WO1990015038A2 - Verfahren zur staubbindung in dünger-granulaten - Google Patents

Verfahren zur staubbindung in dünger-granulaten Download PDF

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Publication number
WO1990015038A2
WO1990015038A2 PCT/EP1990/000797 EP9000797W WO9015038A2 WO 1990015038 A2 WO1990015038 A2 WO 1990015038A2 EP 9000797 W EP9000797 W EP 9000797W WO 9015038 A2 WO9015038 A2 WO 9015038A2
Authority
WO
WIPO (PCT)
Prior art keywords
granules
mixture
molasses
dust
dust binding
Prior art date
Application number
PCT/EP1990/000797
Other languages
German (de)
English (en)
French (fr)
Other versions
WO1990015038A3 (de
Inventor
Arno Singewald
Otto Wendt
Günter Nürnberger
Dieter Paetz
Wolfgang Walczyk
Klaus-Dieter Müller
Original Assignee
Kali Und Salz Aktiengesellschaft
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kali Und Salz Aktiengesellschaft filed Critical Kali Und Salz Aktiengesellschaft
Priority to EP90907031A priority Critical patent/EP0431091B1/de
Priority to CA002033326A priority patent/CA2033326C/en
Publication of WO1990015038A2 publication Critical patent/WO1990015038A2/de
Publication of WO1990015038A3 publication Critical patent/WO1990015038A3/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05D—INORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C; FERTILISERS PRODUCING CARBON DIOXIDE
    • C05D1/00—Fertilisers containing potassium
    • C05D1/005—Fertilisers containing potassium post-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • B01J2/30—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic using agents to prevent the granules sticking together; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D5/00—Sulfates or sulfites of sodium, potassium or alkali metals in general
    • C01D5/004—Preparation in the form of granules, pieces or other shaped products
    • C—CHEMISTRY; METALLURGY
    • C05—FERTILISERS; MANUFACTURE THEREOF
    • C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/20—Mixtures of one or more fertilisers with additives not having a specially fertilising activity for preventing the fertilisers being reduced to powder; Anti-dusting additives

Definitions

  • the invention relates to a method for preventing dust formation when loading or transporting granules or pellets, in particular fertilizer granules.
  • Fertilizers are increasingly being produced in granular form and transported in bulk. Dry press granulation is predominantly used to produce the granules, which forms the fine salt into flakes, from which the
  • Binding agents of organic or inorganic character such as molasses, starch, calcium chloride as well as alkali and alkaline earth metal sulfates and nitrates in the grain compacting of Thomas phosphate in the order of magnitude
  • DE-PS 36 18 058 describes a method for granulating water-soluble fertilizers with
  • Post-treatment alone is not sufficient to remove the adhering residual fine dust or to improve the abrasion resistance of the edges, corners and also sides of the granulate.
  • ⁇ J from DD-PS 136 956 a method is known to improve the abrasion resistance of potash fertilizer granules characterized in that the potash fertilizer is subjected to an after-treatment after the granulating process, which consists, after a
  • DE-OS 30 03 883 supplements the aforementioned patent application by * establishing a temperature range of 80-100 ° C, according to which an optimum gain in strength should be achieved according to the OS, if at the same time a minimum dwell time of 10 seconds guaranteed in an atmosphere of high humidity.
  • the treatment method described requires a great deal of effort for the systems downstream of the actual granulation and screening and can only be used directly by the producer, since the heat required for the process comes from the production of the granulate. This method is therefore not applicable, for example - quite apart from the investment and the resulting maintenance costs - for granulated potash products that have to be stored for a long time in interim storage and reloaded from there. It is known that a longer storage time and the associated physical effects, such as storage pressure and changes in atmospheric humidity, can have negative effects on granules treated in this way. (tendency to bake)
  • the invention is therefore based on the object of providing a method for preventing dust formation when loading and transporting granules or pellets, in particular fertilizer granules, which meets all the requirements to be placed on them, such as environmental friendliness, long shelf life of the treated granules, and ease of use fulfilled in an optimal way.
  • a mixture of at least two organic substances which are fully soluble with one another is added to the granules, the second organic substance being a water-soluble, oxygen-containing hydrocarbon and the first organic substance having an adhesive effect and the second oxygen-containing organic substance controls the moisture content of the mixture.
  • the dust binding mixture to be used must therefore have an adhesive effect on the surface of the granules, it must not be diluted by excessive moisture absorption, and it must not release so much moisture through drying processes that its adhesive and adhesive properties are lost.
  • viscous substances are used which have a relatively high viscosity at room temperature and have water-repellent properties.
  • Such viscous substances should have a flash point that is as high as possible, since as a rule these viscous substances have to be atomized at approx. 80 ° C. in order to achieve a good distribution.
  • the long shelf life of the goods treated in this way is due to the long-acting dust binding capacity of the dust binding mixture according to the invention.
  • a preferred mixture (dust binding mixture) consists of molasses and at least one other water-soluble, oxygen-containing hydrocarbon. The mixture is added to the granules in a very finely divided form.
  • the molasses takes on the adhesive effect and thus the dust binding, while the second organic substance, by controlling the water vapor pressure of the solution, keeps the dust binding mixture as a film on the granules moist and thus active.
  • the particularly suitable molasses is obtained as a second raw sugar level in beet sugar production.
  • Water-soluble, oxygen-containing hydrocarbons from the group glycerol, polyethylene glycol were found as the second organic substance and triethanolamine, alone or as a mixture of two of these compounds. These meet the requirements for a dust binder to a particular degree.
  • the substances glycerin, polyethylene glycol and triethanola, alone or as a mixture should each account for at least 10% of the total amount of the dust binding mixture (including molasses).
  • the invention relates in particular to a homogeneous mixture of molasses and the second organic substance in a mixing ratio of 1: 0.3 to 1: 2.
  • the homogeneous mixture can be prepared without problems in a container provided with a stirrer at room temperature.
  • the application to the granules subjected to the loading process and already freed from the fine dust by sieving can be carried out at room temperature up to a maximum temperature of 50 ° C. with appropriate pressure application and nozzle selection. In contrast to other, purely organic, non-aqueous dust binders, heating is not absolutely necessary.
  • the dust binding to be achieved is determined according to the method described below:
  • Samples of the granules to be conditioned are freed of any adhering particles by sieving.
  • the binder to be examined is then evenly distributed and sprayed onto the 200 g samples. After application, exactly 1%, based on the granulate weight, of dust ( ⁇ 0.2 mm) of the bulk material is added again and the entire samples are mixed in a sample bottle for five minutes while rotating.
  • the samples thus obtained are then examined, for example, after a storage period, in that the entire contents of the sample bottle are sieved on an Alpine air jet machine with an inserted 0.063 mm sieve.
  • the sieving time must be exactly three minutes. Then the inserted and dust-laden filter paper is either weighed out or in the case of soluble dusts such as e.g. B. Potash salts, the dust washed out and the amount determined by titration. The dust binding is calculated in percent from this value.
  • soluble dusts such as e.g. B. Potash salts
  • a potassium sulfate granulate coming from the press granulation with downstream screening is stored unconditionally in the warehouse.
  • the granulate is subjected to a fine dust sieve in bulk before loading and then treated with the dust-binding agent before the tape is ejected before being taken up into the warehouse.
  • the media temperature is on average at room temperature.
  • a mixture of 50% molasses (content 47 lbs) and 50% glycerol (with a content of 86% and a density of 1.23 g / cm) is used in an amount of 0.8% ⁇ based on the K to be conditioned -SO ⁇ granules.
  • the granulate coming from the press granulation with downstream screening is fed directly to the loading process.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Fertilizers (AREA)
PCT/EP1990/000797 1989-06-07 1990-05-17 Verfahren zur staubbindung in dünger-granulaten WO1990015038A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP90907031A EP0431091B1 (de) 1989-06-07 1990-05-17 Verfahren zur staubbindung in dünger-granulaten
CA002033326A CA2033326C (en) 1989-06-07 1990-05-17 Process for binding dust in fertilizer granules

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3918523A DE3918523A1 (de) 1989-06-07 1989-06-07 Verfahren zur staubbindung in duenger-granulaten
DEP3918523.0 1989-06-07

Publications (2)

Publication Number Publication Date
WO1990015038A2 true WO1990015038A2 (de) 1990-12-13
WO1990015038A3 WO1990015038A3 (de) 1991-02-07

Family

ID=6382233

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP1990/000797 WO1990015038A2 (de) 1989-06-07 1990-05-17 Verfahren zur staubbindung in dünger-granulaten

Country Status (6)

Country Link
EP (1) EP0431091B1 (en, 2012)
CA (1) CA2033326C (en, 2012)
DD (1) DD300100A5 (en, 2012)
DE (1) DE3918523A1 (en, 2012)
IL (1) IL94644A0 (en, 2012)
WO (1) WO1990015038A2 (en, 2012)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6971897B1 (en) 2003-10-29 2005-12-06 Tyco Electronics Corporation Gel-filled telephone jack
DE102008045459A1 (de) 2008-09-02 2010-03-04 Chemson Polymer-Additive Ag Verfahren zur Vermeidung der Verbreitung von teilchenförmigem Material in Luft
WO2017077350A1 (en) * 2015-11-04 2017-05-11 Quevenendol Limited Method for coating fertilizer beads with elemental sulfur
AU2012233010B2 (en) * 2011-10-28 2017-06-01 Robert Hamilton Hall Improvements in and relating to soil treatments

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4232567C1 (de) * 1992-09-29 1994-02-10 Kali & Salz Ag Verfahren zur Verhinderung einer Staubbildung beim Verladen oder Transportieren eines sulfatischen Düngergranulats
EP2325289B1 (de) 2009-11-10 2012-08-22 FireStixx Holz-Energie GmbH Verfahren und Vorrichtung zur Bearbeitung eines Trockenbrennstoffes
DE102015115468A1 (de) 2015-09-14 2017-03-16 Maschinenfabrik Köppern GmbH & Co KG Verfahren zur Konditionierung von Düngemittelgranulat
CA2975179A1 (en) 2015-01-28 2016-08-04 Maschinenfabrik Koppern Gmbh & Co. Kg Method for conditioning fertilizer granules

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE291265C (en, 2012) *
DE621739C (de) * 1931-01-11 1935-11-13 I G Farbenindustrie Akt Ges Verfahren zur Verbesserung der Lagerfaehigkeit und Streubarkeit von durch Umsetzung der Komponenten erhaltenen Mischduengern
US3195999A (en) * 1963-07-24 1965-07-20 Grace W R & Co Composition consisting essentially of crystalline urea coated with sugar
CH481676A (de) * 1965-09-10 1969-11-30 Agripat Sa Verfahren zur Herstellung nichtstäubender pulvriger Mittel, welche feste organische Stoffe aus der Gruppe der Agrikulturchemikalien enthalten, und gemäss diesem Verfahren erhaltene, nichtstäubende Mittel
FR2061865A5 (en, 2012) * 1969-07-31 1971-06-25 Paris Blancs Mineraux
LU60193A1 (en, 2012) * 1970-01-16 1971-09-22
US4689251A (en) * 1986-01-29 1987-08-25 Desoto, Inc. Anticaking and antidusting composition
DE3618058C1 (de) * 1986-05-28 1987-02-19 Kali & Salz Ag Verfahren zum Granulieren von wasserloeslichen Duengemitteln mit hohem Kieseritanteil

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6971897B1 (en) 2003-10-29 2005-12-06 Tyco Electronics Corporation Gel-filled telephone jack
DE102008045459A1 (de) 2008-09-02 2010-03-04 Chemson Polymer-Additive Ag Verfahren zur Vermeidung der Verbreitung von teilchenförmigem Material in Luft
AU2012233010B2 (en) * 2011-10-28 2017-06-01 Robert Hamilton Hall Improvements in and relating to soil treatments
WO2017077350A1 (en) * 2015-11-04 2017-05-11 Quevenendol Limited Method for coating fertilizer beads with elemental sulfur

Also Published As

Publication number Publication date
CA2033326C (en) 1999-08-17
IL94644A0 (en) 1991-04-15
DD300100A5 (de) 1992-05-21
EP0431091B1 (de) 1997-04-02
WO1990015038A3 (de) 1991-02-07
DE3918523C2 (en, 2012) 1993-09-23
CA2033326A1 (en) 1990-12-08
EP0431091A1 (de) 1991-06-12
DE3918523A1 (de) 1990-12-13

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