US20040231461A1 - Method for producing ultrafine dispersion water of noble metal ultrafine particles - Google Patents

Method for producing ultrafine dispersion water of noble metal ultrafine particles Download PDF

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Publication number
US20040231461A1
US20040231461A1 US10/492,333 US49233304A US2004231461A1 US 20040231461 A1 US20040231461 A1 US 20040231461A1 US 49233304 A US49233304 A US 49233304A US 2004231461 A1 US2004231461 A1 US 2004231461A1
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Prior art keywords
noble metal
water
metal particles
super
fine
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Abandoned
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US10/492,333
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English (en)
Inventor
Yoshihiro Hirata
Yoshio Ueda
Hiroaki Takase
Kazuaki Suzuki
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Phild Co Ltd
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Phild Co Ltd
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Assigned to PHILD CO., LTD. reassignment PHILD CO., LTD. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: SUZUKI, KAZUAKI, HIRATA, YOSHIHIRO, TAKASE, HIROAKI, UEDA, YOSHIO
Publication of US20040231461A1 publication Critical patent/US20040231461A1/en
Priority to US11/862,048 priority Critical patent/US8128789B2/en
Abandoned legal-status Critical Current

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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/044—Suspensions
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L33/00—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof
    • A23L33/10—Modifying nutritive qualities of foods; Dietetic products; Preparation or treatment thereof using additives
    • A23L33/16—Inorganic salts, minerals or trace elements
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00—Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/04—Drugs for disorders of the alimentary tract or the digestive system for ulcers, gastritis or reflux esophagitis, e.g. antacids, inhibitors of acid secretion, mucosal protectants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P1/00—Drugs for disorders of the alimentary tract or the digestive system
    • A61P1/14—Prodigestives, e.g. acids, enzymes, appetite stimulants, antidyspeptics, tonics, antiflatulents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P27/00—Drugs for disorders of the senses
    • A61P27/02—Ophthalmic agents
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P3/00—Drugs for disorders of the metabolism
    • A61P3/02—Nutrients, e.g. vitamins, minerals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P9/00—Drugs for disorders of the cardiovascular system
    • A61P9/12—Antihypertensives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
    • A61K2800/83—Electrophoresis; Electrodes; Electrolytic phenomena

Definitions

  • This invention relates to a method and apparatus for efficiently producing micro-dispersion water of super-fine noble metal particles.
  • the invention also relates to healthy drinking water or cosmetic lotion that applies the obtained noble metal micro-dispersion water.
  • noble metals have been again drawing the attention of the increasingly health-conscious public.
  • noble metals in ion or fine particle form are now known to offer more remarkable health-promoting function than noble metals themselves or in flake form, such as gold foil.
  • the published technologies relating to the use of aqueous solution or water dispersion of noble metal ions and fine noble metal particles include the technology to mix with polyolefin molding resin an inorganic antibacterial agent produced by fixing to zeolite ion-exchange material gold ions and ions of other metals offering antibacterial function, in order to provide an antibacterial beverage tank that can protect the drink from bacteriophages permeating through the walls of the polyethylene beverage tank while keeping the original flavor of the drink (Registered Japanese Utility Model No.
  • the inventors developed the present invention after diligently studying ways to produce healthy water containing super-fine noble metal particles, based on the assumption that providing drinking water containing such noble metal ions and fine noble metal particles would embody an easy way to improve health and thereby enable improvement of various conditions.
  • noble metal ions and fine noble metal particles offer potentially high health-promoting function and disease-curing effect.
  • the modes of applying noble metals for these purposes include aqueous solution or water dispersion of noble metal ions and fine noble metal particles, but the conventional methods required high production costs and therefore did not provide desired economy. These methods also posed technical problems that remain unresolved, such as the insufficient health-promoting effects of the products and unverified safety of using chemical electrolytes in the human body.
  • the present invention aims to solve these problems by creating micro-dispersion water of noble metal ions and fine noble metal particles and allowing the obtained water to be utilized in health-promoting applications such as bioactive materials, health food materials, cosmetics and drugs.
  • the present invention is a development of a new method and apparatus for producing micro-dispersion water of super-fine noble metal particles.
  • the present invention allows for production of micro-dispersion water of super-fine noble metal particles by causing plasma discharge in water between an electrode made of noble metal and its counter electrode equipped on a high-voltage discharge generator and then causing the generated noble metal ion vapor to contact, and micro-disperse in, water.
  • the trial tests of the obtained micro-dispersion water of super-fine noble metal particles confirmed that the water exhibited remarkable effects in improving physical condition and relieving fatigue, among others, and could be effectively used as drinking water.
  • micro-dispersion water of super-fine noble metal particles refers to water in which very fine particles of noble metal are micro-dispersed, unlike other types of water in which noble metal powder or foil is simply floating.
  • the present invention comprises of (1) through (7) below:
  • a method for producing micro-dispersion water of super-fine noble metal particles by causing plasma discharge in water between an electrode made of noble metal and its counter electrode equipped on a high-voltage discharge generator and then causing the generated noble metal ion vapor to contact, and micro-disperse in, water.
  • An apparatus for producing micro-dispersion water of super-fine noble metal particles comprising a power supply for high-voltage/current discharge, a high-voltage discharge generator equipped with a noble metal electrode and its counter electrode, a water tank, a water inlet to the water tank, an outlet for produced water, and a discharge pump.
  • Micro-dispersion water of super-fine noble metal particles obtained by causing plasma discharge in water between an electrode made of noble metal and its counter electrode equipped on a high-voltage discharge generator and then causing the generated noble metal ion vapor to contact, and micro-disperse in, water.
  • FIG. 1 A flow chart outlining the process proposed by the present invention
  • FIG. 2 An apparatus for producing micro-dispersion water of super-fine noble metal particles as proposed by the present invention.
  • gold and platinum particles do not dissolve or disperse in water. Therefore, even when a dispersed state of fine gold or platinum particles is somehow achieved in water, the surface area of particles is small relative to the weight of gold or platinum mixed into water, thus resulting in poor cost-efficiency. The dispersed particles will also settle quickly. Therefore, any method that achieves such temporary dispersion does not satisfy the technical requirements.
  • the present invention was developed as a technology to produce micro-dispersion water of super-fine noble metal particles by causing plasma discharge in water between an electrode made of noble metal and its counter electrode equipped on a high-voltage discharge generator and then causing the generated noble metal ion vapor to contact, and micro-disperse in, water, based on the assumption that micro-dispersing super-fine noble metal particles of micron to nano-scale, which are smaller than fine noble metal particles, would improve the various shortcomings mentioned above.
  • One feature of the present invention is that it has realized a production and utilization of water in which super-fine noble metal particles of micron to nano-order are micro-dispersed, which are finer than the normal fine noble metal particles as mentioned above. This way, stable micro-dispersion water in which super-fine noble metal particles remain dispersed without settling for a longer period of time compared with water in which flakes of noble metal foil or fine noble metal particles are simply floating. Its physical properties make the obtained water safe for human consumption just like normal water, and the water also provides high functions in promoting health, among others.
  • the primary feature of the present invention is that it provides a method to produce micro-dispersion water of super-fine noble metal particles by causing plasma discharge in water between an electrode made of noble metal and its counter electrode and then causing the generated noble metal ion vapor to contact, and micro-disperse in, water. This process is outlined in FIG. 1.
  • the basic production method proposed by the present invention is to continuously or intermittently feed water into the water tank and cause plasma discharge in water between an electrode made of noble metal and its counter electrode and thus heat the noble metal to high temperatures to generate noble metal vapor, and then cause the generated noble metal ion vapor to instantly contact water and micro-disperse in water. At this time, very small “super-fine” noble metal particles of micron to nano-scale are generated and micro-dispersed.
  • fusing of the noble metal electrode can be prevented by vibrating or sliding in the water tank the noble metal electrode and its counter electrode equipped on the high-voltage discharge generator, and the amount of micro-dispersion can be controlled easily for generation of instant arc. Since the noble metal electrode will be consumed as super-fine particles, an electrode having a bar or wire shape is fed. Additionally, there is no need to select a different power supply for a given purpose, because the amount of current flowing through the circuit can be adjusted easily by changing the diameter and length of the counter electrode made of carbon, etc.
  • the produced water is retrieved from the outlet using the discharge pump and can be used directly without filtering.
  • filtering the water using a filter system, etc. will remove a trace amount of fine noble metal particles with a larger particle size and help yield micro-dispersion water in which only super-fine particles are micro-dispersed.
  • the residue of fine noble metal particles left on the filter can be recovered by backwash and reused, as necessary, to improve economy.
  • the apparatus for producing noble metal micro-dispersion water proposed by the present invention provides an apparatus for producing micro-dispersion water in which super-fine noble metal particles are micro-dispersed, wherein the apparatus comprising a power supply for high-voltage/current discharge ( 2 ), a high-voltage discharge generator ( 1 ) equipped with a noble metal electrode ( 6 ) and its counter electrode ( 7 ), a water tank ( 3 ), a water inlet to the water tank ( 8 ), an outlet for produced micro-dispersion water of super-fine noble metal particles ( 9 ), and a discharge pump ( 10 ).
  • a power supply for high-voltage/current discharge 2
  • a high-voltage discharge generator 1
  • the apparatus comprising a power supply for high-voltage/current discharge ( 2 ), a high-voltage discharge generator ( 1 ) equipped with a noble metal electrode ( 6 ) and its counter electrode ( 7 ), a water tank ( 3 ), a water inlet to the water tank ( 8 ), an outlet for produced micro-disp
  • An electrode feeder ( 4 ) that feeds the electrode pair on the high-voltage discharge generator, an electrode-vibrating/sliding device ( 5 ) that vibrates or slides the electrodes, and a filter system ( 11 ) for the obtained micro-dispersion water will be attached as adjuncts.
  • the production container used in the present invention comprising the water tank ( 3 ) made of metal, or preferably steel, wherein water is supplied from the inlet ( 8 ) and the noble metal electrode ( 6 ) and its counter electrode ( 7 ) on the high-voltage discharge generator ( 1 ) are submerged in water.
  • the water tank ( 3 ) made of metal, or preferably steel, wherein water is supplied from the inlet ( 8 ) and the noble metal electrode ( 6 ) and its counter electrode ( 7 ) on the high-voltage discharge generator ( 1 ) are submerged in water.
  • the obtained micro-dispersion water can be used directly, or fed by the discharge pump ( 10 ) to pass through the filter system ( 11 ) to obtain filtered product ( 12 ).
  • a desirable filter system is one using hollow-fiber membranes of micron order mesh, instead of ion-exchange membranes or reverse-osmosis membranes, in order to filter only super-fine particles through.
  • Filtering will provide drinking water meeting the food sanitation standards or cosmetic lotion meeting the cosmetics material standards.
  • One example of filtration using hollow-fiber membrane filter is to provide hollow-fiber membranes of 50 microns, 25 microns, 3 microns, 0.5 micron and 0.1 micron at the point where the produced water is discharged from the reaction tank, and then let the water pass through these membranes sequentially. Filtered fine noble metal particles can be recovered via backwash and reused for added economy.
  • the high-function water obtained by the present invention can be used as healthy drinking water, health-promoting agent, cosmetics, food preservative, freshness-keeping agent for food, insecticide, deodorant, etc.
  • gold is expected to offer excellent levels of stability, intestinal absorption and other physiological effects in the body, partly due to the ion-releasing effect and very large active surface area of its super-fine particles, and partly due to the unique characteristics and physiochemical stability of gold itself.
  • An example of the present invention is explained according to the drawings. Note, however, that the present invention is not limited to this example.
  • This example uses the apparatus shown in FIG. 2 for producing micro-dispersion water in which super-fine noble metal particles are micro-dispersed, comprising a 200-liter water tank ( 3 ), and a high-voltage discharge generator ( 1 ) equipped with a noble metal electrode ( 6 ) and its counter electrode ( 7 ).
  • a gold or platinum bar is used as the noble metal electrode, while the same metal or carbon is used as the counter electrode, and the two electrodes are charged with electricity for one hour.
  • the electrodes may be fixed plates, or bars or wires that are successively fed using an auxiliary device. Either way, the electrodes are vibrated or slid by an electrode-vibrating/sliding device ( 5 ), and plasma discharge is caused in water between the noble metal electrode and its counter electrode by supplying power to the high-voltage discharge generator ( 1 ).
  • the production container is a pressure-resistant water tank ( 3 ) made of metal, or preferably steel, wherein water is fed through an inlet ( 8 ) and the noble metal ion vapor generated from the noble metal electrode via plasma discharge between the electrodes is caused to instantly contact, and micro-disperse in, water, in order to provide micro-dispersion water in which super-fine noble metal particles are micro-dispersed.
  • the produced noble metal micro-dispersion water is fed by a pump ( 10 ) through a filter system ( 11 ), as appropriate, to be obtained as product ( 12 ).
  • the filter system uses hollow-fiber membranes of 50 microns, 25 microns, 3 microns, 0.5 micron and 0.1 micron, and the water is passed through these membranes sequentially.
  • micro-dispersion water was used in the trial tests as described below:
  • This test involved a group of ten males and females different from the above subjects.
  • Table 1 shows the subjects' evaluations of the water provided by the present invention and the comparison water explained below.
  • a gold bar was used as electrode material to obtain the above high-function healthy drinking water in which super-fine gold particles are micro-dispersed.
  • the present invention provides a new method and apparatus for producing micro-dispersion water of super-fine noble metal particles, as well as healthy drinking water utilizing this newly developed micro-dispersion water of super-fine noble metal particles.
  • the compact apparatus reduces the capital investment, and its design allows for easy, low-cost production of micro-dispersion water of super-fine noble metal particles.
  • this micro-dispersion water of super-fine noble metal particles is used as drinking water or cosmetic lotion, such water/lotion will exhibit remarkable effects in the improvement of health functions, such as improvement of physical condition and increase in appetite, due to the bioactivity of super-fine noble metal particles.

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  • Bioinformatics & Cheminformatics (AREA)
  • Nutrition Science (AREA)
  • Food Science & Technology (AREA)
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  • Dermatology (AREA)
  • Dispersion Chemistry (AREA)
  • Polymers & Plastics (AREA)
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  • Heart & Thoracic Surgery (AREA)
  • Obesity (AREA)
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  • Ophthalmology & Optometry (AREA)
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  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)
  • Colloid Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Non-Alcoholic Beverages (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
US10/492,333 2001-10-12 2002-10-11 Method for producing ultrafine dispersion water of noble metal ultrafine particles Abandoned US20040231461A1 (en)

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JP2001315257 2001-10-12
JP2001315205 2001-10-12
JP2001-315205 2001-10-12
JP2001-315257 2001-12-10
PCT/JP2002/010566 WO2003032756A1 (fr) 2001-10-12 2002-10-11 Procede permettant d'obtenir une dispersion aqueuse ultrafine constituee de particules ultrafines de metal noble

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EP (1) EP1444903B1 (pl)
JP (1) JP4154333B2 (pl)
KR (1) KR100862898B1 (pl)
CN (1) CN1242702C (pl)
AT (1) ATE358993T1 (pl)
BR (1) BR0213250A (pl)
CA (1) CA2463462A1 (pl)
DE (1) DE60219506T2 (pl)
DK (1) DK1444903T3 (pl)
ES (1) ES2282478T3 (pl)
HK (1) HK1068234A1 (pl)
HU (1) HUP0401888A2 (pl)
MX (1) MXPA04003400A (pl)
NO (1) NO20041816L (pl)
PL (1) PL368616A1 (pl)
PT (1) PT1444903E (pl)
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US20070163678A1 (en) * 2004-08-28 2007-07-19 Nano Plasma Center Co., Ltd. Gold or silver particles with paramagnetism, and composition containing thereof
US20080011614A1 (en) * 2001-10-12 2008-01-17 Yoshihiro Hirata Method for producing ultrafine dispersion water of noble metal ultrafine particles
US20090178933A1 (en) * 2008-01-14 2009-07-16 Taofang Zeng Method for Making Nanoparticles or Fine Particles
US20160324150A1 (en) * 2007-02-12 2016-11-10 Archer Daniels Midland Company Adjuvants and methods of using them

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JP2008050679A (ja) * 2006-08-28 2008-03-06 Ikuo Iwasaki 金属粉体の製造方法及び製造装置
KR100888520B1 (ko) * 2007-07-05 2009-03-11 김순남 인공수 제조방법
KR100957823B1 (ko) * 2008-04-10 2010-05-13 (주)솔고나노어드벤스 스틱형상의 액체 주입형 카트리지를 이용한 금속 나노콜로이드 생성 장치 및 스틱형상의 액체 주입형 카트리지
JP2010120868A (ja) * 2008-11-18 2010-06-03 Taikoo:Kk バナジウムイオン含有水の製造方法および製造装置
US9067263B2 (en) * 2009-01-15 2015-06-30 Gr Intellectual Reserve, Llc Continuous, semicontinuous and batch methods for treating liquids and manufacturing certain constituents (e.g., nanoparticles) in liquids, apparatuses and nanoparticles and nanoparticle/liquid solution(s) and colloids resulting therefrom
KR102131575B1 (ko) * 2009-07-08 2020-07-08 클레네 나노메디슨, 인크. 의학적 치료를 위한 신규한 금계 나노결정 및 이를 위한 전기화학 제조 방법
US8889081B2 (en) 2009-10-15 2014-11-18 Medivators Inc. Room fogging disinfection system
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US8480784B2 (en) * 2010-09-15 2013-07-09 Mahdieh Malekzadeh Method of producing high purity silver nanoparticles
CN103702689B (zh) 2011-05-27 2016-08-17 马尔科尔净化装置公司 包括使用净化物质的环境控制的净化系统
US9381588B2 (en) 2013-03-08 2016-07-05 Lotus BioEFx, LLC Multi-metal particle generator and method
JP6375191B2 (ja) * 2014-07-08 2018-08-15 株式会社Kri 金属ナノ粒子分散液の製造方法、金属クラスターを含む溶液、その製造方法およびその塗膜並びにアスコルビン酸センサー
PL423403A1 (pl) * 2017-11-10 2019-05-20 Liw Lewant Fabryka Wyrobow Z Tworzyw Sztucznych Spolka Z Ograniczona Odpowiedzialnoscia Urządzenie do uwalniania jonów metali lub minerałów do roztworów wodnych oraz sposób uwalniania jonów metali lub minerałów w roztworze wodnym
RU196297U1 (ru) * 2019-07-29 2020-02-25 Федеральное государственное бюджетное учреждение науки Институт электрофизики и электроэнергетики Российской академии наук (ИЭЭ РАН) Устройство для изготовления водной дисперсии наночастиц
CN110961646B (zh) * 2019-11-07 2023-08-04 深圳航科新材料有限公司 金属粉末及其制备方法
CN111331146B (zh) * 2020-03-10 2021-07-06 深圳航科新材料有限公司 石墨烯包覆的超细粉体及其制备方法
CN111230134B (zh) * 2020-03-10 2023-08-04 深圳航科新材料有限公司 多元合金粉末及其快速制备方法
CN111821314A (zh) * 2020-03-25 2020-10-27 巫远程 一种治疗近视和白内障眼药水及其制作方法

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US20050092132A1 (en) * 2001-10-29 2005-05-05 Yoshihiro Hirata Method and apparatus for the production of metal powder
US7118684B2 (en) * 2001-10-12 2006-10-10 Phild Co., Ltd. Treatment of fiber with water containing fine powder of noble metal dispersed therein

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US8128789B2 (en) 2012-03-06
DK1444903T3 (da) 2007-08-06
KR100862898B1 (ko) 2008-10-13
KR20050035133A (ko) 2005-04-15
PL368616A1 (pl) 2005-04-04
ATE358993T1 (de) 2007-05-15
DE60219506D1 (de) 2007-05-24
CN1242702C (zh) 2006-02-22
EP1444903B1 (en) 2007-04-11
JPWO2003032756A1 (ja) 2005-01-27
EP1444903A4 (en) 2004-12-22
TWI255695B (en) 2006-06-01
MXPA04003400A (es) 2004-06-18
US20080011614A1 (en) 2008-01-17
HUP0401888A2 (hu) 2005-03-29
NO20041816L (no) 2004-05-04
CN1564662A (zh) 2005-01-12
CA2463462A1 (en) 2003-04-24
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