 그로부터 제조된 항공기 부품 |
| DK0918095T3 (da) * | 1997-11-20 | 2003-07-21 | Alcan Tech & Man Ag | Fremgangsmåde til fremstilling af en strukturkomponent af en aluminiums-trykstøbelegering |
-
1998
- 1998-08-21 DE DE19838015A patent/DE19838015C2/de not_active Expired - Fee Related
-
1999
- 1999-08-10 RU RU2000112645/02A patent/RU2226567C2/ru not_active IP Right Cessation
- 1999-08-10 EP EP99952346A patent/EP1025270B1/de not_active Expired - Lifetime
- 1999-08-10 JP JP2000566481A patent/JP2002523621A/ja active Pending
- 1999-08-10 US US09/530,067 patent/US6315948B1/en not_active Expired - Lifetime
- 1999-08-10 CN CN99801195A patent/CN1107120C/zh not_active Expired - Lifetime
- 1999-08-10 WO PCT/DE1999/002491 patent/WO2000011231A1/de not_active Ceased
- 1999-08-10 ES ES99952346T patent/ES2173759T3/es not_active Expired - Lifetime
- 1999-08-10 CA CA002306726A patent/CA2306726C/en not_active Expired - Lifetime
- 1999-08-10 DE DE59901293T patent/DE59901293D1/de not_active Expired - Lifetime
- 1999-08-10 AT AT99952346T patent/ATE216735T1/de active
Also Published As
| Publication number | Publication date |
|---|---|
| ES2173759T3 (es) | 2002-10-16 |
| RU2226567C2 (ru) | 2004-04-10 |
| EP1025270A1 (de) | 2000-08-09 |
| DE19838015C2 (de) | 2002-10-17 |
| WO2000011231A1 (de) | 2000-03-02 |
| DE59901293D1 (de) | 2002-05-29 |
| CA2306726A1 (en) | 2000-03-02 |
| DE19838015A1 (de) | 2000-03-02 |
| CN1274391A (zh) | 2000-11-22 |
| ATE216735T1 (de) | 2002-05-15 |
| CA2306726C (en) | 2008-07-29 |
| CN1107120C (zh) | 2003-04-30 |
| US6315948B1 (en) | 2001-11-13 |
| JP2002523621A (ja) | 2002-07-30 |
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