US20110251347A1 - Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation - Google Patents

Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation Download PDF

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Publication number
US20110251347A1
US20110251347A1 US13/057,678 US200913057678A US2011251347A1 US 20110251347 A1 US20110251347 A1 US 20110251347A1 US 200913057678 A US200913057678 A US 200913057678A US 2011251347 A1 US2011251347 A1 US 2011251347A1
Authority
US
United States
Prior art keywords
styrene
butadiene
diblock copolymer
molecular weight
average molecular
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/057,678
Other languages
English (en)
Inventor
Daniel F. Graves
Peter W. Boerner
John R. Schreffler
Christine M. Rademacher
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Firestone Polymers LLC
Original Assignee
Firestone Polymers LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Firestone Polymers LLC filed Critical Firestone Polymers LLC
Priority to US13/057,678 priority Critical patent/US20110251347A1/en
Assigned to FIRESTONE POLYMERS, LLC reassignment FIRESTONE POLYMERS, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: RADEMACHER, CHRISTINE M, GRAVES, DANIEL F, BOERNER, PETER W, SCHREFFLER, JOHN R
Publication of US20110251347A1 publication Critical patent/US20110251347A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
    • C08F297/04—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes
    • C08F297/044—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type polymerising vinyl aromatic monomers and conjugated dienes using a coupling agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/005—Processes for mixing polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene
    • C08J2325/10—Copolymers of styrene with conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
    • C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure

Definitions

  • the present disclosure in another embodiment, relates to a process for producing specific styrene-butadiene diblock copolymer-containing blends that are not an agglomeration.
  • the process involves blending a solution of styrene-butadiene diblock copolymer with a solution of a styrene-butadiene multiblock thermoplastic elastomer, and drying the blends.
  • the bound styrene content of the styrene-butadiene diblock copolymer differ from the bound styrene content of the styrene-butadiene multiblock thermoplastic elastomer.
  • the blends or compositions, and the process comprise a styrene-butadiene multiblock thermoplastic elastomer that has a number average molecular weight (M n ) ranging from about 0.5 to about 2 times the number average molecular weight (M n ) of the styrene-butadiene diblock copolymer.
  • M n number average molecular weight
  • the blends or compositions, or the process, herein involve the presence of a styrene-butadiene diblock copolymer in an amount ranging from greater than zero to less than 100% based on total polymer, and the presence of a styrene-butadiene multiblock thermoplastic elastomer in an amount ranging from about greater than zero to about 100% based on total polymer.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Graft Or Block Polymers (AREA)
US13/057,678 2008-08-05 2009-08-05 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation Abandoned US20110251347A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US13/057,678 US20110251347A1 (en) 2008-08-05 2009-08-05 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8623408P 2008-08-05 2008-08-05
PCT/US2009/052787 WO2010017261A2 (en) 2008-08-05 2009-08-05 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation
US13/057,678 US20110251347A1 (en) 2008-08-05 2009-08-05 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/052787 A-371-Of-International WO2010017261A2 (en) 2008-08-05 2009-08-05 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US14/686,123 Continuation US9840619B2 (en) 2008-08-05 2015-04-14 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation

Publications (1)

Publication Number Publication Date
US20110251347A1 true US20110251347A1 (en) 2011-10-13

Family

ID=41664179

Family Applications (2)

Application Number Title Priority Date Filing Date
US13/057,678 Abandoned US20110251347A1 (en) 2008-08-05 2009-08-05 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation
US14/686,123 Expired - Fee Related US9840619B2 (en) 2008-08-05 2015-04-14 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation

Family Applications After (1)

Application Number Title Priority Date Filing Date
US14/686,123 Expired - Fee Related US9840619B2 (en) 2008-08-05 2015-04-14 Styrene/butadiene diblock copolymer-containing blends that are not an agglomeration and a process for preparation

Country Status (9)

Country Link
US (2) US20110251347A1 (ko)
EP (1) EP2310432A4 (ko)
JP (1) JP5628803B2 (ko)
KR (2) KR20170018978A (ko)
CN (1) CN102159607B (ko)
BR (1) BRPI0916625A8 (ko)
MX (1) MX2011001362A (ko)
TW (1) TWI450927B (ko)
WO (1) WO2010017261A2 (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10351475B2 (en) * 2014-05-29 2019-07-16 Asahi Kasei Kabushiki Kaisha Asphalt composition

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR102034670B1 (ko) * 2017-11-21 2019-11-08 금호석유화학 주식회사 전도성 수지 조성물 및 그 제조방법

Citations (9)

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US4087484A (en) * 1973-12-13 1978-05-02 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resin
US4421588A (en) * 1981-10-22 1983-12-20 Aeplc Plastics alloy compositions
US4892903A (en) * 1986-07-07 1990-01-09 Shell Oil Company Elastomeric fibers, structures fashioned therefrom and elastomeric films
JPH1017611A (ja) * 1996-06-28 1998-01-20 Nippon Zeon Co Ltd ブロック共重合体の製造方法
US6451964B1 (en) * 1999-10-28 2002-09-17 Asahi Kasei Kabushiki Kaisha Method for removing hydrocarbon solvent from solution of hydrogenated block copolymer in hydrocarbon solvent
US20030176574A1 (en) * 2002-02-07 2003-09-18 St. Clair David J. Adhesives and sealants from controlled distribution block copolymers
US20040151901A1 (en) * 1998-11-12 2004-08-05 3M Innovative Properties Company Oriented polypropylene films for adhesive tape
US20060229411A1 (en) * 2005-04-06 2006-10-12 Stephen Hatfield Hot melt pressure sensitive adhesives based on blends of styrene/butadiene copolymers
US20090171024A1 (en) * 2005-12-21 2009-07-02 Carnegie Mellon University Preparation of block copolymers

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DE3037390A1 (de) * 1980-10-03 1982-05-13 Gebr. von der Wettern GmbH, 5000 Köln Belag, verfahren zu seiner herstellung und seine herstellung und seine verwendung
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US5660498A (en) * 1996-01-16 1997-08-26 Freeman; Roger Patching system and method for repairing roadways
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US6417270B1 (en) * 2001-01-09 2002-07-09 Firestone Polymers, Llc Means of producing high diblock content thermoplastic elastomers with functional termination
JP2006519269A (ja) * 2003-02-21 2006-08-24 クレイトン・ポリマーズ・リサーチ・ベー・ベー 接着剤組成物、およびそれから得られるテープおよびラベル
DE10330820B4 (de) * 2003-07-08 2005-11-10 Kraton Polymers Research B.V. Polymermodifiziertes Bitumen mit verbesserter Rückverformung und Asphaltstrassendecken dieses umfassend
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US20050182194A1 (en) * 2004-02-13 2005-08-18 Qiwei He Adhesive containing radial block copolymer
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MX2007008594A (es) * 2005-01-14 2007-09-11 Firestone Polymers Llc Metodo para inhibir la aglomeracion de copolimeros de bloques.
KR100655635B1 (ko) 2005-06-07 2006-12-08 금호석유화학 주식회사 고점도 배수성 아스팔트 개질재 및 그의 제조방법
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US4087484A (en) * 1973-12-13 1978-05-02 Sumitomo Chemical Company, Limited Process for producing transparent block copolymer resin
US4421588A (en) * 1981-10-22 1983-12-20 Aeplc Plastics alloy compositions
US4892903A (en) * 1986-07-07 1990-01-09 Shell Oil Company Elastomeric fibers, structures fashioned therefrom and elastomeric films
JPH1017611A (ja) * 1996-06-28 1998-01-20 Nippon Zeon Co Ltd ブロック共重合体の製造方法
US20040151901A1 (en) * 1998-11-12 2004-08-05 3M Innovative Properties Company Oriented polypropylene films for adhesive tape
US6451964B1 (en) * 1999-10-28 2002-09-17 Asahi Kasei Kabushiki Kaisha Method for removing hydrocarbon solvent from solution of hydrogenated block copolymer in hydrocarbon solvent
US20030176574A1 (en) * 2002-02-07 2003-09-18 St. Clair David J. Adhesives and sealants from controlled distribution block copolymers
US20060229411A1 (en) * 2005-04-06 2006-10-12 Stephen Hatfield Hot melt pressure sensitive adhesives based on blends of styrene/butadiene copolymers
US20090171024A1 (en) * 2005-12-21 2009-07-02 Carnegie Mellon University Preparation of block copolymers

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US10351475B2 (en) * 2014-05-29 2019-07-16 Asahi Kasei Kabushiki Kaisha Asphalt composition

Also Published As

Publication number Publication date
JP5628803B2 (ja) 2014-11-19
EP2310432A4 (en) 2011-11-30
JP2011530625A (ja) 2011-12-22
US9840619B2 (en) 2017-12-12
BRPI0916625A8 (pt) 2018-03-06
EP2310432A2 (en) 2011-04-20
WO2010017261A3 (en) 2010-04-15
TW201009007A (en) 2010-03-01
CN102159607A (zh) 2011-08-17
KR20110042206A (ko) 2011-04-25
WO2010017261A2 (en) 2010-02-11
US20150218363A1 (en) 2015-08-06
TWI450927B (zh) 2014-09-01
CN102159607B (zh) 2014-03-12
MX2011001362A (es) 2011-07-28
KR20170018978A (ko) 2017-02-20
BRPI0916625A2 (pt) 2017-07-04

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Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:GRAVES, DANIEL F;BOERNER, PETER W;SCHREFFLER, JOHN R;AND OTHERS;SIGNING DATES FROM 20110412 TO 20110516;REEL/FRAME:026475/0132

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