WO1999046307A1 - Polymere fluore stabilise et procede de stabilisation associe - Google Patents
Polymere fluore stabilise et procede de stabilisation associe Download PDFInfo
- Publication number
- WO1999046307A1 WO1999046307A1 PCT/JP1999/001120 JP9901120W WO9946307A1 WO 1999046307 A1 WO1999046307 A1 WO 1999046307A1 JP 9901120 W JP9901120 W JP 9901120W WO 9946307 A1 WO9946307 A1 WO 9946307A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- group
- tetrafluoroethylene
- fluoropolymer
- polymer
- hexafluoropropylene
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/44—Preparation of metal salts or ammonium salts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/10—Copolymer characterised by the proportions of the comonomers expressed as molar percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2810/00—Chemical modification of a polymer
- C08F2810/40—Chemical modification of a polymer taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains
Definitions
- the present invention relates to a stabilized fluorinated polymer and a method for stabilizing a fluorinated polymer.
- a stabilized fluorinated polymer that can prevent brown or gray-brown coloring that occurs when the polymer is heated and is free from foaming, and a method for stabilizing a fluorinated polymer to obtain such a stabilized fluorinated polymer About.
- an emulsion copolymer of tetrafluoroethylene and hexafluoropropylene when melt processed into the final product, contains volatiles in the final product due to heat and shear-labile polymer ends. Bubbles or voids due to the substance can occur.
- the type of unstable polymer terminal varies depending on the polymerization method and the type of polymerization initiator and chain transfer agent.
- an ordinary persulfate e.g., ammonium persulfate, potassium persulfate, etc.
- a carboxylic acid terminal is formed, and the carboxylic acid terminal is volatilized during melt processing. It is a source of sexual substances.
- US Pat. No. 3,085,083 proposes a wet heat treatment.
- the treatment speed is increased by adding salt or base, and the concentration of salt or base added is set to 100 to 60 ppm. It is not the concentration set focusing on unstable terminal groups.
- an emulsion polymer of tetrafluoroethylene and hexafluoropropylene may become grayish brown or brown during the melt processing to the final product, due to melting conditions. Severity, residue of polymerization initiator, presence of contamination, carbonization of low molecular weight substances, etc.
- One object of the present invention is to provide a stabilized fluorinated polymer from which unstable terminal groups have been removed and which do not foam upon heating.
- Another object of the present invention is to provide a method for effectively removing an unstable terminal group and coloring caused by the unstable terminal group from a fluorine-containing polymer having an unstable terminal group such as a carboxylic acid terminal group.
- An object of the present invention is to provide a method capable of removing even a binding portion of an unstable main chain.
- the amount of unpaired electrons on carbon atoms represented by spin density in electron spin resonance measurement at a temperature of 10 K is preferably 1.0 X 10 14 spinsZ g or less. Is a melt-molded fluoropolymer containing 50 ppmJ ⁇ of basic components.
- a fluorinated polymer having a carboxylic acid terminal group or a terminal group which can be hydrolyzed by heating at 200 ° C. or more to form a sulfonic acid group is stabilized.
- a compound containing an alkali metal or an alkaline earth metal is converted to the number of atoms of the alkali metal or the alkaline earth metal, ammonia is converted to the number of molecules of the ammonia, or the ammonium group is converted to the number of atoms of the ammonia.
- the compound containing was converted to the number of ammonium groups, added to the fluorine-containing polymer in an amount of 0.1 to 10% of the total number of the terminal groups, and added in an atmosphere containing moisture at 200.
- a method is provided that includes heating at a temperature of at least ° C.
- the amount of unpaired electrons on a carbon atom represented by spin density in electron spin resonance (ESR) measurement at a temperature of 10 K is 1.0 X 1 g, preferably 1.0 X 10 13 spinsZ g or less. If the spin density is within this range, the fluoropolymer is hardly or not colored even when heated.
- the degree of coloration depends on the severity of the melting conditions, the residue of the polymerization initiator, and the presence of contamination, but the main cause is the temperature of 200 ° C or higher. Is presumed to be a carbon atom appearing in the polymer. Coloring degree When the unpaired electrons on the carbon atoms of the fluoropolymer samples having different matches were measured by ESR, a good correlation was found between the degree of coloring and the unpaired electrons (spin density). The guess seems to be reasonable.
- the stabilized fluorinated polymer of the present invention contains a basic component (for example, a compound containing an alkali metal or an alkaline earth metal used in the method of the present invention, ammonia, or a compound containing an ammonium group) of preferably 5 Oppm or less. Should be contained at a concentration of 25 ppm or less.
- a basic component for example, a compound containing an alkali metal or an alkaline earth metal used in the method of the present invention, ammonia, or a compound containing an ammonium group
- the amount of the basic component is within the above range, it is possible to reduce the amount of carbon atoms considered to be a cause of coloring while performing the terminal stabilization reaction.
- Compounds containing alkali metal or alkaline earth metal include hydroxides and salts (eg, carbonates and sulfates) of these metals, and compounds containing an ammonium group include ammonium hydroxide. It can be used, and preferable examples thereof include rhodium hydroxide, sodium hydroxide, potassium carbonate, potassium sulfate, calcium carbonate, ammonia, ammonium hydroxide, and the like. Ammonia can be used as a gas or as aqueous ammonia.
- the amount of the compound containing an alkali metal or an alkaline earth metal, ammonia, or a compound containing an ammonium group depends on the type of the fluoropolymer to be treated.
- the number of molecules or the number of ammonium groups is 0.1 to 10%, preferably 0.2 to 5% of the total number of the terminal groups to be stabilized.
- the reaction rate of terminal stabilization increases, but the coloring of the polymer is reduced. It cannot be completely removed, and the polymer itself deteriorates and the melt viscosity decreases.
- fluoropolymers stabilized by the method of the present invention are: tetrafluoroethylene, hexafluoropropylene, phenol. Copolymer of at least two monomers selected from the group consisting of monofluoroalkyl biel ether, ethylene, vinylidene fluoride, and trifluoroethylene, tetrafluoroethylene alone And a homopolymer of vinylidene fluoride, and a homopolymer of black trifluoroethylene.
- perfluoroalkyl butyl ether has the formula:
- n is an integer from 1 to 4.
- one to Kisafuruoro propylene copolymer (FEP) is 72 to 96 wt% Tetorafuru Oroechiren and 4 to 28 weight 0/0 to the Preferably, it is a copolymer of fluoropropylene.
- FEP Kisafuruoro propylene copolymer
- PFA tetrafluoroethylene-perfluoroalkylbierether copolymer
- the copolymer is preferably Roechire ting 1-8 weight 0/0 per full O b alkylvinyl E one ether of the copolymer, in case a tetrafluoropropoxy O b ethylene one ethylene copolymer (ETFE) is It is preferred that the copolymer is a copolymer of ethylene, 74.5 to 89.3% by weight, tetrafluoro / rheo ethylene and 1 1, 2 to 55.5% by weight of ethylene.
- These polymers may be copolymerized with other monomers in an amount that does not impair the essential properties of each polymer.
- Such other monomers include hexafluoro mouth propylene (when the fluoropolymer does not contain hexafluoropropylene), perfluoroalkylbier ether (the fluoropolymer includes perfluoroalkyl vinyl ether) ), Ethylene (when the fluoropolymer does not contain ethylene), vinylidene fluoride (when the fluoropolymer is vinylidenefluoride) Chlorofluoroethylene (when the fluoropolymer does not contain chlorotrifluoroethylene).
- the fluorinated polymer is produced by emulsion polymerization or suspension polymerization, and these polymers are tetrafluoroethylene-hexafluoropropylene copolymer (FEP) and tetrafluoroethylene.
- FEP tetrafluoroethylene-hexafluoropropylene copolymer
- PFA ethylene-perfluorovinylether polymer
- the fluoropolymer stabilized by the method of the present invention may be in a dry state or a wet state. In the case of a wet state, it is preferable that the fluoropolymer is washed with water until the pH of the cleaning solution becomes 4 or more before the heat treatment. This is expected because if the acidity of the polymer is high (the pH is low), the added compound containing an alkali metal or alkaline earth metal, or a compound containing an ammonia or ammonium group is consumed in the neutralization reaction. This is because it cannot contribute to stabilization of the terminal group.
- potassium hydroxide is regenerated during the reaction, and reacts again with the untreated carboxylic acid terminal group, and one CF 2 H as a stable terminal group can be generated one after another.
- terminal groups When the terminal groups are treated with a compound containing ammonia or an ammonium group, most of them are gaseous, so that it is preferable to heat them in a closed container.
- heating can also be performed during melt-kneading, in which case the residence time is 10 minutes or more, and the effective volume ratio (effective space in vessel / space in vessel) is greater than 0.3, and K- Pv / z Zn 2 [where ⁇ is the required power per unit volume
- the method of the present invention is preferably performed in the presence of oxygen.
- Air is usually used as an oxygen source, but oxygen may be used after dilution with an inert gas (eg, nitrogen, argon, etc.).
- the concentration of oxygen is not particularly limited, but is usually 5 to 50% by volume of the atmosphere, preferably 10 to 30% by volume.
- the kneader preferably used in the method of the present invention has a longer residence time compared to a normal twin-screw extruder (at least 10 minutes, preferably 10 to 120 minutes), and a structure (effective volume). Rate and power coefficient are different from conventional twin-screw extruders.
- the effective volume ratio of the twin-screw extruder of the prior art is usually 0.3 or less, whereas the so-called “surface renewal kneader” is preferably used in the present invention.
- the effective floor area ratio is greater than 0.3, and is often greater than 0.5.
- the effective space in the container refers to the volume of space when a paddle, a shaft, and the like are inserted into the device
- the space in the container refers to the space volume when no paddle, shaft, and the like are inserted into the device.
- the power coefficient K defined by the above equation is between 8000 and 12000 for a twin-screw extruder, but less than 8 000 for a surface-renewal-type kneader, and is often 7000 or less.
- the surface-renewal type kneader has both self-cleaning properties and high piston flow during continuous operation.
- Representative surface renewal type kneaders are: HVR, SCR, NEW-SCR manufactured by Mitsubishi Heavy Industries, Ltd .; Vivolac manufactured by Sumitomo Heavy Industries, Ltd .; Hitachi Glasses wing polymerization machine, Hitachi lattice wing polymerization machine; (LI ST) AP—MACH I NE, NEW AP—MACH I NE, etc.
- the treatment of the present invention removes almost all unstable ends and / or unstable backbone linkages, leaving unstable terminal groups with stable perfluoromethyl ends (one CF 3 ), difluorohydride It can be converted into a terminal (one CF 2 H), an acid amide terminal (one CO NH 2 ), and a methyl ester terminal (one C ⁇ OCH 3 ).
- Quantitative determination of unstable and stable end groups can be performed by infrared analysis. This measuring method is described in U.S. Pat. No. 3,085,083, U.S. Pat. No. 4,675,380, Japanese Patent Application Laid-Open No. H4-120507, and the like. The disclosures of these US patents are incorporated herein by reference. According to this measuring method, number number of each terminal group is measured as the number per 10 6 carbon atoms.
- the amount of a substance that evaporates when a polymer is melted can be evaluated by measuring a known volatile substance index: VI value. The method for measuring this value will be described below.
- the container is evacuated to a vacuum of no more than two feet Hg and placed in a high temperature block maintained at 380 ° C to achieve thermal equilibrium.
- VI (P 40 -P 0 ) XV / l 0 / W
- the volatile matter index is preferably smaller than 25, and if it is larger than 25, bubbles and voids will be generated in an amount that can be a problem during melt processing.
- the present invention stabilizes unstable terminal groups of the fluoropolymer, eliminates coloring after melt molding or firing, and in some cases, reduces unstable bonding sites in the main chain. Can be standardized.
- a FEP polymer dispersion prepared by emulsion polymerization using ammonium persulfate (APS) and containing 2.0 kPa's melt viscosity and 12 mol% hexafluoropropylene is coagulated with nitric acid, and then polymerized.
- 1 kg of this polymer is put into a kneader (internal volume 1 L) with an effective volume ratio of 0.82 (effective volume in the container Z and space in the container) made of a corrosion-resistant material, and the rotation speed is 5 O rpm. And kneaded.
- the temperature of the kneader was set at 380 ° C. Simultaneously with the start of kneading, 85 ° C. saturated humid air was supplied in 0.1 NL minutes.
- Best carboxylic acid end groups of the polymer used in this example is 8 5 0 per 1 0 6 carbon atoms, potassium atoms hydroxide force Li in um added about the best carboxylic acid end groups Equivalent to 3%.
- Example 2 The treatment was carried out in the same manner as in Example 1, except that 30 ppm of sodium hydroxide was used instead of the hydroxylating power room.
- the number of sodium atoms in the added sodium hydroxide corresponds to about 4.5% of the total number of rubonic acid end groups. Table 2 shows the results. As in Example 1, when the kneading time was 45 minutes or more, the melt was not colored and the VI value was low.
- Example 3 The treatment was carried out in the same manner as in Example 1, except that the concentration of the hydroxylating water was 300 ppm.
- Table 3 shows the results in which the number of potassium atoms corresponds to about 30% of the total number of rubonic acid end groups. The melt viscosity of the polymer decreased, deterioration was observed, and the color did not disappear even after kneading for 60 minutes.
- the treatment was carried out in the same manner as in Example 1, except that the concentration of the hydration power was 0.3 ppm.
- the number of calcium atoms in the added hydroxide hydroxide in this comparative example corresponds to about 0.03% of the total number of rubonic acid end groups. Table 4 shows the results. The longer the kneading time, the higher the molecular weight.
- Example 3 The same polymer used in Example 1 was added to the liter 1 kg and 10 cc of water are added, and an aqueous solution of ammonium hydroxide is further added in such an amount that the number of ammonium groups becomes 2.5% of the total number of sulfonic acid terminal groups. Heated for hours.
- the polymer was heated in the same procedure as in Example 3, except that the aqueous ammonium hydroxide solution was added in such an amount that the number of ammonium groups was 0.05% of the total number of rubonic acid terminal groups. After drying the polymer, the total number of rubonic acid end groups was measured. As a result, it was 450 per 10 6 carbon atoms.
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/623,756 US6777501B1 (en) | 1998-03-09 | 1999-03-09 | Stabilized fluorine-containing polymer and method for stabilizing fluorine containing polymer |
EP99907884A EP1083189A4 (en) | 1998-03-09 | 1999-03-09 | STABILIZED FLUORINATED POLYMER AND METHOD OF STABILIZING THE SAME |
US10/880,537 US7151141B2 (en) | 1998-03-09 | 2004-07-01 | Stabilized fluorine-containing polymer and method for stabilizing fluorine-containing polymer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP5663198 | 1998-03-09 | ||
JP10/56631 | 1998-03-09 |
Related Child Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09623756 A-371-Of-International | 1999-03-09 | ||
US09/623,756 A-371-Of-International US6777501B1 (en) | 1998-03-09 | 1999-03-09 | Stabilized fluorine-containing polymer and method for stabilizing fluorine containing polymer |
US10/880,537 Division US7151141B2 (en) | 1998-03-09 | 2004-07-01 | Stabilized fluorine-containing polymer and method for stabilizing fluorine-containing polymer |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999046307A1 true WO1999046307A1 (fr) | 1999-09-16 |
Family
ID=13032670
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP1999/001120 WO1999046307A1 (fr) | 1998-03-09 | 1999-03-09 | Polymere fluore stabilise et procede de stabilisation associe |
Country Status (4)
Country | Link |
---|---|
US (2) | US6777501B1 (ja) |
EP (1) | EP1083189A4 (ja) |
CN (1) | CN100379772C (ja) |
WO (1) | WO1999046307A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1170303A1 (en) * | 1998-11-04 | 2002-01-09 | Daikin Industries, Ltd. | Method of stabilizing fluoropolymer |
JP2002249585A (ja) * | 2000-12-21 | 2002-09-06 | Daikin Ind Ltd | 含フッ素重合体の改質法およびその制御方法 |
JP2003082020A (ja) * | 2001-09-11 | 2003-03-19 | Daikin Ind Ltd | 含フッ素重合体の製造方法 |
JP2007246928A (ja) * | 1998-11-13 | 2007-09-27 | Daikin Ind Ltd | フッ素ゴム架橋用組成物 |
US7309743B2 (en) | 1998-11-13 | 2007-12-18 | Daikin Industries, Ltd. | Fluorine-containing elastomer and composition thereof for crosslinking |
WO2021112232A1 (ja) * | 2019-12-04 | 2021-06-10 | 日東電工株式会社 | 光学用樹脂組成物の製造方法及び光学用樹脂組成物 |
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CN1882614B (zh) | 2003-11-20 | 2011-01-19 | 大金工业株式会社 | 含氟聚合物制造方法及含氟聚合物的物质 |
EP1914251A1 (en) | 2006-10-17 | 2008-04-23 | Solvay Solexis S.p.A. | Process for stabilizing fluoropolymer having ion exchange groups |
WO2008127461A2 (en) * | 2006-12-12 | 2008-10-23 | 3M Innovative Properties Company | Thermally stable fluoropolymers |
JP5545639B2 (ja) * | 2010-04-30 | 2014-07-09 | 三井・デュポンフロロケミカル株式会社 | フッ素樹脂成形品およびその製造方法 |
CN113285078A (zh) | 2013-07-02 | 2021-08-20 | 旭化成株式会社 | 电解质溶液、电解质膜、电极催化剂层、膜电极接合体和燃料电池 |
CN103435735B (zh) * | 2013-09-10 | 2015-08-05 | 上海三爱富新材料股份有限公司 | 可熔性聚四氟乙烯的后处理方法 |
US9862811B2 (en) | 2014-09-04 | 2018-01-09 | Honeywell International, Inc. | Methods for synthesizing stabilized polymers of chlorotrifluoroethylene and products manufactured using such polymers |
US10294339B2 (en) * | 2015-01-20 | 2019-05-21 | Daikin Industries, Ltd. | Method for producing modified molded article of fluororesin |
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1999
- 1999-03-09 WO PCT/JP1999/001120 patent/WO1999046307A1/ja not_active Application Discontinuation
- 1999-03-09 US US09/623,756 patent/US6777501B1/en not_active Expired - Lifetime
- 1999-03-09 CN CNB998038105A patent/CN100379772C/zh not_active Expired - Lifetime
- 1999-03-09 EP EP99907884A patent/EP1083189A4/en not_active Withdrawn
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2004
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1170303A1 (en) * | 1998-11-04 | 2002-01-09 | Daikin Industries, Ltd. | Method of stabilizing fluoropolymer |
EP1170303A4 (en) * | 1998-11-04 | 2004-03-31 | Daikin Ind Ltd | METHOD FOR STABILIZING A FLUOROPOLYMER |
JP2007246928A (ja) * | 1998-11-13 | 2007-09-27 | Daikin Ind Ltd | フッ素ゴム架橋用組成物 |
US7309743B2 (en) | 1998-11-13 | 2007-12-18 | Daikin Industries, Ltd. | Fluorine-containing elastomer and composition thereof for crosslinking |
US7772327B2 (en) | 1998-11-13 | 2010-08-10 | Daikin Industries, Ltd. | Fluorine-containing elastomer and composition thereof for crosslinking |
JP2002249585A (ja) * | 2000-12-21 | 2002-09-06 | Daikin Ind Ltd | 含フッ素重合体の改質法およびその制御方法 |
JP2003082020A (ja) * | 2001-09-11 | 2003-03-19 | Daikin Ind Ltd | 含フッ素重合体の製造方法 |
WO2021112232A1 (ja) * | 2019-12-04 | 2021-06-10 | 日東電工株式会社 | 光学用樹脂組成物の製造方法及び光学用樹脂組成物 |
JP2021088661A (ja) * | 2019-12-04 | 2021-06-10 | 日東電工株式会社 | 光学用樹脂組成物の製造方法及び光学用樹脂組成物 |
Also Published As
Publication number | Publication date |
---|---|
EP1083189A4 (en) | 2006-03-15 |
US6777501B1 (en) | 2004-08-17 |
CN100379772C (zh) | 2008-04-09 |
CN1292803A (zh) | 2001-04-25 |
EP1083189A1 (en) | 2001-03-14 |
US7151141B2 (en) | 2006-12-19 |
US20040242793A1 (en) | 2004-12-02 |
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