US20160068722A1 - Self-adhesive compound and use thereof in an adhesive tape - Google Patents

Self-adhesive compound and use thereof in an adhesive tape Download PDF

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Publication number
US20160068722A1
US20160068722A1 US14/780,879 US201414780879A US2016068722A1 US 20160068722 A1 US20160068722 A1 US 20160068722A1 US 201414780879 A US201414780879 A US 201414780879A US 2016068722 A1 US2016068722 A1 US 2016068722A1
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Prior art keywords
resin
adhesive
pressure
sensitive adhesive
elastomer
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US14/780,879
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Inventor
Daniel Schmitz-Stapela
Thorsten Krawinkel
Thilo Dollase
Anika Petersen
Tanja Striberny
Andreas Westphal
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Tesa SE
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Tesa SE
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Assigned to TESA SE reassignment TESA SE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: WESTPHAL, ANDREAS, STRIBERNY, TANJA, SCHMITZ-STAPELA, DANIEL, DOLLASE, THILO, KRAWINKEL, THORSTEN, PETERSEN, Anika
Assigned to TESA SE reassignment TESA SE CHANGE OF ADDRESS Assignors: TESA SE
Publication of US20160068722A1 publication Critical patent/US20160068722A1/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02—Vinyl aromatic monomers and conjugated dienes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/105—Esters; Ether-esters of monocarboxylic acids with phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3435—Piperidines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
    • C08K5/3472—Five-membered rings
    • C08K5/3475—Five-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C08L57/02—Copolymers of mineral oil hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38—Pressure-sensitive adhesives [PSA]
    • C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/387—Block-copolymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2453/00—Presence of block copolymer
    • C09J2453/003—Presence of block copolymer in the primer coating

Definitions

  • the invention relates to a pressure-sensitive adhesive and also to the use thereof in a pressure-sensitive adhesive strip comprising at least one layer, which is redetachable without residue or destruction by extensive stretching substantially in the bond plane.
  • PSAs Pressure-sensitive adhesives
  • PSAs are adhesives which permit a durable join to the substrate even under relatively weak applied pressure and which after use can be detached from the substrate again substantially without residue.
  • PSAs At room temperature, PSAs have a permanently pressure-sensitively adhesive effect, hence having a sufficiently low viscosity and a high initial tack, so that they wet the surface of the particular bonding base even under low applied pressure.
  • the bondability of the adhesives derives from their adhesive properties, and the redetachability from their cohesive properties.
  • Elastically or plastically highly extensible pressure-sensitive adhesive strips which can be detached again without residue or destruction by extensive stretching in the bond plane are known from, for example, U.S. Pat. No. 4,024,312 A, DE 33 31 016 C2, WO 92/01132 A1, WO 92/11333 A1, DE 42 22 849 A1, WO 95/06691 A1, DE 195 31 696 A1, DE 196 26 870 A1, DE 196 49 727 A1, DE 196 49 728 A1, DE 196 49 729 A1, DE 197 08 364 A1, DE 197 20 145 A1, DE 198 20 854 A1 and DE 100 03 318 A1, and are also referred to below as strippable pressure-sensitive adhesive strips.
  • Strippable self-adhesive tapes of this kind are used frequently in the form of single- or double-sidedly pressure-sensitively adhesive adhesive-sheet strips, which preferably have a nonpressure-sensitively adhesive grip region, from which the detachment operation is initiated.
  • Fields of use of aforesaid strippable pressure-sensitive adhesive strips include in particular the residueless and nondestructively redetachable fixing of light to moderately heavy articles in the home, workplace, and office. In these applications they replace conventional fastening means such as, for example, drawing pins, roundhead needles, thumb tacks, nails, screws, conventional self-adhesive tapes, and liquid adhesives.
  • Key to the successful use of the pressure-sensitive adhesive strips is not only the possibility of residueless and nondestructive redetachment of bonded articles, but also their quick and easy bonding and also their secure hold for the envisaged period of bonding. It should be borne in mind in particular here that the adhesive strips must function on a large number of substrates, in order to be able to serve as a universal fixing in the home, workplace, and office.
  • Pressure-sensitive adhesive strips of these kinds are available commercially, in the form of the tesa Powerstrips® and 3M Command Adhesives.
  • styrene block copolymer-based PSAs Very high holding performance has been realizable to date, commercially, only with styrene block copolymer-based PSAs. These styrene block copolymers always include unsaturated polydiene blocks. Polydienes are intrinsically susceptible to thermooxidative aging and may be damaged by radiation and ozone.
  • a further key aspect of such strips, especially when they are to be used on transparent surfaces such as windows, is their transparency.
  • tesa markets strippable transparent products with moderate holding performance as tesa Powerstrips® Deco. 3M offers transparent adhesive strips featuring a holding performance of up to 900 g.
  • EP 1 418 212 A1 describes transparent adhesive strips, redetachable without residue or destruction, which are of triple-ply design.
  • the middle layer contributes the major part of the mechanical properties to the product properties, but is unstable toward UV light and ozone on account of its formulation.
  • the outer layers take on a filter function for ozone and UV light.
  • a disadvantage of this approach is its multilayerness, which necessitates a multistage production process. Furthermore, the achievable holding performances are limited due to the adhesive formulation forming the outer layers.
  • Multilayer products or those which include carriers always have the disadvantage either that highly specific machines are required for production, or that a multiplicity of individual process steps have to be carried out. Both of these are detrimental to the production costs.
  • the object is therefore to provide pressure-sensitive adhesives which exhibit high holding and bonding performance, high transparency, minimal tinting, and sufficient stability with respect to light, heat, and ozone, and sufficient tear strength, and also self-adhesive products comprising such pressure-sensitive adhesives.
  • Corresponding self-adhesive products are preferably of single-layer (carrier-free) design.
  • the invention relates accordingly to a pressure-sensitive adhesive at least comprising
  • the invention further relates to a pressure-sensitive adhesive at least comprising
  • the pressure-sensitive adhesive is advantageously formulated such that it has a specific viscoelastic behavior. Viscoelastic behavior is displayed by many polymers and all PSAs. Their mechanical properties are distinguished by a combination of elastic and viscous components (regarding the viscoelasticity, see, for example, J. D. Ferry, Viscoelastic Properties of Polymers, 3 rd edn., 1980, J. Wiley, Hoboken, pages 1 to 3). The reason for this is the required ozone resistance, which in the case of extensible materials is dependent not only on the chemical properties of the formula ingredients (K. W. Ho, J. Polym. Sci. A—Polym.
  • the ozone resistance is particularly relevant for the detachment of the adhesive strips. Where detachment takes place with extension, thereby permitting substrate destruction and residues of adhesive to be avoided, a high tear strength on the part of the adhesive strips is a desideratum. The tear strength can be adjusted effectively through block copolymers, but ozone damage may exert a significantly adverse effect on the susceptibility to tearing.
  • the viscoelastic properties also have an influence on ozone resistance.
  • this can be illustrated by looking at the ozone resistance of pure (unformulated) polybutadiene block copolymers and comparing the results with adhesives which comprise polybutadiene block copolymers that are the same but are already formulated with tackifying resins.
  • the pure polybutadiene block copolymers are chemically reactive toward ozone (K. W. Ho, J. Polym. Sci. A—Polym. Chem., 1986, 24, pages 2467 to 2468).
  • An assumed possible mechanism is that known as the Criegee mechanism, via which attack on the main-chain double bond may be accompanied by chain scission within the polybutadiene block.
  • G′ storage modulus
  • G′′ loss modulus
  • G′′/G′ ratio G′′/G′, identified as loss factor tan ⁇ (tan delta), which can be determined by Dynamic Mechanical Analysis (DMA) (see test J).
  • DMA Dynamic Mechanical Analysis
  • G′ is a measure of the elastic component
  • G′′ a measure of the viscous component of a substance. Both variables are dependent on the deformation frequency and the temperature.
  • the loss factor tan ⁇ is a measure of the elasticity and the flow capacity of the substance under investigation.
  • the variables can be determined using a rheometer.
  • the material under investigation is exposed to a sinusoidally oscillating shearing stress in, for example, a plate/plate arrangement.
  • the deformation is measured as a function of time, and the time offset of this deformation ⁇ (gamma) relative to the introduction of the shearing stress ⁇ (tau) is measured.
  • This time offset (phase shift between shear stress vector and deformation vector) is identified as phase angle ⁇ (delta).
  • the derivations are as follows:
  • adhesive formulations for transparent, residuelessly redetachment-free adhesive strips are advantageous in respect not only of technical adhesive properties but also application-relevant ozone resistance when they exhibit a specific viscoeleastic behavior, having been formulated in fact such that the tan ⁇ at application temperature (here 25° C.) at 10 rad/s (frequency of the oscillating shearing stress) is at least 0.20 and at 100 rad/s is at least 0.40 (according to test J).
  • the tan ⁇ at application temperature (here 25° C.) at 10 rad/s is not more than 0.40 and at 100 rad/s is not more than 1.00.
  • An elastomer employed comprises, to an extent of at least 90 wt % (based on the total elastomer amount), a polybutadiene block copolymer or a mixture of different polybutadiene block copolymers.
  • This polybutadiene block copolymer or these polybutadiene block copolymers are copolymers comprising polymer blocks predominantly formed by vinylaromatics (A blocks), preferably styrene, and those predominantly formed by polymerization of 1,3-butadiene (B blocks).
  • the polybutadiene block copolymer is not hydrogenated in the polybutadiene block.
  • At least one polybutadiene block copolymer is a triblock copolymer or a higher multiblock copolymer having at least two A blocks.
  • a triblock copolymer it may have a linear A-B-A structure.
  • block copolymers of radial architecture and also star-shaped and linear multiblock copolymers. All of the aforementioned polymers may be utilized alone or in a mixture with one another. Further components present may be A-B diblock copolymers.
  • the weight-average molar mass of the block copolymers is customarily between 50 000 g/mol and 500 000 g/mol, preferably between 75 000 g/mol and 200 000 g/mol.
  • the block copolymers of the PSAs preferably possess polystyrene end blocks as A blocks.
  • polystyrene blocks polymer blocks based on other aromatic-containing homopolymers and copolymers as vinylaromatics (preferably C 8 to C 12 aromatics), having glass transition temperatures of greater than 75° C., may also be utilized, such as ⁇ -methylstyrene-containing aromatic blocks, for example.
  • Identical or different A blocks may also be included, furthermore. Glass transition temperatures are determined according to test L.
  • a blocks are also referred to as “hard blocks”.
  • B blocks are also called “soft blocks” or “elastomer blocks”. This reflects the inventive selection of the blocks in line with their glass transition temperatures (for A blocks at least 40° C., more particularly at least 60° C., and for B blocks up to ⁇ 50° C., more particularly not more than ⁇ 80° C.). These figures pertain to the pure, unblended block copolymers.
  • the polybutadiene block copolymers have a polyvinylaromatic fraction of 20 wt % to 40 wt %, preferably between 25 wt % and 35 wt %. Too low a polyvinylaromatic fraction leads to inadequate physical crosslinking, caused by microphase separation within the polybutadiene block copolymers. The physical crosslinking is important for the holding performance and the tear strength. In the case of too high a polyvinlylaromatic fraction, on the other hand, the adhesive loses tack.
  • the polybutadiene block copolymers resulting from the A and B blocks may comprise identical or different B blocks, in terms of microstructure (relative ratio of the forms of monomer linkage possible for polybutadiene, 1,4-cis, 1,4-trans, and 1,2-vinyl: preference is given to a 1,4-fraction (cis+trans) of >75%, very preferably of >90%, based on the polybutadiene blocks, and a 1,4-cis fraction of >40%, based on the polybutadiene blocks) and/or of chain length.
  • microstructure relative ratio of the forms of monomer linkage possible for polybutadiene, 1,4-cis, 1,4-trans, and 1,2-vinyl
  • a high fraction of 1,4-linkage and especially 1,4-cis-linkage on the part of the monomer units in the polybutadiene blocks results in advantageous tension/extension characteristics, resulting in sufficient extensibility, which is important for the residueless redetachment under stretching.
  • the fraction of the polybutadiene block copolymers, more particularly polystyrene-polybutadiene block copolymers, in total, based on the overall pressure-sensitive adhesive, is at least 40 wt %, preferably at least 45 wt %.
  • a result of an inadequate fraction of polybutadiene block copolymers is that the cohesion of the PSA is relatively low and, for example, the tip-shear test is no longer passed.
  • the maximum fraction of the polybutadiene block copolymers, more particularly polystyrene-polybutadiene block copolymers, in total, based on the overall pressure-sensitive adhesive, is not more than 60 wt %, preferably not more than 55 wt %. Too high a fraction of polybutadiene block copolymers may have the consequence, in turn, that the PSA is barely still pressure-sensitively adhesive.
  • an elastomer mixture which, based on the total amount of elastomer used, comprises at least 50 wt %, preferably at least 60 wt %, of A-B-A triblock copolymer and, as a complement, 50 wt % or, as a preferred complement, 40 wt % of A-B diblock copolymer.
  • the requirements can be met not only in terms of holding and bonding performance, residueless redetachability, and optical properties, but also in respect of resistance (oxidative aging), despite the fact that the polybutadiene block copolymers are unsaturated compounds, if formulation takes place in accordance with the invention and, in particular, there is a correspondingly advantageous viscoelastic behavior present.
  • tackifying resin kind 1 is a hydrocarbon resin.
  • the selection of the tackifying resin kind 1 influences the tinting of the adhesive formulation, its resistance, and the compatibility with the remaining formulation ingredients, especially the polybutadiene block copolymer-based elastomer.
  • Tackifying resin kind 1 includes nonhydrogenated and preferably partly hydrogenated hydrocarbon resins having a softening temperature (Ring & Ball) of at least 90° C. and preferably of not more than 125° C. Very preferably the softening temperature is at least 95° C. and not more than 115° C.
  • Examples of representatives of tackifying resin kind 1 include hydrogenated and nonhydrogenated polymers of dicyclopentadiene, nonhydrogenated, partially hydrogenated or selectively hydrogenated hydrocarbon resins based on C 5 , C 5 /C 9 or C 9 monomer streams, polyterpene resins based on ⁇ -pinene and/or ⁇ -pinene and/or ⁇ -limonene.
  • Hydrocarbon resins preferably have a Gardener value of ⁇ 1. The Gardener value is determined according to ASTM D1544. It involves dissolving 50 wt % of resin in 50 wt % of toluene and investigating the color using reference specimens.
  • Tackifying resins of tackifying resin kind 1 having a softening temperature of not more than 110° C. have a degree of hydrogenation of between 90% and 0% (where 100% means fully hydrogenated and 0% nonhydrogenated), preferably between 90% and 50%.
  • Tackifying resins of tackifying resin kind 1 having a softening temperature of greater than 110° C. have a degree of hydrogenation of between 70% and 0%, preferably between 70% and 50%.
  • the selection of the correct degree of hydrogenation is important in relation to the compatibility of the tackifying resins with the elastomers.
  • Tackifying resin kind 1 where it comprises a partly hydrogenated tackifying resin, is employed, according to a further preferred embodiment of the invention, in a fraction of at least 25 wt % and not more than 60 wt %, preferably at least 30 wt % and not more than 50 wt % (based on the adhesive composition).
  • Tackifying resin kind 1 where it comprises a nonhydrogenated tackifying resin, is employed, according to a further preferred embodiment of the invention, in a fraction of at least 15 wt % and not more than 30 wt %, preferably at least 18 wt % and not more than 28 wt % (based on the adhesive composition).
  • Tackifying resin kind 2 is employed depending on the selection of tackifying resin kind 1.
  • tackifying resin kind 2 is a hydrocarbon resin (nonhydrogenated, partly or fully hydrogenated), a terpene-phenolic resin or a rosin (nondisproportionated or disproportionated, partly or fully hydrogenated). Tackifying resin kind 2 substantially influences the balance between holding performance (cohesion) and bonding performance (adhesion).
  • the degree of hydrogenation of the tackifying resins of tackifying resin kind 2 is at least 0% and not more than 100%, preferably not more than 70%. If the resin is unhydrogenated or only slightly hydrogenated, then typically as little as possible is used, since otherwise there may be tinting of the adhesive.
  • Resins of tackifying resin kind 2 have a softening temperature of at least 90° C. and preferably not more than 115° C.
  • Tackifying resins of tackifying resin kind 2 having a softening temperature of at least 90° C. and not more than 105° C. are employed up to a proportion of amount of resin kind 1 to amount of resin kind 2 of 1:1.
  • Tackifying resins of tackifying resin kind 2 having a softening temperature of >105° C. are employed (based on the total adhesive) in a proportion of not more than 25 wt %, preferably not more than 15 wt %.
  • tackifying resin kind 1 If a resin having a softening temperature of not more than 110° C. is used as tackifying resin kind 1, then there is no need for tackifying resin kind 2, though it can be selected in order to carry out fine-tuning of the technical adhesive properties in accordance with requirements.
  • At least one of the resins of resin kind 1 and resin kind 2 is partly hydrogenated.
  • the proportion of partly hydrogenated resin in the total adhesive is preferably at least 25 wt %, very preferably at least 30 wt %.
  • the total tackifying resin content of the adhesive is at least 30 wt %, preferably at least 40 wt %, and not more than 60 wt %, preferably not more than 50 wt %.
  • the plasticizing resin serves for the final fine-tuning of the cohesion/adhesion balance.
  • a plasticizing resin or plasticizing-resin mixture having a melt viscosity at 25° C. and 1 Hz of at least 25 Pa*s, preferably of at least 50 Pa*s, and a softening temperature of ⁇ 25° C.
  • the melt viscosity is determined according to test K.
  • the plasticizing resin may very preferably be a hydrocarbon-based or a rosin-based plasticizing resin.
  • the plasticizing resin or plasticizing-resin mixture is employed with a fraction of 0 wt % and not more than 6 wt %, based on the total adhesive composition.
  • Protectants in particular may be added as further additives to the adhesive. They include primary and secondary aging inhibitors, light and UV stabilizers, and flame retardants, and also fillers, provided the optical properties still meet the stated requirements.
  • Typical amounts for use of an additive are up to 1 wt %, based on the total adhesive composition.
  • Particularly advantageous are aging inhibitors which leave behind no colored residues on bonding substrates (in this regard, see the prior art in EP 1 341 862 B1).
  • Fillers can be added at higher levels, typically in a fraction of up to 5 wt %, based on the total adhesive composition.
  • the adhesive of the invention is antiozonant-free.
  • Formulations of the invention have the following profile of properties:
  • a transparent adhesive strip which is detachable by extensive stretching and which is constructed carrierlessly from this pressure-sensitive adhesive. Production is preferably solvent-free. Solvent-containing processes, however, are also conceivable.
  • Typical product constructions are adhesive tapes (adhesive transfer tapes), adhesive sheets and diecuts (adhesive strips).
  • Layer thicknesses are at least 25 ⁇ m, preferably at least 100 ⁇ m, and up to 2 mm. Very preferred layer thicknesses are between about 500 ⁇ m and about 800 ⁇ m. Diverse application possibilities are also conceivable for adhesive tapes between about 150 ⁇ m and about 400 ⁇ m.
  • Adhesive sheets can take on any desired extents in both dimensions.
  • Adhesive tapes are, for example, 2 mm, 5 mm, 10 mm, 20 mm, or 50 mm wide.
  • Adhesive tapes may be in the form of wound rolls.
  • adheresive tape encompasses, in the sense of this invention, all sheetlike structures such as two-dimensionally extended sheets or sheet sections, tapes with extended length and limited width, tape sections, diecuts, labels, and the like.
  • Diecuts typically have a length of at least 5 mm. Lengths may also be 10 mm, 20 mm, 50 mm, 100 mm, or more.
  • Widths are typically at least 2 mm. Widths may also be 5 mm, 10 mm, 20 mm, 50 mm, or more.
  • the diecuts are customarily longer than they are broad, with the stretching for redetachment in that case lying advantageously along the longitudinal axis. All angles of the diecuts may be 90° or deviations therefrom. Also possible are forms in which the diecut is tapered in at least one direction and in particular runs to a point. Edges may also be rounded.
  • Adhesive products especially diecuts, may include grip tab regions, which are not tacky on the top and/or bottom face of the diecut.
  • This region serves as a grip tab, which is pulled in order to produce the extensive stretching especially in the bond plane, and is therefore nonadhesive preferably on both sides, as a result in particular of the application of foil or paper sections.
  • the region may be produced by irradiation, powdering, or neutralization of the adhesive.
  • a varnish or a primer may be applied at the corresponding sites.
  • the surface moreover, may be modified by chemical treatment such as etching, in order in each case to generate nonadhesive zones.
  • Adhesive products are provided in particular on a release liner (preferably siliconized paper or foil).
  • the liner may be release-furnished on one side.
  • a second ply of a liner is used to mask the second surface (especially in the case of diecuts).
  • the liner may also be release-furnished on both sides. In that case it is possible to operate with one liner ply (especially in the case of adhesive tapes).
  • the core of the invention lies clearly in the use of the PSAs of the invention in single-layer pressure-sensitive adhesive strips redetachable without residue or destruction by extensive stretching substantially in the bond plane, it would not do justice to the invention if the PSAs of the invention could not also be used in multilayer PSA strips.
  • the ozone stability of formulations according to the invention can be utilized advantageously.
  • the concept of the invention therefore also encompasses constructions having an extensible carrier in the middle of the adhesive strips, in which case the extensibility of the carrier must be sufficient to ensure detachment of the adhesive strip by extensive stretching.
  • Serving for example as carriers may be highly stretchable films.
  • Examples of extensible carriers which can be used advantageously are transparent versions from WO 2011/124782 A1, DE 10 2012 223 670 A1, WO 2009/114683 A1, WO 2010/077541 A1, WO 2010/078396 A1.
  • PSAs of the invention may form the middle, the inner, and the outer layers of the adhesive strips.
  • internal layers may be constructed alternatively from adhesives based on styrene block copolymers saturated in the elastomer block, and on the basis of styrene block copolymers unsaturated in the elastomer block.
  • Single-sidedly pressure-sensitive adhesive strips may be obtained, for example, by rendering the pressure-sensitive adhesive strip inert on one side.
  • the adhesive strip of the invention may be used with outstanding effect for the bonding of an article on a hydrophilic surface.
  • the adhesive strip of the invention can be used advantageously in an assembly where the adhesive strip is bonded between two substrates of which at least one is transparent and/or one substrate is designed in such a way that a load can be affixed thereto.
  • the transparent substrate(s) in this case may consist of glass or of plastics such as polycarbonates, poly(meth)acrylates, or polystyrenes.
  • the substrate suitable for accommodating a load may be a hook element.
  • a substrate is at the same time transparent.
  • the tip-shear load starting from the substrate on account of the load is transferred to the adhesive strip.
  • FIG. 1 shows the pressure-sensitive adhesive strip of the invention where the core layer consists of an adhesive
  • FIG. 2 shows the pressure-sensitive adhesive strip of the invention where the core layer consists of a carrier
  • FIG. 3 shows how an article is bonded on a substrate using an adhesive strip as per FIG. 1 ,
  • FIG. 4 shows the method for detaching the article bonded with the pressure-sensitive adhesive strip
  • FIG. 5 shows dynamic-mechanical profiles of adhesives of the invention, and of materials/formulations employed for comparison, and
  • FIG. 6 shows the diagrammatic representation for evaluating a glass transition temperature by test L.
  • FIG. 7 shows micrographs of adhesive sheets after the ozone test. a) No ozone damage b) slight ozone damage c) severe ozone damage
  • FIG. 1 shows the pressure-sensitive adhesive strip 10 of the invention wherein the core layer 1 consists of the adhesive of the invention, which is redetachable by extensive stretching particularly in the bond plane.
  • the core layer 1 has a region which serves as a grip tab, on which pulling takes place in order to effect the extensive stretching particularly in the bond plane of the core layer 1 .
  • This region is rendered nonpressure-sensitive adhesive on both sides by the application of preferably siliconized foil or paper sections 6 .
  • FIG. 2 shows the pressure-sensitive adhesive strip 10 of the invention wherein the core layer 1 consists of a carrier which is redetachable by extensive stretching particularly in the bond plane.
  • Applied on the carrier 1 are two adhesive layers 2 , 3 of the invention, which preferably have the same composition.
  • FIG. 3 shows how an article 11 is bonded to a substrate 12 —a hydrophilic substrate, for example—using an adhesive strip 10 as per FIG. 1 .
  • the article 11 is a hook. 11 and/or 12 may be transparent in configuration.
  • FIG. 4 shows the method for detaching the article 11 bonded with the pressure-sensitive adhesive strip 10 .
  • Pulling takes place from the grip tab of the adhesive strip 10 in the direction of the bond plane, leading to stretching. On account of the stretching, the core layer loses bond strength, and parts from the substrate 12 .
  • the stretching of the core layer 1 is continued until separation of the core layer 1 from the substrate 12 is complete.
  • FIG. 5 represents the measurement plots for examples 1 to 10, obtained according to test method J. From the data, the advantageous tan ⁇ ranges can be read off.
  • FIG. 6 shows, diagrammatically, the procedure for determining the glass transition temperature from a thermogram recorded according to test L.
  • Test A Tip-Shear Holding Power
  • the tip-shear holding power Following application of the selected tip-shear load by the hanging-on of a weight (20 N with 50 mm lever arm), a record is made of the time taken for the bond to fail (i.e., the tip-shear holding power).
  • the test conditions are 23° C. and a relative humidity of 50%. For many applications, the higher the tip-shear holding power, the better.
  • the specimens are then pressed for 10 seconds under an applied pressure of 100 N per 10 cm 2 of pressure-sensitive adhesive surface, followed by conditioning at 40° C. for 15 minutes.
  • the test panels are subsequently fixed horizontally, with the grippable region of the adhesive strips pointing downward.
  • a clip (20 g) is used to fasten a weight of 50 g to the nonadhesive grip tab, and so the resulting peeling load (approximately 0.7 N per 20 mm of adhesive-strip width) acts orthogonally to the bond plane.
  • peel travel units: mm per 24 h
  • the specimens thus obtained are pressed on with a force of 500 N for 5 seconds, after which they are left in the unloaded state for 5 minutes.
  • the steel plates each have a bore at their bottom end to accommodate an S-shaped steel hook.
  • the bottom end of the steel hook carries a further steel plate, which allows the test arrangement to be fixed for measurement in the lower jaw of a tensile testing machine.
  • the bonds are stored at +40° C. for 24 hours.
  • the adhesive-sheet strip After reconditioning to RT, the adhesive-sheet strip is removed at a pulling speed of 1000 mm/min parallel to the bond plane and without contact with the edge regions of the two steel plates. During this procedure, the required detachment force in N is recorded. The parameter reported is the maximum of the stripping stress values in N/cm.
  • each sheet of adhesive under test in dimensions of 20 mm ⁇ 50 mm, provided at one end on both sides with a nonpressure-sensitively adhesive grip tab region (obtained by laminating application of 25 ⁇ m-thick, biaxially oriented polyester film of dimensions 20 mm ⁇ 13 mm), are bonded between two glass plates. The bond is made such that the grip tab protrudes from the bondline by 10 mm.
  • each adhesive strip Prior to the application of the second glass plate, each adhesive strip is pressed on with a force of 100 N.
  • the adhesive strips are then irradiated for seven days with a sunlight lamp (Osram Ultra Vitalux 300 W) through the glass plate from a distance of 80 cm.
  • the test temperature is 25° C. After the seven day storage, the adhesive strips are parted by pulling, with pulling taking place at an angle of 15°. The number of torn adhesive strips is recorded. The result is reported in % torn adhesive strips.
  • the procedure is as per DIN 6174, and the color characteristics are investigated in the CIELab three-dimensional space, formed by the three color parameters L*, a* and b*. This is done using a BYK Gardener spectro-guide instrument, equipped with a D/65° lamp.
  • L* indicates the gray value
  • a* the color axis from green to red
  • b* the color axis from blue to yellow.
  • the positive value range for b* indicates the intensity of the yellow color component.
  • a white ceramic tile with a b* of 1.68 was used as reference. This tile also serves as a sample holder, onto which the adhesive layer under test is laminated. Colorimetry takes place on the pure adhesive layer at a thickness of 650 ⁇ m in each case, after the adhesive layer has been freed from the release liners.
  • the transparency or degree of transmittance is the ratio of the luminous power arriving at the reverse face of a body through which light is irradiated, to the luminous power incident on the front face. Transmission is curtailed by reflection and possibly absorption.
  • transmittance (1 ⁇ reflectance ⁇ absorptance).
  • Transmission and haze are determined in accordance with ASTM D1003 on a haze-gard plus from Byk-Gardner. The procedure for this was that of ASTM D1003.
  • the adhesive strip is first adhered without bubbles to a glass microscopy slide precleaned with isopropanol (VWR, ECN 631-1552, #201107). Thereafter a PET film 50 ⁇ m thick (Melinex® 401, DuPont Teijin Films) is laminated on using a manual roller, with strict attention paid to absence of bubbles and absence of dust. The resulting laminate is stored at 60° C. for 3 days and then subjected to measurement.
  • the weight-average molecular weight M w was determined by gel permeation chromatography (GPC).
  • the eluent used was THF, measurement took place at 23° C.
  • the precolumn used was PSS-SDV, 5 ⁇ , 10 3 ⁇ , ID 8.0 mm ⁇ 50 mm. Separation took place using the columns PSS-SDV, 5 ⁇ , 10 3 and also 10 4 and 10 6 each with ID 8.0 mm ⁇ 300 mm.
  • the tackifier resin softening temperature is carried out according to the relevant methodology, which is known as Ring & Ball and is standardized according to ASTM E28.
  • a suitable pen is used to mark two parallel lines 6 cm apart on a stoneware tile (V&B Fliesen GmbH, Rotensteiner Weg, 66663 Merzig, article No. 1106TW02). Thereafter a distance of 3 cm in length is drawn in on a sheet of adhesive with dimensions of 50 mm ⁇ 20 mm (length ⁇ width) in the longitudinal direction. The adhesive sheet is then stretched to exactly twice its length and in the extended condition is fixed on the stoneware tile in such a way that the markings on adhesive sheet and tile overlap. The adhesive film is lined with release foil and pressed on the tile with a 2 kg roller-applied weight, so that the tension of the adhesive sheet is retained. The sample has its liner removed again, and is then stored open for 72 hours at 25° C.
  • the specimens are considered ozone-resistant if there is no perceptible damage (cracks, holes, clouding) of the specimen. Appearance of this kind is shown in FIG. 1 a.
  • the dynamic glass transition temperature data are based on the determination by means of dynamic-mechanical analysis (DMA) at low frequencies (frequency sweep; measuring range: 0.01 to 512 rad/s; temperature: 25° C.; deformation 1%; Rheometric ARES class; parallel plate arrangement, sample thickness 1 mm: sample diameter 25 mm: measuring head: 2000 g spring-mounted with standard force (2 k Bendix)).
  • DMA dynamic-mechanical analysis
  • a shear stress sweep was carried out in a shear stress-controlled DSR 200 N rheometer from Rheometrics Scientific, in rotation.
  • a cone/plate measuring system with a diameter of 25 mm (cone angle 0.1002 rad) was employed; the measuring head was air-mounted and suitable for standard force measurements.
  • the slot was 0.053 mm and the measuring temperature 25° C.
  • the frequency was varied from 0.002 Hz to 200 Hz, and the melt viscosity at 1 Hz was recorded.
  • the glass transition temperature of polymer blocks in block copolymers was determined by means of dynamic scanning calorimetry (DSC). For this purpose about 5 mg of the untreated block copolymer samples were weighed into an aluminum crucible (volume 25 ⁇ l) and closed with a perforated lid. For the measurement, a DSC 204 F1 from Netzsch was used, and was operated under nitrogen for inertization. The sample was cooled first to ⁇ 150° C., then heated at a heating rate of 10 K/min up to +150° C., and cooled again to ⁇ 150° C. The subsequent second heating curve was run again at 10 K/min and the change in the heat capacity was recorded. Glass transitions are identified as steps in the thermogram. The glass transition temperature is evaluated as follows (see FIG.
  • a tangent is applied in each case to the baseline of the thermogram before ⁇ circle around (1) ⁇ and after ⁇ circle around (2) ⁇ of the step.
  • a balancing line ⁇ circle around (5) ⁇ is placed parallel to the ordinate in such a way that it intersects the two tangents, specifically so as to form two areas ⁇ circle around (3) ⁇ and ⁇ circle around (4) ⁇ of equal content (between each tangent, the balancing line, and the measuring plot).
  • the point of intersection of the balancing lines thus positioned with the measuring plot gives the glass transition temperature.
  • the kneading compounds were taken from the kneader and allowed to cool to room temperature.
  • compositions were placed between two plies of siliconized release paper and pressed to hand specimens with a layer thickness of 650 ⁇ m, using a hot press from Lauffer GmbH & CO KG, model RLKV 25, at 130° C.

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Adhesive Tapes (AREA)
US14/780,879 2013-04-15 2014-04-03 Self-adhesive compound and use thereof in an adhesive tape Abandoned US20160068722A1 (en)

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CN114641547A (zh) * 2019-11-04 2022-06-17 德莎欧洲股份公司 发泡粘合剂层和包含该发泡粘合剂层的胶带
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US20190062610A1 (en) 2019-02-28
US10717906B2 (en) 2020-07-21
EP2986683A1 (de) 2016-02-24
CN105121577B (zh) 2017-09-22
KR102200965B1 (ko) 2021-01-08
JP2016519710A (ja) 2016-07-07
JP6525957B2 (ja) 2019-06-05
CN105121577A (zh) 2015-12-02

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