US20050232883A1 - Method for treating hair fibers - Google Patents

Method for treating hair fibers Download PDF

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Publication number
US20050232883A1
US20050232883A1 US11/097,167 US9716705A US2005232883A1 US 20050232883 A1 US20050232883 A1 US 20050232883A1 US 9716705 A US9716705 A US 9716705A US 2005232883 A1 US2005232883 A1 US 2005232883A1
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US
United States
Prior art keywords
reducing composition
hair fibers
hair
reducing
chosen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/097,167
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English (en)
Inventor
Thomas Fondin
Anne Sabbagh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LOreal SA
Original Assignee
LOreal SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=35096497&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=US20050232883(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to FR0450667A priority Critical patent/FR2868305B1/fr
Priority to EP05300250.7A priority patent/EP1584329B2/de
Priority to CN200510071739A priority patent/CN100574741C/zh
Priority to MXPA05003491A priority patent/MXPA05003491A/es
Priority to BRPI0501718-1A priority patent/BRPI0501718A/pt
Priority to KR1020050027818A priority patent/KR20060045454A/ko
Priority to US11/097,167 priority patent/US20050232883A1/en
Priority to JP2005107896A priority patent/JP2005290003A/ja
Application filed by LOreal SA filed Critical LOreal SA
Assigned to L'OREAL S.A. reassignment L'OREAL S.A. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SABBAGH, ANNE, FONDIN, THOMAS
Publication of US20050232883A1 publication Critical patent/US20050232883A1/en
Priority to US13/541,117 priority patent/US9675822B2/en
Priority to US15/584,472 priority patent/US10702464B2/en
Abandoned legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D1/00—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor
    • A45D1/02—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor with means for internal heating, e.g. by liquid fuel
    • A45D1/04—Curling-tongs, i.e. tongs for use when hot; Curling-irons, i.e. irons for use when hot; Accessories therefor with means for internal heating, e.g. by liquid fuel by electricity
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D7/00—Processes of waving, straightening or curling hair
    • A45D7/02—Processes of waving, straightening or curling hair thermal
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/04—Preparations for permanent waving or straightening the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

Definitions

  • Disclosed herein is a method for treating hair fibers by applying a reducing composition and then heating the hair with a heating iron.
  • the usual practice to permanently reshape hair comprises first opening the keratin disulfide bonds (cystine) with a composition comprising a reducing agent.
  • the disulfide bonds are then re-formed, optionally after rinsing the hair, by applying to the hair, which has been straightened or placed beforehand under tension with suitable means such as curlers or the equivalent, an oxidizing composition also called a fixing solution, so as to give the desired form to the hair.
  • an oxidizing composition also called a fixing solution
  • Reducing compositions that can be used to carry out the first step of this method generally comprise compounds comprising a thiol group, such as thioglycolic acid, cysteine, cysteamine, thiolactic acid, and glycerol monothioglycolate.
  • a thiol group such as thioglycolic acid, cysteine, cysteamine, thiolactic acid, and glycerol monothioglycolate.
  • the reducing agent concentration may be very high, often up to 15% by weight, relative to the total weight of the reducing composition.
  • Patent Application No. JP 2000 256 146 describes a process to permanently reshape the hair, comprising the application of a cosmetic composition comprising from 2 to 11% reducing agents and from 0.2 to 4% diammonium dithiodiglycolate. After the reducing composition is applied, a heating iron is used at a temperature from 60 to 220° C.
  • the resulting shape is irreversible.
  • the difference between the parts of the hair that have been treated and the hair roots is very noticeable as the hair regrows.
  • a hair fiber treating method that compensates for at least one of the drawbacks of the prior art.
  • Such a method would also ideally preserve the natural aspect of the hair so as to limit the so-called ‘root effect’, that is to say the contrast between the parts which have been treated and the roots, and also ideally reduce the hair fiber treating time and obtain long-lasting results.
  • the present inventors have found that it is possible to counteract at least one of the drawbacks of the prior art and to achieve at least one of the desirable results listed above, by carrying out a hair fiber treating method without fixing the hair, comprising applying to the hair fibers at least one reducing composition comprising at least one reducing agent chosen from compounds comprising at least one thiol group, wherein the at least one reducing agent is present in an amount of less than 3% by weight, relative to the total weight of the at least one reducing composition, and wherein the at least one reducing composition does not comprise an aminothiol compound or if the composition does comprise at least one aminothiol compound, it is present in an amount of less than 5% by weight, relative to the total weight of the at least one reducing composition, and raising the temperature of the hair fiber using a heating iron at a temperature of at least 60° C., wherein the temperature of the hair fiber is raised before or after the hair fibers are optionally rinsed.
  • a method of treating hair fibers without fixing the hair comprising:
  • ‘without fixing the hair’ or ‘without a hair-fixing step’ means without any additional application of a composition comprising a chemical oxidizing agent, such as hydrogen peroxide or a bromate.
  • a chemical oxidizing agent such as hydrogen peroxide or a bromate.
  • the at least one reducing composition may have a pH of less than or equal to 9, provided that the at least one reducing composition does not comprise an aminothiol compound.
  • the at least one reducing composition does not comprise dithiodiglycolic acid or any salt thereof.
  • the at least one reducing composition may, for example, be applied onto wet and clean hair fibers.
  • aminothiol compound means a thiol comprising at least one NH moiety.
  • the thiols used as the at least one reducing agent may, for example, be chosen from aminothiols, such as cysteine and derivatives thereof, i.e., N-acetylcysteine, cysteamine and derivatives thereof, C 1 -C 4 acylated derivatives thereof, such as N-acetyl cysteamine and N-propionyl cysteamine, and non-aminated thiols, such as thiolactic acid and esters thereof, such as glycerol monothiolactate, thioglycolic acid and esters thereof, such as glycerol and glycol monothioglycolate, and thioglycerol.
  • aminothiols such as cysteine and derivatives thereof, i.e., N-acetylcysteine, cysteamine and derivatives thereof, C 1 -C 4 acylated derivatives thereof, such as N-acetyl cysteamine and N-propionyl cysteamine
  • the thiol may be provided, if needed, in the form of at least one salt thereof, such as alkali metal or ammonium salts. In one embodiment, ammonium thioglycolate may be used.
  • the thiol may be provided, if needed, in the form of at least one salt thereof, such as aminothiol halogenides.
  • L-cysteine hydrochloride may be used.
  • aminothiols examples include sugar N-mercapto-alkyl amides, such as N-(mercapto-2-ethyl)-gluconamide, pantheteine, and N-(mercaptoalkyl)- ⁇ -hydroxyalkyl amides such as those described in Patent Application No. EP-A-354 835 and N-mono- and N,N-dialkylmercapto 4-butyramides, such as those described Patent Application No. EP-A-368 763, aminomercaptoalkyl amides, such as those described Patent Application No. EP-A-432 000 and alkylaminomercaptoalkyl amides such as those described in Patent Application No. EP-A-514 282.
  • sugar N-mercapto-alkyl amides such as N-(mercapto-2-ethyl)-gluconamide, pantheteine
  • N-(mercaptoalkyl)- ⁇ -hydroxyalkyl amides such as those described in Patent Application No. EP-A-3
  • non-aminated thiols examples include a mixture of hydroxy-2-propyl thioglycolate (2/3) and hydroxy-2 methyl-1 ethyl thioglycolate (67/33) described in Patent Application No. FR-A-2 679 448, ⁇ -mercaptopropionic acid and derivatives thereof, and thiomalic acid.
  • the total concentration of thiols in the at least one reducing composition is as follows:
  • the pH of the at least one reducing composition may be adjusted by means of at least one agent chosen from alkaline agents and acidifying agents.
  • the alkaline agents may, for example, be chosen from ammonia; organic amines, such as monoethanolamine, diethanolamine, triethanolamine, 1,3-propanediamine, and 2-amino-2-methyl-1-propanol; alkaline and ammonium carbonate or bicarbonate; organic carbonate, such as guanidine carbonate; alkaline hydroxide, such as soda.
  • the acidifying agents may, for example, be chosen from hydrochloric acid, acetic acid, lactic acid, oxalic acid. and boric acid.
  • the at least one reducing composition may, for example, comprise at least one cosmetically acceptable solvent chosen, for example, from water, C 1 -C 6 alcohols, for example, alkanols such as ethanol, propanol, and isopropanol; polyhydric alcohols, such as propyleneglycol, pentanediol and glycerine; benzyl alcohol; polyol ethers; C 2 -C 6 esters; N-methylpyrrolidone (NMP); and C 3 -C 6 cetones.
  • C 1 -C 6 alcohols for example, alkanols such as ethanol, propanol, and isopropanol
  • polyhydric alcohols such as propyleneglycol, pentanediol and glycerine
  • benzyl alcohol polyol ethers
  • C 2 -C 6 esters such as N-methylpyrrolidone (NMP); and C 3 -C 6 cetones.
  • the at least one reducing composition may also comprise at least one cosmetic additive.
  • the at least one cosmetic additive may, for example, be chosen from volatile and non volatile, linear and cyclic silicones; cationic, non ionic, anionic and amphoteric polymers; peptides and derivatives thereof; protein hydrolyzates; waxes; swelling agents and penetrating agents; agents that are able to increase the efficiency of the at least one reducing agent, such as a SiO 2 /polydimethylsiloxane mixture, dimethylisosorbitol, urea and derivatives thereof; anionic, cationic, non ionic, amphoteric, and zwitterionic surfactants; active agents for combating hair loss; anti-dandruff agents; natural and synthetic, associative and unassociative thickeners; suspension agents; sequestering agents; opacifying agents; dyes; sunscreen agents; vitamins and provitamins; fatty acids; fatty alcohols; mineral, vegetable, and synthetic oils; and fragrances and preserving agents.
  • cationic polymer means any polymer comprising cationic moieties and/or moieties that are ionizable to cationic moieties.
  • cationic polymers examples include polyamine, polyaminoamide and quaternary polyammonium type-polymers, which are known products.
  • Polyamine, polyaminoamide and quaternary polyammonium type-polymers suitable for use in the at least one reducing composition are those, for example, described in French Patent Nos. FR 2 505 348 and FR 2 542 997. These polymers may be chosen from at least one of the following:
  • cationic polymers that can be used include cationic proteins or cationic protein hydrolyzates, polyalkyleneimines, for example, polyethylene imines, polymers with vinyl pyridine or vinyl pyridinium moieties, polyamine and epichlorhydrine condensation products, quaternary polyureylenes, and chitin derivatives.
  • polyalkyleneimines for example, polyethylene imines, polymers with vinyl pyridine or vinyl pyridinium moieties, polyamine and epichlorhydrine condensation products, quaternary polyureylenes, and chitin derivatives.
  • the cationic polymers may be chosen from hexadimethrine chloride and dimethyldiallylammonium chloride homopolymers and copolymers.
  • the at least one cosmetic additive may also be chosen from silicones.
  • Silicones that are suitable for use as the at least one cosmetic additive include polydimethylsiloxanes; quaternized polyorganosiloxanes, such as those described in French Patent Application No. FR 2 535 730; polyorganosiloxanes comprising alkoxycarbonylalkyl moieties modified with aminoalkyl moieties, such as those described in U.S. Pat. No.
  • polyorganosiloxanes such as polydimethylsiloxane-polyoxyalkyl copolymer of dimethicone copolyol; a polydimethylsiloxane with stearoxy(stearoxy dimethicone) end groups; a polydimethylsiloxane-dialkylammonium acetate copolymer and a polydimethyl-siloxane polyalkylbetaine copolymer described in British Patent No. GB 2,197,352; and organo polysiloxanes modified by mercapto or mercaptoalkyl moieties such as those described in French Patent No. FR 1 530 369 and in European Patent Application No. EP 295 780.
  • the at least one cosmetic additive may also be chosen from fatty acids and fatty alcohols.
  • the fatty acids may, for example, be chosen from C 8 -C 30 carboxylic acids, such as palmitic acid, oleic acid, linoleic acid, myristic acid, stearic acid, lauric acid, and mixtures thereof.
  • the fatty alcohols may, for example, be chosen from C 8 -C 30 alcohols, such as palmityl, oleyl, linoleyl, myristyl, stearyl, and lauryl alcohols.
  • the at least one reducing composition used in the method disclosed herein may be provided in a form chosen from an optionally thickened lotion, a cream, a gel, and a foam.
  • the method disclosed herein comprises applying the at least one reducing composition as defined above to hair fibers. Once the at least one reducing composition has been applied, it can be left on the hair fibers, optionally under a drying helmet, for a time period ranging from 5 to 60 minutes, for example, from 5 to 30 minutes.
  • the method further comprises, after applying the reducing composition, optionally rinsing the hair fibers, then raising the temperature of the hair fibers, with a heating iron at a temperature of at least 60° C.
  • iron means any heating device which functions by contacting the hair fibers.
  • the end of the iron coming into contact with the hair may have various forms. It may, for example, have a plane surface, such as a flat iron. It may also have a rounded surface, such as a round iron.
  • the iron may be applied proceeding by successive separated touches for a few seconds or by gradually moving or sliding along hair locks.
  • the hair fiber temperature may be raised at a temperature ranging from 60° C. to 250° C., such as from 120° C. to 220° C.
  • the hair fibers are not rinsed out before heat is applied in the form of the heating iron for raising the temperature of the hair fibers.
  • the method disclosed herein may also include partially pre-drying the hair fibers before raising the temperature of the hair fibers, so as to prevent any substantial steam development that might burn the hands of the hair stylist and the scalp of the user.
  • This pre-drying may be done, for example, by using a hair drier, a hood, or it is also possible to let the hair dry naturally.
  • the hair fiber treating method disclosed herein was carried out using a reducing composition.
  • Tested reducing compositions were as follows: Reducing composition 1 L-Cysteine 1.4 g MEXOMERE PO 2.5 g 2-amino-2-methyl-1-propanol qs pH 9 Demineralized water qs 100 g Reducing composition 2 Thioglycolic acid 1.1 g MEXOMERE PO 2.5 g 2-amino-2-methyl-1-propanol qs pH 9 Demineralized water qs 100 g Reducing composition 3 L-Cysteine 1.4 g Thioglycolic acid 0.3 g MEXOMERE P0 2.5 g 2-amino-2-methyl-1-propanol qs pH 9 Demineralized water qs 100 g Reducing composition 4 L-Cysteine 1.4 g 2-amino-2-methyl-1-propanol qs pH 9 Demineralized water qs 100 g
  • a reducing composition such as previously described was applied onto the hair and left on for 5 minutes.
  • the hair was then partially pre-dried using a hair drier before being treated using a flat iron heated to 180° C.
  • the hair fiber showed a good texture, a well controlled volume, a good respect of the color and a long term durability of the effects.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Veterinary Medicine (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Emergency Medicine (AREA)
  • Dermatology (AREA)
  • Cosmetics (AREA)
US11/097,167 2004-04-02 2005-04-04 Method for treating hair fibers Abandoned US20050232883A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR0450667A FR2868305B1 (fr) 2004-04-02 2004-04-02 Procede de traitement capillaire et utilisation dudit procede
EP05300250.7A EP1584329B2 (de) 2004-04-02 2005-04-01 Haarbehandlungsverfahren und dessen Einsatz
CN200510071739A CN100574741C (zh) 2004-04-02 2005-04-01 头发纤维护理方法及所述方法的应用
MXPA05003491A MXPA05003491A (es) 2004-04-02 2005-04-01 Metodo de tratamiento de las fibras del cabello y uso de este metodo.
BRPI0501718-1A BRPI0501718A (pt) 2004-04-02 2005-04-01 método de tratamento de fibra de cabelo sem etapa de fixação do cabelo e uso do método
KR1020050027818A KR20060045454A (ko) 2004-04-02 2005-04-02 모발 섬유 처리 방법 및 상기 방법의 용도
US11/097,167 US20050232883A1 (en) 2004-04-02 2005-04-04 Method for treating hair fibers
JP2005107896A JP2005290003A (ja) 2004-04-02 2005-04-04 毛髪繊維の処理方法及び該方法の使用
US13/541,117 US9675822B2 (en) 2004-04-02 2012-07-03 Method for treating hair fibers
US15/584,472 US10702464B2 (en) 2004-04-02 2017-05-02 Method for treating hair fibers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0450667A FR2868305B1 (fr) 2004-04-02 2004-04-02 Procede de traitement capillaire et utilisation dudit procede
FR0450667 2004-04-02
US57192204P 2004-05-18 2004-05-18
US11/097,167 US20050232883A1 (en) 2004-04-02 2005-04-04 Method for treating hair fibers

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US13/541,117 Continuation US9675822B2 (en) 2004-04-02 2012-07-03 Method for treating hair fibers

Publications (1)

Publication Number Publication Date
US20050232883A1 true US20050232883A1 (en) 2005-10-20

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ID=35096497

Family Applications (3)

Application Number Title Priority Date Filing Date
US11/097,167 Abandoned US20050232883A1 (en) 2004-04-02 2005-04-04 Method for treating hair fibers
US13/541,117 Active US9675822B2 (en) 2004-04-02 2012-07-03 Method for treating hair fibers
US15/584,472 Expired - Fee Related US10702464B2 (en) 2004-04-02 2017-05-02 Method for treating hair fibers

Family Applications After (2)

Application Number Title Priority Date Filing Date
US13/541,117 Active US9675822B2 (en) 2004-04-02 2012-07-03 Method for treating hair fibers
US15/584,472 Expired - Fee Related US10702464B2 (en) 2004-04-02 2017-05-02 Method for treating hair fibers

Country Status (8)

Country Link
US (3) US20050232883A1 (de)
EP (1) EP1584329B2 (de)
JP (1) JP2005290003A (de)
KR (1) KR20060045454A (de)
CN (1) CN100574741C (de)
BR (1) BRPI0501718A (de)
FR (1) FR2868305B1 (de)
MX (1) MXPA05003491A (de)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2868305B1 (fr) * 2004-04-02 2006-06-30 Oreal Procede de traitement capillaire et utilisation dudit procede
JP5089053B2 (ja) * 2006-01-31 2012-12-05 株式会社ミルボン 脱染用組成物
FR2911272B1 (fr) * 2007-01-12 2009-03-06 Oreal Composition reductrice destinee a etre mise en oeuvre dans un procede de deformation permanente des fibres keratiniques comprenant de la cysteine et de l'acide thiolactique ou l'un de leurs sels
FR2944438B1 (fr) 2009-04-15 2011-06-17 Oreal Procede de mise en forme des cheveux au moyen d'une composition reductrice et d'un chauffage.
FR2965481B1 (fr) 2010-10-01 2013-04-19 Oreal Procede de traitement des fibres keratiniques mettant en oeuvre au moins un reducteur soufre, au moins un polymere cationique et au moins un mercaptosiloxane
US8607803B2 (en) 2011-09-29 2013-12-17 The Procter & Gamble Company Hair treatment process providing dispersed colors by light diffraction
DE102011084188A1 (de) * 2011-10-10 2013-04-11 BSH Bosch und Siemens Hausgeräte GmbH Haarstyling- und/oder Haarglättmittel mit zugkraftverstärkendem Mittel
US9216144B2 (en) 2013-03-28 2015-12-22 The Procter & Gamble Company Hair treatment process providing dispersed colors by light diffraction
FR3039374B1 (fr) * 2015-07-29 2019-12-20 L'oreal Procede de traitement de fibres capillaires
BR112019006350B8 (pt) * 2016-09-30 2021-11-03 Oreal Composição cosmética para cabelo, método para tratar o cabelo e método para conferir ao cabelo um ou mais efeitos de cuidado
JP7353754B2 (ja) * 2018-12-14 2023-10-02 ロレアル ケラチン繊維の矯正法
FR3146405A1 (fr) * 2023-03-10 2024-09-13 L'oreal Procédé de recourbement des fibres kératiniques avec application d’une composition aqueuse comprenant de la cystéine et/ou l’un de ses sels et chauffage desdites fibres

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US20130000661A1 (en) 2013-01-03
JP2005290003A (ja) 2005-10-20
FR2868305B1 (fr) 2006-06-30
MXPA05003491A (es) 2005-10-06
EP1584329B1 (de) 2014-11-05
CN1698569A (zh) 2005-11-23
CN100574741C (zh) 2009-12-30
KR20060045454A (ko) 2006-05-17
US20170231887A1 (en) 2017-08-17
US10702464B2 (en) 2020-07-07
EP1584329A1 (de) 2005-10-12
BRPI0501718A (pt) 2006-04-18
US9675822B2 (en) 2017-06-13
EP1584329B2 (de) 2021-05-19
FR2868305A1 (fr) 2005-10-07
US20170095408A9 (en) 2017-04-06

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