US20120031040A1 - Plant for packaging confectionary products in a sterile manner - Google Patents

Plant for packaging confectionary products in a sterile manner Download PDF

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Publication number
US20120031040A1
US20120031040A1 US13/132,522 US200913132522A US2012031040A1 US 20120031040 A1 US20120031040 A1 US 20120031040A1 US 200913132522 A US200913132522 A US 200913132522A US 2012031040 A1 US2012031040 A1 US 2012031040A1
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US
United States
Prior art keywords
modules
module
assembly
strip
plant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/132,522
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English (en)
Inventor
Fabio Federici
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Soremartec SA
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Assigned to SOREMARTEC S.A. reassignment SOREMARTEC S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: FEDERICI, FABIO
Publication of US20120031040A1 publication Critical patent/US20120031040A1/en
Assigned to SOREMARTEC S.A. reassignment SOREMARTEC S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SOREMARTEC S.A.
Abandoned legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B9/00Enclosing successive articles, or quantities of material, e.g. liquids or semiliquids, in flat, folded, or tubular webs of flexible sheet material; Subdividing filled flexible tubes to form packages
    • B65B9/02Enclosing successive articles, or quantities of material between opposed webs
    • B65B9/04Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B25/00Packaging other articles presenting special problems
    • B65B25/005Packaging other articles presenting special problems packaging of confectionery
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02Sterilising, e.g. of complete packages
    • B65B55/025Packaging in aseptic tunnels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B55/00Preserving, protecting or purifying packages or package contents in association with packaging
    • B65B55/02Sterilising, e.g. of complete packages
    • B65B55/04Sterilising wrappers or receptacles prior to, or during, packaging
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B59/00Arrangements to enable machines to handle articles of different sizes, to produce packages of different sizes, to vary the contents of packages, to handle different types of packaging material, or to give access for cleaning or maintenance purposes
    • B65B59/04Machines constructed with readily-detachable units or assemblies, e.g. to facilitate maintenance
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65BMACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
    • B65B9/00Enclosing successive articles, or quantities of material, e.g. liquids or semiliquids, in flat, folded, or tubular webs of flexible sheet material; Subdividing filled flexible tubes to form packages
    • B65B9/02Enclosing successive articles, or quantities of material between opposed webs
    • B65B9/04Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material
    • B65B9/045Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material for single articles, e.g. tablets

Definitions

  • the present invefttion relates to a plant for packaging confectionary products in a sterile manner in sterile containers or packages.
  • Each of said plants comprises a plurality of stations, which are aligned with one another along a packaging path and are all housed within a common tunnel that defines a “sterile” area or rather an area controlled in its degree of bacteriological contamination in order to ensure the sterility of the packaging.
  • a first thermoformable strip which defines an end wall of the tunnel and, after being sterilized, is heated, in a purposely designed station, and then passes into a thermoforming station for making one or more housings or compartments designed to receive, each, at least one of the aforesaid products.
  • compartments with the products to be packaged inside are then sealed by means of a second strip that is also previously sterilized and that delimits at the top a terminal length of the aforesaid tunnel and is heat-sealed on the first strip before the various compartments are physically separated from one another in a dinking station.
  • the width of the strips and the step of advance of the strips themselves are already determined in the design stage and optimized as a function of the dimensions, geometry and, in general, type of individual format or container originally conceived so that the change in format inevitably generates an increase in waste, i.e., in the amount of strips not used in the processes of thermoforming and/or closing, to such an extent as to render production less economically advantageous given, as is known, the high incidence of the cost of the strips on the overall cost of the packaged product.
  • the aim of the present invention is to provide a plant for packaging confectionary products in sterile containers, the constructional characteristics of which enable a simple and inexpensive solution of the problems set forth above.
  • a plant for packaging confectionary products in sterile containers comprising, arranged along a packaging path, at least one first assembly for sterilization and heating of a first thermoformable strip, a forming assembly for making on said first strip at least one compartment for housing said confectionary products, an assembly for feeding a confectionary product into said compartment, a second assembly for sterilization and feed of a second closing strip towards said first strip, a welding sealing assembly for connecting together said strips and closing said confectionary product within said housing compartment, a cutting assembly for cutting said strips and making at least one said container, and a sterile duct extending along said packaging path and designed to contain a sterile gas, said duct being common to said assemblies and being delimited at least partially by said strips, the plant being characterized in that each said assembly forms part of a respective operating module that is independent of the other modules and coupled to the adjacent modules in a releasable way.
  • each said module comprises a respective supporting frame that is independent of the supporting frames of the other modules, the frames supporting respective operating means designed to perform the specific function of said module and part of the frames themselves a respective half-shell casing distinct from the other casings and connected to the adjacent casings via releasable sealing means; each said casing delimiting a respective length of said sterile duct.
  • FIG. 1 is a schematic perspective view of a preferred embodiment of the plant according to teachings of the present invention.
  • FIG. 2 is similar to FIG. 1 and illustrates the plant broken down into some of its constitutive elements
  • FIG. 3 illustrates, at an enlarged scale, a detail of FIGS. 1 and 2 ;
  • FIG. 4 illustrates, in perspective view, a component of the plant of FIGS. 1 and 2 .
  • FIG. 1 designated as a whole by 1 is a plant for packaging confectionary products in sterile containers.
  • confectionary products is meant both products in a solid or granular form and products in the form of a liquid or a cream.
  • the plant 1 has a modular composition or is made up of units that are mutually independent, i.e., autonomous from the mechanical, electrical, electronic, pneumatic, and management standpoints.
  • the plant 1 comprises, in succession along a packaging path P, a module 3 for feed and sterilization of a thermoformable strip 4 , which is wound off a spool 5 and fed step by step along the packaging path P by drawing devices, which are known and not described in detail.
  • the plant 1 then comprises a module 6 for heating of the thermoformable strip 4 and a module 7 for thermoforming of the thermoformable strip 4 itself.
  • the module 7 provides on the strip 4 a plurality of housings or compartments 8 having dimensions and relative positioning determined in the design stage according to the product, the type of container to be made, and the width of the strip 4 itself.
  • the plant 1 Downstream of the module 7 , in the direction of advance of the strip 4 , the plant 1 further comprises a dispensing module 9 for feeding the product to be packaged into each of the housings or compartments 8 , and a further module 10 for feed and sterilization of a heat-sealable strip 11 that can be wound off a spool 12 carried the module 10 itself.
  • the plant 1 Downstream of the module 10 , the plant 1 further comprises a welding module 13 for welding the strip 11 onto the portion of the strip 4 not involved the previous thermoforming process so as to close in a fluid-tight way each of the housings or compartments 8 , and a dinking module 14 for separating the various housings or compartments 8 from one another to form a plurality of sterile containers, which are fed towards an outlet 15 of the plant 1 by a conveyor belt 16 that forms part of the dinking module 14 itself.
  • a welding module 13 for welding the strip 11 onto the portion of the strip 4 not involved the previous thermoforming process so as to close in a fluid-tight way each of the housings or compartments 8
  • a dinking module 14 for separating the various housings or compartments 8 from one another to form a plurality of sterile containers, which are fed towards an outlet 15 of the plant 1 by a conveyor belt 16 that forms part of the dinking module 14 itself.
  • Each of the modules 3 , 6 , 7 , 9 , 10 , 13 and 14 comprises a respective operating assembly, which is in itself known; said assemblies are designated by 3 a, 6 a, 7 a, 9 a, 10 a, 13 a and 14 a , respectively.
  • the operating assemblies are pneumatically connected to a pneumatic source via dedicated valve assemblies of their own (not illustrated) and electrically connected to respective electronic control units 3 b, 6 b, 7 b, 9 b, 10 b, 13 b and 14 b.
  • the electronic control units 3 b, 6 b, 7 b, 9 b, 10 b, 13 b and 14 b are each dedicated exclusively to the corresponding operating assembly 3 a, 6 a, 7 a, 9 a, 10 a, 13 a and 14 a, are independent of one another, and are, in turn, electrically connected and controlled by a general control unit 18 for managing the entire plant 1 .
  • Each module 3 , 6 , 7 , 9 , 10 , 13 and 14 further comprises a respective structure or frame 3 c, 6 c, 7 c, 9 c, 10 c, 13 c and 14 c for supporting the corresponding operating assembly 3 a, 6 a , 7 a, 9 a, 10 a, 13 a and 14 a and the various electrical and pneumatic wiring/components; each frame 3 c, 6 c, 7 c, 9 c, 10 c , 13 c and 14 c is separate from and independent of the other frames and is set alongside and coupled to the frames adjacent thereto in a releasable way, for example via fast-coupling assemblies (not visible in the attached figures).
  • Each frame 3 c, 6 c, 7 c, 9 c, 10 c, 13 c and 14 c is supported by a guide-and-slide assembly of its own, comprising a slide defined by a plurality of bottom resting feet or portions 20 ( FIGS. 1 and 3 ) of the respective frame itself; in the particular example described, the portions 20 have respective bottom terminal seats 21 shaped like a U set upside down and engaged by a corresponding rectilinear guide 22 in a slidable way.
  • the guide 22 forms part of the aforesaid guide-and-slide assembly and part of a rail 23 for relative positioning, which is common to all the modules 3 , 6 , 7 , 9 , 10 , 13 and 14 , extends parallel to the path P, and is stably fixed on the floor.
  • each of the modules 3 , 6 , 7 , 9 , 10 , 13 and 14 can be translated along the rail 23 and hence along the aforesaid packaging path P independently of the other modules and, in particular, can be uncoupled from the rail 23 itself and moved away by simple vertical lifting, as illustrated for the module in FIG. 2 .
  • one or more modules have their respective frames arranged, each, on a respective motor-driven trolley or other equivalent means for movement of the module, designed to be controlled in position independently of the other trolleys, for displacement in a direction transverse to the aforesaid packaging path P, between an operative advanced position, in which the corresponding frame extends along the path P in a pre-determined position, and an extracted position, in which the frame is set outside of the packaging path P and in which the module does not take part in the packaging process.
  • Each of the frames supports an intermediate resting surface K, which is substantially coplanar to the surfaces K of the other frames, and on which the thermoformable strip 4 rests during its advance towards the outlet 15 .
  • the various surfaces K define at least part of a sliding guide for the thermoformable strip 4 .
  • Each of the frames arranged upstream of the sealing assembly 13 moreover supports a respective half-shell 3 d, 6 d, 7 d, 9 d and 10 d , which is set only above the corresponding resting surface K with its concavity facing the corresponding plane surface K itself and is coupled to the half-shells adjacent to it in a releasable way via the interposition of respective gaskets or labyrinth seals designated by 25 .
  • each half-shell 6 d, 7 d, 9 d and 10 d comprises a corresponding top wall 26 set facing, and superimposed only on, the corresponding plane resting surface K and -vertically raised with respect to the corresponding plane surface K itself, and two side walls 27 , which face one another and extend upwards once again starting from the respective flat resting surface K.
  • Each of the top walls 26 has a size measured parallel to the corresponding surface K and orthogonal to the path P that can be varied as a function of the width of the thermoformable strip 4 and of the strip 11 and a through opening traversed by a mobile element of the respective operating assembly 6 a, 7 a, 9 a, 10 a.
  • each half-shell 6 d, 7 d, 9 d and 10 d delimits, with a corresponding intermediate portion of the thermoformable strip 4 , a respective length of a continuous tunnel 30 ( FIG.
  • thermoformable strip 4 which is closed upstream by the feed and sterilization assembly 3 and downstream by the closing strip 11 , which progressively converges towards the underlying thermoformable strip 4 before being welded to the thermoformable strip 4 itself.
  • Supplied into the tunnel 30 is sterile air and, in general, a sterile gas containing nitrogen at a variable pressure of between 0.01 and 1 bar to create a sterile environment, in which all the packaging operations are performed.
  • each one of the modules that make up the plant 1 is perfectly interchangeable or replaceable with another functionally equivalent module, i.e., a module that performs the same function as the replaced module and can be chosen from among a plurality of modules having constructional characteristics different from one another.
  • constructional characteristics is meant the characteristics of the module that enable variation of the type, i.e., geometry and/or dimensions, of the containers produced.
  • a corresponding adjustable half-shell for forming the sterile environment enables arbitrary variation of the transverse dimensions of the tunnel 30 and makes it hence possible to use thermoformable and closing strips of different width.
  • the half-shells provided enable use of thermoformable and closing strips of widths that vary in a percentage of ⁇ 15% with respect to a given width and hence optimization of the surface of the thermoformable strip 4 , reducing to a minimum the waste resulting from dinking.
  • the fact of using a common guide rail and of coupling the different modules to the same rail in an axially slidable way makes it possible, on the one hand, to ensure always a precise positioning of the modules along the path P of advance, and on the other, to replace any of the modules by simply sliding the others along the rail.
  • sliding along the rail enables replacement of an existing module with another module having a different longitudinal dimension, i.e., a dimension measured in the direction of the packaging path.
  • the new module may be positioned in a space not necessarily identical to the one left free by the previous module.
  • said implementation enables insertion of additional modules that are able to satisfy different working processes, e.g., working processes that comprise a number of a dispensing station.
  • the plant 1 could comprise a number of modules different from the one indicated by way of example, and said modules could present frames or shapes that differ from the ones indicated once again by way of example.
  • the half-shells for obtaining the sterile environment could be provided in a way different from the one indicated by way of example once again in the perspective of facilitating transformation of the plant according to the widths of the strips to be used.

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Containers And Plastic Fillers For Packaging (AREA)
  • Packages (AREA)
  • Auxiliary Devices For And Details Of Packaging Control (AREA)
US13/132,522 2008-12-03 2009-12-02 Plant for packaging confectionary products in a sterile manner Abandoned US20120031040A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
ITTO2008A000896A IT1392253B1 (it) 2008-12-03 2008-12-03 Impianto per il confezionamento di prodotti dolciari in confezioni sterili
ITTO2008A000896 2008-12-03
PCT/IB2009/007625 WO2010064125A2 (en) 2008-12-03 2009-12-02 Plant for packaging confectionary products in a sterile manner

Publications (1)

Publication Number Publication Date
US20120031040A1 true US20120031040A1 (en) 2012-02-09

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US13/132,522 Abandoned US20120031040A1 (en) 2008-12-03 2009-12-02 Plant for packaging confectionary products in a sterile manner

Country Status (10)

Country Link
US (1) US20120031040A1 (zh)
EP (1) EP2382132B1 (zh)
CN (1) CN102300774B (zh)
BR (1) BRPI0917061B8 (zh)
CA (1) CA2745651C (zh)
ES (1) ES2404836T3 (zh)
IT (1) IT1392253B1 (zh)
MX (1) MX2011005890A (zh)
RU (1) RU2519866C2 (zh)
WO (1) WO2010064125A2 (zh)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013104359A1 (de) * 2013-04-29 2014-10-30 Krones Aktiengesellschaft Verpackungsmaschine, verpackungsanlage und verfahren zum betreiben einer verpackungsmaschine
US9637314B2 (en) 2010-11-08 2017-05-02 Krones Aktiengesellschaft Machine for processing and/or packaging objects and method for modifying a conveying section of this machine
WO2018024365A1 (de) * 2016-08-04 2018-02-08 Focke & Co. (Gmbh & Co. Kg) Verpackungsmaschine sowie verfahren zum bereitstellen eines steuerprogramms für diese
WO2018222859A1 (en) * 2017-05-31 2018-12-06 Allegiance Corporation Packaging machine and modular attachment for use with a packaging machine for providing modular vented opening package sealing
DE102011015249B4 (de) 2011-03-28 2021-09-09 Gerhard Schubert Gmbh Bearbeitungsmaschine
US20220396385A1 (en) * 2019-11-11 2022-12-15 Khs Gmbh Linear filling machine for filling containers with filling material
EP4059852A3 (en) * 2021-03-18 2023-06-07 Osgood Industries, LLC Modular frame interface

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011100784A1 (de) 2011-05-06 2012-11-08 Multivac Sepp Haggenmüller Gmbh & Co. Kg Schneidstation mit Komplettschnittwerkzeug
DE102012004341A1 (de) * 2012-03-07 2013-09-12 Gea Cfs Germany Gmbh Verpackungslinie
DE102014106333B4 (de) * 2014-05-07 2023-02-16 Pester Pac Automation Gmbh Vorrichtung
DE102017006614A1 (de) * 2017-07-12 2019-01-17 Focke & Co. (Gmbh & Co. Kg) Verpackungsmaschine
FR3078319B1 (fr) * 2018-02-28 2020-11-06 Acemma Systeme d'ensachage a gueule ouverte
DE102020207931A1 (de) * 2020-06-25 2021-12-30 Krones Aktiengesellschaft Verpackungsmaschine und Verfahren zur Herstellung von Gebinden

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US3766709A (en) * 1972-01-28 1973-10-23 Zausner Foods Corp Sterilizing device for container filling machines
US4566251A (en) * 1985-01-07 1986-01-28 Ex-Cell-O Corporation Carton forming, sterilizing, filling and sealing machine
US4807420A (en) * 1985-12-24 1989-02-28 Barker Michael J Horizontal form-fill-seal packaging machines
US5069017A (en) * 1989-07-15 1991-12-03 Karl Fabricius Aseptic filling machine for food
US6484475B1 (en) * 1999-02-02 2002-11-26 Kisters Kayat, Inc. Modular packaging machine
US6976347B2 (en) * 2002-09-13 2005-12-20 Alkar-Rapidpak, Inc. Surface pasteurization method
US7506486B2 (en) * 2005-07-29 2009-03-24 Infinity Machine & Engineering Corp. Modular packaging system

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SE423517B (sv) * 1972-08-11 1982-05-10 Tetra Pak Dev Sett att under aseptiska betingelser forpacka sterilt fyllgods i behallare
FR2615170B1 (fr) * 1987-05-12 1989-08-18 Remy & Cie E P Machine de conditionnement automatique de recipients
DE20305759U1 (de) * 2003-04-08 2004-08-19 Finnah Engineering Und Packaging Gmbh Maschine zum Abfüllen von flüssigen Nahrungs- und Genußmitteln in Becher
EP1508519A1 (en) * 2003-08-20 2005-02-23 Mars Incorporated Method and device for packaging products and array of packaged products
EP1645513A3 (en) * 2004-09-21 2006-04-19 Philip Morris Products S.A. Modular packing assembly
DE102006045292A1 (de) * 2006-09-22 2008-04-10 Emil Pester Gmbh Maschine zum Verpacken von Gegenständen in Blisterpackungen

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3766709A (en) * 1972-01-28 1973-10-23 Zausner Foods Corp Sterilizing device for container filling machines
US4566251A (en) * 1985-01-07 1986-01-28 Ex-Cell-O Corporation Carton forming, sterilizing, filling and sealing machine
US4807420A (en) * 1985-12-24 1989-02-28 Barker Michael J Horizontal form-fill-seal packaging machines
US5069017A (en) * 1989-07-15 1991-12-03 Karl Fabricius Aseptic filling machine for food
US6484475B1 (en) * 1999-02-02 2002-11-26 Kisters Kayat, Inc. Modular packaging machine
US6976347B2 (en) * 2002-09-13 2005-12-20 Alkar-Rapidpak, Inc. Surface pasteurization method
US7506486B2 (en) * 2005-07-29 2009-03-24 Infinity Machine & Engineering Corp. Modular packaging system

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9637314B2 (en) 2010-11-08 2017-05-02 Krones Aktiengesellschaft Machine for processing and/or packaging objects and method for modifying a conveying section of this machine
DE102011015249B4 (de) 2011-03-28 2021-09-09 Gerhard Schubert Gmbh Bearbeitungsmaschine
DE102013104359A1 (de) * 2013-04-29 2014-10-30 Krones Aktiengesellschaft Verpackungsmaschine, verpackungsanlage und verfahren zum betreiben einer verpackungsmaschine
WO2018024365A1 (de) * 2016-08-04 2018-02-08 Focke & Co. (Gmbh & Co. Kg) Verpackungsmaschine sowie verfahren zum bereitstellen eines steuerprogramms für diese
CN109689508A (zh) * 2016-08-04 2019-04-26 佛克有限及两合公司 包装机以及为其提供控制程序的方法
WO2018222859A1 (en) * 2017-05-31 2018-12-06 Allegiance Corporation Packaging machine and modular attachment for use with a packaging machine for providing modular vented opening package sealing
US20220396385A1 (en) * 2019-11-11 2022-12-15 Khs Gmbh Linear filling machine for filling containers with filling material
EP4059852A3 (en) * 2021-03-18 2023-06-07 Osgood Industries, LLC Modular frame interface

Also Published As

Publication number Publication date
WO2010064125A3 (en) 2010-11-25
BRPI0917061B1 (pt) 2020-09-24
EP2382132A2 (en) 2011-11-02
RU2011127220A (ru) 2013-01-10
RU2519866C2 (ru) 2014-06-20
ITTO20080896A1 (it) 2010-06-04
CA2745651C (en) 2016-12-13
CA2745651A1 (en) 2010-06-10
ES2404836T3 (es) 2013-05-29
EP2382132B1 (en) 2013-02-13
IT1392253B1 (it) 2012-02-22
CN102300774B (zh) 2015-05-13
MX2011005890A (es) 2011-12-06
CN102300774A (zh) 2011-12-28
BRPI0917061B8 (pt) 2020-12-08
BRPI0917061A2 (pt) 2017-10-03
WO2010064125A2 (en) 2010-06-10

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