US20160309856A1 - Flame-resistant closure piece, and flame-resistant finish or coating - Google Patents

Flame-resistant closure piece, and flame-resistant finish or coating Download PDF

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Publication number
US20160309856A1
US20160309856A1 US15/103,889 US201415103889A US2016309856A1 US 20160309856 A1 US20160309856 A1 US 20160309856A1 US 201415103889 A US201415103889 A US 201415103889A US 2016309856 A1 US2016309856 A1 US 2016309856A1
Authority
US
United States
Prior art keywords
flame
resistant
closure piece
finish
closure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US15/103,889
Other languages
English (en)
Inventor
Konstantinos Poulakis
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Gottlieb Binder GmbH and Co KG
Original Assignee
Gottlieb Binder GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gottlieb Binder GmbH and Co KG filed Critical Gottlieb Binder GmbH and Co KG
Assigned to GOTTLIEB BINDER GMBH & CO. KG reassignment GOTTLIEB BINDER GMBH & CO. KG ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: POULAKIS, KONSTANTINOS
Publication of US20160309856A1 publication Critical patent/US20160309856A1/en
Abandoned legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0069—Details
    • A44B18/0092—Details flame retardant
    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0003—Fastener constructions
    • A44B18/0015—Male or hook elements
    • A44B18/0019—Male or hook elements of a mushroom type
    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0069—Details
    • A44B18/008—Hooks or loops provided with means to reinforce the attachment, e.g. by adhesive means
    • A—HUMAN NECESSITIES
    • A44—HABERDASHERY; JEWELLERY
    • A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
    • A44B18/00—Fasteners of the touch-and-close type; Making such fasteners
    • A44B18/0069—Details
    • A44B18/0088—Mixed male and female members
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/016—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes
    • C09J175/06—Polyurethanes from polyesters

Definitions

  • the invention relates to a flame-resistant closure piece that is adapted to a corresponding closure piece such that a detachable closure is formed, said closure piece having at least one flat basic fabric consisting of warp threads and weft threads and having functional elements that protrude on the front side of the basic fabric, wherein the basic fabric is provided with a flame-resistant finish.
  • the invention further relates to a flame-resistant finish or coating for a closure piece, in particular for the aforementioned closure piece.
  • EP-B-0 883 354 discloses a flame-retardant fastening element, in particular a closure piece, which is adapted for releasable engagement to a second fastening element, and which has
  • the prior art fastening element thus fulfills the requirements of the vertical burn test without attachment to a substrate set forth in F.A.R. 25.853(a)(1)(i).
  • the provision or specification to this effect relates to such fastening systems that relate in particular to applications in vehicle and aircraft technology and that are used, for example, for fastening wall panels to the carrier structure of a cab of a railroad vehicle or for securing seat cover materials to airplane passenger seats and the like.
  • stringent flame-resistance requirements which can be considerably more stringent than those set forth in the aforementioned specification, are now being placed on these fastening systems.
  • the non-flame retardant, pressure-sensitive adhesive is furthermore a foam layer consisting of a pressure-sensitive acrylic foam adhesive, wherein thus-constituted adhesives are described by way of examples in more detail in WO-A-2005/017060. While the prior art solution already provides a very effective flame-retardant closure, it can nevertheless be expensive to implement, especially when it comes to the incorporation of the U-shaped fastening elements in the backing layer.
  • EP-B-0 883 354 already discloses the use of carbon material for producing a flame-retardant closure.
  • This prior art solution forming a flame-retardant closure or closure piece makes provision such that the loops as well as the basic material of the loop portion as basic fabric, from which the loops protrude as functional pieces or functional elements, are composed of carbon fibers. Accordingly, the hooks of the hook portion itself should be formed from wire.
  • the loop portion as well as the hook portion, as a further functional element have a textile nature in the prior art solution so that they can be processed, in particular sewn on, like standard textile contact closures, their flame resistance is ca.
  • EP-B-1 973 440 has already proposed a flame-retardant closure having at least one closure piece with at least one flat basic fabric consisting of warp threads and weft threads and having protruding functional threads on the front side of the basic fabric that at least partially penetrate the basic fabric and form the individual closure elements, wherein the basic fabric is non-flame retardant and has, at least on portions of its back side, a backing layer with a flame-resistant medium and/or with an active extinguishing medium, wherein the basic fabric has a finish and wherein the backing layer has, on its side facing away from the basic fabric, a bonding component in the form of an adhesive layer, for example.
  • the flame-resistant material for the backing layer can preferably be selected from the following substance groups:
  • the invention addresses the problem of creating a flame-resistant closure piece plus a flame-retardant finish that can be generally used for closure pieces, which satisfy the general criteria and specifications for flame resistance while retaining the advantages of the prior art, in particular ensuring a very high level of flame retardancy, and to improve them such that they can be obtained more easily and more economically from a manufacturing technology standpoint.
  • This problem is solved by a flame-resistant closure piece with the features of claim 1 and by a flame-resistant finish or coating according to the configuration of features of independent claim 11 .
  • Advantageous further configurations are the subject matter of the subordinate claims.
  • the basic fabric and the functional elements are predominantly, preferably entirely, made of flame-resistant plastic materials. Because all relevant components for constructing a closure piece (i.e., the basic fabric consisting of warp and weft threads as well as the functional elements and the finish) consist of flame-resistant materials, the specified criteria such as FAR or AIMS test can be readily met or fulfilled.
  • the selection of the finish according to the configuration of features of claim 11 plays a key role in this process.
  • the finish itself or a coating to be applied to the closure piece is formed from a solvent-free, moisture-curing, reactive polyurethane prepolymer-based melt adhesive, all kinds of flame-resistant closure pieces can be generated in a functionally secure and cost-effective manner. There is no counterpart to this in the prior art.
  • flame-resistant closure pieces can be created if the warp and weft threads of the basic fabric are made of PA66 plastic materials and if PP plastic materials are used as thread material for the functional elements such as loops and/or mushroom-like fastening elements.
  • the threads composed of PA66 and/or PP plastic materials have flame retardant additives that contain phosphorus compounds and/or triazine compounds and/or graphite constituents.
  • finish of the flame-resistant closure piece or other closure pieces particular preference is given to using materials as finishes that have significant amounts of polyester-polyol or polyether-polyol within a melt adhesive system.
  • melt adhesive is a composition with the following formula:
  • the finish or melt adhesive can completely saturate the basic fabric consisting of warp and weft threads and also parts of the functional elements, provided that the latter are formed from pile threads at least partially interwoven in said basic fabric.
  • the finish can also be applied to the bottom side of a backing piece that, as a component of a cast closure, then bears the functional elements on its opposite top side.
  • an additional adhesive layer likewise preferably configured as flame-resistant and having a pressure-sensitive adhesive can be applied on the bottom side of the closure piece that faces away from the functional elements.
  • FIG. 1 the fabric structure of a contact closure piece viewed from above;
  • FIG. 2 a side view of the flat contact closure piece according to FIG. 1 .
  • FIG. 1 shows a view from above of a portion of a flat contact closure piece that can be extended ad infinitum within the image plane in either image direction, the geometric dimensions of the woven fabric depending upon the specifications of the weaving machine on which the closure piece is produced.
  • these closure pieces are packaged for later use as rolls of contact closure tape (not illustrated).
  • the closure piece consists of warp threads 10 and weft threads 12 , which are transversely interwoven to form the basic fabric 14 for the contact closure piece. Furthermore, in the basic fabric 14 functional threads 16 are provided in the form of pile threads, which form a further component of the basic fabric 14 . The respective functional thread 16 then forms the individual functional or closure elements 18 for the flat contact closure piece, which shall be explained in more detail in the following. Furthermore, rather than threads the technical term yarns is often used.
  • FIG. 1 An arrow 20 indicating the production direction for the closure piece to be manufactured is visible on the top side of FIG. 1 .
  • the respective weft threads 12 are arcuately configured in the nature of a sine or a cosine wave, and the warp threads 10 run parallel to the production direction 20 and parallel to each other in rectilinear arrangement at the intersections between warp threads 10 and weft threads 12 .
  • the weft threads 12 are in an arcuately running arrangement in the basic fabric 14 , wherein in alternating sequence, the respective weft thread 12 passes over a warp thread 10 and passes under the next consecutive one.
  • the advantages of such an arcuate configuration are explained in more detail in document DE-B-102 40 986 of the patent holder and therefore shall not be discussed any further here.
  • the functional or pile thread 16 forms a loop 22 above each place where it passes under the basic fabric 14 , and then forms another loop 24 immediately afterwards, thus creating a V-binding.
  • Other types of binding are conceivable here, such as a W-binding or other similar binding of the functional thread 16 .
  • Said loops 22 , 24 form a type of closure elements 18 , and if the loops 22 , 24 remain closed as shown in FIG. 1 , a fleece-type contact closure piece arises in which hook or mushroom-type closure elements can engage in these loops 22 , 24 in such a way as to obtain a releasable contact closure as part of a closure or fastening system as a whole.
  • a fleece-type contact closure piece arises in which hook or mushroom-type closure elements can engage in these loops 22 , 24 in such a way as to obtain a releasable contact closure as part of a closure or fastening system as a whole.
  • an individual weft thread 12 can also consist of a weft thread pair or be multi-threaded.
  • warp threads 10 which according to the cross sectional or schematic view of FIG. 2 , in each case pass over a pair of weft threads 12 of the second closure piece and subsequently pass under this pair of weft threads 12 in alternating sequence.
  • the respective functional or pile thread 16 skipping a weft thread pair 12 in each case, passes over the next two weft thread pairs 12 in the sequence shown.
  • the loops of a first kind 22 and of another kind 24 are arranged offset relative to each other on the basic fabric 14 , wherein the loops of the first kind 22 form essentially closed O-shaped loops, and the loops of the second kind 24 are V-shaped or U-shaped in configuration.
  • a so-called repeating pattern for a function thread 16 therefore repeats itself in the direction of the weft threads 10 after five warp threads 10 .
  • the closure piece according to FIGS. 1 and 2 is constructed as described in greater detail in the following.
  • the warp threads 10 and the weft threads 12 are thus formed from PA66 plastic materials, which in this case are monofilament polyamide threads or yarns.
  • Said thread or yarn systems are provided with a flame-retardant additive, in particular in the form of a phosphorus compound.
  • the flame-retardant mechanism acts in the gas phase in particular, and the effect is permanent and wash-resistant.
  • use is made of an intrinsically flame-retardant polyamide fiber that does not contain any halogens.
  • the textile properties of the PA fiber are not negatively impacted by the flame-retardant additive, and the fiber turns out to be high-strength.
  • the polyamide-66 fiber in particular fulfills the specifications of DIN 4102-1, B1).
  • the pile threads 16 which as explained will eventually form the functional elements, consist of PP plastic materials.
  • the PP fibers are marketed under the brand name LIFOFLAM 70/101 PP, and the polypropylene fiber is also high-strength and has a flame-retardant agent in the form of a suitable phosphorus compound.
  • So-called triazine compounds and/or thread systems containing graphite or other carbon constituents can also be used as flame-retardant additives in lieu of the aforementioned phosphorus compounds.
  • the basic fabric 14 In order to provide the basic fabric 14 with a secure attachment and in particular to prevent the pile threads 16 from being pulled out of the basic fabric 14 under load, it is advantageous to provide the basic fabric 14 with a finish 30 , in particular to apply the finish 30 in such a way that all threads in the basic fabric system are coated with the finish 30 .
  • this layer is artificial rubber-based or acrylate-based.
  • this layer is likewise practical to constitute the acrylate as an aqueous dispersion and add a flame-retardant agent to it, which agent is marketed under the trade name Apyrol PP46 and contains ammonium salts in addition to polyphosphoric acids.
  • Apyrol PP46 a flame-retardant agent
  • an additional adhesive layer 32 is applied to the bottom side of the finish 30 facing away from the protruding functional elements 18 .
  • This adhesive layer 32 which is applied to the finish 30 like a coating, can consist of, for example, a flame-resistant pressure-sensitive adhesive or adhesive system. If the adhesive layer 32 is covered by a suitable paper material (not illustrated) on the surface exposed to the surroundings, the closure piece can be set directly on third components after the cover paper on the adhesive layer 32 is removed.
  • finish 30 constituting the finish 30 from a solvent-free, moisture-curing, reactive polyurethane prepolymer-based melt adhesive has proven to be particularly advantageous from a flame retardancy standpoint.
  • a polyurethane melt adhesive is marketed under the brand name AdtraPUR F 9131-UV.
  • the finish to be applied like a coating for the basic fabric 14 should in particular be applied at the rate of between 40 to 200 g/m 2 , preferably 120 g/m 2 .
  • the particularly preferred finish to apply has the following formula:
  • UV stabilizers and so-called antioxidants which owing to their low concentration cannot negatively impact the process parameters during the manufacturing of the closure piece.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Slide Fasteners, Snap Fasteners, And Hook Fasteners (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US15/103,889 2013-12-27 2014-11-19 Flame-resistant closure piece, and flame-resistant finish or coating Abandoned US20160309856A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102013022112.9A DE102013022112A1 (de) 2013-12-27 2013-12-27 Schwer entflammbares Verschlussteil sowie schwer entflammbare Appretur oder Beschichtung
DE102013022112.9 2013-12-27
PCT/EP2014/003085 WO2015096877A1 (de) 2013-12-27 2014-11-19 Schwer entflammbares verschlussteil sowie schwer entflammbare appretur oder beschichtung

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2014/003085 A-371-Of-International WO2015096877A1 (de) 2013-12-27 2014-11-19 Schwer entflammbares verschlussteil sowie schwer entflammbare appretur oder beschichtung

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US16/402,393 Division US20190254387A1 (en) 2013-12-27 2019-05-03 Flame-resistant finish or coating

Publications (1)

Publication Number Publication Date
US20160309856A1 true US20160309856A1 (en) 2016-10-27

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Family Applications (2)

Application Number Title Priority Date Filing Date
US15/103,889 Abandoned US20160309856A1 (en) 2013-12-27 2014-11-19 Flame-resistant closure piece, and flame-resistant finish or coating
US16/402,393 Abandoned US20190254387A1 (en) 2013-12-27 2019-05-03 Flame-resistant finish or coating

Family Applications After (1)

Application Number Title Priority Date Filing Date
US16/402,393 Abandoned US20190254387A1 (en) 2013-12-27 2019-05-03 Flame-resistant finish or coating

Country Status (6)

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US (2) US20160309856A1 (de)
EP (1) EP3086682A1 (de)
JP (1) JP6594882B2 (de)
CN (1) CN105848512A (de)
DE (1) DE102013022112A1 (de)
WO (1) WO2015096877A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20210267321A1 (en) * 2020-02-19 2021-09-02 Leonard A. Duffy Self-Sealing Closure System and Method

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP7144781B2 (ja) * 2018-10-25 2022-09-30 ダイニック株式会社 鉄道車両用座席表地部材及びその製造方法
US20200277718A1 (en) * 2019-02-28 2020-09-03 Velcro BVBA Making soft fabric touch fasteners
DE102019006683A1 (de) 2019-09-24 2021-03-25 Gottlieb Binder Gmbh & Co. Kg Windel
DE102022127854A1 (de) 2022-10-24 2024-04-25 Gottlieb Binder Gmbh & Co. Kg Verschlussteil

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Publication number Priority date Publication date Assignee Title
US20210267321A1 (en) * 2020-02-19 2021-09-02 Leonard A. Duffy Self-Sealing Closure System and Method

Also Published As

Publication number Publication date
EP3086682A1 (de) 2016-11-02
JP2017501811A (ja) 2017-01-19
DE102013022112A1 (de) 2015-07-02
JP6594882B2 (ja) 2019-10-23
US20190254387A1 (en) 2019-08-22
WO2015096877A1 (de) 2015-07-02
CN105848512A (zh) 2016-08-10

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