US6884471B2 - Method of producing a light-scattering layer on a glass or glass ceramic body - Google Patents

Method of producing a light-scattering layer on a glass or glass ceramic body Download PDF

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Publication number
US6884471B2
US6884471B2 US10/702,328 US70232803A US6884471B2 US 6884471 B2 US6884471 B2 US 6884471B2 US 70232803 A US70232803 A US 70232803A US 6884471 B2 US6884471 B2 US 6884471B2
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United States
Prior art keywords
light
scattering layer
glass
layer
glass ceramic
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Expired - Fee Related
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US10/702,328
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English (en)
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US20040115352A1 (en
Inventor
Bernd Schultheis
Cora Krause
Karsten Wermbter
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Schott AG
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Schott AG
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Assigned to SCHOTT GLAS reassignment SCHOTT GLAS ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KRAUSE, CORA, SCHULTHEIS, BERND, WERMBTER, KARSTEN
Publication of US20040115352A1 publication Critical patent/US20040115352A1/en
Assigned to SCHOTT AG reassignment SCHOTT AG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SCHOTT GLAS
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Publication of US6884471B2 publication Critical patent/US6884471B2/en
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
    • C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/001—General methods for coating; Devices therefor
    • C03C17/002—General methods for coating; Devices therefor for flat glass, e.g. float glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
    • C03C17/04—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass by fritting glass powder
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22—Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/02—Pretreatment of the material to be coated, e.g. for coating on selected surface areas
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/10—Oxides, borides, carbides, nitrides or silicides; Mixtures thereof
    • C23C4/11—Oxides
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/40—Coatings comprising at least one inhomogeneous layer
    • C03C2217/42—Coatings comprising at least one inhomogeneous layer consisting of particles only

Definitions

  • the invention relates to a light-scattering layer on a transparent body, in particular consisting of a glass or a glass ceramic, as well to a method producing such a layer. More particularly, the invention relates to a method of preparing a light-scattering layer on a glass ceramic cooktop.
  • Ceramic colors such as commonly utilized for the decoration of the top surfaces of glass ceramic cooktops cannot be used on the lower side of a glass ceramic cooktop, since they reduce the mechanical stability during baking such that a sufficient impact resistance is not provided any more.
  • the impact resistance deteriorates to values below 0.5 Joule.
  • the glass ceramic layer produced in this way is only intended as an insulation layer in glass ceramic cooktops that are provided with a contact heater on the lower side of the glass ceramic plate.
  • Such an insulation layer is necessary when using contact heaters, since the electric resistance of a glass ceramic decreases with increasing temperature (NTC characteristic).
  • An insulation layer manufactured in this way thus comprises a large layer thickness on the order of several hundred micrometers and is optimized with respect to its insulating characteristics.
  • adhesion problem when applying ceramic particles by thermal spraying onto a glass or a glass ceramic surface. Namely, it has been found that the common pretreatment of the surface to be coated by surface roughening blasting is not possible, since thereby the mechanical stability of the glass or glass ceramic surface is impaired.
  • a method comprising providing a transparent body consisting of a glass or a glass ceramic, preheating the body to a temperature between 200 and 450° C., but below the glass transition temperature and applying a layer of a maximum thickness of 100 micrometers to a surface thereof by thermal spraying.
  • ceramic materials which includes, among others, aluminum oxide, titanium oxide, boron nitride, zirconium oxide, silicon nitride or mixtures thereof.
  • aluminum oxide and titanium oxide offer a particularly good adhesion of the applied light-scattering layer to the surface of the coated body. While titanium oxide seems to be particularly suited for the production of opaque layers, since titanium oxide has a white color, aluminum oxide is suitable for the production of translucent light-scattering layers, in case a small layer thickness is selected, as well as the production of opaque layers, in case a larger layer thickness is selected.
  • layer thicknesses of at least 20 ⁇ m, in particular of about 30 to 60 ⁇ m, in particular of about 40 to 50 ⁇ m are suitable.
  • the layer thickness should, preferably, be smaller than 20 ⁇ m.
  • colored particles may be utilized for its production, such as iron oxide particles, or colored particles may only be admixed thereto.
  • color pigments may be admixed to aluminum oxide or titanium oxide which offers a particularly goods adhesion to a glass or glass ceramic surface.
  • powder of ground glass or ground glass ceramic can be admixed to the particles, as long as the resulting mixture is still thermally sprayable.
  • the powder may also be prepared from recycling material.
  • the body is heated to a temperature of at least 100° C., preferably to a temperature of at least 200° C., in particular to a temperature of about 200 to 450° C., before the particles are applied by spraying.
  • a temperature of at least 100° C. preferably to a temperature of at least 200° C., in particular to a temperature of about 200 to 450° C.
  • glass ceramics such as Ceran® available from Schott, in this temperature region a particularly good adhesion of the sprayed glass ceramic layer can be ensured.
  • the body is preheated to a temperature below the glass transition temperature, since beyond that the form stability is impaired.
  • a prior annealing process can be utilized which must be performed anyway during manufacture of the body.
  • spraying of the particles may follow directly onto a prior annealing treatment in a crystallization furnace during manufacture of a glass ceramic or may follow an annealing process in a pre-stressing furnace during manufacture of a pre-stressed glass sheet.
  • a prior annealing treatment in a crystallization furnace during manufacture of a glass ceramic or may follow an annealing process in a pre-stressing furnace during manufacture of a pre-stressed glass sheet.
  • the exit temperatures usually are in a region between 450 and 700° C.
  • a plasma spraying process or possibly a flame spraying process is utilized.
  • the characteristics of the light-scattering layer produced in this way can be influenced.
  • the particles are deformed to lens-shaped splats due to the high kinetic energy.
  • the particle size is in a region between about 5 and 30 ⁇ m, wherein the median particle size is usually in the range between 1 and 20 ⁇ m.
  • the particle size can additionally be influenced by the selected operating parameters during this coating process.
  • FIG. 1 a portion of a plate-shaped body consisting of a glass ceramic and comprising a light-scattering layer according to the invention is shown in cross-sectional view;
  • FIG. 2 is a schematic diagram of the manufacturing process of the plate-shaped body 10 shown in FIG. 1 .
  • a transparent body 12 comprises a thin plasma sprayed coating 16 consisting of Al 2 O 3 at one of its surfaces 14 .
  • the body manufactured in this way is designated in total with numeral 10 .
  • FIG. 1 is merely of exemplary nature and is, in particular, not drawn to scale.
  • the transparent body is a cooktop consisting of the lithium-aluminosilicate glass ceramic manufactured by the company Schott Glas and marketed under the trademark Ceran®. While the thickness of the plate-shaped body or sheet 12 is usually at least several millimeters (typically about 4 to 6 millimeters), the thickness of the coating 16 applied by thermal spraying is usually smaller than 100 ⁇ m.
  • the layer 16 consists of a ceramic material, e.g. of aluminum oxide, titanium oxide, boron nitride, zirconium oxide, silicon nitride or mixtures thereof. If desired, additional color pigments, such as Fe 2 O 3 particles, may be added to these materials.
  • the layer 16 thus consists of a plurality of individual particles, this layer acts as a light-scattering layer.
  • the particle sizes usually are in a range of about 1 to 20 ⁇ m, wherein typically a median of about 5 ⁇ m results, wherein 90% of the particles may have a diameter of smaller than 30 ⁇ m.
  • the particle sizes can be influenced depending on the selected starting material and on the selected process parameters during thermal spraying.
  • the light-scattering layer 16 shall be opaque, then it is applied with a layer thickness of more than 20 ⁇ m, typically with a layer thickness of about 40 to 50 ⁇ m. However, if a translucent light-scattering layer 16 is desired, then a layer thickness of less than 20 ⁇ m, e.g. about 10 to 15 ⁇ m, is preferred. Naturally, the opaqueness or the translucency, respectively, of the layer 16 are in addition influenced by the type of the selected layer material.
  • a layer consisting of aluminum oxide is translucent also at relatively small layer thicknesses, e.g. a layer consisting of titanium oxide is more opaque, since titanium oxide offers a whitish color by nature.
  • a good adhesion of the light-scattering layer 16 to the surface 14 of the body 12 is ensured by several measures.
  • the coefficients of thermal expansion of the material of which the light-scattering layer 16 consists, and the material of which the body 12 consists, should not differ to a large extent, to possibly avoid thermally induced stresses.
  • the light-scattering layer 16 should be produced of a material the coefficient of thermal expansion of which is relatively small.
  • the adhesion of the light-scattering layer 16 and the long-term stability is considerably enhanced even at thermal cycling, if the body 12 is pre-heated before the treatment, wherein for the coating of glass ceramic in particular temperatures in a region between about 200 up to 450° C. have been found to be particularly advantageous.
  • the small layer thickness of the light-scattering layer 16 facilitates a good adhesion, while at larger layer thicknesses thermally induced stresses have a considerably more pronounced effect due the differences between the coefficients between thermal expansion, thus in particular fracturing may occur or delaminations in the rim region of the coating.
  • the coating process follows immediately to a prior annealing process during manufacture of the body 12 so that an operation as energy saving as possible is ensured.
  • a prior annealing process for manufacture of the body 12
  • the coating of a glass ceramic plate of Ceran® by a plasma burner 20 could immediately follow thermal treatment of the body 12 in a crystallization furnace 18 in which the partial crystallization of the lithium base glass is reached during manufacture of the glass ceramic.
  • thermal treatment steps of various manufacturing processes can be utilized in an energy saving way by allowing an immediately following coating process.
  • the coating may also be effected only on selected regions.
  • the respective regions to be excluded can be masked by means of a protective coating in a masking process, the protective coating being removed again after thermal spraying.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Dispersion Chemistry (AREA)
  • Composite Materials (AREA)
  • Surface Treatment Of Glass (AREA)
  • Optical Elements Other Than Lenses (AREA)
  • Laminated Bodies (AREA)
  • Coating By Spraying Or Casting (AREA)
US10/702,328 2001-05-10 2003-11-06 Method of producing a light-scattering layer on a glass or glass ceramic body Expired - Fee Related US6884471B2 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10122718A DE10122718C2 (de) 2001-05-10 2001-05-10 Verfahren zur Erzeugung einer Streulichtschicht auf einer transparenten Kochplatte sowie dessen Verwendung
DE10122718.3 2001-05-10
PCT/EP2002/003269 WO2002090280A2 (fr) 2001-05-10 2002-03-22 Couche de lumiere diffusee et procede permettant de la produire, notamment pour recouvrir du verre ou de la vitroceramique

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2002/003269 Continuation WO2002090280A2 (fr) 2001-05-10 2002-03-22 Couche de lumiere diffusee et procede permettant de la produire, notamment pour recouvrir du verre ou de la vitroceramique

Publications (2)

Publication Number Publication Date
US20040115352A1 US20040115352A1 (en) 2004-06-17
US6884471B2 true US6884471B2 (en) 2005-04-26

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US10/702,328 Expired - Fee Related US6884471B2 (en) 2001-05-10 2003-11-06 Method of producing a light-scattering layer on a glass or glass ceramic body

Country Status (6)

Country Link
US (1) US6884471B2 (fr)
EP (1) EP1404625B1 (fr)
JP (1) JP2004535348A (fr)
DE (2) DE10122718C2 (fr)
ES (1) ES2232751T3 (fr)
WO (1) WO2002090280A2 (fr)

Cited By (1)

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DE102008012891A1 (de) 2008-03-06 2009-09-10 Schott Ag Glaskeramikartikel mit einer anorganischen lichtstreuenden Beschichtung, Verfahren zu seiner Herstellung und Beschichtungszusammensetzung

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DE10355160B4 (de) 2003-11-26 2008-04-03 Schott Ag Beschichtete Glaskeramikplatte, Verfahren zu ihrer Herstellung und Kochfeld mit einer solchen Glaskeramikplatte
FR2873791B1 (fr) * 2004-07-30 2006-11-03 Eurokera Plaque en materiau verrier pour dispositif de type insert de cheminee ou poele.
JP2007225781A (ja) * 2006-02-22 2007-09-06 Hitachi Displays Ltd 液晶表示装置
DE102006062166B4 (de) 2006-12-22 2009-05-14 Heraeus Quarzglas Gmbh & Co. Kg Quarzglas-Bauteil mit Reflektorschicht sowie Verfahren zur Herstellung desselben
WO2010084924A1 (fr) * 2009-01-26 2010-07-29 旭硝子株式会社 Procédé de production d'un substrat pour dispositifs électroniques, procédé de fabrication d'un dispositif électronique, substrat pour dispositifs électroniques et dispositif électronique
US8528886B2 (en) * 2009-02-02 2013-09-10 Corning Incorporated Material sheet handling system and processing methods
US20110290316A1 (en) * 2010-05-28 2011-12-01 Daniel Warren Hawtof Light scattering inorganic substrates by soot deposition
DE102011009235A1 (de) 2011-01-22 2012-07-26 Schott Ag Festigkeitssteigernde Beschichtung auf Polyurethan-basis
DE102011010118A1 (de) * 2011-02-02 2012-08-02 Osram Opto Semiconductors Gmbh Keramisches Konversionselement, Halbleiterchip mit einem keramischen Konversionselement und Verfahren zur Herstellung eines keramischen Konversionselements
US8789998B2 (en) 2011-08-31 2014-07-29 Corning Incorporated Edge illumination of an ion-exchanged glass sheet
DE102011115379B4 (de) 2011-10-10 2018-09-27 Schott Ag Beschichtetes Glas- oder Glaskeramik-Substrat mit haptischen Eigenschaften und Glaskeramik-Kochfeld
DE202012012372U1 (de) 2012-12-20 2013-01-16 Schott Ag Beschichtetes Glas- oder Glaskeramik-Substrat mit haptischen Eigenschaften
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DE102014119594B9 (de) 2014-12-23 2020-06-18 Schott Ag Borosilikatglas mit niedriger Sprödigkeit und hoher intrinsischer Festigkeit, seine Herstellung und seine Verwendung
RU2595074C2 (ru) * 2015-01-20 2016-08-20 Автономная некоммерческая организация высшего профессионального образования "Белгородский университет кооперации, экономики и права" Способ получения декоративных покрытий на стеклокремнезите
US10120111B2 (en) 2016-12-14 2018-11-06 Google Llc Thin ceramic imaging screen for camera systems
CN107721185A (zh) * 2017-01-04 2018-02-23 李正飞 一种能成像的钢化玻璃的制备工艺
JP7049076B2 (ja) * 2017-07-12 2022-04-06 日本パーカライジング株式会社 静電粉体塗料、並びに塗膜を有する塗装物品及びその製造方法
ES2703017A1 (es) * 2017-09-06 2019-03-06 Bsh Electrodomesticos Espana Sa Dispositivo de campo de cocción
WO2021039304A1 (fr) * 2019-08-30 2021-03-04 パナソニックＩｐマネジメント株式会社 Élément translucide et système de source de lumière

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GB1547530A (en) 1976-09-08 1979-06-20 Bisch Andre Process for producing vitreous coating and coated substrates obained thereby
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DE4013253A1 (de) 1989-04-28 1991-05-23 Inst Materialforschung Und Anw Verfahren zur herstellung von farbflachglaesern und zum aufbringen von farbigen und farblosen schichten und dekoren auf flachglas
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US6037572A (en) 1997-02-26 2000-03-14 White Consolidated Industries, Inc. Thin film heating assemblies
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102008012891A1 (de) 2008-03-06 2009-09-10 Schott Ag Glaskeramikartikel mit einer anorganischen lichtstreuenden Beschichtung, Verfahren zu seiner Herstellung und Beschichtungszusammensetzung

Also Published As

Publication number Publication date
DE10122718A1 (de) 2002-11-21
WO2002090280A2 (fr) 2002-11-14
JP2004535348A (ja) 2004-11-25
DE50201688D1 (de) 2005-01-05
EP1404625B1 (fr) 2004-12-01
DE10122718C2 (de) 2003-04-17
WO2002090280A3 (fr) 2004-01-15
ES2232751T3 (es) 2005-06-01
US20040115352A1 (en) 2004-06-17
EP1404625A2 (fr) 2004-04-07

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