US6756095B2 - Heat-sealable laminate - Google Patents

Heat-sealable laminate Download PDF

Info

Publication number
US6756095B2
US6756095B2 US09/758,092 US75809201A US6756095B2 US 6756095 B2 US6756095 B2 US 6756095B2 US 75809201 A US75809201 A US 75809201A US 6756095 B2 US6756095 B2 US 6756095B2
Authority
US
United States
Prior art keywords
facestock
laminate
adhesive layer
layer
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US09/758,092
Other languages
English (en)
Other versions
US20020127361A1 (en
Inventor
Richard L. Sandt
Mark D. Kittel
Henry Lum, Jr.
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CCL Label Inc
Original Assignee
Avery Dennison Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Avery Dennison Corp filed Critical Avery Dennison Corp
Priority to US09/758,092 priority Critical patent/US6756095B2/en
Assigned to AVERY DENNISON CORPORATION reassignment AVERY DENNISON CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LUM, HENRY, JR., KITTEL, MARK D., SANDT, RICHARD L.
Priority to EP01991303A priority patent/EP1358066B1/en
Priority to CA2433664A priority patent/CA2433664C/en
Priority to DE60141712T priority patent/DE60141712D1/de
Priority to AT01991303T priority patent/ATE462562T1/de
Priority to PCT/US2001/049084 priority patent/WO2002055295A1/en
Priority to MXPA03006203A priority patent/MXPA03006203A/es
Priority to JP2002556004A priority patent/JP2004524993A/ja
Publication of US20020127361A1 publication Critical patent/US20020127361A1/en
Publication of US6756095B2 publication Critical patent/US6756095B2/en
Application granted granted Critical
Assigned to CCL LABEL, INC. reassignment CCL LABEL, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: AVERY DENNISON CORPORATION
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • G—PHYSICS
    • G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
    • G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
    • G09F3/00—Labels, tag tickets, or similar identification or indication means; Seals; Postage or like stamps
    • G09F3/08—Fastening or securing by means not forming part of the material of the label itself
    • G09F3/10—Fastening or securing by means not forming part of the material of the label itself by an adhesive layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1481—Dissimilar adhesives
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/14—Layer or component removable to expose adhesive
    • Y10T428/1486—Ornamental, decorative, pattern, or indicia
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24851—Intermediate layer is discontinuous or differential
    • Y10T428/2486—Intermediate layer is discontinuous or differential with outer strippable or release layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
    • Y10T428/24934—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including paper layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2813—Heat or solvent activated or sealable
    • Y10T428/2817—Heat sealable
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2839—Web or sheet containing structurally defined element or component and having an adhesive outermost layer with release or antistick coating
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2843—Web or sheet containing structurally defined element or component and having an adhesive outermost layer including a primer layer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2848—Three or more layers

Definitions

  • This invention relates to heat-sealable laminates. These heat-sealable laminates may be used to provide pictorial and/or print designs or messages (e.g., labels, decals, etc.) that can be adhered to substrates (e.g., metal, plastic, leather, paper or textile substrates) such as automotive interior surfaces, hard plastic component parts, consumer durable goods, and other identification systems.
  • substrates e.g., metal, plastic, leather, paper or textile substrates
  • Heat-sealable labels are used in automotive interiors to provide instructional and/or warning labels on seat belts, visors, dashboards, and the like. A typical construction for these labels is illustrated in FIG. 1 .
  • label 100 has a paper carrier 110 and a release coating 120 adhered to one side of the paper carrier 110 .
  • Ink or graphics layer 130 is adhered to the release coating 120 and heat-activatable adhesive layer 140 is adhered to ink or graphics layer 130 .
  • the label 100 is placed on substrate 150 (e.g., seat belt, visor, etc.) with the adhesive layer 140 in contact with the substrate 150 . Heat and pressure are applied to the label 100 through the paper carrier 110 to heat seal the label 100 to the substrate 150 .
  • the paper carrier 110 is then removed from the heat-sealed label.
  • the release coating 120 separates with the paper carrier 110 .
  • the ink or graphics layer 130 and adhesive layer 140 remain adhered to the substrate 150 .
  • This invention relates to a heat-sealable laminate, comprising: a facestock having an upper surface and a lower surface; a heat-activatable first adhesive layer underlying the lower surface of the facestock; and a second adhesive layer overlying the upper surface of the facestock; with the proviso that the laminate is characterized by the absence of either an adhesion promoting layer or an abrasion-resistant transparent coating layer positioned between the upper surface of the facestock and the second adhesive layer.
  • the inventive laminate further comprises an adhesion promoting layer positioned between the upper surface of the facestock and the second adhesive layer.
  • the inventive laminate further comprises an abrasion-resistant transparent coating layer positioned between the upper surface of the facestock and the second adhesive layer.
  • the inventive laminate further comprises an ink or graphics layer positioned between the upper surface of the facestock and the second adhesive layer.
  • the heat-activatable first adhesive layer is adhered to the lower surface of the facestock and the inventive laminate further comprises an ink or graphics layer adhered to the heat-activatable first adhesive layer on the side of the heat-activatable first adhesive layer that is opposite the side of the heat-activatable first adhesive layer that is in contact with the facestock.
  • the inventive laminate further comprises an ink or graphics layer positioned between the lower surface of the facestock and the heat-activatable first adhesive layer.
  • the heat-activatable first adhesive layer is adhered to the lower surface of the facestock and the inventive laminate further comprises an ink or graphics layer positioned between the upper surface of the facestock and the second adhesive layer, and another ink or graphics layer adhered to the heat-activatable first adhesive layer on the side of the heat-activatable first adhesive layer that is opposite the side of the heat-activatable first adhesive layer that is in contact with the facestock.
  • the inventive laminate further comprises a carrier sheet overlying the second adhesive layer.
  • the inventive laminate further comprises an ink or graphics layer overlying the upper surface of the facestock and an adhesion promoting layer positioned between the ink or graphics layer and the upper surface of the facestock.
  • the inventive laminate further comprises an ink or graphics layer overlying the upper surface of the facestock and an abrasion-resistant transparent coating layer positioned between the ink or graphics layer and the second adhesive layer.
  • the inventive laminate further comprises a transparent film layer having an upper surface and a lower surface, and another adhesive layer adhered to the lower surface of the transparent film layer, the another adhesive layer being positioned between the transparent film layer and the upper surface of the facestock.
  • the inventive laminate is adhered to a substrate.
  • These heat-sealable laminates may be used to provide pictorial and/or print designs or messages (e.g., labels, decals, etc.) that can be adhered to substrates (e.g., metal, plastic, leather, paper or textile substrates) such as automotive interior surfaces (e.g., seat belts, visors, dashboards, headrests, seat-backs, door panels, headliners, carpet, flooring, seat covers, etc.), hard plastic component parts (e.g., appliance parts, motor fluid caps, engine housings, etc.), consumer durable goods (e.g., helmets, vacuum cleaners, sports equipment, etc.), other identification systems (e.g., livestock tags, lock box tags, etc.), and the like.
  • substrates e.g., metal, plastic, leather, paper or textile substrates
  • automotive interior surfaces e.g., seat belts, visors, dashboards, headrests, seat-backs, door panels, headliners, carpet, flooring, seat covers, etc.
  • hard plastic component parts
  • FIG. 1 is a schematic illustration of the side of a prior art label, the label being heat sealed to a substrate.
  • FIG. 2 is a schematic illustration of the side view of a heat-sealable laminate embodying the present invention in a particular form.
  • FIG. 3 is a schematic illustration of the side view of an alternative embodiment of the heat-sealable laminate of the present invention.
  • FIG. 4 is a schematic illustration of the side view of still another embodiment of the heat-sealable laminate of the present invention.
  • FIG. 5 is a schematic illustration of the side view of still another embodiment of the heat-sealable laminate of the present invention.
  • FIG. 6 is a schematic illustration of the side view of still another embodiment of the heat-sealable laminate of the present invention.
  • FIG. 7 is a schematic illustration of the side view of still another embodiment of the heat-sealable laminate of the present invention.
  • FIG. 8 is a schematic illustration of the side view of still another embodiment of the heat-sealable laminate of the present invention.
  • FIG. 9 is a schematic illustration of the side view of still another embodiment of the heat-sealable laminate of the present invention.
  • FIG. 10 is a schematic illustration of the side view of still another embodiment of the heat-sealable laminate of the present invention.
  • FIG. 11 is a schematic illustration showing the heat-sealable laminate of FIG. 3 being adhered to a substrate.
  • FIG. 12 is a schematic illustration showing the heat-sealable laminate of FIG. 3 adhered to a substrate with the carrier sheet and second adhesive layer of the laminate removed.
  • FIG. 13 is a schematic illustration of a plan view of the heat-sealable laminate of FIG. 3, with an array of printed messages formed in the ink or graphics layer of the laminate.
  • overlies and cognate terms such as “overlying” and the like, when referring to the relationship of one or a first layer relative to another or a second layer, refers to the fact that the first layer partially or completely lies over the second layer.
  • the first layer overlying the second layer may or may not be in contact with the second layer.
  • one or more additional layers may be positioned between the first layer and the second layer.
  • underlies and cognate terms such as “underlying” and the like have similar meanings except that the first layer partially or completely lies under, rather than over, the second layer.
  • transparent when referring to one or more layers overlying the ink or graphics layer(s) of the inventive heat-sealable laminate means that the ink or graphics layer(s) can be seen through such layer or layers.
  • abrasion-resistant transparent coating layer refers to a transparent coating layer that may be included with or excluded from the inventive heat-sealable laminate and when included provides protection against abrasions that would be expected during the normal use and handling of the laminate.
  • adheresion promoting layer refers to a coating layer that may be included with or excluded from the inventive heat-sealable laminate and when included is made from a radiation-curable, solvent-based or water-based primer and positioned between two layers for the purpose of increasing the adhesion between such layers.
  • primer refers to a coating composition comprised of a lacquer dissolved in a diluent.
  • lacquer refers to a film-forming material that is dissolved in a diluent.
  • the inventive heat-sealable laminate in one of its illustrated embodiments, is generally indicated by the reference numeral 200 , and is comprised of: a facestock 210 which has an upper surface 214 and a lower surface 216 ; a heat-activatable first adhesive layer 217 underlying and adhered to surface 216 ; a second adhesive layer 230 overlying and adhered to the upper surface 214 ; and a carrier sheet 240 adhered to the second adhesive layer 230 .
  • the upper surface 214 of facestock 210 may be a printable surface.
  • the heat-activatable first adhesive layer 217 has an upper side or surface 218 in contact with the lower surface 216 of facestock 210 , and a lower side or surface 219 that is opposite the side or surface 218 that is in contact with the facestock.
  • Surface 219 may be a printable surface.
  • the underside 246 of carrier sheet 240 is in contact with the second adhesive layer 230 .
  • the upper surface 245 of carrier sheet 240 optionally may have a release coating layer adhered to it.
  • the heat-sealable laminate 200 A depicted in FIG. 3 is identical to the heat-sealable laminate 200 depicted in FIG. 2, with the exception that the heat-sealable laminate 200 A includes an ink or graphics layer 220 positioned between the upper surface 214 and the second adhesive layer 230 . In all other respects the laminates 200 and 200 A are the same.
  • the heat-sealable laminate 200 B depicted in FIG. 4 is identical to the heat-sealable laminate 200 A depicted in FIG. 3, with the exception that the heat-sealable laminate 200 B includes an adhesion-promoting layer 250 positioned between the upper surface 214 and the ink or graphics layer 220 . In all other respects the laminates 200 A and 200 B are the same.
  • the heat-sealable laminate 200 C depicted in FIG. 5 is identical to the heat-sealable laminate 200 A depicted in FIG. 3, with the exception that the heat-sealable laminate 200 C includes an abrasion-resistant transparent coating layer 260 positioned between the ink or graphics layer 220 and the second adhesive layer 230 . In all other respects the laminates 200 A and 200 C are the same.
  • the heat-sealable laminate 200 D depicted in FIG. 6 is identical to the heat-sealable laminate 200 A depicted in FIG. 3, with the exception that the heat-sealable laminate 200 D includes a transparent film layer 290 underlying second adhesive layer 230 and an adhesive layer 280 positioned between the ink or graphics layer 220 and the transparent film layer 290 . In all other respects the laminates 200 A and 200 D are the same.
  • the heat-sealable laminate 200 E depicted in FIG. 7 is identical to the heat-sealable laminate 200 A depicted in FIG. 3, with the exception that the heat-sealable laminate 200 E includes an adhesion-promoting layer 250 positioned between the upper surface 214 and the ink or graphics layer 220 , a transparent film layer 290 underlying and in contact with the second adhesive layer 230 , and an adhesive layer 280 positioned between the ink or graphics layer 220 and the transparent film layer 290 . In all other respects the laminates 200 A and 200 E are the same.
  • the heat-sealable laminate 200 F depicted in FIG. 8 is identical to the heat-sealable laminate 200 depicted in FIG. 2, with the exception that the heat-sealable laminate 200 F includes ink or graphics layer 221 positioned between lower surface 216 and heat-activatable first adhesive layer 217 . Facestock 210 in heat-sealable laminate 200 F is transparent.
  • the heat-sealable laminate 200 G depicted in FIG. 9 is identical to the heat-sealable laminate 200 depicted in FIG. 2, with the exception that the heat-sealable laminate 200 G includes ink or graphics layer 223 underlying and adhered to lower surface 219 . Facestock 210 in heat-sealable laminate 200 G is transparent.
  • the heat-sealable laminate 200 H depicted in FIG. 10 is identical to the heat-sealable laminate 200 A depicted in FIG. 3, with the exception that the heat-sealable laminate 200 H includes ink or graphics layer 223 underlying and adhered to lower surface 219 . Facestock 210 in heat-sealable laminate 200 H is transparent. In this embodiment, the print and/or coloring of the two ink or graphics layers 220 and 223 should be coordinated so that the overlying layer 220 does not block the desired visible features in the underlying layer 223 .
  • any layer, including the facestock 210 , that overlies the ink or graphics layers 220 , 221 and/or 223 should be transparent so that the ink or graphics layers may be viewed through such facestock and layers.
  • the upper surface 214 may be corona treated to raise the surface energy of the surface to allow for enhanced printing on it.
  • the lower surface 216 may be corona treated to enhance the adhesion between the lower surface 216 and the adhesive layer 217 .
  • Corona treating involves discharging up to about 10,000 volts of electricity from a ceramic electrode to a ground roll over which the film is passing. This high voltage field called “corona” alters the surface of the film. Treating the surface of the film raises the surface energy of the film (measured in terms of dyne level) and allows for enhanced printing.
  • the facestock 210 may have overall thickness of about 1 to about 25 mils, and in one embodiment about 1 to about 20 mils, and in one embodiment about 1 to about 15 mils, and in one embodiment about 1 to about 10 mils, and in one embodiment about 2 to about 7 mils, and in one embodiment about 3 to about 5 mils.
  • the thickness of heat-activatable adhesive layers 218 and 330 may range from about 0.1 to about 10 mils, and in one embodiment about 0.1 to about 5 mils, and in one embodiment about 0.3 to about 2 mils.
  • the facestock 210 may be comprised of metal foil, polymer film, paper sheet, or combinations thereof.
  • the facestock may be comprised of textile including woven and non-woven fabrics made of natural or synthetic fibers.
  • the facestock may be a single-layered construction or it may be a multi-layered construction. These include polymeric films and multi-layered polymeric films.
  • the multi-layered constructions have two or more layers, and in one embodiment about two to about nine layers, and in one embodiment about two to about seven layers, and in one embodiment about three to about five layers.
  • the layers of such multi-layered constructions may have the same composition and/or size or they may be different.
  • the metal foils include foils of such metals as copper, gold, silver, tin, chromium, zinc, nickel, platinum, palladium, iron, aluminum, steel, lead, brass, bronze, and alloys of the foregoing metals.
  • Examples of such alloys include copper/zinc, copper/silver, copper/tin/zinc, copper/phosphorus, chromium/molybdenum, nickel/chromium, nickel/phosphorous, and the like.
  • the metal foils can be used by themselves or they can be joined or adhered to a polymeric sheet or film to form a multi-layered laminate or construction.
  • the polymer films include polyolefins (linear or branched), polyamides, polystyrenes, nylon, polyesters, polyester copolymers, polyurethanes, polysulfones, styrene-maleic anhydride copolymers, styrene-acrylonitrile copolymers, ionomers based on sodium or zinc salts of ethylene methacrylic acid, polymethyl methacrylates, cellulosics, acrylic polymers and copolymers, polycarbonates, polyacrylonitriles, and ethylene-vinyl acetate copolymers.
  • acrylates such as ethylene methacrylic acid, ethylene methyl acrylate, ethylene acrylic acid and ethylene ethyl acrylate.
  • polymers and copolymers of olefin monomers having, for example, 2 to about 12 carbon atoms, and in one embodiment 2 to about 8 carbon atoms. These include the polymers of ⁇ -olefins having from 2 to about 4 carbon atoms per molecule. These include polyethylene, polypropylene, poly-1-butene, etc.
  • An example of a copolymer within the above definition is a copolymer of ethylene with 1-butene having from about 1 to about 10 weight percent of the 1-butene comonomer incorporated into the copolymer molecule.
  • the polyethylenes that are useful have various densities including low, medium and high density ranges. The low density range is from about 0.910 to about 0.925 g/cm 3 ; the medium density range is from about 0.925 to about 0.940 g/cm 3 ; and the high density range is from about 0.940 to about 0.965 g/cm 3 .
  • An example of a commercially available material that is useful is available from Du Pont under the trade designation Mylar LB; this material is identified as being a biaxially oriented polyester film. Films prepared from blends of copolymers or blends of copolymers with homopolymers also are useful. The films may be extruded as monolayered films or multi-layered films. The films may be oriented films or nonoriented films.
  • the paper sheets include paper, clay coated paper, glassine, paperboard from straw, bark, wood, cotton, flax, cornstalks, sugarcane, bagasse, bamboo, hemp, and similar cellulose materials prepared by such processes as the soda, sulfite or sulfate (Kraft) processes, the neutral sulfide cooking process, alkali-chlorine processes, nitric acid processes, semi-chemical processes, etc.
  • Kraft soda, sulfite or sulfate
  • alkali-chlorine processes alkali-chlorine processes
  • nitric acid processes nitric acid processes
  • semi-chemical processes etc.
  • paper of any basis weight can be employed, paper having basis weights in the range of from about 20 to about 150 pounds per ream (lb/ream) are useful, and papers having weights in the range of from about 30 to about 60 lb/ream can be used.
  • the facestock 210 may be comprised of a polymer-coated paper which is basically a sheet of paper that is coated on either one or both sides with a polymer coating.
  • the polymer coating which may be comprised of a high, medium, or low density polyethylene, polypropylene, polyester, and other similar polymer films, is coated on the paper surface to add strength and/or dimensional stability.
  • the weight of these types of coated paper facestocks can vary over a wide range with weights in the range of about 5 to about 50 lb/ream being useful. In total, the final coated paper facestock may be comprised of between about 10% and about 40% by weight polymer. For two-sided coatings, the quantity of polymer is usually approximately evenly divided between the top and bottom surface of the paper.
  • the facestock 210 may be transparent or it may be pigmented.
  • the pigments that can be used include titanium dioxide, both rutile and anatase crystal structure.
  • the pigment is added to the facestock material in the form of a concentrate containing the pigment and a resin carrier.
  • the concentrate may contain, for example, about 20% to about 80% by weight pigment, and about 20% to about 80% by weight resin carrier.
  • the resin carrier can be any thermoplastic polymer having a melting point in the range of about 100° C. to about 265° C. Examples include polyethylene, polypropylene, polybutylene, polyester, nylon and the like.
  • a titanium dioxide concentrate is used which is comprised of a blend of about 30% to about 70% by weight polypropylene and about 70% to about 30% by weight titanium dioxide.
  • An example of a commercially available pigment concentrate that can be used is available from A. Schulman Inc. under the tradename PolyBatch White P8555 SD, which is identified as a white color concentrate having a coated rutile titanium dioxide concentration of 50% by weight in a polypropylene homopolymer carrier resin.
  • Another example is Ampacet 110233 which is a product of Ampacet Corporation identified as a TiO 2 concentrate containing 50% rutile TiO 2 and 50% low density polyethylene.
  • the concentration of pigment in the facestock 210 can be up to about 25% by weight, and when used is generally in the range of about 5% to about 25% by weight, and in one embodiment about 10% to about 20% by weight.
  • the facestock 210 may include a filler material to increase opacity.
  • the fillers that can be used include calcium carbonate and talc.
  • the filler is added in the form of a concentrate containing the filler and a resin carrier.
  • the concentrate may contain, for example, about 20% to about 80% by weight filler, and about 20% to about 80% by weight resin carrier.
  • the resin carrier can be any thermoplastic polymer having a melting point in the range of about 100° C. to about 265° C. Examples include polyethylene, polypropylene, polybutylene, polyester, nylon, and the like. Also included are thermoplastic copolymers such as ethylene methylacrylate, and the like.
  • a calcium carbonate concentrate which is comprised of a blend of about 50% to about 80% by weight polypropylene and about 20% to about 50% by weight calcium carbonate.
  • An example of a commercially available pigment concentrate that can be used is available from A. Schulman Inc. under the tradename PF 920, which is identified as a calcium carbonate concentrate having a calcium carbonate concentration of 40% by weight in a polypropylene homopolymer carrier resin.
  • Another example is Ampacet 101087 which is a product of Ampacet Corporation identified as a calcium carbonate concentrate containing 30% by weight calcium carbonate and 70% by weight ethylene methylacrylate.
  • the concentration of filler in the facestock may be up to about 40% by weight, and when used is generally in the range of about 10% to about 40% by weigh, and in one embodiment about 10% to about 35% by weight.
  • the heat-activatable first adhesive layer 217 may be made from any heat-activatable adhesive or thermoplastic film material. These include polyolefins (linear or branched), polyamides such as nylon, polyester copolymers, ionomers based on sodium or zinc salts of ethylene methacrylic acid, polyacrylonitriles, and ethylene-vinyl acetate copolymers. Included in this group are the acrylates such as ethylene methacrylic acid, ethylene methyl acrylate, ethylene acrylic acid and ethylene ethyl acrylate.
  • polymers and copolymers of olefin monomers having, for example, 2 to about 12 carbon atoms, and in one embodiment 2 to about 8 carbon atoms.
  • olefin monomers having, for example, 2 to about 12 carbon atoms, and in one embodiment 2 to about 8 carbon atoms.
  • These include the polymers of ⁇ -olefins having from 2 to about 4 carbon atoms per molecule.
  • These include polyethylene, polypropylene, poly-1-butene, etc.
  • An example of a copolymer within the above definition is a copolymer of ethylene with 1-butene having from about 1 to about 10 weight percent of the 1-butene comonomer incorporated into the copolymer molecule.
  • the polyolefins include amorphous polyolefins.
  • the polyethylenes that are useful have various densities including low, medium and high density ranges as defined above.
  • the ethylene/methyl acrylate copolymers available from Chevron under the tradename EMAC can be used. These include EMAC 2260, which has a methyl acrylate content of 24% by weight and a melt index of 2.0 grams/10 minutes @ 190° C., 2.16 Kg; and EMAC SP 2268T, which also has a methyl acrylate content of 24% by weight and a melt index of 10 grams/10 minutes @190° C., 2.16 Kg. Polymer film materials prepared from blends of copolymers or blends of copolymers with homopolymers are also useful.
  • the heat-activatable first adhesive layer 217 generally has a lower melting point than any of the other layers used in the laminates 200 , 200 A, 200 B, 200 C, 200 D, 200 E, 200 F, 200 G or 200 H to permit the layer 217 to function as a heat-activatable adhesive.
  • the melting point, as determined by differential scanning colorimetry at second heat cycle, of the heat-activatable adhesive layer 217 is in the range of about 50° C. to about 150° C., and in one embodiment about 70° C. to about 85° C.
  • the melting point of the heat-activatable adhesive layer 217 is typically at least about 10° C. lower than the melting point of the facestock 210 , and in one embodiment about 10° C.
  • the inventive laminate is to be bonded to a rough or porous substrate (e.g., a woven fabric) it is advantageous that the heat-activatable first adhesive layer 217 be relatively thick and that the difference between the melting point of the heat-activatable first adhesive layer 217 and the melting point of the facestock 210 be relatively high.
  • This provides the inventive heat-sealable laminate with the advantage of preventing or reducing the rough or porous surface of the substrate from showing through the laminate to provide a clear and precise pictorial design and/or print message rather than a fuzzy or out-of-focus looking image.
  • the facestock 210 and/or adhesive layer 217 may contain one or more slip additives.
  • slip additives include primary amides such as stearamide, behenamide, oleamide, erucamide, and the like; secondary amides such as stearyl erucamide, erucyl erucamide, oleyl palmitamide, stearyl stearamide, erucyl stearamide, and the like; ethylene bisamides such as N,N′-ethylenebisstearamide, N,N′-ethylenebisolemide and the like; and combinations of any two or more of the foregoing amides.
  • slip additive An example of a useful slip additive is available from Ampacet under the trade designation 10061; this product is identified as a concentrate containing 6% by weight of a stearamide slip additive.
  • the slip additive may be used at a concentration in the range of up to about 4% by weight, and in one embodiment about 0.05% to about 2% by weight, and in one embodiment about 0.1% to about 0.5% by weight.
  • the facestock 210 and/or adhesive layer 217 may contain one or more antiblock additives. These include natural silica, diatomaceous earth, synthetic silica, glass spheres, ceramic particles, calcium carbonate particles, calcium silicate particles, fatty amide particles, aluminum silicate, and the like. Examples of commercially available antiblock additives include those available from A. Schulman under the trade designation CABL 4040 which is identified as solid pellets containing 5% silicate, 5% ceramic microspheres and the remainder being a low density polyethylene. Schulman AB5, which is an antiblock concentrate available from A. Schulman which comprises 5% solid synthetic amorphous silica in 95% low density polyethylene, can also be used. Polybatch F-20, which is available from A.
  • the antiblock additive may be used at a concentration of up to about 20% by weight, and in one embodiment about 0.1% to about 10% by weight, and in one embodiment about 0.5% to about 5% by weight.
  • the antiblock and slip additives may be added together in the form of a resin concentrate.
  • a resin concentrate is available from DuPont under the tradename Elvax CE9619-1.
  • This resin concentrate contains 20% by weight silica, 7% by weight of an amide slip additive, and 73% by weight of Elvax 3170 (a product of DuPont identified as an ethylene/vinyl acetate copolymer having a vinyl acetate content of 18% by weight).
  • the amount of antiblock and slip additives may be the same or different in each layer. Generally it is desireable to minimize the amount of these additives to avoid ink adhesion and low heat seal bond problems. However, a sufficient amount to prevent blocking of self wound rolls of film is usually desirable.
  • the facestock 210 and/or adhesive layer 217 may contain a minor amount of an adhesive material to enhance the adhesion of the facestock 210 and adhesive layer 217 to each other. Also, or alternatively, a tie layer of an adhesive resin may be positioned between the facestock 210 and adhesive layer 217 to enhance adhesion.
  • the adhesive material may be comprised of an adhesive resin such as ethylene/vinyl acetate copolymer. These include DuPont Elvax 3170 and 3190LG. The adhesive resins available from DuPont under the tradename Bynel can also be used.
  • the adhesive material may be used at a concentration of up to about 100% by weight, and in one embodiment about 45% to about 85% by weight of the facestock 210 and/or adhesive layer 217 .
  • each of such adhesive resin film layer or layers may have a thickness of about 5% to about 40% of the thickness of the facestock 210 , and in one embodiment about 10% to about 25%.
  • the facestock 210 and/or adhesive layer 217 may contain ultraviolet (UV) light absorbers or other light stabilizers. These additives are included to prevent degradation due to sunlight.
  • UV light absorbers or other light stabilizers.
  • One useful type of stabilizer is a hindered amine light stabilizer. Hindered amine light stabilizers are described in the literature such as in U.S. Pat. No. 4,721,531, columns 4 to 9, which are incorporated herein by reference.
  • the hindered amine light stabilizers may, for example, be derivatives of 2,2,6,6-tetraalkyl piperidines or substituted piperizinediones.
  • Tinuvin 111 which is identified as a mixture of 1,3,5-Triazine-2,4,6-triamine, N,N′′′-[1,2-ethanediylbis[[[4,6-bis[butyl(1,2,2,6,6-pentamethyl-4-piperidinyl)amino]-1,3,5-triazin-2-yl]imino]-3,1propanediyl]]-bis[N′,N′′-dibutyl-N′,N′′-bis(1,2,2,6,6-pentamethyl-4-piperidinyl)-and dimethyl succinate polymer with 4-hydroxy-2,2,6,6,-tetramethyl-1-piperidineethanol; Tinuvin 123 which is
  • UV light absorbers include those available from Ciba-Geigy under the Tinuvin name and Great Lakes Chemical Corporation under the trade designation “Lowilite.” Examples include: Tinuvin P, which is identified as 2-(2′-hydroxy-5′-methylphenyl)-benzotriazole; Tinuvin 326, which is identified as 2-(3′-tert-butyl-2′-hydroxy-5′methylphenyl)-5-chlorobenzotriazole; Tinuvin 238, which is identified as 2-(2′hydroxy-3′,5′-di-tert-amylphenyl) benzotriazole; Lowilite 20, which is identified as 2-hydroxy-4-methoxy-benzophenone; Lowilite 22, which is identified as 2-hydroxy-4-n-octoxy-benzophenone; and Lowilite 1200, which is identified as 2-hydroxy-4-n-dodecyloxy-benzophenone.
  • a useful stabilizer is available under the tradename Ampacet 10561 which is a product of Ampacet identified as a UV stabilizer concentrate containing 20% by weight of a UV stabilizer and 80% by weight of a low density polyethylene carrier resin.
  • the concentration of UV absorber or light stabilizer may be up to about 2.5% by weight, and in one embodiment may be about 0.05% to about 1% by weight.
  • the facestock 210 and the adhesive layer 217 may be formed by simultaneous extrusion from two or more extruders and a suitable coextrusion die whereby the facestock 210 and adhesive layer 217 are adhered to each other in a permanently combined state to provide a unitary coextrudate.
  • a tie layer or layers of an adhesive resin may be used and such tie layer or layers may be coextruded with the facestock 210 and adhesive layer 217 .
  • a coating process may be used to lay down one or more of the layers of the facestock 210 as well as the adhesive layer 217 onto a moving web. These processes are well known in the art.
  • the ink or graphics layers 220 , 221 and/or 223 may be mono-colored or multi-colored ink layers, depending on the printed message and/or pictorial design intended for the heat-sealable laminate. These include variable imprinted data such as serial numbers, bar codes, and the like.
  • the thickness of each ink or graphics layer may range from about 0.5 to about 25 microns, and in one embodiment about 0.5 to about 10 microns, and in one embodiment about 0.5 to about 5 microns, and in one embodiment about 1 to about 4 microns, and in one embodiment about 3 microns.
  • the inks used in the ink or graphics layers 220 , 221 and/or 223 may be commercially available water-based, solvent-based or radiation-curable, especially UV curable, inks appropriately chosen for the particular construction of the thermal transfer laminate and/or the particular printing method used.
  • Examples include Sun Sheen (a product of Sun Chemical identified as an alcohol dilutable polyamide ink), Suntex MP (a product of Sun Chemical identified as a solvent-based ink formulated for surface printing acrylic coated substrates, PVDC coated substrates and polyolefin films), X-Cel (a product of Water Ink Technologies identified as a water-based film ink for printing film substrates), Uvilith AR-109 Rubine Red (a product of Daw Ink identified as a UV ink) and CLA91598F (a product of Sun Chemical identified as a multibond black solvent-based ink).
  • Sun Sheen a product of Sun Chemical identified as an alcohol dilutable polyamide ink
  • Suntex MP a product of Sun Chemical identified as a solvent-based ink formulated for surface printing acrylic coated substrates, PVDC coated substrates and polyolefin films
  • X-Cel a product of Water Ink Technologies identified as a water-based film ink for printing film substrates
  • the adhesion-promoting layer 250 which may be included with or excluded from the inventive laminate, is made from a radiation-curable, solvent-based or water-based primer.
  • the adhesion-promoting layer is positioned between two other layers (e.g., two coating layers, one coating layer and one film layer, etc.) and increases adhesion between the two layers.
  • the adhesion-promoting layer 250 may be transparent.
  • the material used to form the adhesion promoting layer is comprised of a lacquer dissolved in a diluent.
  • the lacquer is comprised of one or more polyolefins, polyamides, polyesters, polyester copolymers, polyurethanes, polysulfones, polyvinylidine chloride, styrene-maleic anhydride copolymers, styrene-acrylonitrile copolymers, ionomers based on sodium or zinc salts or ethylene methacrylic acid, polymethyl methacrylates, acrylic polymers and copolymers, polycarbonates, polyacrylonitriles, ethylene-vinyl acetate copolymers, and mixtures of two or more thereof.
  • diluents examples include ethanol, isopropanol, butanol, ethyl acetate, propyl acetate, butyl acetate, toluene, xylene, acetone, methyl ethyl ketone, heptane, and mixtures thereof.
  • the ratio of lacquer to diluent is dependent on the viscosity required for application of the adhesion-promoting layer, the selection of such viscosity being within the skill of the art.
  • adhesion-promoting layer materials examples include CLB04275F—Prokote Primer (a product of Sun Chemical Corporation identified as a solvent based primer).
  • the adhesion-promoting layer 250 may have thicknesses in the range of about 1 to about 4 microns, and in one embodiment about 1.5 to about 3 microns, and in one embodiment about 2 microns.
  • the abrasion-resistant transparent coating layer 260 which may be included with or excluded from the inventive laminate, may be made from any solvent-based, water-based or radiation-curable coating material designed to provide abrasion resistance and optionally enhanced gloss. In one embodiment, this coating layer reduces the bond strength of the second adhesive layer 230 which facilitates removal of the carrier sheet 240 . In one embodiment, this coating layer provides the inventive heat sealable laminate with fire retardant properties.
  • This coating layer may be made from UV curable oligomers such as epoxies, urethanes, polyesters, acrylics, and the like. These are cured by free-radicals generated by photoinitiators after exposure to UV light.
  • Reactive diluents such as hexanediol diacrylate, pentaerythritol, tetraacrylate, N-vinylpyrrolidinone, and the like, can be used to control viscosity of the coating before cure and to modify the crosslink density.
  • Epoxy resins and alkyl vinyl ethers, which are cationically cured, can also be used.
  • Reactive diluents such as vinyl ethers, limonene dioxide, glycidyl ether, and the like, can be used.
  • the coating may also contain wetting agents, leveling agents, waxes, slip aids, and light stabilizers.
  • a commercially available coating material that can be used is RCA01302R-UV Coating which is available from Sun Chemical.
  • Another commercially available coating material that can be used is FireCure AX 3464 which is available from Daw Ink.
  • This coating layer typically has a thickness of about 1 to about 4 microns, and in one embodiment about 1 to about 3 microns, and in one embodiment about 2 microns.
  • the adhesive layer 230 may be comprised of any removable pressure-sensitive adhesive material, or radiation-curable, especially UV curable, adhesive material suitable for coating a film substrate.
  • the adhesive layer 230 is a radiation-curable adhesive layer it is transparent.
  • the adhesive layer 230 is a removable pressure sensitive adhesive layer, it is preferably (but not necessarily) transparent.
  • the radiation-curable adhesive materials may be made from compositions containing multifunctional acrylate monomers and oligomers. Acrylated urethanes and acrylated acrylics are useful.
  • the radiation-curable adhesives may include photoinitiators and optionally surfactants to provide a uniform flow resulting in an even coating.
  • Rad-Cure UV 1008 (a product of Rad-Cure Corporation identified as a UV-curable, solvent-free adhesive containing 70-95% by weight multifunctional acrylate monomers and oligomers, 5-20% by weight photoinitiator and 0-5% by weight surfactants).
  • the removable pressure-sensitive adhesive can be any removable pressure sensitive adhesive known in the art for use with film substrates.
  • the term “removable” is used herein to refer to an adhesive that can adhere to the carrier sheet 240 and the layer underlying it without edge lifting and can be removed without damaging either sheet 240 or the underlying layer.
  • the removable adhesive layer 230 is preferentially adherent to carrier sheet 240 and thus separates from the layer underlying it with carrier sheet 240 when the carrier sheet 240 is removed.
  • the removable pressure-sensitive adhesives that can be used are known in the art and include rubber based adhesives, acrylic adhesives, vinyl ether adhesives, silicone adhesives, and mixtures of two or more thereof.
  • the adhesives may be hot melt, solvent-based or water based adhesives.
  • the pressure sensitive adhesive materials that are useful may contain as a major constituent an adhesive polymer such as acrylic-type polymers; block copolymers; natural, reclaimed, or styrene-butadiene rubbers; tackified natural or synthetic rubbers; or random copolymers of ethylene and vinyl acetate, ethylene-vinyl-acrylic terpolymers, polyisobutylene, poly (vinyl ether), etc.
  • Other materials may be included in the pressure sensitive adhesive such as tackifying resins, plasticizers, antioxidants, fillers, pigments, waxes, etc.
  • the adhesive layer 230 has a thickness that is typically in the range of about 0.5 to about 5 microns, and in one embodiment about 1 to about 4 microns, and in one embodiment about 1.5 to about 2 microns.
  • Each of the layers 220 , 221 , 223 , 230 , 250 and/or 260 may be applied and cured using known techniques.
  • the application techniques include gravure, reverse gravure, offset gravure, roll coating, brushing, knife-over roll, metering rod, reverse roll coating, doctor knife, dipping, die coating, spraying, curtain coating, flexographic, letter press, rotary screen, flat screen, and the like.
  • the applied coating layers may be cured by exposure to heat or to known forms of ionizing or actinic non-ionizing radiation. Curing temperatures that may be used may range from about 40° C. to about 260° C., and in one embodiment about 40° C.
  • Useful types of radiation include ultraviolet light, electron beam, x-ray, gamma-ray, beta-ray, etc. Ultraviolet light is especially useful.
  • the equipment for generating these forms of thermal cure or radiation cure are well known to those skilled in the art.
  • the transparent film layer 290 may be made from any of the polymeric film materials described above as being useful for making the facestock 210 . Polyolefin and especially polyester film materials are useful.
  • the transparent film layer 290 may have a thickness of about 0.25 to about 5 mils, and in one embodiment about 0.5 to about 10 mils, and in one embodiment about 0.5 to about 5 mils, and in one embodiment about 0.5 to about 2 mils, and in one embodiment about 1 mil.
  • the adhesive layer 280 may be comprised of any of the radiation curable or pressure sensitive adhesives described above. Pressure sensitive adhesives are especially useful.
  • the adhesive layer 280 may have a thickness of about 0.1 to about 3 mils, and in one embodiment about 0.3 to about 1.5 mils, and in one embodiment about 0.5 to about 1 mil.
  • the film layer 290 may be placed in contact with the adhesive layer 280 using known techniques.
  • the adhesive 280 is a radiation-curable adhesive
  • the film layer 290 may be placed in contact with the adhesive layer 280 prior to curing the adhesive layer.
  • the adhesive layer is then cured.
  • the adhesive layer 280 is pressure-sensitive adhesive, it may be initially applied to the film layer 290 and then the film layer 290 with applied adhesive is adhered to the layer underlying it. Alternatively, the pressure-sensitive adhesive may be applied to the underlying layer, and then the film layer 290 is placed in contact with the adhesive to adhere the film layer 290 to the underlying layer.
  • the carrier sheet 240 may be placed in contact with the adhesive layer 230 using known techniques.
  • the adhesive 230 is a radiation-curable adhesive
  • the carrier sheet 240 may be placed in contact with the adhesive layer 230 prior to curing the adhesive layer.
  • the adhesive layer is then cured.
  • the adhesive layer 230 is pressure-sensitive adhesive, it may be initially applied to the carrier sheet 240 , and then the carrier sheet with applied adhesive is adhered to the layer underlying it. Alternatively, the pressure-sensitive adhesive may be applied to the underlying layer, and then the carrier sheet 240 is placed in contact with the adhesive to adhere the carrier sheet 240 to the underlying layer.
  • the carrier sheet 240 may be comprised of paper, polymer film, or a combination thereof.
  • any of the paper or polymer films, or combinations thereof, discussed above as being useful as the facestock 210 may be used as the carrier sheet 240 . It is advantageous, however, that the carrier sheet 240 be transparent to permit visibility of the ink or graphics layers 220 , 221 and/or 223 through the carrier sheet 240 (as well as through the other layers positioned between the carrier sheet 240 and the ink or graphics layers 220 , 221 and/or 223 ).
  • the outer surface 245 of the carrier sheet 240 may have a release coating adhered to it to facilitate rolling and unrolling of the inventive heat-sealable laminate. Any release coating known in art may be used. Silicone release coatings are useful.
  • a commercially available polyester film that is useful as the carrier sheet 240 is Douglas Hanson E19506 (a product of Douglas Hanson identified as a clear polyester film having a release coating layer adhered to one side). Untreated polyester film can be used.
  • the carrier sheet 240 typically has a thickness of about 0.25 to about 10 mils, and in one embodiment about 0.5 to about 5 mils, and in one embodiment about 2 mils.
  • the carrier sheet 240 is a polyester film having a thickness of about 0.25 to about 10 mils.
  • the carrier sheet 240 is a polyolefin film having a thickness of about 0.5 to about 5 mils.
  • the carrier sheet 240 is a paper sheet having a thickness of about 1 to about 10 mils.
  • the inventive heat-sealable laminate may be adhered to any substrate using heat-sealing techniques known in the art.
  • the heat-sealable laminate 200 A is placed on substrate 300 with the surface 219 of heat-activatable adhesive layer 217 in contact with the substrate 300 .
  • Heat and pressure are applied to the laminate 200 A by a heated platen in contact with the carrier sheet 240 .
  • the heat passes through the laminate 200 A to the heat-activatable adhesive layer 217 and softens or melts the heat-activatable adhesive layer 217 .
  • the heat and pressure are removed, and the heat-activatable adhesive layer 217 cools and solidifies resulting in the formation of a heat-sealed bond between the laminate 200 A and the substrate 300 .
  • the heat and pressure that are applied are sufficient to soften or melt the heat-activatable adhesive layer 217 .
  • Temperatures in the range of about 100° C. to about 300° C., and in one embodiment about 150° C. to about 250° C., and in one embodiment about 180° C. to about 210° C. may be used.
  • Pressures in the range of about 2 to about 20 psi, and in one embodiment about 8 to about 12 psi may be used.
  • Dwell times of about 0.5 to about 60 seconds, and in one embodiment about 0.5 to 20 seconds, and in one embodiment about 0.5 to about 10 seconds may be used.
  • Any heat-sealing press used for heat-sealing labels tapes, decals, and the like to substrates may be used. These are well known in the art.
  • a plurality or an array of individual images 222 can be formed in the ink or graphics layer 220 of the heat-sealable laminate 200 A (or any of the other illustrated heat-sealable laminates).
  • the images 222 can be viewed from the top (as illustrated in FIG. 3) of the inventive heat-sealable laminate structure.
  • These individual images 222 can be die cut to form separate heat-sealable labels.
  • the substrate 300 may be any substrate material suitable for receiving a heat-sealable laminate.
  • the substrate 300 may be made of metal, plastic, leather, paper, and the like.
  • the substrate 300 may be made of a textile material such as a woven or non-woven fabric made of natural or synthetic materials.
  • the substrate 300 may comprise an automotive interior surface (e.g., seat belt, visor, dashboard, headrest, seat-back, door panel, headliner, carpet, flooring, seat cover, etc.), a hard plastic component part (e.g., appliance part, motor fluid cap, engine housing, etc.), a consumer durable good (e.g., helmet, vacuum cleaner, sports equipment, etc.), other identification system (e.g., livestock tag, lock box tag, etc.), and the like.
  • automotive interior surface e.g., seat belt, visor, dashboard, headrest, seat-back, door panel, headliner, carpet, flooring, seat cover, etc.
  • a hard plastic component part e.g., appliance part, motor fluid cap, engine
  • the carrier sheet 240 is removed using known removal or stripping techniques.
  • the adhesive layer 230 is a removable pressure-sensitive adhesive, it is removed using known techniques. This is illustrated in FIG. 12 .
  • the adhesive layer 230 is a radiation-cured adhesive layer, it remains adhered to the layer underlying it and functions as an additional protective layer.
  • Heat-sealable laminate 200 A (FIG. 3) is prepared using a coextruded polymeric film as the facestock 210 .
  • the facestock 210 has a thermoplastic core layer and an upper thermoplastic film layer adhered to upper surface of the core layer.
  • Heat-activable first adhesive layer 217 is coextruded with the facestock 210 and is adhered to lower surface of the core layer.
  • the overall thickness of the facestock 210 and the adhesive layer 217 is 3.5 mils.
  • the ratio of the thicknesses of the upper thermoplastic film layer to the core layer to the heat-activable first adhesive film layer is 10:60:30.
  • the core layer has the following composition (all percentages being by weight):
  • the upper thermoplastic film layer has the following composition:
  • the heat-activatable first adhesive layer 217 has the following composition:
  • the upper surface of the upper thermoplastic film layer is corona treated.
  • a multi-colored ink or graphics layer 220 providing a pictorial design in combination with a printed message is applied over the corona treated upper surface.
  • the layer 220 is applied using a sequence of three anilox rolls. The following inks are used:
  • Roll 1 Yellow 116 ink (a UV curable ink provided by Daw Ink)
  • Roll 2 Red 186 ink (a UV curable ink provided by Daw Ink)
  • Roll 3 Black ink (a UV curable black ink provided by Werneke Ink)
  • the layer 220 has a thickness of 3 microns.
  • An adhesive layer 230 is applied over the layer 220 using an anilox roll.
  • the adhesive layer material is Rad-Cure UV 1008.
  • the adhesive layer 230 has a thickness of 2 microns.
  • a polyester film carrier sheet 240 having a thickness of 2 mils is adhered to the adhesive layer 230 .
  • the adhesive layer 230 is then UV cured to complete the fabrication of the heat-sealable laminate 200 A.
  • the polyester film that is used is provided by Douglas Hanson under the trade designation E 19506. This is a polyester film having a release coating layer on one of its sides.
  • the underside 246 of the polyester film carrier sheet 240 is in contact with the UV-cured adhesive layer 230 .
  • the upper surface 245 of carrier sheet 240 is the side with the release coating.
  • Each ink application as well as the UV cured adhesive layer are cured using a medium pressure mercury bulb, an arc length of 45 cm, 500 watts per inch, a dichromatic reflector and a line speed of 65 feet per minute.
  • the ink applications are cured using 50% power.
  • the adhesive layer is cured using 100% power.
  • the heat-sealable laminate 200 A from Part A is placed on a substrate 300 .
  • the substrate 300 is a foam-backed polyester upholstery material used for automotive interiors.
  • the heat-activatable first adhesive layer 217 is in contact with the substrate 300 .
  • the resulting composite is placed in a heated press. Heat and pressure are applied to the composite by a heated platen in contact with the polyester film carrier sheet 240 .
  • the temperature is 196° C. and the pressure is 9.1 psi.
  • the dwell time is 2.5 seconds.
  • the heat and pressure are sufficient to soften or melt the heat-activatable adhesive layer 217 .
  • the heat-activatable adhesive layer 217 forms a bond adhering the heat-sealable laminate 200 A to the substrate 300 .
  • the composite is removed from the press with the result being the heat-sealable laminate 200 A being heat-sealed to the substrate 300 .
  • the polyester film carrier sheet 240 is removed leaving the remainder of the laminate 200 A adhered to the substrate 300 .
  • the multi-colored pictorial design formed in the ink or graphics layer 220 is visible.
  • Heat-sealable laminate 200 B (FIG. 4) is prepared using the facestock 210 used in Example 1.
  • the upper surface of the upper thermoplastic film layer is corona treated.
  • An adhesion promoting layer 250 is applied to the corona treated upper surface using an anilox roll.
  • the adhesion promoting material is CLBO-4275F—Prokote Primer.
  • the adhesion promoting material is cured in an oven at a temperature of 40-50° C.
  • Adhesion promoting layer 250 has a thickness of 2 microns.
  • a multi-colored ink or graphics layer 220 providing a pictorial design in combination with a printed message is applied over the adhesion promoting layer 250 .
  • the ink or graphics layer 220 is applied using a sequence of three anilox rolls. The following inks are used:
  • Roll 1 Yellow 116 ink (a UV curable ink provided by Daw Ink)
  • Roll 2 Red 186 ink (a UV curable ink provided by Daw Ink)
  • Roll 3 Black ink (a UV curable black ink provided by Werneke Ink)
  • the ink or graphics layer 220 has a thickness of 3 microns.
  • An adhesive layer 230 is applied over the ink or graphics layer 220 using an anilox roll.
  • the adhesive layer material is Rad-Cure UV 1008.
  • the adhesive layer 230 has a thickness of 2 microns.
  • the polyester film carrier sheet 240 used in Example 1 is adhered to the adhesive layer.
  • the adhesive layer 230 is then UV cured.
  • the side 246 of the polyester film 240 opposite the side 245 with the release coating layer is in contact with the UV-cured adhesive layer 230 .
  • Each ink application as well as the adhesion promoting layer and the UV cured adhesive layer are cured using a medium pressure mercury bulb, an arc length of 45 cm, 500 watts per inch, a dichromatic reflector and a line speed of 65 feet per minute.
  • the ink applications and the adhesion promoting layer are cured using 50% power.
  • the adhesive layer is cured using 100% power.
  • the heat-sealable laminate 200 B from Part A is adhered to a substrate 300 .
  • the substrate is a seat belt material designed for use in automotives.
  • the laminate 200 B is applied to the substrate 300 following the procedure described in Part B of Example 1 with the result being the heat sealing of the laminate 200 B to the seat belt material.
  • the polyester film carrier sheet 240 is removed leaving the remainder of the laminate 200 B adhered to the seat belt material.
  • the multi-colored pictorial design formed in the ink or graphics layer 220 is visible.
  • Heat-sealable laminate 200 C (FIG. 5) is prepared using the facestock 210 used in Example 1.
  • the upper surface of the upper thermoplastic film layer is corona treated.
  • a multi-colored ink or graphics layer 220 providing a pictorial design in combination with a printed message is applied over the corona treated surface.
  • the ink or graphics layer 220 is applied using a sequence of three anilox rolls. The following inks are used:
  • Roll 1 Yellow 116 ink (a UV curable ink provided by Daw Ink)
  • Roll 2 Red 186 ink (a UV curable ink provided by Daw Ink)
  • Roll 3 Black ink (a UV curable black ink provided by Werneke Ink)
  • the ink or graphics layer 220 has a thickness of 3 microns.
  • An abrasion-resistant transparent coating layer 260 is applied over the ink or graphics layer 220 using an anilox roll.
  • the abrasion-resistant transparent coating layer material is RCA01302R-UV Coating.
  • the abrasion-resistant transparent coating layer 260 has a thickness of 2 microns and is UV cured.
  • An adhesive layer 230 is applied over the abrasion-resistant transparent coating layer 260 using an anilox roll.
  • the adhesive layer material is Rad-Cure UV 1008.
  • the adhesive layer 230 has a thickness of 2 microns.
  • the polyester film carrier sheet 240 used in Example 1 is adhered to the adhesive layer 230 .
  • the adhesive layer is then UV cured.
  • the side 246 of the polyester film 240 is in contact with the UV-cured adhesive layer 230 .
  • the other side of the polyester film has the release coating adhered to its surface.
  • Each ink application as well as the abrasion-resistant transparent coating layer, and the UV cured adhesive layer are cured using a medium pressure mercury bulb, an arc length of 45 cm, 500 watts per inch, a dichromatic reflector and a line speed of 65 feet per minute.
  • the ink applications and abrasion-resistant transparent coating layer are cured using 50% power
  • the adhesive layer is cured using 100% power.
  • the heat-sealable laminate 200 C from Part A is adhered to a hard plastic surface following the procedure described in Part B of Example 1 with the result being the heat sealing of the laminate 200 C to the hard plastic surface.
  • the polyester film carrier sheet 240 is removed leaving the remainder of the laminate 200 C adhered to the hard plastic surface.
  • the multi-colored pictorial design formed in the ink or graphics layer 220 is visible
  • the inventive heat-sealable laminates have a number of advantages over the prior art. These include the fact that in embodiments wherein the carrier sheet 240 is transparent, the ink or graphics layer can be seen during application of the laminate to a substrate. This feature allows for precise placement of the ink or graphics layer on the substrate. Because of the presence of the facestock 210 , the ink or graphics layers 220 , 221 and/or 223 as applied to the substrate 300 do not conform to minor surface contours or imperfections in the substrate 300 . Thus, the pictorial design and/or print message provided by the ink or graphics layer 220 , 221 and/or 223 is clear and precise, and has good opacity characteristics. Once applied to the substrate 300 , the ink or graphics layers 220 , 221 and/or 223 of the inventive heat-sealable laminate, in one embodiment, are protected and thus have good chemical resistance characteristics and durability.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Theoretical Computer Science (AREA)
  • Laminated Bodies (AREA)
  • Wrappers (AREA)
US09/758,092 2001-01-10 2001-01-10 Heat-sealable laminate Expired - Lifetime US6756095B2 (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
US09/758,092 US6756095B2 (en) 2001-01-10 2001-01-10 Heat-sealable laminate
MXPA03006203A MXPA03006203A (es) 2001-01-10 2001-12-18 Laminado termosellable.
CA2433664A CA2433664C (en) 2001-01-10 2001-12-18 Heat-sealable laminate
DE60141712T DE60141712D1 (de) 2001-01-10 2001-12-18 Heissversiegelbares laminat
AT01991303T ATE462562T1 (de) 2001-01-10 2001-12-18 Heissversiegelbares laminat
PCT/US2001/049084 WO2002055295A1 (en) 2001-01-10 2001-12-18 Heat-sealable laminate
EP01991303A EP1358066B1 (en) 2001-01-10 2001-12-18 Heat-sealable laminate
JP2002556004A JP2004524993A (ja) 2001-01-10 2001-12-18 熱融着可能積層体

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/758,092 US6756095B2 (en) 2001-01-10 2001-01-10 Heat-sealable laminate

Publications (2)

Publication Number Publication Date
US20020127361A1 US20020127361A1 (en) 2002-09-12
US6756095B2 true US6756095B2 (en) 2004-06-29

Family

ID=25050454

Family Applications (1)

Application Number Title Priority Date Filing Date
US09/758,092 Expired - Lifetime US6756095B2 (en) 2001-01-10 2001-01-10 Heat-sealable laminate

Country Status (8)

Country Link
US (1) US6756095B2 (ja)
EP (1) EP1358066B1 (ja)
JP (1) JP2004524993A (ja)
AT (1) ATE462562T1 (ja)
CA (1) CA2433664C (ja)
DE (1) DE60141712D1 (ja)
MX (1) MXPA03006203A (ja)
WO (1) WO2002055295A1 (ja)

Cited By (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20010051248A1 (en) * 1999-02-16 2001-12-13 Jerdee Gary D. Polymeric based carpet
US20030134114A1 (en) * 2001-12-20 2003-07-17 The Procter & Gamble Company Articles and methods for applying color on surfaces
US20040026024A1 (en) * 2002-05-22 2004-02-12 Ikuo Nakasaka Label affixing method and apparatus
US20040161568A1 (en) * 2003-02-14 2004-08-19 Truog Keith L. Dry paint transfer laminate for use as wall covering
US20040217022A1 (en) * 2003-05-01 2004-11-04 Irvine Alexander J. Flag label
US20040245138A1 (en) * 2001-10-15 2004-12-09 Tapani Penttinen Package lid, method for manufacturing the same and package sealed with the lid
US20040247884A1 (en) * 2001-06-28 2004-12-09 Keeney Sean M. Cut and stack lables of laminated film
US20040247837A1 (en) * 2003-06-09 2004-12-09 Howard Enlow Multilayer film
US20050008809A1 (en) * 2001-10-05 2005-01-13 Dale Miller In-mold labeling method and labeled products
US20060028014A1 (en) * 2004-05-14 2006-02-09 Impaq, Inc. Peel-off label and methods of utilizing the same
US20060246282A1 (en) * 2003-08-15 2006-11-02 Nicolai Bohm Two-side self-adhesive tape whose sides have different adhesive force in particular for removably sticking flexible compact discs to curved surfaces
US20060263595A1 (en) * 2001-12-21 2006-11-23 Tesa Aktiengesellschaft Self-adhesive labels, their production and use
US7281360B1 (en) * 2005-02-11 2007-10-16 Bryce Corporation Thermal laminates and laminating method of food packaging films
US20080017301A1 (en) * 2006-06-29 2008-01-24 3M Innovative Properties Company Transfer films for graphic substrates
US7361403B1 (en) * 2002-10-18 2008-04-22 Lowe Clifford A Multilayer graphic systems
US20080220227A1 (en) * 2006-05-30 2008-09-11 Keeney Cecil M Coated printing stock for use as labels and the like
US20100051706A1 (en) * 2008-09-03 2010-03-04 James Harrison Pagones Sealed cards and methods of producing the same
US7727607B2 (en) 2003-06-09 2010-06-01 The Procter & Gamble Company Multi-layer dry paint decorative laminate having discoloration prevention barrier
US7842364B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7897228B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
US20110070409A1 (en) * 2008-07-25 2011-03-24 Kanji Nishimaki Fabric for marking and method of forming mark with the same
CN102111970A (zh) * 2009-12-28 2011-06-29 深圳富泰宏精密工业有限公司 电子装置壳体及其制作方法
WO2011093958A1 (en) 2010-01-28 2011-08-04 Avery Dennison Corporation Method and systems for applying heat transfer labels
US20110203943A1 (en) * 2010-02-24 2011-08-25 Perry David J Printed sorbents
US20110304132A1 (en) * 2001-06-28 2011-12-15 Keeney Sean M Cut and stack labels of laminated film
US20110311701A1 (en) * 2010-06-22 2011-12-22 William James Lewis Rigid durable non-metallic release laminate for oven cooking and oven containing same
US20130123678A1 (en) * 2009-04-27 2013-05-16 Avery Dennison Corporation Disruptable Adhesive Layer for Fluid Activated Debonding
US8458941B2 (en) 2010-04-20 2013-06-11 Moore Wallace North America, Inc. Shipment labels and related methods
US8563122B1 (en) 2006-12-01 2013-10-22 Design Imaging, Llc Thermoplastic architectural composite laminate materials and associated methods of manufacture
WO2014074766A1 (en) 2012-11-08 2014-05-15 Avery Dennison Corporation Systems, methods, and media for labeling three dimensional surfaces
US20150111453A1 (en) * 2013-10-22 2015-04-23 GM Global Technology Operations LLC Wet pu + gf headliner substrate with acoustic function
US9221573B2 (en) 2010-01-28 2015-12-29 Avery Dennison Corporation Label applicator belt system
US20160232821A1 (en) * 2015-02-05 2016-08-11 Avery Dennison Corporation Label Assemblies for Adverse Environments
US9708509B2 (en) 2012-10-09 2017-07-18 Avery Dennison Corporation Adhesives and related methods
US9926470B2 (en) 2012-10-22 2018-03-27 Avery Dennison Corporation Hybrid material of crosslinked microgel particles dispersed in an adhesive
US10526511B2 (en) 2016-12-22 2020-01-07 Avery Dennison Corporation Convertible pressure sensitive adhesives comprising urethane (meth)acrylate oligomers
US10625915B2 (en) 2008-01-21 2020-04-21 Cpi Card Group—Minnesota, Inc. Ultrasecure card package
US11466180B2 (en) 2017-05-08 2022-10-11 Avery Dennison Corporation Vulcanization tire label

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6758000B2 (en) 2001-01-10 2004-07-06 Avery Dennison Corporation Livestock security tag assembly
JP2003200547A (ja) * 2001-10-26 2003-07-15 Sanwa Leather:Kk 装飾模様を有する皮革等の布帛製品とその製造方法
US6709993B2 (en) * 2001-11-21 2004-03-23 Milliken & Company Camouflage
US20060062955A1 (en) 2003-08-14 2006-03-23 Wen-Feng Liu Self-adhesive laminate and method of making it
US7874022B2 (en) * 2003-11-12 2011-01-25 Mcqueer Pamela S Protective athletic garment
US8464362B2 (en) * 2004-08-13 2013-06-18 Mine Safety Appliances Company Protective helmets and method of manufacture thereof
WO2007095684A1 (en) * 2006-02-24 2007-08-30 Drover's Ay-One Pty. Ltd. Animal identification tag and method of manufacturing same
DE202006011724U1 (de) * 2006-07-31 2007-12-06 Schaefer, Philipp Fahrzeugsitz
US20090033495A1 (en) * 2007-08-03 2009-02-05 Akash Abraham Moldable radio frequency identification device
US20110000970A1 (en) * 2007-08-03 2011-01-06 Avery Dennison Corporation Encapsulated rfid label, and related methods
EP2185663B1 (en) * 2007-09-06 2012-02-29 UPM Raflatac Oy A method for manufacturing a label laminate
CN101457128A (zh) * 2007-12-14 2009-06-17 3M创新有限公司 复合高温胶带及其制造方法
EP2460640B1 (en) 2008-05-05 2014-08-27 A. Schulman, Inc. Multilayer clear over color polyolefin sheets and layered backing structure
DE102009031877A1 (de) 2008-12-23 2010-07-01 Giesecke & Devrient Gmbh Sicherheitselement mit verbessertem Heißsiegelklebstoff
WO2010099290A2 (en) * 2009-02-25 2010-09-02 Avery Dennison Corporation Method for making multi-layer print media by extrusion coating
JP5598793B2 (ja) * 2009-08-26 2014-10-01 貫太郎 野村 織物シール、絹織物シール、及びその製造方法
US9134202B2 (en) 2012-01-26 2015-09-15 Cryoxtract Instruments, Llc Robotic end effector for frozen aliquotter and methods of taking a frozen aliquot from biological samples
MX346688B (es) * 2012-02-20 2017-03-29 Avery Dennison Corp Película multicapa para sistemas multifuncionales de inyección de tinta.
DE102012019543A1 (de) * 2012-08-27 2014-02-27 Trautwein Gmbh & Co. Siegel
KR101347977B1 (ko) * 2012-11-14 2014-01-22 도레이첨단소재 주식회사 후면전극형 태양전지용 백시트 및 그 제조방법
WO2014189649A1 (en) 2013-04-26 2014-11-27 Avery Dennison Corporation Apparatus for dispensing pressure sensitive adhesive labels onto a substrate
EP2804169B1 (de) * 2013-05-16 2016-04-20 S+P Samson GmbH Etikett zum Kennzeichnen von Gegenständen und Herstellungsverfahren
JP6377330B2 (ja) * 2013-09-27 2018-08-22 株式会社フジシール ラベラー用ラベル保持体及びその製造方法
WO2015061267A1 (en) * 2013-10-21 2015-04-30 Avery Dennison Corporation Label assembly and method of dispensing low-stiffness labels
WO2015073104A1 (en) * 2013-11-13 2015-05-21 Air Raid Enterprises, LLC Protective helmet wrap and related method of applying wrap to a protective helmet
WO2015118210A1 (en) * 2014-02-10 2015-08-13 Upm Raflatac Oy Washable label, method and apparatus for preparing said label
CN105980153A (zh) * 2014-02-10 2016-09-28 Upm拉弗拉塔克公司 无内衬可洗涤标签、设备和用于制备标签的方法
DE202015000057U1 (de) 2015-01-13 2016-01-25 S+P Samson Gmbh Etikett zum Kennzeichnen von Gegenständen
US10926520B2 (en) * 2015-02-27 2021-02-23 The Boeing Company Fire-resistant, gas permeable decorative laminate
WO2016170229A1 (en) 2015-04-20 2016-10-27 Kotkamills Group Oyj Method and system for manufacturing a coated paperboard and a coated paperboard
WO2016183369A1 (en) 2015-05-12 2016-11-17 Nulabel Technologies, Inc. Thin film adhesive labels and methods of making thereof
US10325528B2 (en) * 2015-05-28 2019-06-18 Multi-Color Corporation Pressure-sensitive label
US11798437B2 (en) 2015-05-28 2023-10-24 Multi-Color Corporation Pressure-sensitive label
US11430354B2 (en) 2016-04-21 2022-08-30 F.D. Signworks, Llc Photoluminescent identifier system for firefighting equipment
US10074295B2 (en) * 2016-04-21 2018-09-11 F. D. Signworks, LLC Photoluminescent identifier system for firefighting equipment
KR102546280B1 (ko) * 2016-07-22 2023-06-23 삼성디스플레이 주식회사 아크릴계 점착제 및 이를 포함하는 보호 필름
US20190134964A1 (en) * 2017-11-06 2019-05-09 1508235 Ontario Inc. No-Bake Centre Label for Use in Vinyl Record Manufacturing
DE102019208734A1 (de) * 2019-06-14 2020-12-17 Adidas Ag Abriebfestes Material und Herstellungsverfahren

Citations (134)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2862832A (en) 1956-01-09 1958-12-02 Dennison Mfg Co Heat transfer
US2882599A (en) 1957-05-16 1959-04-21 Arthur L Martin Device for taking clippings from magazines or the like
US2990311A (en) 1956-01-09 1961-06-27 Dennison Mfg Co Heat transfer
US3043732A (en) 1957-01-02 1962-07-10 Dennison Mfg Co Top label surprinting
US3108850A (en) 1960-11-23 1963-10-29 American Can Co Labeling of blown plastic containers
US3207822A (en) 1962-08-06 1965-09-21 American Can Co Method of decorating plastic objects
US3231419A (en) 1962-07-02 1966-01-25 Johnson & Johnson Method of making a cured tacky and pressure-sensitive adhesive tape
US3239478A (en) 1963-06-26 1966-03-08 Shell Oil Co Block copolymer adhesive compositions and articles prepared therefrom
US3380868A (en) 1963-11-19 1968-04-30 Nat Distillers Chem Corp Method for producing and orienting polypropylene films
US3484976A (en) 1968-05-28 1969-12-23 John C Shea Liquor bottle registering means and method
US3503826A (en) 1967-01-18 1970-03-31 Erca Process for labelling hollow objects
US3616015A (en) 1969-08-11 1971-10-26 Dennison Mfg Co Clear heat transfer and method of applying the same
US3625752A (en) 1969-10-07 1971-12-07 Johnson & Johnson Precured adhesive tape
US3676202A (en) 1969-10-07 1972-07-11 Johnson & Johnson Pressure-sensitive adhesive tape
US3723170A (en) 1969-12-05 1973-03-27 Johnson & Johnson Pressure-sensitive adhesive tape
US3733002A (en) 1970-10-12 1973-05-15 M Fujio Sealed container
US3758661A (en) 1970-12-24 1973-09-11 Sekisui Chemical Co Ltd Process for producing a synthetic paper
US3783072A (en) 1971-11-02 1974-01-01 Johnson & Johnson Extrusion process for pressure-sensitive adhesive sheets and tapes
US3932328A (en) 1971-11-02 1976-01-13 Johnson & Johnson Hot melt adhesive composition and tape
US3940001A (en) 1972-10-06 1976-02-24 Ethyl Corporation Recyclable plastic containers
US3959908A (en) 1973-12-27 1976-06-01 Lowe Robert R Livestock identification tag
US4028292A (en) 1974-05-23 1977-06-07 Johnson & Johnson Hot melt adhesive
US4081309A (en) 1971-06-23 1978-03-28 Monarch Marking Systems, Inc. Method of making a composite label web
US4137081A (en) 1975-11-05 1979-01-30 Hercules Incorporated Printing plates from polymer with terminal unsaturation
US4174218A (en) 1975-11-05 1979-11-13 Hercules Incorporated Relief plates from polymer with terminal unsaturation
US4175460A (en) 1978-03-27 1979-11-27 Mcphail John D Felt, belt, and fabric trimmer
US4228232A (en) 1979-02-27 1980-10-14 Minnesota Mining And Manufacturing Company Photopolymerizable composition containing ethylenically unsaturated oligomers
US4355967A (en) 1980-09-30 1982-10-26 The Continental Group, Inc. Label applying device
US4359314A (en) 1980-09-30 1982-11-16 The Continental Group, Inc. Transfer device for applying labels to blow molds
US4377616A (en) 1981-12-30 1983-03-22 Mobil Oil Corporation Lustrous satin appearing, opaque film compositions and method of preparing same
USD269154S (en) 1981-05-07 1983-05-31 Freedman Melvin S Cutting tool
US4393115A (en) 1980-07-22 1983-07-12 Toray Industries Multilayered polypropylene film
US4398985A (en) 1980-02-08 1983-08-16 Kimberly-Clark Corporation Releasable, self-detackifying laminate construction
US4406411A (en) 1979-09-10 1983-09-27 Ford Motor Company Reclamation and rejuvenation of plastic and metal from metallized plastic
US4426422A (en) 1977-04-13 1984-01-17 Dennison Manufacturing Company Distortion and chemically resistant heat transfer materials
US4456934A (en) 1982-05-10 1984-06-26 Kollmorgen Technologies Corporation Linear positioning system
US4479770A (en) 1982-12-08 1984-10-30 Plastipak Packaging, Inc. In-mold label dispenser for blow molding machine
US4479771A (en) 1983-10-20 1984-10-30 Plastipak Packaging, Inc. In-mold label dispenser for multiple cavity blow molding machine
US4501798A (en) 1983-05-05 1985-02-26 American Can Company Unbalanced oriented multiple layer film
US4501797A (en) 1982-12-01 1985-02-26 American Can Company Unbalanced oriented multiple layer film
US4528221A (en) 1982-05-11 1985-07-09 Sekisui Kaseihin Kogyo Kabushiki Kaisha Polystyrene foamed sheet suitable for forming
US4528055A (en) 1982-12-17 1985-07-09 Graphic Resources, Inc. Method of manufacturing an elongated label supply
US4544590A (en) 1982-03-17 1985-10-01 Miller Products, Inc. Laminated member and method of making same
US4567681A (en) 1983-11-28 1986-02-04 Owens-Illinois, Inc. Container with plastic label
US4582752A (en) 1985-07-11 1986-04-15 Mobil Oil Corporation Heat shrinkable, lustrous satin appearing, opaque film compositions
US4590020A (en) 1983-03-23 1986-05-20 Toa Nenryo Kogyo Kabushiki Kaisha Method of producing oriented polyethylene film
US4599253A (en) 1981-09-14 1986-07-08 The D. L. Auld Company Method for making decorative emblems and the like and shapes prepared by that method
US4601926A (en) 1985-01-24 1986-07-22 Owens-Illinois, Inc. Process for applying copolyester barrier layer on polyester container
US4616992A (en) 1985-06-12 1986-10-14 Y Technipak Corp. Shuttle-type blow molding machine with in-mold labeling
US4626455A (en) 1985-01-14 1986-12-02 Owens-Illinois, Inc. Coextruded multilayer sheet and sleeve label for bottles
US4639207A (en) 1982-12-08 1987-01-27 Plastipak Packaging, Inc. In-mold label dispenser for blow molding machine
US4704323A (en) 1987-01-07 1987-11-03 Mobil Oil Corporation Resin film laminate
US4704310A (en) 1986-08-25 1987-11-03 Dennison Manufacturing Company Heat transferable laminate
US4710338A (en) 1984-12-18 1987-12-01 Peerless Plastics Packaging Limited Method of manufacturing a molded plastics article incorporating a blank of sheet
US4713273A (en) 1985-02-05 1987-12-15 Avery International Corporation Composite facestocks and liners
US4720416A (en) 1987-03-09 1988-01-19 Mobil Oil Corporation Pressure sensitive label stock material possessing a wrinkle-resistant lustrous, opaque laminate film facing
US4721531A (en) 1986-07-08 1988-01-26 Plasticolors, Inc. Pigment dispersions exhibiting improved compatibility in polyurethane systems
US4721638A (en) 1984-10-01 1988-01-26 Daimatsu Kagaku Kogyo Co., Ltd. Sticking material for preventing resticking
US4729864A (en) 1987-01-28 1988-03-08 Owens-Illinois Plastic Products Inc. In-mold labeling of plastic containers
US4737098A (en) 1986-04-11 1988-04-12 Technipack Corporation In-mold labeling apparatus
US4746556A (en) 1985-03-28 1988-05-24 Daimatsu Kagaku Kogyo Co., Ltd. Easily breakable sticking material
US4758396A (en) 1985-09-14 1988-07-19 Hoechst Aktiengesellschaft Process for the preparation of a biaxially oriented polypropylene film
US4762737A (en) 1985-05-07 1988-08-09 Mobil Oil Corporation Multi-layer non-corrosive plastic film
GB2201681A (en) 1987-03-06 1988-09-07 Swift Adhesives Ltd Heat and pressure activated adhesive compositions
US4794284A (en) 1987-03-26 1988-12-27 Georges Buon Linear D.C. motor with non-ferrous stator core
US4808366A (en) 1987-10-01 1989-02-28 Owens-Illinois Plastic Products Inc. In-mold labeling of injection blow molded hollow plastic articles
US4824912A (en) 1987-08-31 1989-04-25 Mobil Oil Corporation Terblends and films of LLDPE, LMW-HDPE and HMW-HDPE
US4834641A (en) 1987-12-23 1989-05-30 Liquid Container Corporation Apparatus for in-mold labeling of a blow molded article
US4837075A (en) 1986-07-14 1989-06-06 The Dow Chemical Company Coextruded plastic film label for in-mold labeling
US4837088A (en) 1985-02-05 1989-06-06 Avery International Corporation Coextruded core laminates
US4855187A (en) 1988-05-06 1989-08-08 Mobil Oil Corporation Low coefficient of friction biaxially oriented film
US4863772A (en) 1985-11-26 1989-09-05 Avery International Corporation Label stock with dry separation interface
US4870122A (en) 1987-09-28 1989-09-26 Mobil Oil Corporation HdPE films with imbalanced biaxial orientation
US4872707A (en) 1984-03-09 1989-10-10 Grand Rapids Label Company Label or ticket
US4873088A (en) 1983-09-06 1989-10-10 Liposome Technology, Inc. Liposome drug delivery method and composition
US4883697A (en) 1986-07-23 1989-11-28 The Procter & Gamble Company Thermoplastic in-mold labeling label structure for deformable thermoplastic packages
US4886698A (en) 1985-05-24 1989-12-12 Imperial Chemical Industries Plc Multiple-layer polyolefin films
US4892689A (en) 1987-07-14 1990-01-09 Agfa-Gevaert N.V. Process for making curled photographic film
US4892779A (en) 1988-03-18 1990-01-09 Ppg Industries, Inc. Multilayer article of microporous and substantially nonporous materials
US4894259A (en) * 1986-08-29 1990-01-16 Minnesota Mining And Manufacturing Company Process of making a unified pressure-sensitive adhesive tape
US4904324A (en) 1986-12-29 1990-02-27 Owens-Illinois Plastic Products Inc. Method of making plastic container with multilayer label applied by in-mold labeling
US4916025A (en) 1987-09-28 1990-04-10 Mobil Oil Corporation HDPE films with imbalanced biaxial orientation
US4917592A (en) 1988-03-31 1990-04-17 Owens-Illinois Plastic Products, Inc. Apparatus for applying labels to blow molded articles
US4925714A (en) 1985-02-05 1990-05-15 Avery International Corporation Coextruded core laminates
US4935300A (en) 1988-04-13 1990-06-19 Dennison Manufacturing Company Heat transferable laminate
US4946532A (en) 1985-02-05 1990-08-07 Avery International Corporation Composite facestocks and liners
US4953313A (en) 1988-04-19 1990-09-04 Allflex New Zealand Limited Ear tag for animals
US4983348A (en) 1986-10-29 1991-01-08 Wheaton Industries In-mold labeling of injection blow molded products
US4986866A (en) 1989-12-15 1991-01-22 Oji Yuka Goseishi Co., Ltd. Process for producing synthetic label paper
US5019436A (en) 1988-09-19 1991-05-28 Schramer Kurt M Label assembly and method of manufacturing
US5026592A (en) 1987-12-23 1991-06-25 Hoechst Aktiengesellschaft Opaque multilayered film having an inherent resistance to delamination
US5026266A (en) 1988-12-16 1991-06-25 Toppan Publishing Co., Ltd. Label feeder for a mold for plastics moldings
US5032344A (en) 1989-10-05 1991-07-16 Owens-Illinois Plastic Products Inc. Method for applying labels in the molds of a plastic blow molding machine
US5042842A (en) 1990-06-26 1991-08-27 Avery International Corporation High security label
US5073435A (en) 1986-12-23 1991-12-17 Rhone-Poulenc Chimie Composite polyester films
US5075583A (en) 1989-04-28 1991-12-24 Toyota Shatai Kabushiki Kaisha Brushless DC linear motor
US5076977A (en) 1990-01-10 1991-12-31 Eastman Kodak Company Process for controlling curl in polyester film
US5079057A (en) 1986-12-29 1992-01-07 Owens-Illinois Plastic Products Inc. Plastic container with multilayer label applied by in-mold labeling
CA2044079A1 (en) 1990-09-14 1992-03-15 Bruce G. Stokes Extrusion coated synthetic printing paper for in-mold label coupon applications
US5104719A (en) * 1989-08-30 1992-04-14 Revlon, Inc. Heat activated, quick release decals and associated methods
US5126197A (en) 1989-10-26 1992-06-30 Wolff Walsrode Ag Heat-laminatable, high-gloss multilayer films
US5152946A (en) 1991-01-30 1992-10-06 Hercules Incorporated Producing low shrink packaging film
US5186782A (en) 1990-10-17 1993-02-16 Avery Dennison Corporation Method for high speed labelling of deformable substrates
US5223346A (en) 1991-10-23 1993-06-29 Mobil Oil Corporation Hdpe/polypropylene film laminates
US5223315A (en) 1988-04-06 1993-06-29 Toyo Seikan Kaisha Ltd. Container equipped with label and production method thereof
US5242650A (en) 1991-09-09 1993-09-07 Avery Dennison Corporation In-mold labelling a coextruded, stretched and annealed label
US5284688A (en) 1992-04-16 1994-02-08 Unique Label Systems, Inc. Pressure sensitive adhesive labels and manufacture thereof
US5284681A (en) 1991-10-30 1994-02-08 Sumitomo Chemical Co., Ltd. Surface treatment method and coating method of polyamide resin molded articles
US5288548A (en) 1992-07-31 1994-02-22 Mobil Oil Corporation Label face stock
US5308693A (en) 1990-06-26 1994-05-03 Clopay Plastic Products Company, Inc. Unstretched synthetic papers and methods of producing same
US5332542A (en) 1991-07-03 1994-07-26 Oji Yuka Goseishi Co., Ltd. Process for producing labeled hollow container
US5366796A (en) 1991-10-24 1994-11-22 Hoechst Aktiengesellschaft Sealable, matt, biaxially oriented multilayer polyolefin film
US5424650A (en) 1993-09-24 1995-06-13 Rosemont Inc. Capacitive pressure sensor having circuitry for eliminating stray capacitance
US5435963A (en) 1991-09-09 1995-07-25 Rackovan; Mitchell J. In-mold labelling a coextruded, stretched and annealed label
US5475075A (en) 1991-12-13 1995-12-12 Exxon Chemical Patents Inc. Ethylene/longer α-olefin copolymers
US5495944A (en) 1993-10-21 1996-03-05 Burroughs Wellcome Co. Bottle with tamper evident wrapping
US5552451A (en) * 1991-12-31 1996-09-03 Minnesota Mining And Manufacturing Company Removable, low melt viscosity acrylic pressure sensitive adhesives
US5562962A (en) 1990-02-26 1996-10-08 The Dow Chemical Company Extrudable film labelstock for in-mold labeling
US5587214A (en) 1994-05-13 1996-12-24 Media Solutions, Inc. Laminated thermal transfer printable labels
US5595810A (en) * 1993-04-05 1997-01-21 Zweckform B uro-Produkte GmbH Decorative labels and method of their production
US5604006A (en) 1992-01-24 1997-02-18 Cascade Engineering Label inmolding process and article of manufacture produced therefrom
US5614146A (en) 1992-04-06 1997-03-25 Sumitomo Heavy Industries, Ltd. Method and apparatus of supplying labels to injection mold
US5658629A (en) * 1994-03-03 1997-08-19 Morgan Adhesives Company Double-sided silicone coated liner
US5711839A (en) 1995-09-13 1998-01-27 Northstar Print Group Process for the production of in-line gravure-printed in-mold labeled blow molded containers
US5725962A (en) 1993-12-01 1998-03-10 Mobil Oil Corporation Oriented HDPE films with metallized skin layer
US5725261A (en) 1995-12-20 1998-03-10 Mfi Associates, Inc. Identification tag and anchor for use in displaying indicia including graphics and text
US5876816A (en) 1996-07-10 1999-03-02 Avery Dennison Corporation Tamper evident labels and methods of producing the same
CA2012357C (en) 1989-03-17 1999-11-16 Yoshino Kogyosho Co., Ltd. Label and method for in-mold molding using a label thereof
US6001208A (en) 1989-03-17 1999-12-14 Yoshino Kogyosho Co., Ltd. Method for in-mold Molding using a label
US6004682A (en) 1991-09-09 1999-12-21 Avery Dennison Corporation In-mold label film and method
US6146744A (en) 1985-02-05 2000-11-14 Avery Dennison Corporation Composite facestocks
US6150013A (en) 1996-02-23 2000-11-21 Avery Dennison Corporation Low thermal conductivity in-mold label films
US6228486B1 (en) * 1998-10-06 2001-05-08 Avery Dennison Corporation Thermal transfer laminate
US6365254B1 (en) * 1998-02-02 2002-04-02 3M Innovative Properties Company Roll stabilizing release liner

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6159568A (en) * 1992-02-21 2000-12-12 Avery Dennison Corporation Peelable label
US6183862B1 (en) * 1998-09-23 2001-02-06 Avery Dennison Corporation Multilayer PSA construction exhibiting reduced tackifier migration

Patent Citations (140)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2862832A (en) 1956-01-09 1958-12-02 Dennison Mfg Co Heat transfer
US2990311A (en) 1956-01-09 1961-06-27 Dennison Mfg Co Heat transfer
US3043732A (en) 1957-01-02 1962-07-10 Dennison Mfg Co Top label surprinting
US2882599A (en) 1957-05-16 1959-04-21 Arthur L Martin Device for taking clippings from magazines or the like
US3108850A (en) 1960-11-23 1963-10-29 American Can Co Labeling of blown plastic containers
US3231419A (en) 1962-07-02 1966-01-25 Johnson & Johnson Method of making a cured tacky and pressure-sensitive adhesive tape
US3207822A (en) 1962-08-06 1965-09-21 American Can Co Method of decorating plastic objects
US3239478A (en) 1963-06-26 1966-03-08 Shell Oil Co Block copolymer adhesive compositions and articles prepared therefrom
US3380868A (en) 1963-11-19 1968-04-30 Nat Distillers Chem Corp Method for producing and orienting polypropylene films
US3503826A (en) 1967-01-18 1970-03-31 Erca Process for labelling hollow objects
US3484976A (en) 1968-05-28 1969-12-23 John C Shea Liquor bottle registering means and method
US3616015A (en) 1969-08-11 1971-10-26 Dennison Mfg Co Clear heat transfer and method of applying the same
US3625752A (en) 1969-10-07 1971-12-07 Johnson & Johnson Precured adhesive tape
US3676202A (en) 1969-10-07 1972-07-11 Johnson & Johnson Pressure-sensitive adhesive tape
US3723170A (en) 1969-12-05 1973-03-27 Johnson & Johnson Pressure-sensitive adhesive tape
US3733002A (en) 1970-10-12 1973-05-15 M Fujio Sealed container
US3758661A (en) 1970-12-24 1973-09-11 Sekisui Chemical Co Ltd Process for producing a synthetic paper
US4081309A (en) 1971-06-23 1978-03-28 Monarch Marking Systems, Inc. Method of making a composite label web
US3783072A (en) 1971-11-02 1974-01-01 Johnson & Johnson Extrusion process for pressure-sensitive adhesive sheets and tapes
US3932328A (en) 1971-11-02 1976-01-13 Johnson & Johnson Hot melt adhesive composition and tape
US3940001A (en) 1972-10-06 1976-02-24 Ethyl Corporation Recyclable plastic containers
US3959908A (en) 1973-12-27 1976-06-01 Lowe Robert R Livestock identification tag
US4028292A (en) 1974-05-23 1977-06-07 Johnson & Johnson Hot melt adhesive
US4137081A (en) 1975-11-05 1979-01-30 Hercules Incorporated Printing plates from polymer with terminal unsaturation
US4174218A (en) 1975-11-05 1979-11-13 Hercules Incorporated Relief plates from polymer with terminal unsaturation
US4426422A (en) 1977-04-13 1984-01-17 Dennison Manufacturing Company Distortion and chemically resistant heat transfer materials
US4175460A (en) 1978-03-27 1979-11-27 Mcphail John D Felt, belt, and fabric trimmer
US4228232A (en) 1979-02-27 1980-10-14 Minnesota Mining And Manufacturing Company Photopolymerizable composition containing ethylenically unsaturated oligomers
US4406411A (en) 1979-09-10 1983-09-27 Ford Motor Company Reclamation and rejuvenation of plastic and metal from metallized plastic
US4398985A (en) 1980-02-08 1983-08-16 Kimberly-Clark Corporation Releasable, self-detackifying laminate construction
US4393115A (en) 1980-07-22 1983-07-12 Toray Industries Multilayered polypropylene film
US4359314A (en) 1980-09-30 1982-11-16 The Continental Group, Inc. Transfer device for applying labels to blow molds
US4355967A (en) 1980-09-30 1982-10-26 The Continental Group, Inc. Label applying device
USD269154S (en) 1981-05-07 1983-05-31 Freedman Melvin S Cutting tool
US4599253A (en) 1981-09-14 1986-07-08 The D. L. Auld Company Method for making decorative emblems and the like and shapes prepared by that method
US4377616A (en) 1981-12-30 1983-03-22 Mobil Oil Corporation Lustrous satin appearing, opaque film compositions and method of preparing same
US4544590A (en) 1982-03-17 1985-10-01 Miller Products, Inc. Laminated member and method of making same
US4456934A (en) 1982-05-10 1984-06-26 Kollmorgen Technologies Corporation Linear positioning system
US4528221A (en) 1982-05-11 1985-07-09 Sekisui Kaseihin Kogyo Kabushiki Kaisha Polystyrene foamed sheet suitable for forming
US4501797A (en) 1982-12-01 1985-02-26 American Can Company Unbalanced oriented multiple layer film
US4479770A (en) 1982-12-08 1984-10-30 Plastipak Packaging, Inc. In-mold label dispenser for blow molding machine
US4639207A (en) 1982-12-08 1987-01-27 Plastipak Packaging, Inc. In-mold label dispenser for blow molding machine
US4528055A (en) 1982-12-17 1985-07-09 Graphic Resources, Inc. Method of manufacturing an elongated label supply
US4705714A (en) 1983-03-23 1987-11-10 Toa Nenryo Kogyo K.K. Differentially crosslinked and oriented polyethylene film
US4590020A (en) 1983-03-23 1986-05-20 Toa Nenryo Kogyo Kabushiki Kaisha Method of producing oriented polyethylene film
US4501798A (en) 1983-05-05 1985-02-26 American Can Company Unbalanced oriented multiple layer film
US4873088A (en) 1983-09-06 1989-10-10 Liposome Technology, Inc. Liposome drug delivery method and composition
US4479771A (en) 1983-10-20 1984-10-30 Plastipak Packaging, Inc. In-mold label dispenser for multiple cavity blow molding machine
US4567681A (en) 1983-11-28 1986-02-04 Owens-Illinois, Inc. Container with plastic label
US4872707A (en) 1984-03-09 1989-10-10 Grand Rapids Label Company Label or ticket
US4721638A (en) 1984-10-01 1988-01-26 Daimatsu Kagaku Kogyo Co., Ltd. Sticking material for preventing resticking
US4710338A (en) 1984-12-18 1987-12-01 Peerless Plastics Packaging Limited Method of manufacturing a molded plastics article incorporating a blank of sheet
US4626455A (en) 1985-01-14 1986-12-02 Owens-Illinois, Inc. Coextruded multilayer sheet and sleeve label for bottles
US4601926A (en) 1985-01-24 1986-07-22 Owens-Illinois, Inc. Process for applying copolyester barrier layer on polyester container
US4713273A (en) 1985-02-05 1987-12-15 Avery International Corporation Composite facestocks and liners
US4925714A (en) 1985-02-05 1990-05-15 Avery International Corporation Coextruded core laminates
US4837088A (en) 1985-02-05 1989-06-06 Avery International Corporation Coextruded core laminates
US6146744A (en) 1985-02-05 2000-11-14 Avery Dennison Corporation Composite facestocks
US4946532A (en) 1985-02-05 1990-08-07 Avery International Corporation Composite facestocks and liners
US4746556A (en) 1985-03-28 1988-05-24 Daimatsu Kagaku Kogyo Co., Ltd. Easily breakable sticking material
US4762737A (en) 1985-05-07 1988-08-09 Mobil Oil Corporation Multi-layer non-corrosive plastic film
US4886698A (en) 1985-05-24 1989-12-12 Imperial Chemical Industries Plc Multiple-layer polyolefin films
US4616992A (en) 1985-06-12 1986-10-14 Y Technipak Corp. Shuttle-type blow molding machine with in-mold labeling
US4582752A (en) 1985-07-11 1986-04-15 Mobil Oil Corporation Heat shrinkable, lustrous satin appearing, opaque film compositions
US4758396A (en) 1985-09-14 1988-07-19 Hoechst Aktiengesellschaft Process for the preparation of a biaxially oriented polypropylene film
US4863772A (en) 1985-11-26 1989-09-05 Avery International Corporation Label stock with dry separation interface
US4737098A (en) 1986-04-11 1988-04-12 Technipack Corporation In-mold labeling apparatus
US4721531A (en) 1986-07-08 1988-01-26 Plasticolors, Inc. Pigment dispersions exhibiting improved compatibility in polyurethane systems
US4837075A (en) 1986-07-14 1989-06-06 The Dow Chemical Company Coextruded plastic film label for in-mold labeling
US4883697A (en) 1986-07-23 1989-11-28 The Procter & Gamble Company Thermoplastic in-mold labeling label structure for deformable thermoplastic packages
US4704310A (en) 1986-08-25 1987-11-03 Dennison Manufacturing Company Heat transferable laminate
US4894259A (en) * 1986-08-29 1990-01-16 Minnesota Mining And Manufacturing Company Process of making a unified pressure-sensitive adhesive tape
US4983348A (en) 1986-10-29 1991-01-08 Wheaton Industries In-mold labeling of injection blow molded products
US5073435A (en) 1986-12-23 1991-12-17 Rhone-Poulenc Chimie Composite polyester films
US4904324A (en) 1986-12-29 1990-02-27 Owens-Illinois Plastic Products Inc. Method of making plastic container with multilayer label applied by in-mold labeling
US5079057A (en) 1986-12-29 1992-01-07 Owens-Illinois Plastic Products Inc. Plastic container with multilayer label applied by in-mold labeling
US5405667A (en) 1986-12-29 1995-04-11 Owens-Illinois, Inc. Plastic container with multilayer label applied by in-mold labeling
US4704323A (en) 1987-01-07 1987-11-03 Mobil Oil Corporation Resin film laminate
US4729864A (en) 1987-01-28 1988-03-08 Owens-Illinois Plastic Products Inc. In-mold labeling of plastic containers
GB2201681A (en) 1987-03-06 1988-09-07 Swift Adhesives Ltd Heat and pressure activated adhesive compositions
US4720416A (en) 1987-03-09 1988-01-19 Mobil Oil Corporation Pressure sensitive label stock material possessing a wrinkle-resistant lustrous, opaque laminate film facing
US4794284A (en) 1987-03-26 1988-12-27 Georges Buon Linear D.C. motor with non-ferrous stator core
US4892689A (en) 1987-07-14 1990-01-09 Agfa-Gevaert N.V. Process for making curled photographic film
US4824912A (en) 1987-08-31 1989-04-25 Mobil Oil Corporation Terblends and films of LLDPE, LMW-HDPE and HMW-HDPE
US4916025A (en) 1987-09-28 1990-04-10 Mobil Oil Corporation HDPE films with imbalanced biaxial orientation
US4870122A (en) 1987-09-28 1989-09-26 Mobil Oil Corporation HdPE films with imbalanced biaxial orientation
US4808366A (en) 1987-10-01 1989-02-28 Owens-Illinois Plastic Products Inc. In-mold labeling of injection blow molded hollow plastic articles
US4834641A (en) 1987-12-23 1989-05-30 Liquid Container Corporation Apparatus for in-mold labeling of a blow molded article
US5026592A (en) 1987-12-23 1991-06-25 Hoechst Aktiengesellschaft Opaque multilayered film having an inherent resistance to delamination
US4892779A (en) 1988-03-18 1990-01-09 Ppg Industries, Inc. Multilayer article of microporous and substantially nonporous materials
US4917592A (en) 1988-03-31 1990-04-17 Owens-Illinois Plastic Products, Inc. Apparatus for applying labels to blow molded articles
US5223315A (en) 1988-04-06 1993-06-29 Toyo Seikan Kaisha Ltd. Container equipped with label and production method thereof
US4935300A (en) 1988-04-13 1990-06-19 Dennison Manufacturing Company Heat transferable laminate
US4953313B1 (en) 1988-04-19 1993-09-28 Allflex New Zealand Limited Ear tag for animals
US4953313A (en) 1988-04-19 1990-09-04 Allflex New Zealand Limited Ear tag for animals
US4855187A (en) 1988-05-06 1989-08-08 Mobil Oil Corporation Low coefficient of friction biaxially oriented film
US5019436A (en) 1988-09-19 1991-05-28 Schramer Kurt M Label assembly and method of manufacturing
US5026266A (en) 1988-12-16 1991-06-25 Toppan Publishing Co., Ltd. Label feeder for a mold for plastics moldings
CA2012357C (en) 1989-03-17 1999-11-16 Yoshino Kogyosho Co., Ltd. Label and method for in-mold molding using a label thereof
US6001208A (en) 1989-03-17 1999-12-14 Yoshino Kogyosho Co., Ltd. Method for in-mold Molding using a label
US5075583A (en) 1989-04-28 1991-12-24 Toyota Shatai Kabushiki Kaisha Brushless DC linear motor
US5104719A (en) * 1989-08-30 1992-04-14 Revlon, Inc. Heat activated, quick release decals and associated methods
US5032344A (en) 1989-10-05 1991-07-16 Owens-Illinois Plastic Products Inc. Method for applying labels in the molds of a plastic blow molding machine
US5126197A (en) 1989-10-26 1992-06-30 Wolff Walsrode Ag Heat-laminatable, high-gloss multilayer films
US4986866A (en) 1989-12-15 1991-01-22 Oji Yuka Goseishi Co., Ltd. Process for producing synthetic label paper
US5076977A (en) 1990-01-10 1991-12-31 Eastman Kodak Company Process for controlling curl in polyester film
US5562962A (en) 1990-02-26 1996-10-08 The Dow Chemical Company Extrudable film labelstock for in-mold labeling
US5042842A (en) 1990-06-26 1991-08-27 Avery International Corporation High security label
US5308693A (en) 1990-06-26 1994-05-03 Clopay Plastic Products Company, Inc. Unstretched synthetic papers and methods of producing same
CA2044079A1 (en) 1990-09-14 1992-03-15 Bruce G. Stokes Extrusion coated synthetic printing paper for in-mold label coupon applications
US5186782A (en) 1990-10-17 1993-02-16 Avery Dennison Corporation Method for high speed labelling of deformable substrates
US5152946A (en) 1991-01-30 1992-10-06 Hercules Incorporated Producing low shrink packaging film
US5332542A (en) 1991-07-03 1994-07-26 Oji Yuka Goseishi Co., Ltd. Process for producing labeled hollow container
US5733615A (en) 1991-09-09 1998-03-31 Avery Dennison Corporation In-mold label film and method
US6004682A (en) 1991-09-09 1999-12-21 Avery Dennison Corporation In-mold label film and method
US5435963A (en) 1991-09-09 1995-07-25 Rackovan; Mitchell J. In-mold labelling a coextruded, stretched and annealed label
US5242650A (en) 1991-09-09 1993-09-07 Avery Dennison Corporation In-mold labelling a coextruded, stretched and annealed label
US5223346A (en) 1991-10-23 1993-06-29 Mobil Oil Corporation Hdpe/polypropylene film laminates
US5366796A (en) 1991-10-24 1994-11-22 Hoechst Aktiengesellschaft Sealable, matt, biaxially oriented multilayer polyolefin film
US5284681A (en) 1991-10-30 1994-02-08 Sumitomo Chemical Co., Ltd. Surface treatment method and coating method of polyamide resin molded articles
US5475075A (en) 1991-12-13 1995-12-12 Exxon Chemical Patents Inc. Ethylene/longer α-olefin copolymers
US5552451A (en) * 1991-12-31 1996-09-03 Minnesota Mining And Manufacturing Company Removable, low melt viscosity acrylic pressure sensitive adhesives
US5604006A (en) 1992-01-24 1997-02-18 Cascade Engineering Label inmolding process and article of manufacture produced therefrom
US5614146A (en) 1992-04-06 1997-03-25 Sumitomo Heavy Industries, Ltd. Method and apparatus of supplying labels to injection mold
US5284688A (en) 1992-04-16 1994-02-08 Unique Label Systems, Inc. Pressure sensitive adhesive labels and manufacture thereof
US5288548A (en) 1992-07-31 1994-02-22 Mobil Oil Corporation Label face stock
US5595810A (en) * 1993-04-05 1997-01-21 Zweckform B uro-Produkte GmbH Decorative labels and method of their production
US5424650A (en) 1993-09-24 1995-06-13 Rosemont Inc. Capacitive pressure sensor having circuitry for eliminating stray capacitance
US5495944A (en) 1993-10-21 1996-03-05 Burroughs Wellcome Co. Bottle with tamper evident wrapping
US5725962A (en) 1993-12-01 1998-03-10 Mobil Oil Corporation Oriented HDPE films with metallized skin layer
US5658629A (en) * 1994-03-03 1997-08-19 Morgan Adhesives Company Double-sided silicone coated liner
US5587214A (en) 1994-05-13 1996-12-24 Media Solutions, Inc. Laminated thermal transfer printable labels
US5711839A (en) 1995-09-13 1998-01-27 Northstar Print Group Process for the production of in-line gravure-printed in-mold labeled blow molded containers
US5725261A (en) 1995-12-20 1998-03-10 Mfi Associates, Inc. Identification tag and anchor for use in displaying indicia including graphics and text
US6150013A (en) 1996-02-23 2000-11-21 Avery Dennison Corporation Low thermal conductivity in-mold label films
US5876816A (en) 1996-07-10 1999-03-02 Avery Dennison Corporation Tamper evident labels and methods of producing the same
US6294236B1 (en) 1996-07-10 2001-09-25 Avery Dennison Corporation Tamper evident labels and methods of producing the same
US6365254B1 (en) * 1998-02-02 2002-04-02 3M Innovative Properties Company Roll stabilizing release liner
US6228486B1 (en) * 1998-10-06 2001-05-08 Avery Dennison Corporation Thermal transfer laminate
US6461722B1 (en) 1998-10-06 2002-10-08 Avery Dennnison Corporation Thermal transfer laminate

Non-Patent Citations (21)

* Cited by examiner, † Cited by third party
Title
A. Schulman Inc., Product Information Sheet for Polybatch F 20, Jan. 28, 1996.
A. Schulman Inc., Product Information Sheet for Polybatch PF 92 D, Jan. 29, 1996.
A. Schulman Inc., Product Information Sheet for Polybatch White P8555 SD, Mar. 5, 1996.
Adhesion and Bond, Encyclopedia of Polymer Science and Engineering vol. 1, p. 476-546, Interscience Publishers, 2nd Ed. 1985.
Ampacet Product Information, Product 10061, Jul. 28, 1998.
Ampacet Product Information, Slip PE MB, date unknown.
Avery Dennison Corporation, Description of Commercial Heat-Sealable Laminate sold by Avery Dennison prior to Jan. 10, 2000.
Chevron Chemical Co., Technical Data Sheet, Ethylene-Methyl Acrylate Copolymer, EMCA, SP2268PT, Sep. 16, 1994.
Hostaphan Polyester Film, Product Bulletin, 4LD4 Solvent Adherable Film, 10/96.
International Search Report, International Application No. PCT/US01/49084, dated Apr. 18, 2002.
Material Safety Data Sheet, A.J. Daw Printing Ink Co., Inc., Product Uvilith AR-109 Rubine Red, Apr. 14, 1997.
Rad-Cure Corp., Technical Data Sheet for RAD-CURE UV1008, 1990.
Sun Chemical Corp., Health and Safety Dept., Material Safety Data Sheet for RCA01302R-UV Coating, Apr. 9, 1998.
Sun Chemical Corporation, Health and Safety Dept., Material Safety Data Sheet for CLA91598F-Multibond Black, Apr. 9, 1998.
Sun Chemical Corporation, Health and Safety Dept., Material Safety Data Sheet for CLB04275F-Prokote Primer, Apr. 9, 1998.
Sun Chemical, Product Information Sheet for Prokote Primer RLB00201 F/S, Date unknown.
Sun Chemical, Product Information Sheet for SunCure Clear Coating RCA01302R, date unknown.
SunChemical, Flexible Packaging, Product Information Sheet for Sun Sheen, Aug. 1990.
SunChemical, Product Information Sheet for SUNTEX MP, Date unknown.
Union Carbide Research Product Technical Bulletin, UCC Polypropylene WRD-1057 (1997).
Water Ink Technologies, Inc., Technical Datasheet, X-Cel Water-Based Film Inks (Jan. 1, 1998).

Cited By (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7351465B2 (en) * 1999-02-16 2008-04-01 Westlake Longview Corporation Polymeric based carpet
US20010051248A1 (en) * 1999-02-16 2001-12-13 Jerdee Gary D. Polymeric based carpet
US8025944B2 (en) * 2001-06-28 2011-09-27 Walle Corporation Cut and stack labels of laminated film
US20040247884A1 (en) * 2001-06-28 2004-12-09 Keeney Sean M. Cut and stack lables of laminated film
US20110304132A1 (en) * 2001-06-28 2011-12-15 Keeney Sean M Cut and stack labels of laminated film
US20050008809A1 (en) * 2001-10-05 2005-01-13 Dale Miller In-mold labeling method and labeled products
US20040245138A1 (en) * 2001-10-15 2004-12-09 Tapani Penttinen Package lid, method for manufacturing the same and package sealed with the lid
US7897228B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7897227B2 (en) 2001-12-20 2011-03-01 The Procter & Gamble Company Articles and methods for applying color on surfaces
US7709070B2 (en) 2001-12-20 2010-05-04 The Procter & Gamble Company Articles and methods for applying color on surfaces
US20030134114A1 (en) * 2001-12-20 2003-07-17 The Procter & Gamble Company Articles and methods for applying color on surfaces
US20060263595A1 (en) * 2001-12-21 2006-11-23 Tesa Aktiengesellschaft Self-adhesive labels, their production and use
US20040026024A1 (en) * 2002-05-22 2004-02-12 Ikuo Nakasaka Label affixing method and apparatus
US8557379B1 (en) 2002-10-18 2013-10-15 Clifford A. Lowe Multilayer graphic article
US7361403B1 (en) * 2002-10-18 2008-04-22 Lowe Clifford A Multilayer graphic systems
US7722938B2 (en) 2003-02-14 2010-05-25 The Procter & Gamble Company Dry paint transfer laminate
US7905981B2 (en) 2003-02-14 2011-03-15 The Procter & Gamble Company Method of making a dry paint transfer laminate
US7807246B2 (en) 2003-02-14 2010-10-05 The Procter & Gamble Company Dry paint transfer laminate
US7842364B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7842363B2 (en) 2003-02-14 2010-11-30 The Procter & Gamble Company Differential release system for a self-wound multilayer dry paint decorative laminate having a pressure sensitive adhesive
US7846522B2 (en) 2003-02-14 2010-12-07 The Procter & Gamble Company Discoloration-resistant articles for applying color on surfaces and methods of reducing discoloration in articles for applying color on surfaces
US20040161568A1 (en) * 2003-02-14 2004-08-19 Truog Keith L. Dry paint transfer laminate for use as wall covering
US7140135B2 (en) * 2003-05-01 2006-11-28 Wisconsin Label Corporation Flag label
US20040217022A1 (en) * 2003-05-01 2004-11-04 Irvine Alexander J. Flag label
WO2005005161A3 (en) * 2003-06-09 2005-08-04 Avery Dennison Corp Multilayer film
US20040247837A1 (en) * 2003-06-09 2004-12-09 Howard Enlow Multilayer film
US7727607B2 (en) 2003-06-09 2010-06-01 The Procter & Gamble Company Multi-layer dry paint decorative laminate having discoloration prevention barrier
US20060246282A1 (en) * 2003-08-15 2006-11-02 Nicolai Bohm Two-side self-adhesive tape whose sides have different adhesive force in particular for removably sticking flexible compact discs to curved surfaces
US20060028014A1 (en) * 2004-05-14 2006-02-09 Impaq, Inc. Peel-off label and methods of utilizing the same
US7281360B1 (en) * 2005-02-11 2007-10-16 Bryce Corporation Thermal laminates and laminating method of food packaging films
US8356459B1 (en) 2005-02-11 2013-01-22 Bryce Corporation Thermal laminates and laminating method for food packaging films
US20080220227A1 (en) * 2006-05-30 2008-09-11 Keeney Cecil M Coated printing stock for use as labels and the like
US20080017301A1 (en) * 2006-06-29 2008-01-24 3M Innovative Properties Company Transfer films for graphic substrates
US8563122B1 (en) 2006-12-01 2013-10-22 Design Imaging, Llc Thermoplastic architectural composite laminate materials and associated methods of manufacture
US11267628B2 (en) 2008-01-21 2022-03-08 Cpi Card Group—Minnesota, Inc. Ultrasecure card package
US11034497B2 (en) 2008-01-21 2021-06-15 CPI Card Group—Colorado, Inc. Ultrasecure card package
US10625915B2 (en) 2008-01-21 2020-04-21 Cpi Card Group—Minnesota, Inc. Ultrasecure card package
US11905089B2 (en) 2008-01-21 2024-02-20 Cpi Card Group—Minnesota, Inc. Ultrasecure card package
CN102016148A (zh) * 2008-07-25 2011-04-13 Nsk声音马克株式会社 标识用坯布及使用其的标识形成方法
US8304059B2 (en) * 2008-07-25 2012-11-06 Nsk Echo Mark Co., Ltd. Laminated structure for marking and method of forming a mark
US20110070409A1 (en) * 2008-07-25 2011-03-24 Kanji Nishimaki Fabric for marking and method of forming mark with the same
CN102016148B (zh) * 2008-07-25 2013-08-07 Nsk声音马克株式会社 标识用坯布及使用其的标识形成方法
US8172146B2 (en) 2008-09-03 2012-05-08 Moore Wallace North America, Inc. Sealed cards and methods of producing the same
US9302500B2 (en) 2008-09-03 2016-04-05 R.R. Donnelley & Sons Company Sealed cards and methods of producing the same
US20100051706A1 (en) * 2008-09-03 2010-03-04 James Harrison Pagones Sealed cards and methods of producing the same
US8833662B2 (en) 2008-09-03 2014-09-16 R.R. Donnelley & Sons Company Sealed cards and methods of producing the same
US8957277B2 (en) * 2009-04-27 2015-02-17 Avery Dennison Corporation Disruptable adhesive layer for fluid activated debonding
US20130123678A1 (en) * 2009-04-27 2013-05-16 Avery Dennison Corporation Disruptable Adhesive Layer for Fluid Activated Debonding
CN102111970A (zh) * 2009-12-28 2011-06-29 深圳富泰宏精密工业有限公司 电子装置壳体及其制作方法
US9221573B2 (en) 2010-01-28 2015-12-29 Avery Dennison Corporation Label applicator belt system
WO2011093958A1 (en) 2010-01-28 2011-08-04 Avery Dennison Corporation Method and systems for applying heat transfer labels
US9637264B2 (en) 2010-01-28 2017-05-02 Avery Dennison Corporation Label applicator belt system
US20110203943A1 (en) * 2010-02-24 2011-08-25 Perry David J Printed sorbents
US8458941B2 (en) 2010-04-20 2013-06-11 Moore Wallace North America, Inc. Shipment labels and related methods
US8714398B2 (en) * 2010-06-22 2014-05-06 Advanced Flexible Composites, Inc. Rigid durable non-metallic release laminate for oven cooking and oven containing same
US20110311701A1 (en) * 2010-06-22 2011-12-22 William James Lewis Rigid durable non-metallic release laminate for oven cooking and oven containing same
US10533117B2 (en) 2012-10-09 2020-01-14 Avery Dennison Corporation Adhesives and related methods
US9708509B2 (en) 2012-10-09 2017-07-18 Avery Dennison Corporation Adhesives and related methods
US9725623B2 (en) 2012-10-09 2017-08-08 Avery Dennison Corporation Adhesives and related methods
US9738817B2 (en) 2012-10-09 2017-08-22 Avery Dennison Corporation Adhesives and related methods
US11685841B2 (en) 2012-10-09 2023-06-27 Avery Dennison Corporation Adhesives and related methods
US10035930B2 (en) 2012-10-09 2018-07-31 Avery Dennison Corporation Adhesives and related methods
US10040974B2 (en) 2012-10-09 2018-08-07 Avery Dennison Corporation Adhesives and related methods
US10040973B2 (en) 2012-10-09 2018-08-07 Avery Dennison Corporation Adhesives and related methods
US10040978B2 (en) 2012-10-09 2018-08-07 Avery Dennison Corporation Adhesives and related methods
US10457838B2 (en) 2012-10-09 2019-10-29 Avery Dennison Corporation Adhesives and related methods
US11292942B2 (en) 2012-10-09 2022-04-05 Avery Dennison Corporation Adhesives and related methods
US9714365B2 (en) 2012-10-09 2017-07-25 Avery Dennison Corporation Adhesives and related methods
US10597560B2 (en) 2012-10-09 2020-03-24 Avery Dennison Corporation Adhesives and related methods
US11008483B2 (en) 2012-10-09 2021-05-18 Avery Dennison Corporation Adhesives and related methods
US9926470B2 (en) 2012-10-22 2018-03-27 Avery Dennison Corporation Hybrid material of crosslinked microgel particles dispersed in an adhesive
WO2014074766A1 (en) 2012-11-08 2014-05-15 Avery Dennison Corporation Systems, methods, and media for labeling three dimensional surfaces
CN104554064A (zh) * 2013-10-22 2015-04-29 通用汽车环球科技运作有限责任公司 带有声学功能的湿pu+gf车顶衬里基底
US20150111453A1 (en) * 2013-10-22 2015-04-23 GM Global Technology Operations LLC Wet pu + gf headliner substrate with acoustic function
US20160232821A1 (en) * 2015-02-05 2016-08-11 Avery Dennison Corporation Label Assemblies for Adverse Environments
US11049421B2 (en) * 2015-02-05 2021-06-29 Avery Dennison Corporation Label assemblies for adverse environments
US10526511B2 (en) 2016-12-22 2020-01-07 Avery Dennison Corporation Convertible pressure sensitive adhesives comprising urethane (meth)acrylate oligomers
US11466180B2 (en) 2017-05-08 2022-10-11 Avery Dennison Corporation Vulcanization tire label

Also Published As

Publication number Publication date
EP1358066B1 (en) 2010-03-31
MXPA03006203A (es) 2003-12-11
WO2002055295A1 (en) 2002-07-18
EP1358066A4 (en) 2006-09-20
ATE462562T1 (de) 2010-04-15
JP2004524993A (ja) 2004-08-19
EP1358066A1 (en) 2003-11-05
DE60141712D1 (de) 2010-05-12
CA2433664A1 (en) 2002-07-18
US20020127361A1 (en) 2002-09-12
CA2433664C (en) 2011-08-16

Similar Documents

Publication Publication Date Title
US6756095B2 (en) Heat-sealable laminate
US6461722B1 (en) Thermal transfer laminate
US6106982A (en) Imaged receptor laminate and process for making same
US6521312B1 (en) Multilayered film structures and methods of making and using the same
US6758000B2 (en) Livestock security tag assembly
KR100323787B1 (ko) 일축연신다층필름및이를함유하는항공수화물택
CA2261046C (en) Image receptor medium
EP2001683B1 (en) Process for manufacture of polymer film graphics
EP2681006B1 (en) Laser marking process and articles
CA2334908A1 (en) Multilayered thermoplastic film and sign cutting method using the same
US6808776B2 (en) Water-absorbent film construction
US20090120571A1 (en) Heat-sealable label
MXPA99009103A (en) Laminate of transfer term
US10688754B1 (en) Multifunctional contact clear filled pressure sensitive adhesive coated substrates
US10137677B1 (en) Cellulose film pressure sensitive adhesive substrates for high temperature printing
US20040185192A1 (en) Image-recordable, image-recording medium and adhesive sheet structure
KR200166118Y1 (ko) 조명용 광고소재
CA2160442C (en) Durable sheets for printing
EP1444678A1 (en) Image-recordable, image-recording medium and adhesive sheet structure

Legal Events

Date Code Title Description
AS Assignment

Owner name: AVERY DENNISON CORPORATION, CALIFORNIA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:SANDT, RICHARD L.;KITTEL, MARK D.;LUM, HENRY, JR.;REEL/FRAME:011573/0052;SIGNING DATES FROM 20010118 TO 20010123

STCF Information on status: patent grant

Free format text: PATENTED CASE

FPAY Fee payment

Year of fee payment: 4

FPAY Fee payment

Year of fee payment: 8

AS Assignment

Owner name: CCL LABEL, INC., MASSACHUSETTS

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:AVERY DENNISON CORPORATION;REEL/FRAME:032007/0092

Effective date: 20130701

FPAY Fee payment

Year of fee payment: 12