WO1996015888A1 - Procede de compactage de poudres et appareil associe - Google Patents

Procede de compactage de poudres et appareil associe Download PDF

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Publication number
WO1996015888A1
WO1996015888A1 PCT/EP1995/004560 EP9504560W WO9615888A1 WO 1996015888 A1 WO1996015888 A1 WO 1996015888A1 EP 9504560 W EP9504560 W EP 9504560W WO 9615888 A1 WO9615888 A1 WO 9615888A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
frame
powders
die
punch
Prior art date
Application number
PCT/EP1995/004560
Other languages
English (en)
Inventor
Carlo Antonio Camorani
Maris Algeri
Original Assignee
Carlo Antonio Camorani
Maris Algeri
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Carlo Antonio Camorani, Maris Algeri filed Critical Carlo Antonio Camorani
Priority to DE69529997T priority Critical patent/DE69529997D1/de
Priority to EP95940213A priority patent/EP0793565B1/fr
Priority to AU41743/96A priority patent/AU4174396A/en
Priority to BR9509806A priority patent/BR9509806A/pt
Publication of WO1996015888A1 publication Critical patent/WO1996015888A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00—Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02—Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • B28B13/0205—Feeding the unshaped material to moulds or apparatus for producing shaped articles supplied to the moulding device in form of a coherent mass of material, e.g. a lump or an already partially preshaped tablet, pastil or the like
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00—Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02—Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B13/00—Feeding the unshaped material to moulds or apparatus for producing shaped articles; Discharging shaped articles from such moulds or apparatus
    • B28B13/02—Feeding the unshaped material to moulds or apparatus for producing shaped articles
    • B28B13/0215—Feeding the moulding material in measured quantities from a container or silo
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B3/00—Producing shaped articles from the material by using presses; Presses specially adapted therefor
    • B28B3/02—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form
    • B28B3/08—Producing shaped articles from the material by using presses; Presses specially adapted therefor wherein a ram exerts pressure on the material in a moulding space; Ram heads of special form with two or more rams per mould
    • B28B3/083—The juxtaposed rams working in the same direction
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B28—WORKING CEMENT, CLAY, OR STONE
    • B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B5/00—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping
    • B28B5/02—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type
    • B28B5/021—Producing shaped articles from the material in moulds or on moulding surfaces, carried or formed by, in or on conveyors irrespective of the manner of shaping on conveyors of the endless-belt or chain type the shaped articles being of definite length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B30—PRESSES
    • B30B—PRESSES IN GENERAL
    • B30B15/00—Details of, or accessories for, presses; Auxiliary measures in connection with pressing
    • B30B15/30—Feeding material to presses
    • B30B15/302—Feeding material in particulate or plastic state to moulding presses

Definitions

  • a method for compacting powders, and a relative apparatus A method for compacting powders, and a relative apparatus.
  • the invention concerns a method and relative apparatus for forming powders, that is, a procedure for manufacturing pressed ceramic, particularly paving or lining tiles.
  • the prior art comprises forming methods whereby the matrix of a die for ceramic materials is filled with powders, or mixtures of powder and granules, in one or more phases, prior to it being pressed to obtain a compacted article which is then sent to be fired, after, possibly, it has been dried.
  • Such methods entail lengthy idle times when loading the matrix, in as much as the trolley used for distributing the powders has to be made to advance in order to fill the matrix and, subsequently, in order to enable the punch of the press to be lowered, said trolley has to be retracted at a moderate speed so as to avoid disturbing the distribution of the powder beneath it.
  • Loading the matrix by means of a trolley is not at all satisfactory, in that it implies an intrinsic undesirable lack of homogeneity in the distribution of the powders, caused mainly by the mixing and/or uncontrolled displacement of the powders themselves with the movement of the trolley, depending also on factors that are variable with time in an unpredictable manner, for example, depending on the environmental conditions, or the physical state of the powders to be treated, its granulometry, humidity, pour rate and other factors besides.
  • the stroke of the press has to include a deaeration phase, that is, an initial portion of the down stroke of the punch into the matrix has to be carried out at a reduced velocity to enable the air inside the mass of powder being pressed to escape: this in order to avoid the formation of lenticular pockets of air inside the mass which, when the thrust exerted by the punch ceases, tends to cause the article to disintegrate.
  • a deaeration phase that is, an initial portion of the down stroke of the punch into the matrix has to be carried out at a reduced velocity to enable the air inside the mass of powder being pressed to escape: this in order to avoid the formation of lenticular pockets of air inside the mass which, when the thrust exerted by the punch ceases, tends to cause the article to disintegrate.
  • a further aspect of the technical problem is that of achieving a greater rapidity and efficiency in feeding the ceramic presses.
  • layer of powders signifies both a homogeneous layer of pulverulent material and a layer consisting of a plurality of separate layers superimposed on each other, that may also comprise decorating substances.
  • binders is used to represent powder of various granulometries and/or various colours, even mixed together.
  • decorating substances signifies substances selected from the group comprising: powders, ceramic paints, colour in the form of powder or liquid solution, ceramic mixtures and their combinations.
  • the invention resolves said technical problem by adopting a method for forming ceramic articles, comprising forming a layer of powders on conveying means which conveys it to a die, subsequently, isolating a portion of said inside a frame of said die, the frame having an outline substantially corresponding to the profile of the article to be compacted, by bringing, from above, said frame adjacent to said conveying means, and compacting the portion of said layer isolated by said frame, still positioned on said conveying means, by means of a punch of said die, which engages internally slidably with said frame.
  • the method comprises preparing of a homogeneous, continuous mass of said powders, pre-compacting of said mass to obtain a flat pre-formed semifinished product that has peripheral dimensions that are slightly smaller than that of the pressed tile, and pressing of said pre-formed semifinished product.
  • the supply of the powders, and/or granules, to the pre- compacting station being advantageously achieved with the distribution of said powders, in a continuous layer that has a substantially uniform thickness and density.
  • Said layer being obtained with dropping said mass of powders in a controlled manner from a relative batching means, for example, a hopper with a adjustable outlet section for pouring said mass of powders onto an underlying conveyor belt.
  • the powders may be poured onto a table movable with a reciprocating straight-line motion between a loading position under the hopper and a pre-compacting position under the corresponding press.
  • decorating substances may advantageously be distributed, for example, powders, that have varying granulometries and/or colours, even co-ordinated with those of the base, on the layer of powders, and/or granules, and/or on the top surface of the pre-formed semifinished products.
  • the distribution of said decorating substances may take place, in particular, on the stretch of said conveyor, or table, included between said hopper and the pre-compacting station of the layer of powders.
  • the distribution of the decorating substances may be effected directly on said conveyor, or said table, upstream of said hopper.
  • the decorating substances may consist of powders, ceramic paints, in liquid or powder form, or mixes of these, or of coloured clay-based mixtures.
  • the apparatus for the formation of the ceramic articles comprises conveying means for conveying a layer of powders to a die, said die comprising a punch that may move in a direction that is substantially orthogonal to said layer, which is associated with a relative cross-member to cause the powders to be pressed and with a frame that may move in a direction that is substantially orthogonal to said layer, independently of said punch, being shaped so as to couple with it and to enable said punch to slide inside it, said frame also being such as to isolate a portion of said layer on said conveying means.
  • the apparatus comprises batching means for the continuous dosage of predetermined quantities of powders onto underlying first conveying means that transfer said powders in the form of a substantially continuous layer towards a pre-compacting die; the apparatus also having second conveying means to transfer the pre-compacted articles to a pressing station.
  • said first conveying means consist of a conveyor belt wound in a closed loop on a number of rollers, at least one of which being motorised, said belt having an active section passing through said pre-compacting station.
  • the pre-compacting station advantageously includes a punch held above said belt which is lowered onto the powders to be pre-compacted inside a frame which is vertically mobile in co-ordination with the movements of the punch,- a striking block being positioned beneath said belt to operate, with its top surface, as a sliding plane for the belt once the thrust of the press ceases.
  • the belt is driven with intermittent motion, with advancement phases alternating with static phases to achieve the pre-compaction of the powders; said batching and/or distributing devices being coupled to relative driving means in a direction that is substantially parallel to the longitudinal direction of the conveyor belt; said driving means being such as to enable a constant relative velocity to be maintained between the conveyor and said batching and/or distribution devices.
  • said conveyor belt is driven in a continuous uniform motion and the pre- compacting station has relative driving means that transfer the pre-compacting die in a horizontal direction substantially parallel to the longitudinal direction of said conveyor.
  • the pressing die for the pre-compacted semifinished products is made to co ⁇ operate with a device for the continuous extraction and/or supply of pressed tiles, advantageously consisting of a pair of chains closed in a loop on corresponding pinions, driven synchronously, the chains being connected to each other by transverse elements acting as impellers for said tiles and/or said pre-compacted semifinished products.
  • a device for the continuous extraction and/or supply of pressed tiles advantageously consisting of a pair of chains closed in a loop on corresponding pinions, driven synchronously, the chains being connected to each other by transverse elements acting as impellers for said tiles and/or said pre-compacted semifinished products.
  • This enables the further advantage of reducing the time required to load and evacuate the pressing die.
  • the increase in productivity is due in particular to the drastic reduction in the time required to load the pressing die, due to the elimination of the movements of the powders, and/or granules, in the area close to the matrix of the die.
  • the increase in productivity is also due to the reduction in the pressing times, in that, with the introduction of the pre-compacting phase of the powder, the deaeration of the soft mass occurs for the most part before it is pressed.
  • Figure 2 is a partially sectioned side view of the pre- compacting press for the semifinished products in the starting phase of the pressing;
  • Figure 3 is a partially sectioned side view of the pre- compacting press for the semifinished products in the pressing phase
  • Figure 4 is a partially sectioned side view of the pre- compacting press for the semifinished products in the removal phase
  • Figure 5 is a partially sectioned side view of the pre- compacting press for the semifinished products in the return to initial position phase,-
  • Figure 6 is a partially sectioned side view of the press for pressing ceramic tiles in the extraction phase of the pressed tile
  • Figure 7 is a partially sectioned side view of a press as in Figure 6 in the starting phase of the pressing
  • Figure 8 is a partially sectioned side view of a press as in Figure 6 in the pressing phase
  • Figure 9 is a partially sectioned and interrupted side view of an apparatus for the embodiment of the method according to the invention, in a version with distribution of the decorating substances upstream of the batching means for the distribution of the mass of powders and/or granules making up the body of the tile;
  • Figure 10 is a Cartesian diagram with, on the ordinate, the velocity of the conveyor, shown with a continuous line, and the velocity of the batching means and/or distributing means, shown with a dotted line, and with time on the abscissa, referring to a version of apparatus having conveyor belt driven with intermittent motion;
  • Figure 11 is a diagram, referring to the same version of apparatus, with, on the ordinate, the space covered by the conveyor, shown with a continuous line, and, with a dotted line, the space covered by the batching and/or distributing means, and with the time elapsed on the abscissa;
  • Figure 12 is a schematic vertical section of a die for pressing pre-compacted semifinished products having a device for loading and evacuating the matrix, in the extraction phase of the formed tile;
  • Figure 13 is a section as in Figure 12, but in the starting phase of the pressing,-
  • Figure 14 is a section as in Figure 12, but in the phase where the semifinished product is loaded and the punch is cleaned by means of a rotary brush device,-
  • Figure 15 is an enlarged lateral section of the die of Figure 12, but with a rotary brush device for alternately cleaning the base of the matrix and the punch, in the phase at the end of the pressing;
  • Figure 16 is a vertical section as in Figure 15, but in the extraction phase of the pressed tile;
  • Figure 17 is a section as in Figure 15, but in the starting phase of the pressing;
  • Figure 18 is a section as in Figure 15, but in the initial extraction phase of the pressed tile;
  • Figure 19 is a section as in Figure 15, but showing the cleaning of the active face of the punch with the driving device shown in a dotted line,-
  • Figure 20 is a section as in Figure 15, but showing the introduction of a pre-compacted article in the matrix of the die,-
  • Figure 21 is a plan view of Figure 19;
  • Figure 22 is a section as in Figure 19, but in a variation relating to the device for extracting the pressed tiles, acting also as a device for feeding them to the matrix of the die
  • Figure 23 is a section as in Figure 22, but in the configuration during the cleaning of the active face of the punch;
  • Figure 24 is a side view as in Figure 1, but in a variation where the return stretch of the conveyor belt passes through the pre-compacting die;
  • Figure 25 is section XXV-XXV of Figure 1, but highlighting the striking block of the pre-compacting press supported straddling the return stretch of the conveyor belt;
  • Figure 26 is a transverse section as in Figure 25, but in a variation with the striking block of the pre-compacting press supported flexibly on the relative base;
  • Figure 27 is a plan view of an apparatus according to the invention, but in a version with a line for pre-compacting the powders extending in a direction parallel to the pressing line, said lines being interconnected by means of conveying means arranged perpendicularly to both lines,
  • Figure 28 is a schematic side view of a forming apparatus according to the invention, in a version with single stage pressing, during the advancement phase of the conveyor;
  • Figure 29 is a schematic view as in Figure 28 during the pressing phase,-
  • Figure 30 is a partial, schematic side view of the dosing devices for distributing the powders and/or granules, showing the relative actuating means,-
  • Figure 31 is a top view of Figure 30;
  • Figure 32 is a section XXXII-XXXII of Figure 28;
  • Figure 33 is a section as in Figure 32, but during the pressing phase;
  • Figure 34 is section XXIV-XXXIV, partial and enlarged, of Figure 32;
  • Figure 35 is a view in direction XXXV-XXXV of Figure 32;
  • Figure 36 is section XXXVI-XXXVI of Figure 35;
  • Figure 37 is a section as in Figure 32, in a version with the frame supported on the base and the bottom of the isobaric version of the pressing die;
  • Figure 38 is a section as in Figure 37, but during pressing;
  • Figure 39 is a section as in Figure 32, in a variant with the frame connected rigidly to the cross-member,- Figure 40 is a section as in Figure 39, but during pressing;
  • Figure 41 is a side view as in Figure 9, but with distributing means that are able to form an undulated layer of powders and/or granules.
  • the apparatus 1 for forming ceramic articles comprises conveying means, consisting, for example, of a conveyor belt 2 wound in a closed loop on rollers, at least one of which is coupled to driving means, having a straight, upper active section resting on a support plane 4.
  • conveying means consisting, for example, of a conveyor belt 2 wound in a closed loop on rollers, at least one of which is coupled to driving means, having a straight, upper active section resting on a support plane 4.
  • the active section of the conveyor belt 2 has above it a batching means, for example, a hopper 5, for. the distribution of the powders, that are destined to make up the body of the pressed tile 6, the opening of the hopper having a vertical batching blade 7, vertically adjustable in order to vary the thickness of the layer 8 of powders.
  • the conveyor belt 2 passes through the pre-compacting die 9, including a punch 10 positioned above the belt 2, sliding inside a matrix 11, and a striking block 12 positioned beneath the conveyor belt 2 to support it during the compaction so as to obtain a pre-formed article 17.
  • the striking block 12 may have an upper plate 12a, directly in contact with the lower face of the conveyor belt 2, made of a porous material, obtained, for example, by sintering, for example metal, or other suitable material: in this case the conveyor also being made of a gas-permeable material, that is, porous, for example fabric.
  • the pre-compaction pressure may be vary widely, depending on the type of powders used, the degree of final pressing, the aesthetic effect required for the final product and other factors besides.
  • the pre-compaction pressure has to be such as to permit a pre-compacted semifinished product to be obtained that is sufficiently resistant to enable it to be transferred and handled towards the pressing station without it being damaged.
  • the pre-compaction of said powders and/or granules is such that a flat pre-formed semifinished product is obtained that has peripheral dimensions that are slightly smaller than those of the pressed tile and a thickness that is slightly greater than that of the pressed tile.
  • the die 9 may be stationary, wherein case the layer 8 is made to advance intermittently with the batching means 5 being coupled to driving means not shown acting in a longitudinal direction F parallel to the direction of conveyor belt 2.
  • the pre-compaction die 9 may be made mobile with intermittent motion synchronous with the speed of translation of the active section of the conveyor belt 2 in the direction indicated by arrow Fl, by means of substantially horizontal driving means parallel to the direction of the conveyor belt 2.
  • distributing means 13, 14 for distributing powders onto the layer 8, in order to improve the appearance of the pressed tile, or to give it particular physical, or mechanical properties.
  • Said distributing means which may be chosen from a wide range, for example, of decorating machines for ceramic tiles, amongst which there also are serigraphy machinery, may consist of, for example, hoppers 15, whose outlet section is controlled by a corresponding batching roller 16, whose peripheral surface is smooth, or even etched, to project non coherent decorating elements continuously, or even intermittently.
  • a powder, or granule, batching means 14 may consist of a pair of vibrating, superimposed sieves 14a, 14b, the lower sieve 14b being suitably screened in order to deposit the loose material onto predetermined areas of the layer 8.
  • the pre-compacted articles 17, produced by die 9 are transferred onto second conveying means, advantageously comprsing, for example, a roller conveyor 18, with motorised rollers 18a, to feed the press 19.
  • second conveying means advantageously comprsing, for example, a roller conveyor 18, with motorised rollers 18a, to feed the press 19.
  • a hopper 20 that collects and recycles excess powder 19a sending it to batching means 5 by means of conduits not shown.
  • Transferring means i. e. an impeller 22 for the pre-formed articles 17 and/or the pressed tiles 6 is movable on the roller conveyor 18 with reciprocating motion.
  • the frame 11 of the compacting die 9 has lower edges 23 having wedge-shaped sections in a plane perpendicular to the conveyor belt: in this way it is possible to achieve an optimal separation from the layer 8 of powders of the mass destined to form the tile 6, without altering the density of the layer 8: the particular shape of the edges 23 determine the formation of mounds 24 of excess material in the area corresponding to the external edges of the frame 11.
  • the die 9 is activated in its return stroke in a direction F2 opposite to Fl, as shown in Figure 5.
  • the pre-formed article 17 is sent, by means of the second conveying means, for example, a roller conveyor 18, to press 19 for the formation of the tile 6 and its removal, by a further motorised roller conveyor 25, possibly supplied by oscillating feeder arm 25a with suction pad 25b.
  • the second conveying means for example, a roller conveyor 18, to press 19 for the formation of the tile 6 and its removal, by a further motorised roller conveyor 25, possibly supplied by oscillating feeder arm 25a with suction pad 25b.
  • FIG 7 shows how the impeller 22, driven towards the press 19 in the direction indicated by arrow F3, is pulled back in the opposite direction, as indicated by arrow F4, at the end of the advancement stroke with a stretch of rising inclined trajectory to avoid interference with the article already ready to be inserted in the press.
  • the press 19 has punch 26, matrix 27 with mobile base 28.
  • Figure 9 shows how the batching means for the powders and/or granules that go to make up the body of the pressed tile 6 may feed, by means of distributing means 13, 14, the conveyor belt 2 on which a layer 29 of decorating substance, or even a number of superimposed layers 29, 29a, has already been distributed.
  • the batching means may include, under a hopper 5 containing the powder, an upper conveyor belt 30 that deposits the powder on the conveyor belt 2 by gravity feed. This prevents the distribution of the decorating substances 29, 29a from being disturbed by the distribution, onto the same conveyor belt, of the powder that will form the body of the tile.
  • the powders are dropped very gently from the upper conveyor belt, this being achievable by inclining said conveyor belt in the advancement direction Fl of the layer of powder, in such a way as to limit to the minimum possible value the vibrations to which the powders are subjected.
  • an inclined slide 30a may be provided in association with a conveyor with a horizontal upper active section.
  • a blade 31 may advantageously be provided, supported transversely over conveyor 2 to scrape the upper surface of the layer 8.
  • a powder preparation apparatus arranged as in Figure 9 enables the tiles to be pressed with their top side facing downwards, which enables the use of normal "plunger” type punches.
  • the punch 10 of the pre-compaction die may have a convex active surface, so as to obtain a concave top surface in the pre-compacted semifinished product which may be filled with paint and/or clay grains, or powders, by means of distributing means 16, 21.
  • grains, or granulate material may be distributed on the top face of the pre-compacted article, designed to impart particular decorative motifs to the support, which become incorporated in the mass of the support during pressing.
  • This enables a defect inherent in the methods according to the prior art to be eliminated, whereby the distribution of granules in a mass of powder constituting the main body of the tile entails the granules sinking during pressing up to a point where they almost disappear beneath its top surface making it necessary to perform the costly procedure of smoothing the article after it has been pressed or after firing.
  • This type of tile may otherwise only be manufactured by resorting to the so called "double loading" forming methods, which involve considerable time wasting and high costs.
  • FIGs in Figures 10, 11 refer to a stepped advancement of the conveyor belt 2, and therefore of the layer 8, and refer to a condition included between a time TO at the beginning of the cycle and a time Tl relating to the end of the movement in one step.
  • the variation of the relative speed of the conveyor belt 2, that is, of the layer of powders 8, with respect to batching means 13, 14 and/or distributors 5 is such that the relative speed Vrel of the layer with respect to the batching means and/or distributors, that is, the difference in ordinate between the continuous line diagram of the speed VI and the dotted line of V2 is kept constant at all times during the cycle.
  • the die 19 may be equipped with a device 32 for extracting the pressed tiles 6 from the sliding plane of the relative matrix 27, said device being made up of a pair of chains 33 each closed in a loop on respective geared pinions 34, free to rotate, 34a motorised, these last being interconnected to a shaft 35 coupled to driving means not shown, by means of driving cogs 36 and chain transmission 37 ( Figure 19) .
  • the pair of chains 33 is interconnected by at least one transverse element 35, acting as impeller, advantageously by a pair of such impellers, positioned opposite each other, one connecting the pair of lower, active stretches of said chains, the other connecting the upper, return stretch.
  • Figure 14 shows how there may be a pair of impellers 22, 22a, integral with one another, the first of which, further back, for inserting the semifinished products in the press 19, the other, further forward, for extracting the pressed tiles 6.
  • a rotary brush 38 may be associated with the pair of impellers 22, 22a to clean the lower active surface of the punch 26 and/or the mobile base 28 of the matrix 27.
  • a rotary cleaning brush device 38 may be positioned between the stretches of chain 33, driven by chain 38a, supported on a pair of end limbs 39, the cleaning device being mobile between two positions on opposite sides of the punch 26 and being made to brush over, alternately, the upper surface of the mobile base 28 and the lower surface of the punch 26.
  • Figures 22, 23 show how the chains 33 are interconnected by a set of four transverse elements 35 that have both the function of removing the pressed tiles and of feeding the semifinished products to the pressing die.
  • FIG. 24 shows how the return stretch of the conveyor belt 2, with reference to the version of apparatus having the conveyor belt with intermittent step-by-step advancement motion, may pass through the pre-compac ion die 9 between the active stretch of the same conveyor belt and the striking block 12a by means of a pair positioning rollers 3a, with, possibly, the interposition of a plate, not shown, of material with a low coefficient of friction. This greatly simplifies the operation of substituting the conveyor belt when it becomes worn.
  • Figure 25 shows how the striking block 12, 12a is positioned straddling the conveyor belt 2 by means of a pair of lateral elements, or sills 12b, running longitudinally with respect to the conveyor belt 2 on the base 43 of the supporting structure 12c of the pre- compaction press so as to form a cavity I, sufficiently large to permit the passage through it of the return stretch of the conveyor belt 2.
  • Figure 26 shows how the striking block 12, 12a may be supported by elastic means 40, on a base plate 41 fixed to the base 43 and interconnecting the columns forming the load bearing structure 12c of the press 19 so as to form a cavity I, of variable amplitude, to allow the passage of the return stretch of the conveyor belt 2: when the punch 10 and the frame 11 descend towards the conveyor belt 2 to pre-compact the area of layer 8 that is to be formed, the block 12, 12a is lowered to a point where it blocks both the active and the return stretch of the conveyor belt 2 against the plate 41; when the pre-compaction thrust ceases, elastic elements 40 lift the striking block 12, 12a so that the conveyor belt is free to be advanced by another step so as to bring the next portion of layer 8 to the press 19.
  • Figure 27 shows a layout of an apparatus including a pre- compaction line, defined by the longitudinal extent of the conveyor belt 2, and a pressing line, defined by the positioning of the rollers of the roller conveyors 18, 25: between said pre-compaction line and said pressing line are positioned third conveying means 44, for example a pair of closed loop belts wound on corresponding pairs of pulleys.
  • the semifinished products transiting on said third conveying means may be subjected to various types of applications to decorate their top faces, or to further processing, such as, for example, drying, brushing, or other treatments besides.
  • Figures 28 to 41 show a version of the apparatus with single pressing phase, structurally analogous to the apparatus as in the previous Figures: therefore the compacting press 19 may directly form the ceramic tiles; a layer 29b of decorating substances may be distributed on the layer 8.
  • driving means which is able to ensure that a constant relative velocity is maintained, as in the diagram as in Figures 10, 11, between the conveyor belt 2 and the distributing means 5, 13: to this end the conveyor 2 has an end roller 3 coupled to relative actuating means, first transmitting means 50, for example, comprising a chain wound on a driving sprocket wheel 51, that is coupled to relative actuating means 52, and a driven wheel 53, made integral with roller 3.
  • Second actuating means 54 for example consisting of a further chain, are placed between a further driven sprocket wheel 54a ( Figure 31) , integral with the same roller 3, and an idler sprocket wheel 55 supported on the side of the conveyor belt 2.
  • the chain 54 is wound on a driving wheel 56, coupled to relative independent actuating means 57, in a section of it having a profile as in an omega due to the deviation upwards induced by a pair of idler wheels 58.
  • the sprocket wheels 56, 58 are supported on a trolley 59 which supports the distributing means 5, 13, for distributing said powders.
  • the independent actuating means 57 impart a constant speed of rotation to the relative drive wheel 56, therefore, when the conveyor belt 2 is stationary, that is during the working strokes of the punch 10 and of the matrix 11, the trolley moves towards the roller 3 distributing a layer 8 of uniform density; when an end-of-stroke position has been reached signalled by a first sensor 60, the actuating means 52 are activated in uniformly accelerated motion, so that the trolley may slow down progressively, stop and invert its direction of movement, initiating its movement away from the roller 3; having followed the uniform deceleration and acceleration ramps, the trolley moves away from the roller 3 at a noticeably constant velocity with respect to the conveyor belt 2 whilst the distributing means 5, 13 continue to distribute a uniform layer of powders on the layer 2.
  • a limit switch 61 determines the stoppage of the machine should the trolley 59 fail to invert its motion, as could occur should the actuating means 52 jam up, or due to machine stoppage caused by an interruption in the operating cycle of the press.
  • a cross-member 62 of a press through which passes a conveyor belt 2 is coupled at its lower side to a frame 11 by means of a plurality hydraulic cylinders 63, connected hydraulically in series in such a way as to avoid deflection of the frame during pressing and to maintain parallelism with respect to the plane of the conveyor belt 2.
  • the arrangement in series enables the creation of an hydraulic transmission between cylinders 63 connected to each other in such a way as to maintain the stems 64 of said cylinders acting on various zones of the surface of the frame 11 at the same time.
  • each cylinder 63 has a stem protruding from a chamber of the cylinder containing the pressurised fluid: the connection between the cylinders is such that one chamber is connected on the side from which the relative stem protrudes to the chamber of another cylinder on the opposite side from which the stem protrudes.
  • the active sections of the chambers have to be the same in order to guarantee the same stroke of stems 64.
  • the branches 65 of hydraulic circuit connecting cylinders 63 coupled together, have an inlet 66 for supplying oil and for maintaining a constant volume of oil in the circuit, by means of a solenoid valve not shown.
  • the frame 11 has lateral appendages 67 which come to rest, at the end of the pressing stroke, on lateral abutments 68 protruding from the block 12.
  • the frame may have an intermediate baffle 70, having a concave bottom face 71 in the shape of a V involved with conduits 72 pointing upwards to discharge powders trapped between the walls of the concave face 71 during the pressing stroke.
  • Vertical driving means for driving the frame 11 may be positioned between the block 12 and the appendages 67.
  • the punches 10 are driven by moving the cross-member 62 in a manner not shown.
  • the striking block 12 may have isobaric zones 75, defined by a membrane 76 delimiting a cavity with a number of compartments containing incompressible fluid, positioned below the conveyor belt 2 in a zone corresponding to that of the punch 10; the conveyor belt may have impressions 78 defining the supporting zones of the tile being formed and their alternate cavities 78a.
  • the membrane 79 may delimit a single chamber 80 for the incompressible fluid.
  • a stiffening plate 81 may be positioned between membrane 79 and the rear face of the conveyor belt 2.
  • the frame 11 is supported by the cross-member 62 by means of distancing elements 82 fixed to the appendages 67, together with the punches 10.
  • Vertical driving means 83 are positioned between the punches 10 and the cross-member 62, consisting, for example, of hydraulic cylinders having stems 84 integral with said punches.
  • Figure 41 shows a structure of the distributing means 5, 13 suitable for obtaining the distribution of the powders in a layer 8 having a undulated bottom layer 8a, defining cavities 78b.
  • the pre-compaction die may be associated with a number of presses by means of conveying means for the semifinished products, such as, for example, motorised roller conveyors, with conveyors arranged in straight lines or with perpendicular offshoots, or other besides .
  • conveying means for the semifinished products such as, for example, motorised roller conveyors, with conveyors arranged in straight lines or with perpendicular offshoots, or other besides .
  • the trasferring means i. e. impeller 22, 22a, 25, 25a, 25b, feeding the press with the pre-compacted articles 17, or extracting the pressed tiles 7 may be associated with forming apparatus for forming ceramic articles different from those described in the present specification.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Press-Shaping Or Shaping Using Conveyers (AREA)
  • Devices For Post-Treatments, Processing, Supply, Discharge, And Other Processes (AREA)

Abstract

Procédé de compactage de poudres comprenant les étapes consistant à former une couche (8, 8a) de poudres sur un dispositif convoyeur (2), lequel transporte cette couche vers un outillage de frappe (9), à isoler une partie de la couche (8, 8a) à l'intérieur d'un cadre (11) de cet outillage (9), en apportant ledit cadre (11) au voisinage du dispositif convoyeur (2), et à compacter la partie de la couche (8, 8a) qui a été isolée au moyen du cadre (11), à l'aide d'une matrice (10) de l'outillage de frappe, laquelle descend à l'intérieur du cadre (11). L'invention concerne également un appareil destiné à former des articles en céramique et qui comprend un dispositif convoyeur (2) destiné à transporter une couche de poudres (8, 8a) vers un outillage de frappe (9), lequel (9) comprend une matrice (10) qui est mobile dans une direction sensiblement perpendiculaire à la couche (8, 8a) et est associée à un élément transversal (62), afin de provoquer le pressage des poudres, ainsi qu'un cadre (11), mobile dans une direction sensiblement perpendiculaire à la couche (8, 8a), indépendamment de la matrice (10), et à l'intérieur duquel la matrice peut pénétrer par coulissement, ledit cadre servant de moyen d'isolation d'une partie de la couche (8, 8a) sur le dispositif convoyeur (2).
PCT/EP1995/004560 1994-11-22 1995-11-20 Procede de compactage de poudres et appareil associe WO1996015888A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE69529997T DE69529997D1 (de) 1994-11-22 1995-11-20 Verfahren und vorrichtung zum verdichten von pulverförmingen stoffen
EP95940213A EP0793565B1 (fr) 1994-11-22 1995-11-20 Procede de compactage de poudres et appareil associe
AU41743/96A AU4174396A (en) 1994-11-22 1995-11-20 A method for compacting powders, and a relative apparatus
BR9509806A BR9509806A (pt) 1994-11-22 1995-11-20 Processo para compactação de pós e um aparelho relacionado

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT94MO000159 IT1269274B (it) 1994-11-22 1994-11-22 Metodo per la formatura di piastrelle ceramiche ed impianto relativo
ITMO94A000159 1994-11-22

Publications (1)

Publication Number Publication Date
WO1996015888A1 true WO1996015888A1 (fr) 1996-05-30

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1995/004560 WO1996015888A1 (fr) 1994-11-22 1995-11-20 Procede de compactage de poudres et appareil associe

Country Status (7)

Country Link
EP (1) EP0793565B1 (fr)
CN (1) CN1062504C (fr)
AU (1) AU4174396A (fr)
BR (1) BR9509806A (fr)
DE (1) DE69529997D1 (fr)
IT (1) IT1269274B (fr)
WO (1) WO1996015888A1 (fr)

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EP0822044A1 (fr) * 1996-07-30 1998-02-04 Ceramiche Dual S.r.l. Dispositif d'alimentation pour moules dans les presses pour la fabrication de carreaux en céramique émaillés pressés et moyens de mise en oeuvre correspondants
WO1998023424A2 (fr) * 1996-11-22 1998-06-04 Carlo Antonio Camorani Fabrication de matieres pulverulentes
EP0858873A1 (fr) * 1997-02-18 1998-08-19 Gruppo Concorde S.p.A. Dispositif pour le pressage de poudres, en particulier dispositif et procédé pour le pressage de carreaux en céramique
EP0860256A1 (fr) * 1997-02-21 1998-08-26 SACMI COOPERATIVA MECCANICI IMOLA S.c.r.l. Procédé pour transférer de la poudre céramique d'une zone de prélèvement à une zone d'utilisation
EP0940234A2 (fr) * 1998-03-02 1999-09-08 Sertam Società a Responsabilità Limitata Méthode et dispositif pour la fabrication de carreaux en céramique
EP0995563A1 (fr) * 1998-10-15 2000-04-26 Ronflette S.A. Installation et procédé pour la fabrication d'éléments en céramique tels que carreaux et produits similaires par pressage de poudre
EP0995562A1 (fr) * 1998-10-15 2000-04-26 Ronflette S.A. Dispositif pour la fabrication d'éléments en céramique tels que carreaux et produits similaires par pressage de poudre
EP1136212A1 (fr) * 2000-03-23 2001-09-26 Ronflette S.A. Dispositif perfectionné pour la fabrication d'articles en céramique, comme par exemple des dalles, des carreaux et des articles similaires par pressage de poudre
EP1250990A2 (fr) * 2001-04-20 2002-10-23 Ghi.Tech. S.R.L. Moule avec des cavités modulaires pour le façonnage d'articles céramiques
EP1266733A2 (fr) * 2001-06-12 2002-12-18 SACMI - Cooperativa Meccanici Imola - Soc. Coop. a.R.L. Procédé et installation pour la fabrication de carreaux et dalles en céramique de grande dimension
EP1321256A2 (fr) * 2001-12-21 2003-06-25 SACMI COOPERATIVA MECCANICI IMOLA Soc. Coop. a r.l. Procédé et installation pour la fabrication de carreaux et dalles en céramique, et carreaux et dalles ainsi fabriqués
US6630457B1 (en) 1998-09-18 2003-10-07 Orthogene Llc Functionalized derivatives of hyaluronic acid, formation of hydrogels in situ using same, and methods for making and using same
EP1375097A2 (fr) * 2002-06-28 2004-01-02 L.B. Officine Meccaniche S.p.A. Installation pour le pré-pressage d'ébauches en céramique pulvérulente et pour remplir la cavité d'un moule avec ces ébauches
EP1433580A2 (fr) * 2002-12-26 2004-06-30 Jian Xu Procédé et dispositif de fabrication de produits céramiques
WO2004071733A1 (fr) * 2003-02-17 2004-08-26 Sacmi Cooperativa Meccanici Imola Societa' Cooperativa Procede et usine pour former des tuiles ou des plaques ceramiques
EP1366874A3 (fr) * 2002-05-31 2005-04-27 Cerservice S.r.l. Dispositif pour la fabrication d'une masse cohérente en poudre céramique
WO2006045728A1 (fr) * 2004-10-20 2006-05-04 Luca Toncelli Appareil servant a repartir, dans une couche mince, un melange a base de ceramique ou pierre agglomeree
US7267536B2 (en) * 2001-05-08 2007-09-11 Sacmi-Cooperativa Meccanici Imola-Soc. Coop. A.R.L. Apparatus for forming large-dimension ceramic tiles
DE19951109B4 (de) * 1999-10-23 2009-10-08 Weinmann & Partner Gmbh Vorrichtung zum Befüllen von Gebäudeelementen, insbesondere von Wand- oder Deckenelementen in Holzrahmenkonstruktion
CN1738705B (zh) * 2003-01-20 2010-05-26 萨克米伊莫拉机械合作社合作公司 用于成形陶瓷板或者陶瓷砖的方法和设备
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WO2010146189A1 (fr) * 2009-06-15 2010-12-23 Ozono I&D, S.L. Procédé et installation pour la formation de feuilles, de dalles et de carreaux de céramique
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Cited By (64)

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Publication number Priority date Publication date Assignee Title
EP0822044A1 (fr) * 1996-07-30 1998-02-04 Ceramiche Dual S.r.l. Dispositif d'alimentation pour moules dans les presses pour la fabrication de carreaux en céramique émaillés pressés et moyens de mise en oeuvre correspondants
WO1998023424A2 (fr) * 1996-11-22 1998-06-04 Carlo Antonio Camorani Fabrication de matieres pulverulentes
WO1998023424A3 (fr) * 1996-11-22 1998-08-20 Carlo Antonio Camorani Fabrication de matieres pulverulentes
EP1175982A2 (fr) * 1996-11-22 2002-01-30 Ronflette S.A. Fabrication de matières pulvérentes
EP1175982A3 (fr) * 1996-11-22 2002-05-15 Ronflette S.A. Fabrication de matières pulvérentes
EP0858873A1 (fr) * 1997-02-18 1998-08-19 Gruppo Concorde S.p.A. Dispositif pour le pressage de poudres, en particulier dispositif et procédé pour le pressage de carreaux en céramique
EP0860256A1 (fr) * 1997-02-21 1998-08-26 SACMI COOPERATIVA MECCANICI IMOLA S.c.r.l. Procédé pour transférer de la poudre céramique d'une zone de prélèvement à une zone d'utilisation
EP0940234A3 (fr) * 1998-03-02 2000-03-29 Sertam Società a Responsabilità Limitata Méthode et dispositif pour la fabrication de carreaux en céramique
EP0940234A2 (fr) * 1998-03-02 1999-09-08 Sertam Società a Responsabilità Limitata Méthode et dispositif pour la fabrication de carreaux en céramique
US7196180B2 (en) 1998-09-18 2007-03-27 Orthogene Llc Functionalized derivatives of hyaluronic acid, formation of hydrogels in situ using same, and methods for making and using same
US6630457B1 (en) 1998-09-18 2003-10-07 Orthogene Llc Functionalized derivatives of hyaluronic acid, formation of hydrogels in situ using same, and methods for making and using same
EP0995563A1 (fr) * 1998-10-15 2000-04-26 Ronflette S.A. Installation et procédé pour la fabrication d'éléments en céramique tels que carreaux et produits similaires par pressage de poudre
EP0995562A1 (fr) * 1998-10-15 2000-04-26 Ronflette S.A. Dispositif pour la fabrication d'éléments en céramique tels que carreaux et produits similaires par pressage de poudre
DE19951109B4 (de) * 1999-10-23 2009-10-08 Weinmann & Partner Gmbh Vorrichtung zum Befüllen von Gebäudeelementen, insbesondere von Wand- oder Deckenelementen in Holzrahmenkonstruktion
EP1136212A1 (fr) * 2000-03-23 2001-09-26 Ronflette S.A. Dispositif perfectionné pour la fabrication d'articles en céramique, comme par exemple des dalles, des carreaux et des articles similaires par pressage de poudre
EP1250990A2 (fr) * 2001-04-20 2002-10-23 Ghi.Tech. S.R.L. Moule avec des cavités modulaires pour le façonnage d'articles céramiques
EP1250990A3 (fr) * 2001-04-20 2003-12-03 Ghi.Tech. S.R.L. Moule avec des cavités modulaires pour le façonnage d'articles céramiques
US7267536B2 (en) * 2001-05-08 2007-09-11 Sacmi-Cooperativa Meccanici Imola-Soc. Coop. A.R.L. Apparatus for forming large-dimension ceramic tiles
EP1266733A3 (fr) * 2001-06-12 2004-01-28 SACMI - Cooperativa Meccanici Imola - Soc. Coop. a.R.L. Procédé et installation pour la fabrication de carreaux et dalles en céramique de grande dimension
US7252489B2 (en) 2001-06-12 2007-08-07 Sacmi-Cooperativa Meccanici Imola-Soc. A.R.L. Method and plant for forming large-dimension ceramic slabs and tiles
EP1266733A2 (fr) * 2001-06-12 2002-12-18 SACMI - Cooperativa Meccanici Imola - Soc. Coop. a.R.L. Procédé et installation pour la fabrication de carreaux et dalles en céramique de grande dimension
EP1321256A2 (fr) * 2001-12-21 2003-06-25 SACMI COOPERATIVA MECCANICI IMOLA Soc. Coop. a r.l. Procédé et installation pour la fabrication de carreaux et dalles en céramique, et carreaux et dalles ainsi fabriqués
EP1321256A3 (fr) * 2001-12-21 2004-05-26 SACMI COOPERATIVA MECCANICI IMOLA Soc. Coop. a r.l. Procédé et installation pour la fabrication de carreaux et dalles en céramique, et carreaux et dalles ainsi fabriqués
EP1366874A3 (fr) * 2002-05-31 2005-04-27 Cerservice S.r.l. Dispositif pour la fabrication d'une masse cohérente en poudre céramique
EP1375097A3 (fr) * 2002-06-28 2005-06-29 L.B. Officine Meccaniche S.p.A. Installation pour le pré-pressage d'ébauches en céramique pulvérulente et pour remplir la cavité d'un moule avec ces ébauches
EP1375097A2 (fr) * 2002-06-28 2004-01-02 L.B. Officine Meccaniche S.p.A. Installation pour le pré-pressage d'ébauches en céramique pulvérulente et pour remplir la cavité d'un moule avec ces ébauches
EP1433580A3 (fr) * 2002-12-26 2005-10-12 Foshanlinghai Ceramic SCI & TECH Co. Ltd. Procédé et dispositif de fabrication de produits céramiques
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CN1738705B (zh) * 2003-01-20 2010-05-26 萨克米伊莫拉机械合作社合作公司 用于成形陶瓷板或者陶瓷砖的方法和设备
CN100493875C (zh) * 2003-02-17 2009-06-03 萨克米伊莫拉机械合作社合作公司 成型瓷砖或板的方法和设备
WO2004071733A1 (fr) * 2003-02-17 2004-08-26 Sacmi Cooperativa Meccanici Imola Societa' Cooperativa Procede et usine pour former des tuiles ou des plaques ceramiques
WO2006045728A1 (fr) * 2004-10-20 2006-05-04 Luca Toncelli Appareil servant a repartir, dans une couche mince, un melange a base de ceramique ou pierre agglomeree
KR101238523B1 (ko) * 2004-10-20 2013-02-28 루카 톤셀리 덩어리 석재 또는 세라믹재료를 포함한 혼합물을 얇은 층으로 분포시키기 위한 장치
US7837454B2 (en) 2004-10-20 2010-11-23 Luca Toncelli Apparatus for distributing in a thin layer a mix based on agglomerate stone or ceramic material
US8940223B2 (en) 2007-03-28 2015-01-27 Luca Toncelli Method of manufacturing slabs of ceramic material
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US9174358B2 (en) 2007-07-16 2015-11-03 Luca Toncelli Method and apparatus for manufacturing slabs with veined effect
ITTV20090036A1 (it) * 2009-03-10 2010-09-11 Luca Toncelli Apparecchiatura e metodo per la fabbricazione di lastre ad effetto venato
WO2010103456A1 (fr) * 2009-03-10 2010-09-16 Luca Toncelli Appareil et procédé de fabrication de dalles à effet marbré
US9579821B2 (en) 2009-03-10 2017-02-28 Luca Toncelli Apparatus and method for manufacturing slabs with a veined effect
WO2010146189A1 (fr) * 2009-06-15 2010-12-23 Ozono I&D, S.L. Procédé et installation pour la formation de feuilles, de dalles et de carreaux de céramique
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KR101882546B1 (ko) * 2011-04-22 2018-07-26 베커 아이피 홀딩스 리미티드 압축물들을 생성시키기 위한 장치들, 시스템 및 방법들, 및 이에 의해 생성되는 압축물들
US9487444B2 (en) 2011-04-22 2016-11-08 Mass S.P.A. Apparatuses, system and methods for forming pressed articles and pressed articles formed thereby
RU2603146C2 (ru) * 2011-04-22 2016-11-20 ВЕКОР АйПи ХОЛДИНГС ЛТД Устройства, система и способы формования прессованных изделий и прессованные изделия, полученные прессованием с помощью этих устройств и способов
CN102602026A (zh) * 2012-03-28 2012-07-25 河北工业大学 一种粉料模压成型产品的生产装置
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CN103341906A (zh) * 2013-03-07 2013-10-09 河北工业大学 一种珍珠岩吸音板成型生产线
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US11020875B2 (en) 2015-11-16 2021-06-01 System Ceramics S.P.A. Forming element for ceramic articles
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IT201800010612A1 (it) * 2018-11-27 2020-05-27 Granitifiandre Spa Metodo ed impianto per la formatura di lastre ceramiche
EP3659769A1 (fr) * 2018-11-27 2020-06-03 Granitifiandre Societa' Per Azioni Procédé et installation de formation de plaques en céramique
WO2021108234A3 (fr) * 2019-11-25 2021-07-22 Corning Incorporated Procédé et appareil de commande d'extrémité arrière de translation et de rotation d'une pièce crue
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BR9509806A (pt) 1997-10-21
CN1173154A (zh) 1998-02-11
EP0793565B1 (fr) 2003-03-19
CN1062504C (zh) 2001-02-28
AU4174396A (en) 1996-06-17
EP0793565A1 (fr) 1997-09-10
DE69529997D1 (de) 2003-04-24
ITMO940159A0 (it) 1994-11-22
IT1269274B (it) 1997-03-26
ITMO940159A1 (it) 1996-05-22

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