US3421956A - Method of etching sic - Google Patents

Method of etching sic Download PDF

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Publication number
US3421956A
US3421956A US436918A US43691865A US3421956A US 3421956 A US3421956 A US 3421956A US 436918 A US436918 A US 436918A US 43691865 A US43691865 A US 43691865A US 3421956 A US3421956 A US 3421956A
Authority
US
United States
Prior art keywords
etching
silicon carbide
melt
etched
sic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US436918A
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English (en)
Inventor
Ekkehard Ebert
Werner Spielmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
International Business Machines Corp
Original Assignee
International Business Machines Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by International Business Machines Corp filed Critical International Business Machines Corp
Application granted granted Critical
Publication of US3421956A publication Critical patent/US3421956A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/53After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
    • C04B41/5338Etching
    • C04B41/5361Etching with molten material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/0445Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising crystalline silicon carbide
    • H01L21/0475Changing the shape of the semiconductor body, e.g. forming recesses

Definitions

  • This invention relates to a method of etching silicon carbide.
  • etching technique In the fabrication of semiconductor elements, such as diodes, transistors or similar components, extensive use is made of the etching technique since like hardly any other material processing technique it makes possible the processing of small and very small bodies in a simple manner.
  • a particular advantage of this technique resides in the fact that, by using etchants reacting exclusively or preferably with certain given materials, it is possible to effect a zone selection when bodies consisting dilferent substances or masks consisting of suitable substances are employed.
  • etchants and etching techniques For the numerous semiconductor substances that have been disclosed so far and for the various problems arising in processing them, a large variety of etchants and etching techniques have been provided with which it has been possible to obtain optimum results in the individual fields.
  • this invention provides a method of etching silicon carbide in which the bodies or surfaces to be etched, after having first been lapped by mechanical means to a roughness of preferably below 1 micron, cleaned by ultrasonic treatment, washed with HFHNO and rinsed with aqua destillata and alcohol, are placed into a melt consisting of Na O and NaNO
  • An especially advantageous temperature range has proved to be that between 400 C. and 600 C.
  • a 1:1 mixture ratio of the said substance has shown to be favorable, but other mixture ratios are also possible which for special applications may in certain circumstances deviate greatly from the 1:1 ratio.
  • the silicon carbide bodies etched by this technique are eroded symmetrically and exhibit perfectly planar surfaces.
  • a melt consisting essentially of sodium peroxide and sodium nitrite; the weight ratio between the sodium peroxide and sodium nitrite being on the order of 1 to 1; and maintaining contact between said surface and said melt until the desired amount of etching has taken place; said melt being maintained during the etching step at a temperature between about 400 C. and 600 C.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Weting (AREA)
US436918A 1964-03-06 1965-03-03 Method of etching sic Expired - Lifetime US3421956A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEJ25392A DE1242972B (de) 1964-03-06 1964-03-06 Verfahren zum AEtzen von SiC

Publications (1)

Publication Number Publication Date
US3421956A true US3421956A (en) 1969-01-14

Family

ID=7202205

Family Applications (1)

Application Number Title Priority Date Filing Date
US436918A Expired - Lifetime US3421956A (en) 1964-03-06 1965-03-03 Method of etching sic

Country Status (5)

Country Link
US (1) US3421956A (fr)
AT (1) AT251651B (fr)
DE (1) DE1242972B (fr)
FR (1) FR1439074A (fr)
GB (1) GB1023749A (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3607448A (en) * 1968-10-21 1971-09-21 Hughes Aircraft Co Chemical milling of silicon carbide
US3878005A (en) * 1973-06-18 1975-04-15 Rockwell International Corp Method of chemically polishing metallic oxides
US4465550A (en) * 1982-06-16 1984-08-14 General Signal Corporation Method and apparatus for slicing semiconductor ingots
US4946547A (en) * 1989-10-13 1990-08-07 Cree Research, Inc. Method of preparing silicon carbide surfaces for crystal growth
US4981551A (en) * 1987-11-03 1991-01-01 North Carolina State University Dry etching of silicon carbide
US5725413A (en) * 1994-05-06 1998-03-10 Board Of Trustees Of The University Of Arkansas Apparatus for and method of polishing and planarizing polycrystalline diamonds, and polished and planarized polycrystalline diamonds and products made therefrom
US8609323B2 (en) 2009-12-01 2013-12-17 University Of Massachusetts System for producing patterned silicon carbide structures
CN104505338A (zh) * 2014-12-24 2015-04-08 国家电网公司 一种碳化硅晶片外延前预清洗方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3607448A (en) * 1968-10-21 1971-09-21 Hughes Aircraft Co Chemical milling of silicon carbide
US3878005A (en) * 1973-06-18 1975-04-15 Rockwell International Corp Method of chemically polishing metallic oxides
US4465550A (en) * 1982-06-16 1984-08-14 General Signal Corporation Method and apparatus for slicing semiconductor ingots
US4981551A (en) * 1987-11-03 1991-01-01 North Carolina State University Dry etching of silicon carbide
US4946547A (en) * 1989-10-13 1990-08-07 Cree Research, Inc. Method of preparing silicon carbide surfaces for crystal growth
US5725413A (en) * 1994-05-06 1998-03-10 Board Of Trustees Of The University Of Arkansas Apparatus for and method of polishing and planarizing polycrystalline diamonds, and polished and planarized polycrystalline diamonds and products made therefrom
US8609323B2 (en) 2009-12-01 2013-12-17 University Of Massachusetts System for producing patterned silicon carbide structures
CN104505338A (zh) * 2014-12-24 2015-04-08 国家电网公司 一种碳化硅晶片外延前预清洗方法
CN104505338B (zh) * 2014-12-24 2017-11-07 国家电网公司 一种碳化硅晶片外延前预清洗方法

Also Published As

Publication number Publication date
AT251651B (de) 1967-01-10
FR1439074A (fr) 1966-05-20
DE1242972B (de) 1967-06-22
GB1023749A (en) 1966-03-23

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