WO1991018074A1 - Lubricant composition for metal working - Google Patents

Lubricant composition for metal working Download PDF

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Publication number
WO1991018074A1
WO1991018074A1 PCT/JP1991/000534 JP9100534W WO9118074A1 WO 1991018074 A1 WO1991018074 A1 WO 1991018074A1 JP 9100534 W JP9100534 W JP 9100534W WO 9118074 A1 WO9118074 A1 WO 9118074A1
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WO
WIPO (PCT)
Prior art keywords
carbon atoms
compound
oil
glycol
straight
Prior art date
Application number
PCT/JP1991/000534
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
Saburo Koyama
Yasunori Tomari
Seiichi Shido
Toshio Saito
Original Assignee
Idemitsu Kosan Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Kosan Co., Ltd. filed Critical Idemitsu Kosan Co., Ltd.
Priority to DE69114672T priority Critical patent/DE69114672T2/de
Priority to KR1019920700066A priority patent/KR970010855B1/ko
Priority to EP91908465A priority patent/EP0484542B1/de
Publication of WO1991018074A1 publication Critical patent/WO1991018074A1/ja

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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M127/00Lubricating compositions characterised by the additive being a non- macromolecular hydrocarbon
    • C10M127/02Lubricating compositions characterised by the additive being a non- macromolecular hydrocarbon well-defined aliphatic
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    • C10M101/00Lubricating compositions characterised by the base-material being a mineral or fatty oil
    • C10M101/02Petroleum fractions
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    • C10M105/00Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C10M105/02Well-defined hydrocarbons
    • C10M105/04Well-defined hydrocarbons aliphatic
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    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04Hydroxy compounds
    • C10M129/06Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M129/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04Hydroxy compounds
    • C10M129/06Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/08Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least 2 hydroxy groups
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    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04Hydroxy compounds
    • C10M129/10Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04Hydroxy compounds
    • C10M129/10Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring
    • C10M129/14Hydroxy compounds having hydroxy groups bound to a carbon atom of a six-membered aromatic ring containing at least 2 hydroxy groups
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    • C10M129/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/26Carboxylic acids; Salts thereof
    • C10M129/28Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/38Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms
    • C10M129/40Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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    • C10M133/00Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen
    • C10M133/02Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing nitrogen having a carbon chain of less than 30 atoms
    • C10M133/04Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M133/12Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to a carbon atom of a six-membered aromatic ring
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    • C10M145/00Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M145/24Polyethers
    • C10M145/26Polyoxyalkylenes
    • C10M145/28Polyoxyalkylenes of alkylene oxides containing 2 carbon atoms only
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    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M145/26Polyoxyalkylenes
    • C10M145/30Polyoxyalkylenes of alkylene oxides containing 3 carbon atoms only
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    • C10M145/18Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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    • C10M145/26Polyoxyalkylenes
    • C10M145/36Polyoxyalkylenes etherified
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    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
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    • C10M173/02Lubricating compositions containing more than 10% water not containing mineral or fatty oils
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    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02Water
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    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/003Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
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    • C10N2050/00Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01Emulsions, colloids, or micelles
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2080/00Special pretreatment of the material to be lubricated, e.g. phosphatising or chromatising of a metal

Definitions

  • the present invention relates to a lubricating oil composition for metalworking, and more particularly, to a lubricating oil composition containing a specific straight-chain or alcohol and the like, and particularly to aluminum and its alloys.
  • the present invention relates to a lubricating oil composition that is excellent in cleaning (removability) of wear powder generated during metal working.
  • wear powder adheres to the surface of the workpiece and causes various problems.
  • the inventors of the present invention have conducted plastic working and cutting of aluminum, steel, brass and other metals or alloys.
  • the removal of abrasion powder generated (washability) is good, and the workability is excellent, and the surface condition of the work material is also excellently finished.
  • alcohols, glycols, polyalkylene glycols, as well as base oils containing straight chain olefins having 6 to 40 carbon atoms can be achieved by using a fatty acid.
  • the present invention relates to (a) a base oil mainly composed of a straight chain olefin having 6 to 40 carbon atoms, and (b) an alcohol, a glycol, a polyalkylene. It is intended to provide a lubricating oil composition for metalworking, comprising at least one compound selected from the group consisting of alcohol, polyalkylene glycol derivatives and fatty acids. .
  • the present invention provides a lubricating oil for metal working, comprising (a) a base oil and (c) at least one compound of a phenol compound and an amide compound. It also provides an oil composition.
  • the linear oil constituting the base oil of the component (a) has 6 to 40 carbon atoms as described above. Those with less than 6 carbon atoms are not suitable because of their low flash points. Those with more than 40 carbon atoms are difficult to use because they are solid. Yes, it is difficult to mix and dissolve with mineral oil, synthetic oil, other additives, etc., which is unsuitable. Those with more than 40 carbon atoms are not common and are difficult to obtain. Among these straight-chain olefins, compounds having one double bond in the molecule and having 6 to 30 carbon atoms are preferred, and in particular, those having 12 to 30 carbon atoms. The best refrain (ie, n — the best ref) is best.
  • linear derivatives include 1-octene, 1-decene, 1-dodecene, 1-tetradene, and 1-hexadecene. , 11-year-old decadecene, 11-eicosene, or a mixture of these.
  • These straight-chain olefins can be obtained by various production methods, and for example, a polymer obtained by polymerizing ethylene by ordinary means can be used. It is possible to use Chilengo Lingmar.
  • the above-mentioned straight-chain olefin may be used alone as the base oil of the component (a), but it is also possible to use mineral oil and mineral oil or synthetic oil together. You may use.
  • water can be mixed.
  • the mineral oil or synthetic oil to be blended here usually has a kinematic viscosity of 0.5 to 500 cSt at 40, especially 0.5 to 500 cSt.
  • Those of 3 OcSt are preferably used.
  • various types of mineral oils can be mentioned, for example, paraffinic, intermediate or naphthenic crude oils.
  • Pressure distillation or normal pressure Distillate oil obtained by distilling residual oil from distillation under reduced pressure, or refined oil obtained by purifying it according to a conventional method, for example, solvent refined oil, hydrogenated refined oil, deoiled oil, etc. Blowing oil, clay clay oil, etc. can be mentioned.
  • these mineral oils are blended with the above-mentioned straight chain olefin, the resulting lubricant has improved oxidation stability.
  • synthetic oils other than the above-mentioned straight chain olefins for example, branched olefins such as polybutene and polypropylene), and the like. Hydride hydride etc. can be used.
  • low-molecular-weight polybutene and low-molecular-weight polypropylene are preferably ⁇ -aged olefin oligomers having 8 to 14 carbon atoms.
  • the mixing ratio is not particularly limited, but is usually a straight-chain oil. At least 3% by weight, preferably 5 to 60% by weight, and mineral oil and Z or synthetic oil at 97% by weight or less, preferably 95 to 40% by weight.
  • the component (b) in the composition of the present invention As the component (b) in the composition of the present invention, as described above, alcohols, glycols, polyalkylene glycols, and polyesters are used. One of the alkylene glycol derivatives and fatty acids is used alone, or two or more are used in combination.
  • aliphatic alcohols are preferred, and among them, carbon atoms of 6 to 40 (particularly carbon atoms of 8 to 40) are preferred.
  • fractional alcohols having more than 40 carbon atoms and linear alcohols having more than 20 carbon atoms may not dissolve in the base oil (a). Yes, it may not be desirable.
  • alcohols include octyl (2-ethylhexyl) alcohol, decyl alcohol, and laurel.
  • Alcohol Millipore alcohol, Cetyl alcohol, Stearyl alcohol-Nore, Eikol Noreole, Ole Examples include inole alcohol, isostearyl alcohol, and oxo alcohol.
  • the mixing ratio of this compound is not particularly limited, but it is usually the whole composition.
  • glycols can be used, but generally, glycols having 2 to 6 carbon atoms, such as ethylene glycol and propylene glycol Glycol; trimethylethylene glycol; 1,4-butanediol; 1,5-pentandiol.
  • the compounding ratio of this compound is usually from 0.05 to 50% by weight, preferably from 0.1 to 20% by weight, based on the whole composition, similarly to the above-mentioned alcohol.
  • Polyalkylene glycol and its derivatives may be of various types, but the general formula (I)
  • R 1 and R 3 each represent a hydrogen or an alkyl group having 1 to 20 carbon atoms, an alkyl-substituted phenyl group or a phenyl group having 7 to 24 carbon atoms, respectively.
  • R 2 represents an ethylene group, a propylene group or a butylene group, and n represents an integer of 2 to 50.
  • fatty acid a straight-chain or branched saturated or unsaturated fatty acid having usually 6 to 40 (preferably 8 to 20) carbon atoms can be mentioned.
  • 6 to 40 preferably 8 to 20 carbon atoms
  • the number of carbon atoms is less than 6, it will be greatly consumed by evaporation and scattering when used, and if it exceeds 40, it will be component (a). May not dissolve in base oil.
  • Do fatty acids would Yo of this, force-flops Li Le acid, force Prin acid, La U-phosphate, millimeter steel phosphate, Roh, 0 Le unknown phosphate, vinegar
  • Thea Li Acid, arachinic acid, behenic acid, isostearic acid, pendecylenic acid, oleic acid, linoleic acid, linolenic acid, arakinic acid Donic acid and the like can be mentioned as suitable.
  • the compounding ratio of this compound is usually 0.05 to 1.0% by weight of the whole composition. If the proportion of the fatty acid exceeds 1.0% by weight, the annealing property is unfavorably reduced.
  • composition of the present invention comprises the above-mentioned components (a) and (b). Instead of the component (b), there are some of the above-mentioned components (a) and (b). In addition to the component (b), at least one compound of the phenolic compound and the amine compound that is the component (c) can be blended.
  • phenolic compound various compounds can be used, and usually, the compound represented by the general formula (H) or (II)
  • each R B is indicates ⁇ alkyl group having 1 to 8 carbon atoms
  • RS and R 7 were each hydrogen or represents an alkyl group having 1 to 6 carbon atoms.
  • DBPC 2, 6-Di-tert-butyl-41-ethyl phenol
  • 2,2'-methyl benzo (4-methyl-6-tert-butyl phenol)
  • 2,2'-methylbenzene (4-ethynole 6-tert-butylphenol) and the like are suitable.
  • R 8 and R 11 each represent hydrogen or an alkyl group having 1 to 10 carbon atoms, and R 8 and R 10 Each represents an alkyl group having 120 carbon atoms;
  • R 12 to R 14 each represent hydrogen or carbon number 1 to
  • di-P-octyl diphenylenamine di-p-butyldiphenylamine, di-p-dinonylenamine, etc.
  • They are suitable for use such as phenyl-naphthylamine, phenyl-naphthylamine, and the like.
  • the compounding ratio of the component (c) is preferably 0.1% by weight or more of the whole composition, and particularly preferably in the range of 0.1 to 2.0% by weight.
  • composition of the present invention may contain an appropriate amount of a well-known oily agent, extreme pressure agent, antioxidant, corrosion inhibitor, antifoaming agent, and the like, if desired.
  • JISA 505 2 HI6 aluminum plate (thickness of 1.2 mm, width of 60 mm, coil) was prepared as the rolled material, and this was used as the work roll diameter.
  • the rolling speed was 100 m / min
  • the forward tension was 170 kgf
  • the forward tension was 40 Okgf, using a four-high rolling mill of 135 sq.m.
  • the rolling method used was a rolling method in which the rolling reduction was increased stepwise from 50.0 ⁇ 54.2 ⁇ 58.3 ⁇ 60.8 ⁇ 63.3 ⁇ 65.8 ⁇ 68.3 (%) in 20 m increments in one pass.
  • the rolled aluminum sheet was cut into short pieces of 1 Ocm in length, tens of sheets were stacked, fixed with thick steel plates, and annealed in a small annealing furnace.
  • the heating conditions of the annealing furnace were as follows: heating was performed in an air atmosphere at a heating rate of 5 eCZ to 330, holding for 30 minutes, and then allowing to cool. After the completion of the heating, the degree of occurrence of the annealing stain on the annealed plate was visually determined, and the annealing property was evaluated. The results are shown in Table 1.
  • a cylindrical aluminum alloy (AC-4A-T6) with a diameter of 80 thighs was prepared as a material for cutting, and this was cut using a cutting tool (carbide P20).
  • the lubricating oil composition of the present invention when used, metal working of various metals and alloys thereof (rolling, drawing, punching, drawing, cold forging, and other plastic working, cutting, and grinding). In addition to improving the washability of wear powder during processing, etc., the annealing property of the processed material is also improved.
  • the lubricating oil composition of the present invention can be used for plastic working and cutting of various metals and alloys including aluminum, aluminum alloy, and aluminum foil. Widely and effectively used as a metalworking fluid for grinding and the like.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
PCT/JP1991/000534 1990-05-14 1991-04-23 Lubricant composition for metal working WO1991018074A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
DE69114672T DE69114672T2 (de) 1990-05-14 1991-04-23 Schmierstoffzusammensetzung für die metallbearbeitung.
KR1019920700066A KR970010855B1 (ko) 1990-05-14 1991-04-23 금속가공용 윤활유 조성물
EP91908465A EP0484542B1 (de) 1990-05-14 1991-04-23 Schmierstoffzusammensetzung für die metallbearbeitung

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2/121361 1990-05-14
JP12136190 1990-05-14

Publications (1)

Publication Number Publication Date
WO1991018074A1 true WO1991018074A1 (en) 1991-11-28

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EP (1) EP0484542B1 (de)
KR (1) KR970010855B1 (de)
DE (1) DE69114672T2 (de)
WO (1) WO1991018074A1 (de)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0853685A (ja) * 1994-08-10 1996-02-27 Idemitsu Kosan Co Ltd 金属加工用潤滑油組成物
KR20020039565A (ko) * 2000-11-22 2002-05-27 이구택 미스트 발생이 억제되는 강판 연마용 연삭유
JP2002322487A (ja) * 2001-04-26 2002-11-08 Idemitsu Kosan Co Ltd 金属加工用潤滑油組成物
JP2003096481A (ja) * 2001-09-21 2003-04-03 Nippon Oil Corp アルミニウム加工用潤滑油組成物
JP2003096482A (ja) * 2001-09-21 2003-04-03 Nippon Oil Corp アルミニウム加工用潤滑油組成物
KR100391164B1 (ko) * 1994-12-22 2003-10-17 카오 가부시키가이샤 알루미늄 및 알루미늄합금판의 저온성형용 윤활제
JP2006022281A (ja) * 2004-07-09 2006-01-26 Sumitomo Light Metal Ind Ltd 冷間圧延潤滑油

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Publication number Priority date Publication date Assignee Title
JP2927644B2 (ja) * 1993-07-02 1999-07-28 出光興産株式会社 金属加工油組成物
CA2099526C (fr) * 1993-07-02 2005-06-21 Hydro-Quebec Additifs pour lubrifiants utilises dans le laminage de feuillards de lithium en films minces
EP0690121A3 (de) * 1994-06-27 1996-07-31 Carrier Corp Schmiermittel für das Formen von Metall
EP1000674B1 (de) * 1994-07-12 2005-05-11 Hydro-Quebec Herstellungsverfahren einer Metalldünnschicht aus einem Alkalimetall oder einer Alkalimetalllegierung durch Walzen eines Metallbands in Gegenwart einer Schmiermittelzusammensetzung
JP3529069B2 (ja) * 1995-11-29 2004-05-24 出光興産株式会社 金属加工油組成物
EP3957708A1 (de) 2020-08-17 2022-02-23 Speira GmbH Kühlschmierstoff für das kaltwalzen von aluminium
WO2022087764A1 (en) * 2020-10-26 2022-05-05 Dow Global Technologies Llc Metal working fluids foam control agent

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EP0048216A1 (de) * 1980-09-12 1982-03-24 Schweizerische Aluminium Ag Öl-in-Wasser-Emulsion zum Kaltwalzen von Aluminium und Aluminiumlegierungen
JPS63202697A (ja) * 1987-02-18 1988-08-22 Nippon Guriisu Kk 鏡面加工用金属加工油剤
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JPH0284495A (ja) * 1988-09-20 1990-03-26 Hitachi Ltd 導電線の製造方法
EP0369320A1 (de) * 1988-11-15 1990-05-23 Idemitsu Kosan Company Limited Schmierölzusammensetzung

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EP0048216A1 (de) * 1980-09-12 1982-03-24 Schweizerische Aluminium Ag Öl-in-Wasser-Emulsion zum Kaltwalzen von Aluminium und Aluminiumlegierungen
JPS63202697A (ja) * 1987-02-18 1988-08-22 Nippon Guriisu Kk 鏡面加工用金属加工油剤
JPH01153794A (ja) * 1987-12-10 1989-06-15 Hakutou Kagaku Kk アルミニウム冷間加工用潤滑油
JPH01282297A (ja) * 1988-05-10 1989-11-14 Hitachi Ltd 伸線加工用潤滑油
JPH0284495A (ja) * 1988-09-20 1990-03-26 Hitachi Ltd 導電線の製造方法
EP0369320A1 (de) * 1988-11-15 1990-05-23 Idemitsu Kosan Company Limited Schmierölzusammensetzung

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0853685A (ja) * 1994-08-10 1996-02-27 Idemitsu Kosan Co Ltd 金属加工用潤滑油組成物
KR100391164B1 (ko) * 1994-12-22 2003-10-17 카오 가부시키가이샤 알루미늄 및 알루미늄합금판의 저온성형용 윤활제
KR20020039565A (ko) * 2000-11-22 2002-05-27 이구택 미스트 발생이 억제되는 강판 연마용 연삭유
JP2002322487A (ja) * 2001-04-26 2002-11-08 Idemitsu Kosan Co Ltd 金属加工用潤滑油組成物
JP2003096481A (ja) * 2001-09-21 2003-04-03 Nippon Oil Corp アルミニウム加工用潤滑油組成物
JP2003096482A (ja) * 2001-09-21 2003-04-03 Nippon Oil Corp アルミニウム加工用潤滑油組成物
JP2006022281A (ja) * 2004-07-09 2006-01-26 Sumitomo Light Metal Ind Ltd 冷間圧延潤滑油
JP4741816B2 (ja) * 2004-07-09 2011-08-10 住友軽金属工業株式会社 冷間圧延潤滑油

Also Published As

Publication number Publication date
EP0484542B1 (de) 1995-11-15
DE69114672D1 (de) 1995-12-21
KR927003454A (ko) 1992-12-18
EP0484542A1 (de) 1992-05-13
EP0484542A4 (en) 1992-10-21
DE69114672T2 (de) 1996-04-18
KR970010855B1 (ko) 1997-07-01

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