US20060145120A1 - Cooling liquid composition for fuel cell - Google Patents
Cooling liquid composition for fuel cell Download PDFInfo
- Publication number
- US20060145120A1 US20060145120A1 US11/330,015 US33001506A US2006145120A1 US 20060145120 A1 US20060145120 A1 US 20060145120A1 US 33001506 A US33001506 A US 33001506A US 2006145120 A1 US2006145120 A1 US 2006145120A1
- Authority
- US
- United States
- Prior art keywords
- methyl
- coolant
- butene
- hexyne
- octene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04029—Heat exchange using liquids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/08—Materials not undergoing a change of physical state when used
- C09K5/10—Liquid materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to a coolant composition for fuel cells, and specifically to such a coolant composition for automobiles.
- the present invention relates to a coolant composition that provides an excellent antifreeze property and is capable of maintaining the electrical conductivity of the coolant adequately low for a long period of time.
- a fuel cell unit which generates electrical power is provided as a stack of a plurality of fuel cells. During power generation, heat is generated from the fuel cells. To cool the fuel cell unit, a cooling plate is inserted between every few fuel cells.
- a fluid path for coolant is provided in each cooling plate in order to cool the fuel cell unit.
- a coolant for a fuel cell unit circulates within the stack of the fuel cells and cools the fuel cells. If the electrical conductivity of the coolant is “high”, the electricity generated in the fuel cells partially flows into the coolant, resulting in loss of electrical power generated in the fuel cell unit.
- the temperature of the coolant is subject to the atmospheric temperature when not in use.
- the atmospheric temperature falls below the freezing point, pure water coolant would freeze, potentially leading to physically damaging the cooling plates.
- the battery performance of the fuel cell system would then deteriorate.
- Such a glycol may be oxidized during use, and may produce ionic substances. Such ionic substances raise electrical conductivity of the coolant.
- the coolant paths of a fuel cell system are generally provided with an ion exchanger or ion exchange resin to remove such ionic substances.
- the capacity of the ion exchanger deteriorates as time goes by because the ion exchanger is “consumed” for removal of the ionic substances.
- an object of the present invention to provide an anti-freeze coolant composition for a fuel cell unit, which is capable of maintaining the electrical conductivity of a coolant low for a long period of time by suppressing generation of ionic substances in the coolant.
- the coolant composition of the present invention is characterized by containing at least one aliphatic alcohol having unsaturated bonds in the molecules thereof.
- the base component of this coolant composition possesses low electrical conductivity and antifreeze properties.
- the base component contains at least one ingredient selected from the group consisting of water, glycols, saturated alcohols and glycol ethers.
- the glycols may be ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol, 1,3-propanediol, 1,3-butanediol, 1,5-pentanediol and hexylene glycol.
- the saturated alcohols may be methanol, ethanol, propanol, butanol, pentanol, hexanol, heptanol and octanol.
- the glycol ethers may be alkyl ether of polyoxy alkylene glycol, such as ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, tetraethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monoethyl ether, triethylene glycol monoethyl ether, tetraethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol monobutyl ether, triethylene glycol monobutyl ether and tetraethylene glycol monobutyl ether.
- polyoxy alkylene glycol such as ethylene glycol monomethyl ether, diethylene glycol monomethyl ether, triethylene glycol monomethyl ether, tetraethylene glycol monomethyl ether, ethylene glycol monoethyl ether, diethylene glycol monoethyl ether, triethylene glycol monoethyl ether, tetraethylene glycol
- the aliphatic alcohols possess unsaturated bonds in the molecules, and maintain electrical conductivity low.
- the electrical conductivity of the coolant according to the present invention is maintained at 10 ⁇ S/cm or below, and the fluctuation in electrical conductivity of the coolant during a long use is maintained within the range from 0 ⁇ S/cm to 10 ⁇ S/cm.
- the aliphatic alcohols of the present invention are not easily removed by the ion exchanger used in the cooling system and are capable of keeping the electrical conductivity of the coolant low for a long time. As they are not removed by the ion exchanger, the expected function of the aliphatic alcohols according to the present invention will last long without losing ion exchanging capability.
- the aliphatic alcohols have 2 to 20 carbon atoms per molecule.
- the aliphatic alcohols may be selected from allyl alcohol, 2-butene-1-ol, 3-butene-1-ol, 1-butene-3-ol, 2-methyl-2-propene-1-ol, 4-pentene-1-ol, 1-pentene-3-ol, 2-pentene-1-ol, 2-methyl-3-butene-2-ol, 3-methyl-2-butene-1-ol, 3-methyl-3-butene-1-ol, 2-hexene-1-ol, 3-hexene-1-ol, 4-hexene-1-ol, 5-hexene-1-ol, 1-hexene-3-ol, 6-heptene-1-ol, 2-heptene-1-ol, 4-heptene-1-ol, 7-octene-1-ol, 2-octene-1-ol, 3-octene-1-ol, 5-oct
- the aliphatic alcohols are contained within the range from 0.01 part by weight to 15 parts by weight against 100 parts by weight of the base component. Outside of this range, satisfactory results will not be attained or waste will result.
- the coolant composition of the present invention may additionally contain an antifoaming agent, coloring agent, etc.
- a conventionally known rust inhibitor such as molybdate, tungstate, sulfate, nitrate and/or benzoate may also be added in an amount that does not increase the electrical conductivity of the coolant of the present invention.
- Embodiment 1 consisted of ethylene glycol, 3-butene-1-ol (aliphatic unsaturated alcohol), and deionized water.
- Embodiment 2 consisted of ethylene glycol, 4-pentene-1-ol (aliphatic unsaturated alcohol), and deionized water.
- Embodiment 3 consisted of ethylene glycol, 2,5-dimethyl-3-hexyne-2,5-diol (aliphatic unsaturated alcohol), and deionized water.
- Comparison 1 consisted of ethylene glycol and deionized water.
- Comparison 2 consisted of ethylene glycol, 1-butanol (aliphatic saturated alcohol), and ion exchanged water.
- Comparison 3 consisted of ethylene glycol, 1-pentanol (aliphatic saturated alcohol), and dedionized water.
- Embodiments 1 to 3 and Comparisons 1 to 3 each had an initial electrical conductivity 0.3 ⁇ S/cm or below, while each of the electrical conductivities of Comparisons 1 to 3 after oxidation was much higher (42.6 for Comparison 1, 43.9 for Comparison 2, and 39.6 for Comparison 3). In contrast, the electrical conductivities of Embodiments 1 to 3 after oxidation all remained within the range from 0 ⁇ S/cm to 9.5 ⁇ S/cm (9.5 for Embodiment 1, 4.4 for Embodiment 2, and 2.9 for Embodiment 3).
- the aliphatic alcohol having unsaturated bonds in the molecules contained in the coolant composition of the present invention prevents generation of ionic substances as a result of oxidation of the base component of the coolant otherwise and is capable of maintaining the electrical conductivity of the coolant low for a long period of time.
- the aliphatic alcohol in the coolant composition of the present invention is not easily removed by an ion exchanger in cooling systems, the duration of effectiveness of the ion exchanger is extended.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Thermal Sciences (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Combustion & Propulsion (AREA)
- Sustainable Energy (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Lubricants (AREA)
- Fuel Cell (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Liquid Carbonaceous Fuels (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/046,244 US8187763B2 (en) | 2003-07-11 | 2008-03-11 | Cooling liquid composition for fuel cell |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/JP2003/008879 WO2005006476A1 (fr) | 2003-07-11 | 2003-07-11 | Composition de fluide de refroidissement pour batterie de piles a combustible |
WOPCT/JP03/08879 | 2003-07-11 | ||
PCT/JP2003/016646 WO2005006475A1 (fr) | 2003-07-11 | 2003-12-24 | Composition de liquide de refroidissement pour pile a combustible |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2003/016646 Continuation WO2005006475A1 (fr) | 2003-07-11 | 2003-12-24 | Composition de liquide de refroidissement pour pile a combustible |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/046,244 Continuation US8187763B2 (en) | 2003-07-11 | 2008-03-11 | Cooling liquid composition for fuel cell |
Publications (1)
Publication Number | Publication Date |
---|---|
US20060145120A1 true US20060145120A1 (en) | 2006-07-06 |
Family
ID=34044620
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/330,015 Abandoned US20060145120A1 (en) | 2003-07-11 | 2006-01-11 | Cooling liquid composition for fuel cell |
US12/046,244 Active 2025-03-30 US8187763B2 (en) | 2003-07-11 | 2008-03-11 | Cooling liquid composition for fuel cell |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/046,244 Active 2025-03-30 US8187763B2 (en) | 2003-07-11 | 2008-03-11 | Cooling liquid composition for fuel cell |
Country Status (5)
Country | Link |
---|---|
US (2) | US20060145120A1 (fr) |
EP (1) | EP1653544A4 (fr) |
CN (1) | CN100382371C (fr) |
AU (2) | AU2003248060A1 (fr) |
WO (2) | WO2005006476A1 (fr) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070075120A1 (en) * | 2005-06-24 | 2007-04-05 | Bo Yang | Methods for inhibiting corrosion in brazed metal surfaces and coolants and additives for use therein |
US20080251756A1 (en) * | 2005-03-02 | 2008-10-16 | Shishiai-Kabushikigaisha | Coolant composition for fuel cell |
US20090219693A1 (en) * | 2008-03-03 | 2009-09-03 | Harris Corporation | Cooling system for high voltage systems |
US8187763B2 (en) | 2003-07-11 | 2012-05-29 | Honda Motor Co., Ltd. | Cooling liquid composition for fuel cell |
CN113652210A (zh) * | 2021-06-28 | 2021-11-16 | 中国船舶重工集团公司第七一八研究所 | 一种低电导率长效冷却液及其制备方法 |
WO2023111687A1 (fr) * | 2021-12-17 | 2023-06-22 | Cci Holdings, Inc. | Système de transfert de chaleur à inhibiteurs organiques non ioniques compatibles avec une exposition au flux dans des opérations de pile à combustible |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5027656B2 (ja) * | 2005-03-30 | 2012-09-19 | シーシーアイ株式会社 | 燃料電池用冷却液組成物 |
CA2577766A1 (fr) * | 2006-02-17 | 2007-08-17 | Nuvera Fuel Cells, Inc. | Methode de nettoyage des piles a combustible |
TWI819397B (zh) * | 2020-10-26 | 2023-10-21 | 日商信越聚合物股份有限公司 | 導電性高分子分散液及其製造方法、含導電性高分子的液體及其製造方法、導電性層疊體及其製造方法、以及電容器及其製造方法 |
Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2595547A (en) * | 1946-07-11 | 1952-05-06 | Schaaf Herman | Electromagnet |
US4105405A (en) * | 1976-11-27 | 1978-08-08 | Henkel Kommanditgesellschaft Auf Aktien | Method and composition for inhibiting corrosion of metals in contact with water |
US4418231A (en) * | 1981-08-07 | 1983-11-29 | Ppg Industries, Inc. | Corrosion inhibited solvent compositions |
US5454967A (en) * | 1992-02-18 | 1995-10-03 | Basf Aktiengesellschaft | Phosphate containing coolant mixtures which are stable in hard water |
US5723061A (en) * | 1995-04-28 | 1998-03-03 | Bp Chemicals Limited | Antifreeze composition comprising a water-soluble alcohol and a corrosion inhibitor system comprising dicarboxylic acids or salts thereof, diazole and a triazole |
US5772912A (en) * | 1995-01-25 | 1998-06-30 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Environmentally friendly anti-icing |
US6040073A (en) * | 1996-08-07 | 2000-03-21 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell |
US6042955A (en) * | 1995-05-25 | 2000-03-28 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell and method of controlling same |
US6309559B1 (en) * | 1999-07-02 | 2001-10-30 | Clariant Gmbh | Silicate-, borate-and phosphate-free cooling fluids based on glycols and having improved corrosion behavior |
US6361891B1 (en) * | 1999-12-20 | 2002-03-26 | Utc Fuel Cells, Llc | Direct antifreeze cooled fuel cell power plant system |
US6391257B1 (en) * | 1998-08-19 | 2002-05-21 | Prestone Products Corporation | Antifreeze compositions comprising carboxylic acid and cyclohexenoic acid |
US20020068360A1 (en) * | 2000-04-17 | 2002-06-06 | Brockbank Kelvin G.M. | Cyclohexanediol cryoprotectant compounds |
US20050244692A1 (en) * | 2002-11-05 | 2005-11-03 | Hiroshi Egawa | Fuel cell coolant composition |
Family Cites Families (94)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2071482A (en) * | 1934-01-31 | 1937-02-23 | Standard Oil Dev Co | Antifreeze |
US2307577A (en) | 1941-02-18 | 1943-01-05 | Du Pont | Noncorrosive liquid |
US2959547A (en) | 1957-01-31 | 1960-11-08 | Ray S Pyle | Aqueous coolant for metal working machines |
DE1217137B (de) | 1964-02-22 | 1966-05-18 | Bp Benzin | Gefrierschutzmittel fuer Kuehlfluessigkeiten |
GB1235101A (en) | 1967-05-01 | 1971-06-09 | Albright & Wilson Mfg Ltd | Improvements relating to electrodeposition of copper |
US4105581A (en) | 1977-02-18 | 1978-08-08 | Drew Chemical Corporation | Corrosion inhibitor |
DE2942864C2 (de) | 1979-10-24 | 1986-11-20 | Hüls AG, 4370 Marl | Kavitationshemmmende, frostsichere Wärmeübertragungsflüssigkeit |
US4351796A (en) | 1980-02-25 | 1982-09-28 | Ciba-Geigy Corporation | Method for scale control |
DE3035327A1 (de) | 1980-09-19 | 1982-05-06 | Hoechst Ag, 6000 Frankfurt | Kuehlfluessigkeit mit korrosions- und kavitationshemmenden zusaetzen |
DE3311636A1 (de) | 1983-03-30 | 1984-10-04 | Bayer Ag, 5090 Leverkusen | Neue fuenfgliedrige stickstoffhaltige heterocyclen, verfahren zu ihrer herstellung sowie ihre verwendung als schaedlingsbekaempfungsmittel |
US4600524A (en) | 1983-12-08 | 1986-07-15 | W. R. Grace & Co. | Composition and method for inhibiting scale |
WO1986000917A1 (fr) | 1984-07-18 | 1986-02-13 | Komáromi Ko^"Olajipari Vállalat | Liquide de transfert thermique |
IN166983B (fr) | 1985-02-11 | 1990-08-18 | Henkel Corp | |
US4806310A (en) | 1985-06-14 | 1989-02-21 | Drew Chemical Corporation | Corrosion inhibitor |
EP0229254A3 (fr) | 1985-11-14 | 1987-08-26 | Asahi Glass Company Ltd. | Electrolyte pour condensateur électrolytique |
US4647392A (en) | 1985-12-27 | 1987-03-03 | Texaco Inc. | Monobasic-dibasic acid/salt antifreeze corrosion inhibitor |
JPS62205183A (ja) | 1986-02-28 | 1987-09-09 | テキサコ・デベロツプメント・コ−ポレ−シヨン | 安定化された、リン酸ベ−スの不凍液用濃縮物組成物及び該組成物を含む水性冷却液組成物 |
US4851145A (en) | 1986-06-30 | 1989-07-25 | S.A. Texaco Petroleum Nv | Corrosion-inhibited antifreeze/coolant composition |
US5080818A (en) | 1987-06-16 | 1992-01-14 | Nippon Shokubai Kagaku Kogyo Co., Ltd. | Antifreeze composition |
JPH01119011A (ja) | 1987-10-30 | 1989-05-11 | Nichicon Corp | 電解コンデンサの駆動用電解液 |
SU1563936A1 (ru) | 1988-05-25 | 1990-05-15 | Научно-производственное объединение "Медоборудование" | Флюс дл пайки меди и ее сплавов |
JPH0231894A (ja) | 1988-07-22 | 1990-02-01 | Mitsubishi Gas Chem Co Inc | 冷却水系のスケール防止剤 |
JPH0674415B2 (ja) | 1989-05-01 | 1994-09-21 | シーシーアイ株式会社 | 冷却液組成物 |
GB8922504D0 (en) | 1989-10-05 | 1989-11-22 | Interox Chemicals Ltd | Hydrogen peroxide solutions |
US5042986A (en) | 1989-10-13 | 1991-08-27 | The Dow Chemical Company | Wrinkle resistant cellulosic textiles |
JP2772578B2 (ja) | 1990-06-29 | 1998-07-02 | シーシーアイ株式会社 | 不凍液 |
US5100571A (en) | 1990-11-13 | 1992-03-31 | Royal Harvest, Inc. | Additive for engine cooling system |
US5269956A (en) | 1991-09-25 | 1993-12-14 | Texaco Chemical Co. | Compatible corrosion inhibitor combinations |
JPH06116764A (ja) | 1992-10-07 | 1994-04-26 | Echiren Chem Kk | 不凍液組成物 |
CA2134908A1 (fr) | 1993-11-04 | 1995-05-05 | Kaveh Sotoudeh | Agents anti-corrosion pour circuits de refroidissement fermes |
JP3318594B2 (ja) | 1993-12-21 | 2002-08-26 | シーシーアイ株式会社 | 冷却液組成物 |
US5417819A (en) | 1994-01-21 | 1995-05-23 | Aluminum Company Of America | Method for desmutting aluminum alloys having a highly reflective surface |
WO1995020956A1 (fr) | 1994-02-07 | 1995-08-10 | Kiss Laboratories S.R.O. | Composition pharmaceutique antitumorale a base de carboplatine, et son procede de production |
JPH0885782A (ja) | 1994-09-16 | 1996-04-02 | Nippon Chem Kogyo Kk | 不凍液組成物 |
US5501811A (en) * | 1995-04-24 | 1996-03-26 | Dow Corning Corporation | Azeotropes of octamethyltrisiloxane and aliphatic or alicyclic alcohols |
JP3240889B2 (ja) * | 1995-08-17 | 2001-12-25 | 日立エーアイシー株式会社 | 電解コンデンサ用電解液 |
JP3790860B2 (ja) | 1996-03-28 | 2006-06-28 | シーシーアイ株式会社 | 冷却液組成物 |
DE19625692A1 (de) | 1996-06-27 | 1998-01-02 | Basf Ag | Silikat-, borat- und nitratfreie Gefrierschutzmittelkonzentrate und diese umfassende Kühlmittelzusammensetzungen |
US5766506A (en) | 1996-09-12 | 1998-06-16 | The Dow Chemical Company | Hard water compatible phosphate-containing heat transfer fluids |
US6284721B1 (en) | 1997-01-21 | 2001-09-04 | Ki Won Lee | Cleaning and etching compositions |
JP3845702B2 (ja) | 1997-03-11 | 2006-11-15 | シーシーアイ株式会社 | 不凍液/冷却液組成物 |
US6280651B1 (en) | 1998-12-16 | 2001-08-28 | Advanced Technology Materials, Inc. | Selective silicon oxide etchant formulation including fluoride salt, chelating agent, and glycol solvent |
JP2000008027A (ja) | 1998-06-26 | 2000-01-11 | Mitsubishi Chemicals Corp | ブライン組成物 |
US6585933B1 (en) | 1999-05-03 | 2003-07-01 | Betzdearborn, Inc. | Method and composition for inhibiting corrosion in aqueous systems |
EP0995785A1 (fr) | 1998-10-14 | 2000-04-26 | Texaco Development Corporation | Inhibiteurs de corrosion et combinaisons synergiques d'inhibiteurs pour la protection des métaux légers dans les fluides de transfert thermique et les liquides de refroidissement de moteurs |
JP2000219981A (ja) | 1999-01-29 | 2000-08-08 | Nippon Chem Kogyo Kk | 不凍液組成物 |
JP2000239658A (ja) | 1999-02-22 | 2000-09-05 | Ipposha Oil Ind Co Ltd | 冷却液組成物 |
JP4242518B2 (ja) * | 1999-08-11 | 2009-03-25 | 出光興産株式会社 | 二酸化炭素冷媒用冷凍機油組成物 |
JP3941030B2 (ja) | 1999-09-02 | 2007-07-04 | シーシーアイ株式会社 | 低リン系冷却液組成物 |
JP4842420B2 (ja) * | 1999-09-28 | 2011-12-21 | トヨタ自動車株式会社 | 冷却液、冷却液の封入方法および冷却システム |
BR0014997B1 (pt) | 1999-10-29 | 2011-05-17 | concentrado anticongelante, e, composição refrigerante aquosa. | |
EP1255806B1 (fr) | 2000-02-14 | 2006-09-27 | The Procter & Gamble Company | Compositions aqueuses stables servant a traiter des surfaces, en particulier des tissus |
JP2001279235A (ja) | 2000-03-29 | 2001-10-10 | Cci Corp | 不凍液/冷却液組成物 |
US20040072055A1 (en) | 2000-04-14 | 2004-04-15 | Getz Matthew George | Graphite article useful as a fuel cell component substrate |
AU5852801A (en) | 2000-05-05 | 2001-11-20 | Rhodia Consumer Specialties Limited | Scale and corrosion inhibitors |
JP4345205B2 (ja) * | 2000-07-14 | 2009-10-14 | トヨタ自動車株式会社 | 絶縁性を考慮した燃料電池の冷却 |
DE10036031A1 (de) | 2000-07-24 | 2002-02-07 | Basf Ag | Gefrierschutzmittelkonzentrate auf Basis von Amiden und diese umfassende Kühlmittelzusammensetzungen zum Schutz von Magnesium und Magnesiumlegierungen |
JP3992428B2 (ja) | 2000-08-16 | 2007-10-17 | 三洋電機株式会社 | 燃料電池システムとその運転方法 |
JP2002105442A (ja) * | 2000-10-02 | 2002-04-10 | Mitsubishi Cable Ind Ltd | 蓄熱材組成物 |
DE10063951A1 (de) | 2000-12-20 | 2002-06-27 | Basf Ag | Kühlmittel für Kühlsysteme in Brennstoffzellenantrieben |
US6818146B2 (en) * | 2001-01-16 | 2004-11-16 | Shell Oil Company | Chemical base for engine coolant/antifreeze with improved thermal stability properties |
US6572690B2 (en) | 2001-03-05 | 2003-06-03 | Hewlett-Packard Development Company, L.P. | Use of mixtures of organic acids to adjust properties of ink-jet inks |
JP2002270472A (ja) | 2001-03-09 | 2002-09-20 | Japan Carlit Co Ltd:The | 電解コンデンサ用電解液及び電解コンデンサ |
JP4119622B2 (ja) | 2001-04-25 | 2008-07-16 | トヨタ自動車株式会社 | 冷却液組成物 |
DE10122769A1 (de) | 2001-05-10 | 2002-11-14 | Basf Ag | Gefrierschutzmittelkonzentrate enthaltend den Farbstoff C.I. Reactive Violet 5 |
DE10128530A1 (de) * | 2001-06-13 | 2002-12-19 | Basf Ag | Kühlmittel für Kühlsysteme in Brennstoffzellenantrieben enthaltend Azolderivate |
JP2002371270A (ja) | 2001-06-15 | 2002-12-26 | Tanikawa Yuka Kogyo Kk | 不凍液 |
CA2398423C (fr) | 2001-09-04 | 2009-11-10 | Rohm And Haas Company | Compositions pour inhiber la corrosion |
JP3600202B2 (ja) * | 2001-09-26 | 2004-12-15 | 三洋電機株式会社 | 固体高分子型燃料電池システム |
US6951666B2 (en) | 2001-10-05 | 2005-10-04 | Cabot Corporation | Precursor compositions for the deposition of electrically conductive features |
EP1304367A1 (fr) * | 2001-10-17 | 2003-04-23 | Texaco Development Corporation | Compositions inhibitants de corrosion et procédés pour des systèmes de refroidissement de piles à combustible |
JP4088447B2 (ja) | 2002-01-16 | 2008-05-21 | トヨタ自動車株式会社 | 自動車用冷却水の再生方法及び再生用添加剤 |
JP2003243338A (ja) | 2002-02-18 | 2003-08-29 | Sumitomo Bakelite Co Ltd | 研磨用組成物 |
US7481948B2 (en) | 2002-02-19 | 2009-01-27 | Honeywell International Inc. | Heat transfer compositions with high electrical resistance for fuel cell assemblies |
US20050109979A1 (en) | 2002-05-02 | 2005-05-26 | Shishiai-Kabushikigaisha | Coolant composition for fuel cell |
WO2003094271A1 (fr) * | 2002-05-02 | 2003-11-13 | Shishiai-Kabushikigaisha | Composition liquide de refroidissement pour pile a combustible |
EP1386952A3 (fr) | 2002-08-02 | 2006-05-24 | Clariant Produkte (Deutschland) GmbH | Agent antigel |
JP2004143191A (ja) | 2002-10-21 | 2004-05-20 | Toyota Motor Corp | 冷却液組成物 |
JP2004143473A (ja) | 2002-10-21 | 2004-05-20 | Toyota Motor Corp | 冷却液組成物及び冷却液組成物用添加剤 |
US7138199B2 (en) * | 2002-10-30 | 2006-11-21 | Mohapatra Satish C | Fuel cell and fuel cell coolant compositions |
JP2004281106A (ja) | 2003-03-13 | 2004-10-07 | Nissan Motor Co Ltd | 燃料電池スタック用冷却液組成物 |
DE10313280A1 (de) | 2003-03-25 | 2004-10-07 | Basf Ag | Gefrierschutzmittelkonzentrate und Kühlmittelzusammensetzungen auf Basis von Polyglykolen und Amiden zum Schutz von Magnesium und dessen Legierungen |
AU2003248060A1 (en) * | 2003-07-11 | 2005-01-28 | Shishiai-Kabushikigaisha | Cooling fluid composition for fuel battery |
CA2534715A1 (fr) | 2003-08-07 | 2005-02-24 | Glendon C. Daly | Fluide caloporteur |
AU2004269423A1 (en) | 2003-09-02 | 2005-03-10 | Alaska Ocean Products | Organic cooling medium and its uses |
EP1683895B1 (fr) | 2003-10-01 | 2018-08-08 | Shishiai-Kabushikigaisha | Composition de solution de refroidissement liquide |
WO2005037950A1 (fr) | 2003-10-16 | 2005-04-28 | Shishiai-Kabushikigaisha | Composition de fluide de refroidissement |
WO2005052086A1 (fr) | 2003-11-26 | 2005-06-09 | Shishiai-Kabushikigaisha | Composition de liquide de refroidissement |
US7452617B2 (en) * | 2003-12-16 | 2008-11-18 | General Motors Corporation | Fuel cell dielectric coolant and evaporative cooling process using same |
EP1698678A1 (fr) | 2003-12-25 | 2006-09-06 | Shishiai-Kabushikigaisha | Composition de vecteur thermique |
EP1739775B1 (fr) | 2004-03-24 | 2011-11-02 | Shishiai-Kabushikigaisha | Composition de fluide de refroidissement pour pile a combustible |
JP2005325300A (ja) | 2004-05-17 | 2005-11-24 | Toyota Motor Corp | 冷却液組成物 |
JPWO2006046275A1 (ja) | 2004-10-25 | 2008-05-22 | シーシーアイ株式会社 | 不凍液/冷却液組成物 |
US7846349B2 (en) | 2004-12-22 | 2010-12-07 | Applied Materials, Inc. | Solution for the selective removal of metal from aluminum substrates |
-
2003
- 2003-07-11 AU AU2003248060A patent/AU2003248060A1/en not_active Abandoned
- 2003-07-11 WO PCT/JP2003/008879 patent/WO2005006476A1/fr not_active Application Discontinuation
- 2003-12-24 CN CNB2003801103823A patent/CN100382371C/zh not_active Expired - Fee Related
- 2003-12-24 EP EP03786294A patent/EP1653544A4/fr not_active Withdrawn
- 2003-12-24 AU AU2003296102A patent/AU2003296102A1/en not_active Abandoned
- 2003-12-24 WO PCT/JP2003/016646 patent/WO2005006475A1/fr active Application Filing
-
2006
- 2006-01-11 US US11/330,015 patent/US20060145120A1/en not_active Abandoned
-
2008
- 2008-03-11 US US12/046,244 patent/US8187763B2/en active Active
Patent Citations (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2595547A (en) * | 1946-07-11 | 1952-05-06 | Schaaf Herman | Electromagnet |
US4105405A (en) * | 1976-11-27 | 1978-08-08 | Henkel Kommanditgesellschaft Auf Aktien | Method and composition for inhibiting corrosion of metals in contact with water |
US4418231A (en) * | 1981-08-07 | 1983-11-29 | Ppg Industries, Inc. | Corrosion inhibited solvent compositions |
US5454967A (en) * | 1992-02-18 | 1995-10-03 | Basf Aktiengesellschaft | Phosphate containing coolant mixtures which are stable in hard water |
US5772912A (en) * | 1995-01-25 | 1998-06-30 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Environmentally friendly anti-icing |
US5723061A (en) * | 1995-04-28 | 1998-03-03 | Bp Chemicals Limited | Antifreeze composition comprising a water-soluble alcohol and a corrosion inhibitor system comprising dicarboxylic acids or salts thereof, diazole and a triazole |
US6214486B1 (en) * | 1995-05-25 | 2001-04-10 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell and method of controlling same |
US6042955A (en) * | 1995-05-25 | 2000-03-28 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell and method of controlling same |
US6040073A (en) * | 1996-08-07 | 2000-03-21 | Honda Giken Kogyo Kabushiki Kaisha | Fuel cell |
US6391257B1 (en) * | 1998-08-19 | 2002-05-21 | Prestone Products Corporation | Antifreeze compositions comprising carboxylic acid and cyclohexenoic acid |
US6309559B1 (en) * | 1999-07-02 | 2001-10-30 | Clariant Gmbh | Silicate-, borate-and phosphate-free cooling fluids based on glycols and having improved corrosion behavior |
US6361891B1 (en) * | 1999-12-20 | 2002-03-26 | Utc Fuel Cells, Llc | Direct antifreeze cooled fuel cell power plant system |
US20020068360A1 (en) * | 2000-04-17 | 2002-06-06 | Brockbank Kelvin G.M. | Cyclohexanediol cryoprotectant compounds |
US20050244692A1 (en) * | 2002-11-05 | 2005-11-03 | Hiroshi Egawa | Fuel cell coolant composition |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8187763B2 (en) | 2003-07-11 | 2012-05-29 | Honda Motor Co., Ltd. | Cooling liquid composition for fuel cell |
US20080251756A1 (en) * | 2005-03-02 | 2008-10-16 | Shishiai-Kabushikigaisha | Coolant composition for fuel cell |
US7670498B2 (en) * | 2005-03-02 | 2010-03-02 | Honda Motor Co., Ltd. | Coolant composition for fuel cell |
US20070075120A1 (en) * | 2005-06-24 | 2007-04-05 | Bo Yang | Methods for inhibiting corrosion in brazed metal surfaces and coolants and additives for use therein |
US8066902B2 (en) * | 2005-06-24 | 2011-11-29 | Prestone Products Corporation | Methods for inhibiting corrosion in brazed metal surfaces and coolants and additives for use therein |
US20090219693A1 (en) * | 2008-03-03 | 2009-09-03 | Harris Corporation | Cooling system for high voltage systems |
US8102643B2 (en) * | 2008-03-03 | 2012-01-24 | Harris Corporation | Cooling system for high voltage systems |
CN113652210A (zh) * | 2021-06-28 | 2021-11-16 | 中国船舶重工集团公司第七一八研究所 | 一种低电导率长效冷却液及其制备方法 |
WO2023111687A1 (fr) * | 2021-12-17 | 2023-06-22 | Cci Holdings, Inc. | Système de transfert de chaleur à inhibiteurs organiques non ioniques compatibles avec une exposition au flux dans des opérations de pile à combustible |
Also Published As
Publication number | Publication date |
---|---|
CN100382371C (zh) | 2008-04-16 |
EP1653544A4 (fr) | 2010-07-28 |
WO2005006476A1 (fr) | 2005-01-20 |
WO2005006475A1 (fr) | 2005-01-20 |
US8187763B2 (en) | 2012-05-29 |
CN1802765A (zh) | 2006-07-12 |
AU2003248060A1 (en) | 2005-01-28 |
AU2003296102A1 (en) | 2005-01-28 |
US20080166615A1 (en) | 2008-07-10 |
EP1653544A1 (fr) | 2006-05-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US8187763B2 (en) | Cooling liquid composition for fuel cell | |
US7201982B2 (en) | Methods for fuel cell coolant systems | |
US7344655B1 (en) | Coolant, method of enclosing coolant, and cooling system | |
CA2449208C (fr) | Refrigerants destines a des systemes de refroidissement dans des entrainements a piles a combustible et contenant des derives d'azole | |
EP1476524B1 (fr) | Compositions de transfert de chaleur presentant une resistance electrique elevee pour assemblage de piles a combustible | |
EP1791206A1 (fr) | Compostition de refroidissement, système de refroidissement et procédé de production d'une composition de refroidissement | |
KR101021207B1 (ko) | 1,3-프로판디올을 함유하는 아졸 유도체계 연료 전지 냉각 시스템용 냉각제 | |
CN1926706B (zh) | 抑制燃料电池用冷却液组合物基剂氧化的方法 | |
EP1501140A1 (fr) | Composition liquide de refroidissement pour pile a combustible | |
US20050109979A1 (en) | Coolant composition for fuel cell | |
EP1855340B1 (fr) | Composition réfrigérante pour pile à combustible | |
US20050244692A1 (en) | Fuel cell coolant composition | |
JP4785527B2 (ja) | 燃料電池用冷却液組成物 | |
EP4354558A1 (fr) | Composition liquide de refroidissement pour pile à combustible | |
JP5027656B2 (ja) | 燃料電池用冷却液組成物 | |
JP2008059990A (ja) | 燃料電池用冷却液組成物 | |
WO2005105948A1 (fr) | Composition d'un moyen de chauffage | |
JP2022109341A (ja) | 冷却液組成物および濃縮冷却液組成物 | |
EP4124640A1 (fr) | Nouvelle utilisation pour des réfrigérants à faible conductivité électrique | |
JP2008059988A (ja) | 燃料電池用冷却液組成物 | |
JPWO2005091412A1 (ja) | 燃料電池用冷却液組成物 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: SHISHIAI-KABUSHIKIGAISHA, JAPAN Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:EGAWA, HIROSHI;KAGA, NOBUYUKI;REEL/FRAME:017332/0988 Effective date: 20060222 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |