US20170338469A1 - Process for making lithiated transition metal oxides - Google Patents

Process for making lithiated transition metal oxides Download PDF

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Publication number
US20170338469A1
US20170338469A1 US15/528,786 US201515528786A US2017338469A1 US 20170338469 A1 US20170338469 A1 US 20170338469A1 US 201515528786 A US201515528786 A US 201515528786A US 2017338469 A1 US2017338469 A1 US 2017338469A1
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US
United States
Prior art keywords
range
precursor
lithium
transition metal
cations
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US15/528,786
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English (en)
Inventor
Aleksei Volkov
Martin Schulz-Dobrick
Simon Schroedle
Jordan Lampert
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BASF SE
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BASF SE
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Assigned to BASF SE reassignment BASF SE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: Volkov, Aleksei, LAMPERT, JORDAN, SCHULZ-DOBRICK, MARTIN, SCHROEDLE, SIMON
Publication of US20170338469A1 publication Critical patent/US20170338469A1/en
Abandoned legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G53/00—Compounds of nickel
    • C01G53/40—Nickelates
    • C01G53/42—Nickelates containing alkali metals, e.g. LiNiO2
    • C01G53/44—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese
    • C01G53/50—Nickelates containing alkali metals, e.g. LiNiO2 containing manganese of the type [MnO2]n-, e.g. Li(NixMn1-x)O2, Li(MyNixMn1-x-y)O2
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/5825—Oxygenated metallic salts or polyanionic structures, e.g. borates, phosphates, silicates, olivines
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H01M4/623—Binders being polymers fluorinated polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/50—Agglomerated particles
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/51—Particles with a specific particle size distribution
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/11—Powder tap density
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
US15/528,786 2014-11-28 2015-11-18 Process for making lithiated transition metal oxides Abandoned US20170338469A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP14195471 2014-11-28
EP14195471.9 2014-11-28
PCT/EP2015/076941 WO2016083205A2 (en) 2014-11-28 2015-11-18 Process for making lithiated transition metal oxides

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2015/076941 A-371-Of-International WO2016083205A2 (en) 2014-11-28 2015-11-18 Process for making lithiated transition metal oxides

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US16/808,650 Division US11670760B2 (en) 2014-11-28 2020-03-04 Process for making lithiated transition metal oxides

Publications (1)

Publication Number Publication Date
US20170338469A1 true US20170338469A1 (en) 2017-11-23

Family

ID=52002767

Family Applications (2)

Application Number Title Priority Date Filing Date
US15/528,786 Abandoned US20170338469A1 (en) 2014-11-28 2015-11-18 Process for making lithiated transition metal oxides
US16/808,650 Active 2036-08-05 US11670760B2 (en) 2014-11-28 2020-03-04 Process for making lithiated transition metal oxides

Family Applications After (1)

Application Number Title Priority Date Filing Date
US16/808,650 Active 2036-08-05 US11670760B2 (en) 2014-11-28 2020-03-04 Process for making lithiated transition metal oxides

Country Status (6)

Country Link
US (2) US20170338469A1 (ja)
EP (1) EP3224882B1 (ja)
JP (1) JP6727201B2 (ja)
KR (1) KR102484028B1 (ja)
CN (1) CN107001072B (ja)
WO (1) WO2016083205A2 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112713263A (zh) * 2020-12-14 2021-04-27 宁波维科新能源科技有限公司 一种偏磷酸盐包覆钴酸锂材料的制备方法及包含其的锂离子电池
US11643338B2 (en) 2019-10-29 2023-05-09 Shandong Zstone New Material Technology Co., Ltd. Method and device for producing lithium transition metal oxide

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102464804B1 (ko) * 2017-11-21 2022-11-09 히타치 긴조쿠 가부시키가이샤 리튬 이온 이차 전지용 정극 활물질의 제조 방법 및 열처리 장치
AU2019353668A1 (en) * 2018-10-05 2021-04-29 Topsoe Battery Materials A/S Sodium metal oxide material for secondary batteries and method of preparation
CN110323073B (zh) * 2019-06-28 2020-04-17 中国地质大学（北京） 一种氧掺杂磷化钴镍-还原氧化石墨烯复合材料的制备方法及其应用

Citations (4)

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US20080254368A1 (en) * 2007-03-30 2008-10-16 Sony Corporation Cathode active material, cathode, nonaqueous electrolyte battery, and method for manufacturing cathode
US20100136412A1 (en) * 2008-11-28 2010-06-03 Kozo Watanabe Method for producing lithium-containing composite oxide and non-aqueous secondary battery
US20140346393A1 (en) * 2012-03-16 2014-11-27 Lg Chem, Ltd. Precursor for preparing lithium composite transition metal oxide and method for preparing the same
US20160064729A1 (en) * 2014-08-29 2016-03-03 Toyota Jidosha Kabushiki Kaisha Method for producing positive electrode active material layer for lithium ion battery, and positive electrode active material layer for lithium ion battery

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DE60234855D1 (de) 2001-10-02 2010-02-04 Valence Technology Inc Auf lithiumübergangsmetalltitanaten basierende lithiumzelle
JP4920475B2 (ja) * 2007-03-30 2012-04-18 ソニー株式会社 正極活物質、正極および非水電解質電池
JP4837651B2 (ja) * 2007-12-06 2011-12-14 株式会社田中化学研究所 酸化ニッケルの製造方法
KR101492304B1 (ko) * 2007-12-28 2015-02-11 도다 고교 가부시끼가이샤 비수전해액 이차 전지용 망간산리튬 및 그의 제조 방법, 및 비수전해액 이차 전지
JP5381024B2 (ja) * 2008-11-06 2014-01-08 株式会社Ｇｓユアサ リチウム二次電池用正極及びリチウム二次電池
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JP5791877B2 (ja) * 2009-09-30 2015-10-07 三洋電機株式会社 正極活物質、この正極活物質の製造方法、及び、正極活物質を用いた非水電解質二次電池
KR101077869B1 (ko) * 2010-04-30 2011-10-28 주식회사 엘지화학 이차전지용 양극
EP2619141B1 (de) * 2010-09-21 2014-07-16 Basf Se Verfahren zur herstellung von modifizierten übergangsmetallmischoxiden
US8980126B2 (en) * 2010-10-08 2015-03-17 Semiconductor Energy Laboratory Co., Ltd. Electrode material and method for manufacturing power storage device
JP5901898B2 (ja) 2011-06-17 2016-04-13 花王株式会社 容器の包装装置
CN102496710B (zh) * 2011-12-31 2014-01-08 湖南杉杉户田新材料有限公司 一种镍基多元正极材料及其制备方法
JP6345118B2 (ja) 2012-10-29 2018-06-20 住友化学株式会社 正極活物質およびその製造方法
CN103682270A (zh) * 2013-12-05 2014-03-26 北京大学 一种类聚阴离子的锂离子电池层状正极材料及其制备方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080254368A1 (en) * 2007-03-30 2008-10-16 Sony Corporation Cathode active material, cathode, nonaqueous electrolyte battery, and method for manufacturing cathode
US20100136412A1 (en) * 2008-11-28 2010-06-03 Kozo Watanabe Method for producing lithium-containing composite oxide and non-aqueous secondary battery
US20140346393A1 (en) * 2012-03-16 2014-11-27 Lg Chem, Ltd. Precursor for preparing lithium composite transition metal oxide and method for preparing the same
US20160064729A1 (en) * 2014-08-29 2016-03-03 Toyota Jidosha Kabushiki Kaisha Method for producing positive electrode active material layer for lithium ion battery, and positive electrode active material layer for lithium ion battery

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11643338B2 (en) 2019-10-29 2023-05-09 Shandong Zstone New Material Technology Co., Ltd. Method and device for producing lithium transition metal oxide
CN112713263A (zh) * 2020-12-14 2021-04-27 宁波维科新能源科技有限公司 一种偏磷酸盐包覆钴酸锂材料的制备方法及包含其的锂离子电池

Also Published As

Publication number Publication date
JP6727201B2 (ja) 2020-07-22
US11670760B2 (en) 2023-06-06
CN107001072B (zh) 2020-05-12
US20200203719A1 (en) 2020-06-25
WO2016083205A2 (en) 2016-06-02
WO2016083205A3 (en) 2016-07-21
EP3224882B1 (en) 2018-04-11
KR102484028B1 (ko) 2023-01-02
JP2018502036A (ja) 2018-01-25
CN107001072A (zh) 2017-08-01
EP3224882A2 (en) 2017-10-04
KR20170090423A (ko) 2017-08-07

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