US20110054081A1 - Formulation and its use - Google Patents
Formulation and its use Download PDFInfo
- Publication number
- US20110054081A1 US20110054081A1 US12/552,338 US55233809A US2011054081A1 US 20110054081 A1 US20110054081 A1 US 20110054081A1 US 55233809 A US55233809 A US 55233809A US 2011054081 A1 US2011054081 A1 US 2011054081A1
- Authority
- US
- United States
- Prior art keywords
- formulation according
- component
- acid
- acrylate
- radical
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 [1*]OCC(C)CC Chemical compound [1*]OCC(C)CC 0.000 description 25
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
- C04B24/243—Phosphorus-containing polymers
- C04B24/246—Phosphorus-containing polymers containing polyether side chains
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
- C04B28/145—Calcium sulfate hemi-hydrate with a specific crystal form
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0066—Use of inorganic compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00612—Uses not provided for elsewhere in C04B2111/00 as one or more layers of a layered structure
- C04B2111/0062—Gypsum-paper board like materials
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/552,338 US20110054081A1 (en) | 2009-09-02 | 2009-09-02 | Formulation and its use |
US13/611,486 US20130005861A1 (en) | 2009-09-02 | 2012-09-12 | Formulation and its use |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US23925909P | 2009-09-02 | 2009-09-02 | |
US12/552,338 US20110054081A1 (en) | 2009-09-02 | 2009-09-02 | Formulation and its use |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/611,486 Division US20130005861A1 (en) | 2009-09-02 | 2012-09-12 | Formulation and its use |
Publications (1)
Publication Number | Publication Date |
---|---|
US20110054081A1 true US20110054081A1 (en) | 2011-03-03 |
Family
ID=43625790
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/552,338 Abandoned US20110054081A1 (en) | 2009-09-02 | 2009-09-02 | Formulation and its use |
US12/870,381 Active 2031-04-02 US8597426B2 (en) | 2009-09-02 | 2010-08-27 | Additives in gypsum panels and adjusting their proportions |
US13/611,486 Abandoned US20130005861A1 (en) | 2009-09-02 | 2012-09-12 | Formulation and its use |
US14/075,880 Active US8801852B2 (en) | 2009-09-02 | 2013-11-08 | Additives in gypsum slurries and adjusting their proportions |
Family Applications After (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/870,381 Active 2031-04-02 US8597426B2 (en) | 2009-09-02 | 2010-08-27 | Additives in gypsum panels and adjusting their proportions |
US13/611,486 Abandoned US20130005861A1 (en) | 2009-09-02 | 2012-09-12 | Formulation and its use |
US14/075,880 Active US8801852B2 (en) | 2009-09-02 | 2013-11-08 | Additives in gypsum slurries and adjusting their proportions |
Country Status (6)
Country | Link |
---|---|
US (4) | US20110054081A1 (fr) |
AR (1) | AR078255A1 (fr) |
CA (1) | CA2773145C (fr) |
MX (1) | MX2012002325A (fr) |
TW (1) | TW201116501A (fr) |
WO (1) | WO2011028817A1 (fr) |
Cited By (18)
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---|---|---|---|---|
US20120172468A1 (en) * | 2010-12-30 | 2012-07-05 | Blackburn David R | Effective use of melamine sulfonate condensate dispersants in wallboard containing foam |
CN103011680A (zh) * | 2012-12-13 | 2013-04-03 | 中国矿业大学(北京) | 抗硫酸盐型有机硅改性聚羧酸系超塑化剂及其制备方法 |
US20130203926A1 (en) * | 2012-02-08 | 2013-08-08 | Bogdan Moraru | Aqueous dispersion |
WO2013117465A1 (fr) * | 2012-02-08 | 2013-08-15 | Basf Se | Dispersion aqueuse |
US20140134407A1 (en) * | 2008-05-06 | 2014-05-15 | Intertape Polymer Corporation | Edge coating for tapes |
US20140135427A1 (en) * | 2011-08-10 | 2014-05-15 | Sika Technology Ag | Process for drying concrete dispersants |
CN103922637A (zh) * | 2014-03-14 | 2014-07-16 | 石家庄市长安育才建材有限公司 | 高性能c80混凝土用减水剂及其制备方法和使用方法 |
WO2016069289A1 (fr) | 2014-10-31 | 2016-05-06 | Rohm And Haas Company | Agent synthétique de rétention d'eau à deux constituants et modificateur de rhéologie destiné à être utilisé dans des ciments, des mortiers et des plâtres |
CN107383358A (zh) * | 2017-07-17 | 2017-11-24 | 上海台界化工有限公司 | 超支化的不饱和聚氧乙烯醚的合成方法及其产品与应用 |
CN108417836A (zh) * | 2018-01-31 | 2018-08-17 | 闽南师范大学 | 一种新型锂离子电池的电极粘结剂及其制备方法 |
RU2689166C1 (ru) * | 2013-12-20 | 2019-05-24 | Констракшн Рисёрч Энд Текнолоджи Гмбх | Добавка для улучшения реологических свойств неорганических вяжущих веществ |
WO2020133777A1 (fr) * | 2018-12-24 | 2020-07-02 | 科之杰新材料集团有限公司 | Réducteur d'eau à base de polycarboxylate de type phosphate et son procédé de préparation |
CN111377645A (zh) * | 2018-12-31 | 2020-07-07 | 江苏苏博特新材料股份有限公司 | 一种适用于机制砂的小分子膦酸减水剂及其制备方法 |
CN111433171A (zh) * | 2017-12-07 | 2020-07-17 | 建筑研究和技术有限公司 | 分散剂组合物 |
CN111533844A (zh) * | 2020-06-04 | 2020-08-14 | 江苏万邦新材料科技有限公司 | 一种改性混凝土保水剂及其制备方法 |
CN111925488A (zh) * | 2020-08-11 | 2020-11-13 | 陈兴涛 | 一种减缩型聚羧酸减水剂及其制备方法 |
CN112313186A (zh) * | 2018-06-21 | 2021-02-02 | 竹本油脂株式会社 | 水硬性组合物用添加剂 |
CN113882155A (zh) * | 2020-07-01 | 2022-01-04 | 中国石油化工股份有限公司 | 一种聚乙二醇马来酰亚胺-苯乙烯类型共聚物上浆剂及其制法和应用 |
Families Citing this family (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9802866B2 (en) * | 2005-06-09 | 2017-10-31 | United States Gypsum Company | Light weight gypsum board |
US7731794B2 (en) | 2005-06-09 | 2010-06-08 | United States Gypsum Company | High starch light weight gypsum wallboard |
US11306028B2 (en) | 2005-06-09 | 2022-04-19 | United States Gypsum Company | Light weight gypsum board |
US9840066B2 (en) | 2005-06-09 | 2017-12-12 | United States Gypsum Company | Light weight gypsum board |
USRE44070E1 (en) | 2005-06-09 | 2013-03-12 | United States Gypsum Company | Composite light weight gypsum wallboard |
US11338548B2 (en) | 2005-06-09 | 2022-05-24 | United States Gypsum Company | Light weight gypsum board |
DK2327672T3 (en) * | 2009-11-16 | 2017-06-06 | Bpb Ltd | GYM-BASED MATERIALS INCLUDING A MEDIUM capable of capturing formaldehyde |
WO2012049077A2 (fr) * | 2010-10-11 | 2012-04-19 | Basf Construction Polymers Gmbh | Dispersant contenant une bouillie de gypse |
US10076853B2 (en) | 2010-12-30 | 2018-09-18 | United States Gypsum Company | Slurry distributor, system, and method for using same |
US9296124B2 (en) | 2010-12-30 | 2016-03-29 | United States Gypsum Company | Slurry distributor with a wiping mechanism, system, and method for using same |
NZ613438A (en) | 2010-12-30 | 2015-05-29 | United States Gypsum Co | Slurry distribution system and method |
MY171701A (en) | 2010-12-30 | 2019-10-23 | United States Gypsum Co | Slurry distributor, system and method for using same |
US9999989B2 (en) | 2010-12-30 | 2018-06-19 | United States Gypsum Company | Slurry distributor with a profiling mechanism, system, and method for using same |
US8323785B2 (en) | 2011-02-25 | 2012-12-04 | United States Gypsum Company | Lightweight, reduced density fire rated gypsum panels |
EP2771158B1 (fr) | 2011-10-24 | 2016-09-14 | United States Gypsum Company | Raccord d'écoulement à branches multiples pour distribution de boues |
RU2638666C2 (ru) | 2011-10-24 | 2017-12-15 | Юнайтед Стэйтс Джипсам Компани | Распределитель суспензии и способ его использования |
CA2851533C (fr) | 2011-10-24 | 2020-01-14 | United States Gypsum Company | Moule multipiece et procede de fabrication d'un distributeur de boue |
PT2592054E (pt) | 2011-11-11 | 2015-02-05 | Omya Int Ag | Suspensões aquosas de materiais compreendendo carbonato de cálcio com baixa aglomeração de depósito |
US10377108B2 (en) | 2012-02-17 | 2019-08-13 | United States Gypsum Company | Gypsum products with high efficiency heat sink additives |
WO2013152963A1 (fr) | 2012-04-11 | 2013-10-17 | Construction Research & Technology Gmbh | Produit de polycondensation à base de composés aromatiques, son procédé de fabrication et son utilisation |
ES2533052T3 (es) | 2012-07-13 | 2015-04-07 | Omya International Ag | Suspensiones acuosas de baja viscosidad y alto contenido de sólidos de materiales que comprenden carbonato de calcio con estabilidad reológica mejorada bajo temperatura aumentada |
US9540810B2 (en) | 2012-10-23 | 2017-01-10 | United States Gypsum Company | Pregelatinized starch with mid-range viscosity, and product, slurry and methods related thereto |
US10399899B2 (en) | 2012-10-23 | 2019-09-03 | United States Gypsum Company | Pregelatinized starch with mid-range viscosity, and product, slurry and methods related thereto |
US9828441B2 (en) | 2012-10-23 | 2017-11-28 | United States Gypsum Company | Method of preparing pregelatinized, partially hydrolyzed starch and related methods and products |
CA2895797C (fr) * | 2012-12-20 | 2017-09-26 | Georgia-Pacific Gypsum Llc | Compositions hydrophobantes comportant un hydroxyde servant a fabriquer des panneaux de gypse resistant a l'eau |
DE202012012306U1 (de) * | 2012-12-21 | 2013-01-16 | Knauf Insulation Gmbh | Holzwolleplatte mit spezifischem Gips |
KR102021857B1 (ko) * | 2013-07-23 | 2019-09-17 | 엘지전자 주식회사 | 이동 단말기 및 그의 파노라마 촬영방법 |
EP2848597A1 (fr) * | 2013-09-17 | 2015-03-18 | Basf Se | Plaque de plâtre légère présentant une résistance améliorée et son procédé de fabrication |
US10189180B2 (en) | 2014-01-15 | 2019-01-29 | United States Gypsum Company | Foam injection system with variable port inserts for slurry mixing and dispensing apparatus |
US10059033B2 (en) | 2014-02-18 | 2018-08-28 | United States Gypsum Company | Cementitious slurry mixing and dispensing system with pulser assembly and method for using same |
US9957551B2 (en) | 2014-05-13 | 2018-05-01 | Life Technologies Corporation | Systems and methods for validation of sequencing results |
US10309771B2 (en) | 2015-06-11 | 2019-06-04 | United States Gypsum Company | System and method for determining facer surface smoothness |
US20160376191A1 (en) | 2015-06-24 | 2016-12-29 | United States Gypsum Company | Composite gypsum board and methods related thereto |
US10662112B2 (en) | 2015-10-01 | 2020-05-26 | United States Gypsum Company | Method and system for on-line blending of foaming agent with foam modifier for addition to cementitious slurries |
US20170096369A1 (en) | 2015-10-01 | 2017-04-06 | United States Gypsum Company | Foam modifiers for gypsum slurries, methods, and products |
CN105254205A (zh) * | 2015-10-06 | 2016-01-20 | 李康 | 一种混凝土保坍剂及其制备方法 |
EP3390489B1 (fr) | 2015-12-17 | 2020-09-09 | Construction Research & Technology GmbH | Réducteur d'eau à base de polycondensat |
CN105646871A (zh) * | 2015-12-31 | 2016-06-08 | 江苏苏博特新材料股份有限公司 | 一种聚合物的制备方法及其应用 |
US10207475B2 (en) | 2016-05-13 | 2019-02-19 | United States Gypsum Company | Mat-faced board |
US10442732B2 (en) | 2016-05-20 | 2019-10-15 | United States Gypsum Company | Gypsum slurries with linear polycarboxylate dispersants |
US9878950B1 (en) * | 2016-07-11 | 2018-01-30 | National Gypsum Properties, Llc | Liquid gypsum set accelerator |
US11225046B2 (en) | 2016-09-08 | 2022-01-18 | United States Gypsum Company | Gypsum board with perforated cover sheet and system and method for manufacturing same |
US10752558B2 (en) * | 2017-11-20 | 2020-08-25 | Continental Building Products Operating Company, LLC | System and method for utilizing canister and hose to move slurry mixture to make gypsum board |
CN108102103B (zh) * | 2017-12-04 | 2020-12-29 | 江苏苏博特新材料股份有限公司 | 一种小分子磷酸基添加剂的制备方法及其应用 |
CN108751785B (zh) * | 2018-07-27 | 2020-12-08 | 石家庄市长安育才建材有限公司 | 一种纳米晶种早强剂及其制备方法 |
CN109021188B (zh) * | 2018-08-29 | 2021-04-20 | 江苏苏博特新材料股份有限公司 | 一种改性酚醛胺缩聚物水泥助磨剂、其制备方法及其应用 |
CN109293885B (zh) * | 2018-09-28 | 2021-04-20 | 镇江苏博特新材料有限公司 | 一种含磷酸基减水剂及其制备方法 |
CN109796152A (zh) * | 2019-03-04 | 2019-05-24 | 淮北旭日建材有限公司 | 一种qs-2缓凝高效减水剂的制作方法及其制备设备 |
WO2023205049A1 (fr) | 2022-04-20 | 2023-10-26 | United States Gypsum Company | Accélérateur de prise de gypse |
Citations (26)
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US3686133A (en) * | 1969-08-21 | 1972-08-22 | Kao Corp | Dispersing composition |
US4501839A (en) * | 1981-03-02 | 1985-02-26 | Sika Ag, Vorm. Kaspar Winkler & Co. | Method of using highly concentrated aqueous solutions of low viscosity of melamine/aldehyde resins for improving building materials |
US4725665A (en) * | 1985-08-23 | 1988-02-16 | Chemie Linz Aktiengesellschaft | Use of salts of water-soluble |
US5158996A (en) * | 1987-08-28 | 1992-10-27 | Sandoz Ltd. | Chemically treated anhydride copolymers and cementitious mixtures containing the copolymers |
US5750634A (en) * | 1995-03-17 | 1998-05-12 | Skw Trostberg Aktiengesellschaft | Water-soluble polycondensation products based on amino-s-triazines and the use thereof |
US5798425A (en) * | 1995-04-07 | 1998-08-25 | Skw Trostberg Aktiengesellschaft | Co-polymers based on oxyalkyleneglycol alkenyl ethers and unsaturated dicarboxylic acid derivatives |
US6139623A (en) * | 1997-01-21 | 2000-10-31 | W. R. Grace & Co.-Conn. | Emulsified comb polymer and defoaming agent composition and method of making same |
US6187941B1 (en) * | 1997-09-06 | 2001-02-13 | Asta Medica Aktiengesellschaft | Process for the preparation of oxazaphosphorine-2-amines |
US6506248B1 (en) * | 1997-04-10 | 2003-01-14 | James Hardie Research Pty Limited | Building products |
US6555683B1 (en) * | 1995-03-31 | 2003-04-29 | Skw Polymers Gmbh | Condensation products based on amino-s-triazines and the use thereof |
US6777517B1 (en) * | 1999-06-11 | 2004-08-17 | Degussa Construction Chemicals Gmbh | Copolymers based on unsaturated mono-or dicarboxylic acid derivatives and oxyalkylene glycol alkenyl ethers, method for the production and use thereof |
US20050239924A1 (en) * | 2002-03-27 | 2005-10-27 | Lettkeman Dennis M | High molecular weight additives for calcined gypsum and cementitious compositions |
US20050250888A1 (en) * | 2002-03-27 | 2005-11-10 | Lettkeman Dennis M | High strength flooring compositions |
US7041167B2 (en) * | 2001-03-05 | 2006-05-09 | James Hardie International Finance B.V. | Low density accelerant and strength enhancing additive for cementitious products and methods of using same |
US7070648B1 (en) * | 2005-06-16 | 2006-07-04 | Lyondell Chemical Technology, L.P. | Preparation of gypsum compositions |
US20060281886A1 (en) * | 2005-06-14 | 2006-12-14 | Manfred Bichler | Polyether-containing copolymer |
US20060278127A1 (en) * | 2005-06-14 | 2006-12-14 | United States Gypsum Company | Gypsum products utilizing a two-repeating unit dispersant and a method for making them |
US20060281837A1 (en) * | 2005-06-14 | 2006-12-14 | United States Gypsum Company | Fast drying gypsum products |
US20060278134A1 (en) * | 2005-06-14 | 2006-12-14 | Lettkeman Dennis M | Modifiers for gypsum slurries and method of using them |
US20060278129A1 (en) * | 2005-06-14 | 2006-12-14 | Qingxia Liu | Effective use of dispersants in wallboard containing foam |
US20060278135A1 (en) * | 2005-06-14 | 2006-12-14 | Qingxia Liu | Method of making a gypsum slurry with modifiers and dispersants |
US20060280970A1 (en) * | 2005-06-14 | 2006-12-14 | United States Gypsum Company | High strength flooring compositions |
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US2078199A (en) | 1936-10-02 | 1937-04-20 | United States Gypsum Co | Heatproofed set-stabilized gypsum plaster |
US3573947A (en) | 1968-08-19 | 1971-04-06 | United States Gypsum Co | Accelerator for gypsum plaster |
DE4411797A1 (de) | 1994-04-06 | 1995-10-12 | Sueddeutsche Kalkstickstoff | Verfahren zur Herstellung von Sulfanilsäure enthaltenden Kondensationsprodukten auf Basis von Amino-s-triazinen |
CA2158820C (fr) * | 1994-09-23 | 2004-11-23 | Steven W. Sucech | Production de placoplatre mousse |
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US5683635A (en) | 1995-12-22 | 1997-11-04 | United States Gypsum Company | Method for preparing uniformly foamed gypsum product with less foam agitation |
US6342284B1 (en) | 1997-08-21 | 2002-01-29 | United States Gysum Company | Gypsum-containing product having increased resistance to permanent deformation and method and composition for producing it |
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US6409825B1 (en) | 2000-11-22 | 2002-06-25 | United States Gypsum Company | Wet gypsum accelerator and methods, composition, and product relating thereto |
US6893752B2 (en) | 2002-06-28 | 2005-05-17 | United States Gypsum Company | Mold-resistant gypsum panel and method of making same |
US20060278128A1 (en) * | 2005-06-14 | 2006-12-14 | United States Gypsum Company | Effective use of dispersants in wallboard containing foam |
US8088218B2 (en) * | 2005-06-14 | 2012-01-03 | United States Gypsum Company | Foamed slurry and building panel made therefrom |
DE102006027035A1 (de) | 2005-06-14 | 2007-01-11 | Basf Construction Polymers Gmbh | Polyether-haltiges Copolymer |
US20080148997A1 (en) * | 2006-12-22 | 2008-06-26 | Blackburn David R | Gypsum compositions with naphthalene sulfonate and modifiers |
-
2009
- 2009-09-02 US US12/552,338 patent/US20110054081A1/en not_active Abandoned
-
2010
- 2010-08-27 US US12/870,381 patent/US8597426B2/en active Active
- 2010-09-01 TW TW099129452A patent/TW201116501A/zh unknown
- 2010-09-01 WO PCT/US2010/047551 patent/WO2011028817A1/fr active Application Filing
- 2010-09-01 MX MX2012002325A patent/MX2012002325A/es active IP Right Grant
- 2010-09-01 AR ARP100103211A patent/AR078255A1/es unknown
- 2010-09-01 CA CA2773145A patent/CA2773145C/fr active Active
-
2012
- 2012-09-12 US US13/611,486 patent/US20130005861A1/en not_active Abandoned
-
2013
- 2013-11-08 US US14/075,880 patent/US8801852B2/en active Active
Patent Citations (29)
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Also Published As
Publication number | Publication date |
---|---|
US8597426B2 (en) | 2013-12-03 |
TW201116501A (en) | 2011-05-16 |
US20110054053A1 (en) | 2011-03-03 |
WO2011028817A1 (fr) | 2011-03-10 |
MX2012002325A (es) | 2012-05-23 |
AR078255A1 (es) | 2011-10-26 |
US20140073711A1 (en) | 2014-03-13 |
CA2773145A1 (fr) | 2011-03-10 |
US20130005861A1 (en) | 2013-01-03 |
CA2773145C (fr) | 2017-01-03 |
US8801852B2 (en) | 2014-08-12 |
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