WO2010064125A2 - Plant for packaging confectionary products in a sterile manner - Google Patents
Plant for packaging confectionary products in a sterile manner Download PDFInfo
- Publication number
- WO2010064125A2 WO2010064125A2 PCT/IB2009/007625 IB2009007625W WO2010064125A2 WO 2010064125 A2 WO2010064125 A2 WO 2010064125A2 IB 2009007625 W IB2009007625 W IB 2009007625W WO 2010064125 A2 WO2010064125 A2 WO 2010064125A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- modules
- module
- assembly
- plant according
- plant
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B9/00—Enclosing successive articles, or quantities of material, e.g. liquids or semiliquids, in flat, folded, or tubular webs of flexible sheet material; Subdividing filled flexible tubes to form packages
- B65B9/02—Enclosing successive articles, or quantities of material between opposed webs
- B65B9/04—Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B25/00—Packaging other articles presenting special problems
- B65B25/005—Packaging other articles presenting special problems packaging of confectionery
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B55/00—Preserving, protecting or purifying packages or package contents in association with packaging
- B65B55/02—Sterilising, e.g. of complete packages
- B65B55/025—Packaging in aseptic tunnels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B55/00—Preserving, protecting or purifying packages or package contents in association with packaging
- B65B55/02—Sterilising, e.g. of complete packages
- B65B55/04—Sterilising wrappers or receptacles prior to, or during, packaging
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B59/00—Arrangements to enable machines to handle articles of different sizes, to produce packages of different sizes, to vary the contents of packages, to handle different types of packaging material, or to give access for cleaning or maintenance purposes
- B65B59/04—Machines constructed with readily-detachable units or assemblies, e.g. to facilitate maintenance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B9/00—Enclosing successive articles, or quantities of material, e.g. liquids or semiliquids, in flat, folded, or tubular webs of flexible sheet material; Subdividing filled flexible tubes to form packages
- B65B9/02—Enclosing successive articles, or quantities of material between opposed webs
- B65B9/04—Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material
- B65B9/045—Enclosing successive articles, or quantities of material between opposed webs one or both webs being formed with pockets for the reception of the articles, or of the quantities of material for single articles, e.g. tablets
Definitions
- the present invention relates to a plant for packaging confectionary products in a sterile manner in sterile containers or packages .
- Each of said plants comprises a plurality of stations, which are aligned with one another along a packaging path and are all housed within a common tunnel that defines a "sterile" area or rather an area controlled in its degree of bacteriological contamination in order to ensure the sterility of the packaging.
- a first thermoformable strip which • •• defines an end wall of the tunnel and, ' after being sterilized, is heated, in a purposely designed station, and then passes into a thermoforming station- for making one or more housings or compartments designed to receive, each, at least one of the aforesaid products.
- compartments with the products to be packaged inside are then sealed by means of a second strip that is also previously sterilized and that delimits at the top a terminal length of the aforesaid tunnel and is heat- sealed on the first strip before the various compartments are physically separated from one another in a dinking station.
- the width of the strips and the step of advance of the strips themselves are already determined in the design stage and optimized as a function of the dimensions, geometry and, in general, type of individual format or container originally conceived so that the change in format inevitably generates an increase in waste, i.e., in the amount of strips not used in the processes of thermoforming and/or closing, to such an extent as to render production less economically advantageous given, as is known, the high incidence of the cost of the strips on the overall cost of the packaged product .
- the aim of the present invention is to provide a plant for packaging confectionary products in sterile containers, the constructional characteristics of which enable a simple and inexpensive solution of the problems set forth above.
- a plant for packaging confectionary products in sterile containers comprising, arranged along a packaging path, at least one first assembly for sterilization and heating of a first thermoformable strip, a forming assembly for making on said first strip at least one compartment for housing said confectionary products, an assembly for feeding a confectionary product into said compartment, a second assembly for sterilization and feed of a second closing strip towards said first strip, a welding sealing assembly for connecting together said strips and closing said confectionary product within said housing compartment, a cutting assembly for cutting said strips and making at least one said container, and a sterile duct extending along said packaging path and designed to contain a sterile gas, said duct being common to said assemblies and being delimited at least partially by said strips, the plant being characterized in that each said assembly forms part of a respective operating module that is independent of the other modules and coupled to the adjacent modules in a releasable way.
- each said module comprises a respective supporting frame that is independent of the supporting frames of the other modules, the frames supporting respective operating means designed to perform the specific function of said module and part of the frames themselves a respective half -shell casing distinct from the other casings and connected to the adjacent casings via releasable sealing means; each said casing delimiting a respective length of said sterile duct.
- Figure 1 is a schematic perspective view of a preferred embodiment of the plant according to teachings of the present invention.
- Figure 2 is similar to Figure 1 and illustrates the plant broken down into some of its constitutive elements;
- Figure 3 illustrates, at an enlarged scale, a detail of Figures 1 and 2 ;
- Figure 4 illustrates, in perspective view, a component of the plant of Figures 1 and 2.
- Figure 1 designated as a whole by 1 is a plant for packaging confectionary products in sterile containers .
- confectionary products is meant both products in a solid or granular form and products in the form of a liquid or a cream.
- the plant 1 has a modular composition or is made up of units that are mutually independent, i.e., autonomous from the mechanical, electrical, electronic, pneumatic, and management standpoints.
- the plant 1 comprises, in succession along a packaging path P, a module 3 for feed and sterilization of a thermoformable strip 4, which is wound off a spool 5 and fed step by step along the packaging path P by drawing devices , which are known and not described in detail .
- the plant 1 then comprises a module 6 for heating of the thermoformable strip 4 and a module 7 for thermoforming of the thermoformable strip 4 itself.
- the module 7 provides on the strip 4 a plurality of housings or compartments 8 having dimensions and relative positioning determined in the design stage according to the product, the type of container to be made, and the width of the strip 4 itself.
- the plant 1 Downstream of the module 7 , in the direction of advance of the strip 4, the plant 1 further comprises a dispensing module 9 for feeding the product to be packaged into each of the housings or compartments 8, and a further module 10 for feed and sterilization of a heat-sealable strip 11 that can be wound off a spool 12 carried 'by the module 10 -itself.
- the plant 1 Downstream of the module 10, the plant 1 further comprises a welding module 13 for welding the strip 11 onto the portion of the strip 4 not involved the previous thermoforming process so as to close in a fluid-tight way each of the housings or compartments 8, and a dinking module 14 for separating the various housings or compartments 8 from one another to form a plurality of sterile containers , which are fed towards an outlet 15 of the plant 1 by a conveyor belt 16 that forms part of the dinking module 14 itself.
- a welding module 13 for welding the strip 11 onto the portion of the strip 4 not involved the previous thermoforming process so as to close in a fluid-tight way each of the housings or compartments 8, and a dinking module 14 for separating the various housings or compartments 8 from one another to form a plurality of sterile containers , which are fed towards an outlet 15 of the plant 1 by a conveyor belt 16 that forms part of the dinking module 14 itself.
- Each of the modules 3, 6, 7, 9, 10, 13 and 14 comprises a respective operating assembly, which is in itself known; said assemblies are designated by 3a, 6a, 7a, 9a, 10a, 13a and 14a, respectively.
- the operating assemblies are pneumatically connected to a pneumatic source via dedicated valve assemblies of their own (not illustrated) and electrically connected to respective electronic control units 3b, 6b, 7b, 9b, 10b, 13b and 14b.
- the electronic control units 3b, 6b, 7b, 9b, 10b, 13b and 14b are each dedicated exclusively to the corresponding operating assembly 3a, 6a, 7a, 9a, 10a, 13a and 14a, are independent of one another, and are, in turn, electrically connected and controlled by a general control unit 18 for managing the entire plant 1.
- Each module 3, 6, 7, 9, 10, 13 and 14 further comprises a respective structure or frame 3c, 6c, 7c, 9c, 10c, 13c and 14c for supporting the corresponding operating assembly 3a, 6a, 7a, 9a, 10a, 13a and 14a and the various electrical and pneumatic wiring/components; each frame 3c, 6c, 7c, Bc 1 10c, 13c and 14c is separate from and independent of the other frames and is set alongside and coupled to the frames adjacent thereto in a releasable way, for example via fast-coupling assemblies (not visible in the attached figures) .
- Each frame 3c, 6c, 7c, 9c, 10c, 13c and 14c is supported by a guide-and- slide assembly of its own, comprising a slide defined by a plurality of bottom resting feet or portions 20 ( Figures 1 and 3) of the respective frame itself; in the particular example described, the portions 20 have respective bottom terminal seats 21 shaped like a U set upside down and engaged by a corresponding rectilinear guide 22 in a slidable way.
- the guide 22 forms part of the aforesaid guide-and- slide assembly and part of a rail 23 for relative, positioning, which is common to all the modules 3, 6, 7, 9, 10, 13 and 14, extends parallel to the path P, and is stably fixed on the floor.
- each of the modules 3, 6, 7, 9, 10, 13 and 14 can be translated along the rail 23 and hence along the aforesaid packaging path P independently of the other modules and, in particular, can be uncoupled from the rail 23 itself and moved away by simple vertical lifting, as illustrated for the module 9 in Figure 2.
- one or more modules have their respective frames arranged, each, on a respective motor-driven trolley or other equivalent means for movement of the module, designed to be controlled in position independently of the other trolleys, for displacement in a direction transverse to the aforesaid packaging path P, between an operative advanced position, in which the corresponding frame extends along the path P in a pre-determined position, and an extracted position, in which the frame is set outside of the packaging path P and in which the module does not take part in the packaging process.
- Each of the frames supports an intermediate resting surface K, which is substantially coplanar to the surfaces K of the other frames, and on which the thermoformable strip 4 rests during its advance towards the outlet 15.
- the various surfaces K define at least part of a sliding guide for the thermoformable strip 4.
- Each of the frames arranged upstream of the sealing assembly 13 moreover supports a respective half-shell 3d, 6d, 7d, 9d and 1Od' which is set only 'above the' corresponding resting surface K with its concavity facing the corresponding plane surface K itself and is coupled to the half -shells adjacent to it in a releasable way via the interposition of respective gaskets or labyrinth seals designated by 25.
- each half-shell 6d, 7d, 9 ⁇ and 1Od comprises a corresponding top wall 26 set facing, and superimposed only on, the corresponding plane resting surface K and -vertically raised with respect to the corresponding plane surface K itself, and two side walls 27, which face one another and extend upwards once again starting from the respective flat resting surface K.
- Each of the top walls 26 has a size measured parallel to the corresponding surface K and orthogonal to the path P that can be varied as a function of the width of the thermoformable strip 4 and of the strip 11 and a through opening traversed by a mobile element of the respective operating assembly 6a, 7a, 9a, 10a.
- each half-shell 6d, 7d, 9d and 1Od delimits, with a corresponding intermediate portion of the thermoformable strip 4, a respective length of a continuous tunnel 30 ( Figure 4), which is closed upstream by the feed and sterilization assembly 3 and downstream by the closing strip 11, which progressively converges towards the underlying thermoformable strip 4 before being welded to the thermoformable strip 4 itself.
- Supplied into the tunnel 30 is sterile air and, in general, a sterile gas containing nitrogen at a variable pressure of between 0.01 and 1 bar to create a sterile environment, in which all the packaging operations are performed.
- each one of the modules that make up the plant 1 is perfectly interchangeable or replaceable with another functionally equivalent module, i.e., a module that performs the same function as the replaced module and can be chosen from among a plurality of modules having constructional characteristics different from one another.
- constructional characteristics is meant the characteristics of the module that enable variation of the type, i.e., geometry and/or dimensions, of the containers produced.
- a corresponding adjustable half-shell for forming the sterile environment enables arbitrary variation of the transverse dimensions of the tunnel 30 and makes it hence possible to use thermoformable and closing strips of different width.
- the half-shells provided enable use of thermoformable and closing strips of widths that vary in a percentage of ⁇ 15.% with respect to a given width and hence optimization of the surface of the thertnoformable strip 4, reducing to a minimum the waste resulting from dinking.
- the fact of using a common guide rail and of coupling the different modules to the same rail in an axially slidable way makes it possible, on the one hand, to ensure always a precise positioning of the modules along the path P of advance, and on the other, to replace any of the modules by simply sliding the others along the rail.
- sliding along the rail enables replacement of an existing module with another module having a different longitudinal dimension, i.e., a dimension measured in the direction of the packaging path.
- the new module may be positioned in a space not necessarily identical to the one left free by the previous module.
- said implementation enables insertion of additional modules that are able to satisfy different working processes, e.g., working processes that comprise a number of a dispensing station.
- the plant 1 could comprise a number of modules different from the one indicated by way of example, and said modules could present frames or shapes that differ from the ones indicated once again by way of example.
- half -shells for obtaining the sterile environment could be provided in a way different from the one indicated by way of example once again in the perspective of facilitating transformation of the plant according to the widths of the strips to be used.
Abstract
Description
Claims
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN200980155986.7A CN102300774B (en) | 2008-12-03 | 2009-12-02 | Plant for packaging confectionary products in a sterile manner |
ES09810781T ES2404836T3 (en) | 2008-12-03 | 2009-12-02 | Plant for sterile packaging products |
RU2011127220/13A RU2519866C2 (en) | 2008-12-03 | 2009-12-02 | Unit for sterile packaging of confectionery products |
BRPI0917061A BRPI0917061B8 (en) | 2008-12-03 | 2009-12-02 | plant for sterile packaging of confectionery products |
US13/132,522 US20120031040A1 (en) | 2008-12-03 | 2009-12-02 | Plant for packaging confectionary products in a sterile manner |
CA2745651A CA2745651C (en) | 2008-12-03 | 2009-12-02 | Plant for packaging confectionary products in a sterile manner |
EP09810781A EP2382132B1 (en) | 2008-12-03 | 2009-12-02 | Plant for packaging confectionary products in a sterile manner |
MX2011005890A MX2011005890A (en) | 2008-12-03 | 2009-12-02 | Plant for packaging confectionary products in a sterile manner. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ITTO2008A000896A IT1392253B1 (en) | 2008-12-03 | 2008-12-03 | PLANT FOR THE PACKAGING OF SWEET PRODUCTS IN STERILE PACKAGING |
ITTO2008A000896 | 2008-12-03 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010064125A2 true WO2010064125A2 (en) | 2010-06-10 |
WO2010064125A3 WO2010064125A3 (en) | 2010-11-25 |
Family
ID=41466866
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/IB2009/007625 WO2010064125A2 (en) | 2008-12-03 | 2009-12-02 | Plant for packaging confectionary products in a sterile manner |
Country Status (10)
Country | Link |
---|---|
US (1) | US20120031040A1 (en) |
EP (1) | EP2382132B1 (en) |
CN (1) | CN102300774B (en) |
BR (1) | BRPI0917061B8 (en) |
CA (1) | CA2745651C (en) |
ES (1) | ES2404836T3 (en) |
IT (1) | IT1392253B1 (en) |
MX (1) | MX2011005890A (en) |
RU (1) | RU2519866C2 (en) |
WO (1) | WO2010064125A2 (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010050524A1 (en) * | 2010-11-08 | 2012-05-10 | Krones Aktiengesellschaft | Machine for processing and / or packaging of articles and method for modifying a transport route of this machine |
EP2520500A1 (en) * | 2011-05-06 | 2012-11-07 | MULTIVAC Sepp Haggenmüller GmbH & Co KG | Cutting station with cutting unit |
DE102012004341A1 (en) * | 2012-03-07 | 2013-09-12 | Gea Cfs Germany Gmbh | packaging line |
EP2942301A1 (en) * | 2014-05-07 | 2015-11-11 | Pester Pac Automation GmbH | Device for machines construction |
EP3428078A1 (en) * | 2017-07-12 | 2019-01-16 | Focke & Co. (GmbH & Co. KG) | Packaging machine |
FR3078319A1 (en) * | 2018-02-28 | 2019-08-30 | Acemma | OPENED GRIP WELLING SYSTEM |
DE102011015249B4 (en) | 2011-03-28 | 2021-09-09 | Gerhard Schubert Gmbh | Processing machine |
WO2021259553A1 (en) * | 2020-06-25 | 2021-12-30 | Krones Aktiengesellschaft | Packaging machine and method for producing packages |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102013104359A1 (en) * | 2013-04-29 | 2014-10-30 | Krones Aktiengesellschaft | PACKAGING MACHINE, PACKAGING APPARATUS AND METHOD FOR OPERATING A PACKAGING MACHINE |
DE102016009406A1 (en) * | 2016-08-04 | 2018-02-08 | Focke & Co. (Gmbh & Co. Kg) | Packaging machine and method for providing a control program therefor |
WO2018222859A1 (en) * | 2017-05-31 | 2018-12-06 | Allegiance Corporation | Packaging machine and modular attachment for use with a packaging machine for providing modular vented opening package sealing |
DE102019130364A1 (en) * | 2019-11-11 | 2021-05-12 | Khs Gmbh | Linear filling machine for filling containers with filling material |
US11447340B1 (en) * | 2021-03-18 | 2022-09-20 | Osgood Industries, Llc | Modular frame interface |
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US3766709A (en) * | 1972-01-28 | 1973-10-23 | Zausner Foods Corp | Sterilizing device for container filling machines |
SE423517B (en) * | 1972-08-11 | 1982-05-10 | Tetra Pak Dev | PUT UNDER ASEPTIC CONDITIONS PACKAGING STERILY FULL GOODS IN CONTAINER |
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ES2017634B3 (en) * | 1985-12-24 | 1991-03-01 | Omnitech (Europe) Ltd | HORIZONTAL INTRODUCTION PACKING MACHINE |
FR2615170B1 (en) * | 1987-05-12 | 1989-08-18 | Remy & Cie E P | AUTOMATIC CONTAINER PACKAGING MACHINE |
DE3923539A1 (en) * | 1989-07-15 | 1991-01-24 | Karl Fabricius | ASEPTIC FILLING MACHINE FOR FOOD |
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DE20305759U1 (en) * | 2003-04-08 | 2004-08-19 | Finnah Engineering Und Packaging Gmbh | Forming, filling and sealing machine, especially for filling of liquid foodstuffs pots, has processing stations adjustable to variable length of sections of film sheet fed in cycle and/or adjustable to varied width of film sheet |
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EP1645513A3 (en) * | 2004-09-21 | 2006-04-19 | Philip Morris Products S.A. | Modular packing assembly |
US7506486B2 (en) * | 2005-07-29 | 2009-03-24 | Infinity Machine & Engineering Corp. | Modular packaging system |
DE102006045292A1 (en) * | 2006-09-22 | 2008-04-10 | Emil Pester Gmbh | Modular packing machine used in packing objects in blister packs, includes removable modules which are respectively provided with independent drive units for transporting and processing blister pack band for forming blister packs of objects |
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2008
- 2008-12-03 IT ITTO2008A000896A patent/IT1392253B1/en active
-
2009
- 2009-12-02 CA CA2745651A patent/CA2745651C/en active Active
- 2009-12-02 CN CN200980155986.7A patent/CN102300774B/en active Active
- 2009-12-02 US US13/132,522 patent/US20120031040A1/en not_active Abandoned
- 2009-12-02 RU RU2011127220/13A patent/RU2519866C2/en active
- 2009-12-02 EP EP09810781A patent/EP2382132B1/en active Active
- 2009-12-02 BR BRPI0917061A patent/BRPI0917061B8/en active IP Right Grant
- 2009-12-02 MX MX2011005890A patent/MX2011005890A/en active IP Right Grant
- 2009-12-02 ES ES09810781T patent/ES2404836T3/en active Active
- 2009-12-02 WO PCT/IB2009/007625 patent/WO2010064125A2/en active Application Filing
Non-Patent Citations (1)
Title |
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None |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102010050524A1 (en) * | 2010-11-08 | 2012-05-10 | Krones Aktiengesellschaft | Machine for processing and / or packaging of articles and method for modifying a transport route of this machine |
US9394113B2 (en) | 2010-11-08 | 2016-07-19 | Krones Ag | Machine for processing and/or packaging objects and method for modifying a conveying section of this machine |
DE102011015249B4 (en) | 2011-03-28 | 2021-09-09 | Gerhard Schubert Gmbh | Processing machine |
EP2520500A1 (en) * | 2011-05-06 | 2012-11-07 | MULTIVAC Sepp Haggenmüller GmbH & Co KG | Cutting station with cutting unit |
US9580193B2 (en) | 2011-05-06 | 2017-02-28 | Multivac Sepp Haggenmueller Se & Co. Kg | Cutting station with complete cutting tool |
DE102012004341A1 (en) * | 2012-03-07 | 2013-09-12 | Gea Cfs Germany Gmbh | packaging line |
EP2822857B1 (en) | 2012-03-07 | 2016-09-14 | GEA Food Solutions Germany GmbH | Packaging line |
EP2942301A1 (en) * | 2014-05-07 | 2015-11-11 | Pester Pac Automation GmbH | Device for machines construction |
EP3428078A1 (en) * | 2017-07-12 | 2019-01-16 | Focke & Co. (GmbH & Co. KG) | Packaging machine |
FR3078319A1 (en) * | 2018-02-28 | 2019-08-30 | Acemma | OPENED GRIP WELLING SYSTEM |
EP3533717A1 (en) * | 2018-02-28 | 2019-09-04 | Acemma | Bagging system with open mouth |
WO2021259553A1 (en) * | 2020-06-25 | 2021-12-30 | Krones Aktiengesellschaft | Packaging machine and method for producing packages |
Also Published As
Publication number | Publication date |
---|---|
WO2010064125A3 (en) | 2010-11-25 |
EP2382132A2 (en) | 2011-11-02 |
BRPI0917061B8 (en) | 2020-12-08 |
ITTO20080896A1 (en) | 2010-06-04 |
RU2011127220A (en) | 2013-01-10 |
US20120031040A1 (en) | 2012-02-09 |
IT1392253B1 (en) | 2012-02-22 |
CA2745651C (en) | 2016-12-13 |
EP2382132B1 (en) | 2013-02-13 |
BRPI0917061A2 (en) | 2017-10-03 |
BRPI0917061B1 (en) | 2020-09-24 |
CN102300774B (en) | 2015-05-13 |
CA2745651A1 (en) | 2010-06-10 |
MX2011005890A (en) | 2011-12-06 |
CN102300774A (en) | 2011-12-28 |
RU2519866C2 (en) | 2014-06-20 |
ES2404836T3 (en) | 2013-05-29 |
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