WO1989012603A2 - Granule de zeolites a liant zeolitique - Google Patents
Granule de zeolites a liant zeolitique Download PDFInfo
- Publication number
- WO1989012603A2 WO1989012603A2 PCT/FR1989/000300 FR8900300W WO8912603A2 WO 1989012603 A2 WO1989012603 A2 WO 1989012603A2 FR 8900300 W FR8900300 W FR 8900300W WO 8912603 A2 WO8912603 A2 WO 8912603A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- zeolite
- agglomerate
- zeolites
- silica sol
- calcination
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B33/00—Silicon; Compounds thereof
- C01B33/20—Silicates
- C01B33/26—Aluminium-containing silicates, i.e. silico-aluminates
- C01B33/28—Base exchange silicates, e.g. zeolites
- C01B33/2807—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures
- C01B33/2815—Zeolitic silicoaluminates with a tridimensional crystalline structure possessing molecular sieve properties; Isomorphous compounds wherein a part of the aluminium ore of the silicon present may be replaced by other elements such as gallium, germanium, phosphorus; Preparation of zeolitic molecular sieves from molecular sieves of another type or from preformed reacting mixtures of type A (UNION CARBIDE trade name; corresponds to GRACE's types Z-12 or Z-12L)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/183—Physical conditioning without chemical treatment, e.g. drying, granulating, coating, irradiation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/16—Alumino-silicates
- B01J20/18—Synthetic zeolitic molecular sieves
- B01J20/186—Chemical treatments in view of modifying the properties of the sieve, e.g. increasing the stability or the activity, also decreasing the activity
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
Definitions
- the present invention relates to a new process for obtaining granular zeolitic molecular sieves consisting solely of zeolitic compounds.
- zeolitic molecular sieves referred to here are crystalline aluminosilicates of general formula
- M represents a cation of valence n
- x is 2 in the case of zeolites A, and takes values between 2 and 6 if they are zeolites X or Y, where y characterizes the hydration state of the zeolite, the value 0 corresponding to anhydrous (calcined) zeolites.
- the crystal structure of these zeolites consists essentially of a three-dimensional skeleton of SiO4 and A104 tetrahedra linked together by sharing an oxygen atom. In the tetrahedral structure, the ratio of the number of oxygen to the total sum of the atoms Si and Al is thus 2.
- a structure entirely formed of tetrahedra SiO4 has a zero electric charge.
- the replacement of Si04 tetrahedra by AlO4 tetrahedra generates a negative charge which is compensated by the inclusion of cations in the network.
- These cations can be exchanged with cations in aqueous solutions, and exchange techniques based on this property are well known to those skilled in the art.
- the geometry of the assembly of the SiO4 and AlO4 tetrahedra is such that the structure comprises cavities, called cages, separated by well-calibrated opening windows. At room temperature, these cages are usually occupied by water. Appropriate heat treatment removes this water and releases a porous system.
- Such zeolites are endowed with remarkable adsorption properties, which arise on the one hand from the importance of the affinity which they develop for certain types of molecules and which make them an adsorption agent of choice, especially when one wishes to reach very low equilibrium pressures of the adsorbate, and on the other hand a high selectivity associated with the narrow distribution of the micropores giving access to the cavities of the crystal structure.
- These structures function like veritable molecular sieves, and hence their popular name. These qualities often make them prefer the more formerly known adsorbent agents such as silica gel, alumina or activated carbon.
- Zeolites are usually obtained in the form of a fine powder, whether they come from natural deposits or from industrial synthesis operations. For their use as adsorption agents, they must be in the form of beads or granules by agglomeration, the binder used is usually a clay mineral, such as bentonite, kaolin or attapulgite. Aluminum hydroxide, silicic acid salts and silica soils have also been proposed as binders.
- agglomeration lies in the introduction into the granular adsorbent of a non-negligible percentage of a phase which does not contribute in any way to its adsorbent properties, and which can even induce harmful behavior in certain applications (for example bentonite catalyzes acid reactions, such as the polymerization of olefins). It has therefore been proposed for a long time to use zeolitisable binders which are activated after having produced the agglomeration.
- US Patent No. 3,119,659 (Taggart et al.) Discloses a process for obtaining molecular sieve particles by agglomeration of zeolite A using kaolin and a sodium hydroxide solution, followed by calcination of the agglomerate, then crystallization from a sodium hydroxide solution.
- the method has the disadvantage of requiring a double treatment of the agglomerate, first a high temperature treatment necessary to transform the kaolin into metakaolin which is the reactive species, then a recrystallization from sodium hydroxide. Consideration has been given to replacing, in the preparation of the extruded, the kaolin by metakaolin, as in the processes described in US Pat. Nos.
- the present invention which overcomes these drawbacks, is a process for obtaining zeolites, in particular zeolites A, with a binder constituted by a zeolitic phase, also of type A, and which comprises the following successive operations:
- Silica soils containing 20 to 40% by weight of SiO 2 are generally used, and preferably soils containing 30% of SiO 2 .
- the weight ratio between the silica provided by the silica sol and the zeolite is between approximately 4 and 15% (these proportions being expressed on the basis of the finished product after calcination at 900 ° C.), ie 12 , 5 to 60% of silica sol at 30% relative to the calcined mass).
- the sodium aluminate solution introduced into the dough amounts of aluminum hydroxide which can vary between 0.2 g and 1.6 g of Al (OH) 3, and amounts of soda between 0.1 g and 0.9 g of NaOH per gram of silica SiO 2 supplied by the silica sol; values which will be compared to the stoichiometric amounts to form zeolite A and which are respectively 1.29 g of aluminum hydroxide and 0.66 g of sodium hydroxide per gram of SiO 2 .
- the consistency of the dough is adjusted by adding water in a suitable amount so that its water content, including the water of hydration of the zeolite, is between 60 and 75% (expressed in weight% relative to l all the anhydrous constituents SiO 2 , Al 2 O3, Na 2 O and zeolite, in other words relative to the mass of the granule after calcination at 900 ° C.).
- This paste is then extruded to obtain yarns, preferably with a diameter of 1.6 to 3.2 mm in diameter; it is also possible to agglomerate the dough into balls by means of a granulation plate, or else to compact it according to techniques well known to one skilled in the art.
- extrudates are left to spontaneous ripening at ambient temperature and humidity for a period of up to 24 hours, then they are baked between 50 and 150 ° C for a period of between approximately 30 minutes and 24 hours; finally, they are calcined at a temperature of at least 450 ° C, without however exceeding 600oC for a period of 30 minutes to 6 hours.
- the process according to the invention has the advantage over the known processes of great simplicity and rapidity in the zeolitization operations of binder which can all be carried out online; these operations are carried out safely in the dry phase, and there is no need for prior gelling of the silica sol with magnesia, nor to recrystallize the agglomerates in a solution in a basic solution after shaping, nor especially to wash after zeolitization; on the other hand, in the absence of any excess of basic reagent, one discards the effect of restricting the opening of the pores of the zeolite, obviously harmful to its adsorption qualities, and at the same time, one gets rid problems of handling more or less sticky agglomerates; installation corrosion problems are also minimized.
- the granulated molecular sieves obtained according to this process offer an adsorption kinetics, a water adsorption capacity greater than 20%, a mechanical resistance to crushing equal to or greater than 6 10 5 Pascals, better than that of agglomerated sieves with using traditional binders. They will find advantageous uses, especially in petrochemicals, for air conditioning in automobiles, as desiccants in insulating double glazing.
- the present invention is not limited to type A molecular sieves. Transposition, in particular to zeolites X and Y, is within the reach of any person skilled in the art.
- a sodium aluminate solution is prepared, according to the procedure of Example 1, but this time, the amounts of soda and alumina contained in this solution are 20 g and 40 g respectively.
- zeolite 4A powder weight equivalent to the material calcined at 900 ° C.
- a wheel mixer 25 g of carboxymethylcellulose and 150 g of silica sol at 30% by weight for 10 minutes.
- Example 3 The extrudates are then placed in an oven at 60 ° C for 16 hours and calcined at 550 ° C for 2 hours.
- the water adsorption capacity measured, under the same conditions as in Example 1, is 24.5% and the mechanical resistance to crushing is 6.2 ⁇ 10 5 Pascals with standard deviation of 1.4.
- Example 3 The water adsorption capacity measured, under the same conditions as in Example 1, is 24.5% and the mechanical resistance to crushing is 6.2 ⁇ 10 5 Pascals with standard deviation of 1.4.
- This example relates to the preparation of sieve extrudates without binder using an aluminate solution more concentrated in sodium hydroxide and alumina than in Examples 1 and 2; moreover, the proportion between soda and alumina is almost stoichiometric.
- a sodium aluminate solution containing 40 g of sodium hydroxide and 70 g of alumina is prepared, according to the procedure of Example 1.
- zeolite 4A powder weight equivalent to the material calcined at 90 ° C.
- 25 g of carboxymethylcellulose and 150 g of silica sol at 30% by weight are mixed in the wheel mixer, for 10 minutes.
- extrudates are then placed in an oven at 100 ° C for 16 hours and then calcined for 2 hours at 550 ° C.
- the water adsorption capacity measured under the same conditions as in Example 1, is 20.6% and the mechanical resistance to crushing is 6.5 10 5 Pascals with a standard deviation of 1.3 .
- a sodium aluminate solution is prepared according to the procedure of Example 1. The amounts of sodium hydroxide and alumina contained in this solution are 30 and 40 g respectively. - 800 g of zeolite 4A powder (weight equivalent to the material calcined at 900 ° C.), 20 g of carboxymethylcellulose and 300 g of 30% silica sol are mixed for 10 minutes.
- the dough is extruded using the PINETTE hydraulic press equipped with a 3.2 mm diameter die.
- the extrudates are matured at room temperature for 24 hours, then placed in an oven at 100 ° C for 2 hours, then calcined at 550 ° C for 2 hours.
- the water adsorption capacity measured according to the conditions of Example 1, is 24.5% and the mechanical resistance to crushing is 5 10 5 Pascals with a standard deviation of 1.4.
- Example 4 differs from Example 4 in that it relates to the preparation of sieve extrudates without binder from a sodium aluminate solution containing more soda and alumina.
- a sodium aluminate solution containing 80 g of sodium hydroxide and 100 g of alumina is prepared, according to the procedure of Example 1.
- the alumina solution and 100 ml of water are then introduced and the mixing is continued for 10 minutes.
- the dough obtained is extruded by means of the PINETTE hydraulic press equipped with a 3.2 mm diameter die.
- the yarns are treated in an oven for 1 hour at 100 ° C and activated at 550 ° C for 2 hours.
- the water adsorption capacity, measured according to the procedure of Example 1, is 19.5% and the mechanical resistance to crushing is 9 10 5 Pascals with a standard deviation of 3.
- a sodium aluminate solution containing 30 g of sodium hydroxide and 60 g of alumina is prepared, according to the procedure of Example 1. These amounts correspond practically to the stoichiometry between soda and alumina.
- zeolite 4A powder weight equivalent to the material calcined at 900 ° C.
- 20 g of carboxymethylcellulose and 300 g of silica sol at 30% by weight are mixed in the wheel mixer, for 10 minutes.
- the dough is extruded using the PINETTE hydraulic press equipped with a 3.2 mm diameter die.
- the yarns are left for 2 hours at 100 ° C in an oven and calcined at 550 ° C for 2 hours.
- Example 7 The water adsorption capacity, measured according to the procedure of Example 1, is 23.1% and the mechanical resistance to crushing is 6.4 10 5 Pascals with a standard deviation of 1, 7.
- Example 7 The water adsorption capacity, measured according to the procedure of Example 1, is 23.1% and the mechanical resistance to crushing is 6.4 10 5 Pascals with a standard deviation of 1, 7.
- This example differs from the previous one by the amount of silica sol added to the paste; the molar ratios between alumina, soda and silica from the silica sol were kept constant.
- the preparation of the sodium aluminate solution is identical to that of Example 1 but this solution contains 45 g of soda and 90 g of alumina.
- the dough is extruded using the PINETTE hydraulic press equipped with a 3.2 mm diameter die.
- the water adsorption capacity measured according to the procedure of Example 1 is 22.6% and the mechanical resistance to crushing is 4 ⁇ 10 5 Pascals with a standard deviation of 1.3.
- Agent HAICOUR, Philippe; CECA S.A. - DRDI, 95, rue Danton, F-92303 Levallois-Perret (FR).
- a paste is pared from a zeolite powder, a silica sol and a sodium aluminate solution. The paste is then extruded, matured at ambient t pature, heat-treated and calcined.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT89907196T ATE100421T1 (de) | 1988-06-17 | 1989-06-15 | Zeolit-granulate mit zeolit-bindemittel. |
DE68912556T DE68912556T2 (de) | 1988-06-17 | 1989-06-15 | Zeolit-granulate mit zeolit-bindemittel. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8808107A FR2632944B1 (fr) | 1988-06-17 | 1988-06-17 | Procede pour la preparation d'agglomeres de tamis moleculaires zeolitiques a liant zeolitique |
FR88/08107 | 1988-06-17 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO1989012603A2 true WO1989012603A2 (fr) | 1989-12-28 |
WO1989012603A3 WO1989012603A3 (fr) | 1990-01-25 |
Family
ID=9367388
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR1989/000300 WO1989012603A2 (fr) | 1988-06-17 | 1989-06-15 | Granule de zeolites a liant zeolitique |
Country Status (6)
Country | Link |
---|---|
US (1) | US5132260A (fr) |
EP (1) | EP0378633B1 (fr) |
JP (1) | JP2719971B2 (fr) |
DE (1) | DE68912556T2 (fr) |
FR (1) | FR2632944B1 (fr) |
WO (1) | WO1989012603A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994011457A1 (fr) * | 1992-11-13 | 1994-05-26 | Ceca S.A. | Blocs adsorbants pour pompes a chaleur chimiques et leur procede d'obtention |
DE102011104006A1 (de) | 2010-12-10 | 2012-06-14 | Süd-Chemie AG | Granulierte Zeolithe mit hoher Adsorptionskapazität zur Adsorption von organischen Molekülen |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9101456D0 (en) * | 1991-01-23 | 1991-03-06 | Exxon Chemical Patents Inc | Process for producing substantially binder-free zeolite |
DE4408302C2 (de) * | 1994-03-11 | 1996-04-04 | Zeochem Kft | Verfahren zur Herstellung und Verwendung eines festen Verbundproduktes zur Wasserbehandlung |
US5493821A (en) * | 1994-05-04 | 1996-02-27 | Uop | Adsorbent for use in double glazed windows |
AU4737896A (en) | 1994-11-23 | 1996-06-17 | Exxon Chemical Patents Inc. | Hydrocarbon conversion process using a zeolite bound zeolite catalyst |
US6070455A (en) * | 1995-07-21 | 2000-06-06 | Bright Solutions, Inc. | Leak detection additives |
WO1999017873A1 (fr) * | 1997-10-08 | 1999-04-15 | Corning Incorporated | Procede de fabrication de corps de tamis moleculaires hydrophiles a petits pores |
WO2000017105A1 (fr) * | 1998-09-22 | 2000-03-30 | Exxon Chemical Patents Inc. | Preparation de zeolites a forte teneur en silice lies par zeolite et utilisation de cette preparation |
DE19959957A1 (de) * | 1999-12-13 | 2001-06-21 | Sued Chemie Ag | Plättchenförmige Preßkörper |
GB0028395D0 (en) * | 2000-11-22 | 2001-01-03 | Ici Plc | Getters |
US8381738B2 (en) * | 2003-12-22 | 2013-02-26 | Philip Morris Usa Inc. | Composite materials and their use in smoking articles |
US7943380B2 (en) * | 2004-06-02 | 2011-05-17 | Bright Solutions, Inc. | Leak detection materials and methods |
KR101155980B1 (ko) | 2009-11-17 | 2012-07-09 | 한창산업 주식회사 | 산소제조용 제올라이트 분자체의 제조방법 |
US20120093715A1 (en) * | 2010-10-19 | 2012-04-19 | Uop Llc | Monolithic zeolite structures with and without hierarchical pore structures and methods for producing the same |
KR101203258B1 (ko) * | 2011-07-05 | 2012-11-21 | 한국화학연구원 | BaX형 제올라이트 성형체 및 그의 제조방법 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1419426A (fr) * | 1964-01-04 | 1965-11-26 | Bayer Ag | Procédé pour la préparation de tamis moléculaires mis en forme |
FR2093833A5 (fr) * | 1970-05-27 | 1972-01-28 | Bayer Ag | |
DE2524484A1 (de) * | 1974-06-06 | 1975-12-18 | Grace W R & Co | Verfahren zur herstellung von harten geformten teilchen aus kristallinem aluminosilikat |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2865867A (en) * | 1956-12-26 | 1958-12-23 | Shell Dev | Solid contact material |
US3377295A (en) * | 1964-12-17 | 1968-04-09 | Grace W R & Co | Process for making high strength molecular sieve nodules and extrudates |
US3764563A (en) * | 1971-04-07 | 1973-10-09 | K Minachev | Method of preparing granulated zeolite catalysts and sorbents |
DE2805546A1 (de) * | 1978-02-10 | 1979-08-16 | Kali Chemie Ag | Verfahren zur herstellung von molekularsieb enthaltenden granulaten guter mechanischer festigkeit |
US4528276A (en) * | 1979-06-18 | 1985-07-09 | Pq Corporation | Zeolite ion exchanger for builders in detergents |
JPS5926923A (ja) * | 1982-08-05 | 1984-02-13 | Kanto Kagaku Kk | ゼオライト成型体の製造方法 |
-
1988
- 1988-06-17 FR FR8808107A patent/FR2632944B1/fr not_active Expired - Lifetime
-
1989
- 1989-06-15 EP EP89907196A patent/EP0378633B1/fr not_active Expired - Lifetime
- 1989-06-15 US US07/477,857 patent/US5132260A/en not_active Expired - Fee Related
- 1989-06-15 DE DE68912556T patent/DE68912556T2/de not_active Expired - Fee Related
- 1989-06-15 JP JP1507010A patent/JP2719971B2/ja not_active Expired - Lifetime
- 1989-06-15 WO PCT/FR1989/000300 patent/WO1989012603A2/fr active IP Right Grant
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1419426A (fr) * | 1964-01-04 | 1965-11-26 | Bayer Ag | Procédé pour la préparation de tamis moléculaires mis en forme |
FR2093833A5 (fr) * | 1970-05-27 | 1972-01-28 | Bayer Ag | |
DE2524484A1 (de) * | 1974-06-06 | 1975-12-18 | Grace W R & Co | Verfahren zur herstellung von harten geformten teilchen aus kristallinem aluminosilikat |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994011457A1 (fr) * | 1992-11-13 | 1994-05-26 | Ceca S.A. | Blocs adsorbants pour pompes a chaleur chimiques et leur procede d'obtention |
DE102011104006A1 (de) | 2010-12-10 | 2012-06-14 | Süd-Chemie AG | Granulierte Zeolithe mit hoher Adsorptionskapazität zur Adsorption von organischen Molekülen |
WO2012076725A1 (fr) | 2010-12-10 | 2012-06-14 | Süd-Chemie AG | Zéolite en granulés présentant une capacité élevée d'adsorption de molécules organiques |
Also Published As
Publication number | Publication date |
---|---|
DE68912556T2 (de) | 1994-07-07 |
JPH02504628A (ja) | 1990-12-27 |
EP0378633B1 (fr) | 1994-01-19 |
EP0378633A1 (fr) | 1990-07-25 |
US5132260A (en) | 1992-07-21 |
FR2632944A1 (fr) | 1989-12-22 |
JP2719971B2 (ja) | 1998-02-25 |
FR2632944B1 (fr) | 1990-10-12 |
WO1989012603A3 (fr) | 1990-01-25 |
DE68912556D1 (de) | 1994-03-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO1989012603A2 (fr) | Granule de zeolites a liant zeolitique | |
CA2266385C (fr) | Procede pour l'obtention de corps granulaires en zeolite lsx a faible taux de liant inerte | |
JPH11513969A (ja) | 分子篩錯体化合物の製造方法 | |
CA1212658A (fr) | Procede de preparation de zeolites synthetiques et zeolites obtenues par ce procede | |
EP0273816B1 (fr) | Nouveau procédé de synthèse de zéolithes du type ferrisilicate, produits ainsi obtenus et leurs utilisations | |
JP3090455B2 (ja) | ゼオライト及びその製造方法 | |
EP1011858B2 (fr) | Adsorbants zeolitiques agglomeres leur procede d'obtention et leur utilisation pour l'adsorption de paraxylene a partir de coupes de c8 aromatiques | |
EP0292363A2 (fr) | Zéolites de structures MFI à base de silice et d'oxyde de titane et procédé de synthèse de celles-ci | |
DE1262864B (de) | Verfahren zur Herstellung von Glimmerplaettchen | |
CA2025937C (fr) | Zeolithe de type beta et son procede de preparation | |
EP1910226A1 (fr) | Materiau mesostructure a forte teneur en aluminium | |
LU82916A1 (fr) | Compositions synthetiques de borosilicate cristallin et procedes de preparation et d'activation de celles-ci | |
FR2634140A1 (fr) | Catalyseur du type aluminosilicate contenant du gallium et son utilisation en aromatisation des gaz legers c2-c4 | |
WO1992011203A1 (fr) | Zeolithe de type mtw et son procede de preparation | |
JPH0521843B2 (fr) | ||
FR2929266A1 (fr) | Materiau mesostructure a forte teneur en aluminium et constitue de particules spheriques de taille specifique | |
EP0419307B1 (fr) | Zéolite de la famille de la mazzite, son procédé de synthèse et son utilisation comme catalyseur | |
JPH0352409B2 (fr) | ||
JPS59148789A (ja) | 高度に結晶性のナトリウムセフオペラゾンの製法 | |
FR2494583A1 (fr) | Complexe de glycerolate de zinc ayant des proprietes therapeutiques, et son procede de preparation | |
JP4016118B2 (ja) | アルミノシリケート | |
EP0345106B1 (fr) | Nouvelles zéolithes de type structural ton, leur préparation et leur utilisation | |
FR2472538A1 (fr) | Procede de production de zeolithes cristallines | |
JP3505730B2 (ja) | 無定形アルミノシリケート及びその用途 | |
RU2146223C1 (ru) | Способ получения синтетического гранулированного фожазита |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A2 Designated state(s): JP KR US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): AT BE CH DE FR GB IT LU NL SE |
|
AK | Designated states |
Kind code of ref document: A3 Designated state(s): JP KR US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A3 Designated state(s): AT BE CH DE FR GB IT LU NL SE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1989907196 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 1989907196 Country of ref document: EP |
|
WWG | Wipo information: grant in national office |
Ref document number: 1989907196 Country of ref document: EP |