US12030702B2 - Can lid made of resin laminate steel sheet for resin-metal composite container, can bottom made of resin laminate steel sheet for resin-metal composite container, and resin-metal composite container - Google Patents

Can lid made of resin laminate steel sheet for resin-metal composite container, can bottom made of resin laminate steel sheet for resin-metal composite container, and resin-metal composite container Download PDF

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US12030702B2
US12030702B2 US17/290,453 US202017290453A US12030702B2 US 12030702 B2 US12030702 B2 US 12030702B2 US 202017290453 A US202017290453 A US 202017290453A US 12030702 B2 US12030702 B2 US 12030702B2
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resin layer
resin
steel sheet
ethylene
based resin
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US17/290,453
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US20220033136A1 (en
Inventor
Nobuo Kadowaki
Kazushi IWAKIRI
Tomohiro Mizutani
Satoshi Kato
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Nippon Steel Corp
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Nippon Steel Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D7/00Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal
    • B65D7/12Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by wall construction or by connections between walls
    • B65D7/34Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by wall construction or by connections between walls with permanent connections between walls
    • B65D7/38Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by wall construction or by connections between walls with permanent connections between walls formed by soldering, welding, or otherwise uniting opposed surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D17/00Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
    • B65D17/06Integral, or permanently secured, end or side closures
    • B65D17/08Closures secured by folding or rolling and pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/085Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B15/00Layered products comprising a layer of metal
    • B32B15/04Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B15/08Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B32B15/09Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
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    • B32B15/18Layered products comprising a layer of metal comprising iron or steel
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    • B32B3/04Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by features of form at particular places, e.g. in edge regions characterised by at least one layer folded at the edge, e.g. over another layer ; characterised by at least one layer enveloping or enclosing a material
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    • B65D15/00Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials
    • B65D15/02Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials of curved, or partially curved, cross-section, e.g. cans, drums
    • B65D15/16Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials of curved, or partially curved, cross-section, e.g. cans, drums with curved, or partially curved, walls made of plastics material
    • B65D15/18Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials of curved, or partially curved, cross-section, e.g. cans, drums with curved, or partially curved, walls made of plastics material with end walls made of metal
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    • B65D15/00Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, sections made of different materials
    • B65D15/24Connections between walls
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    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D17/00Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
    • B65D17/06Integral, or permanently secured, end or side closures
    • B65D17/12Closures secured by soldering, welding, or otherwise uniting opposed surfaces
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D17/00Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
    • B65D17/28Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions at lines or points of weakness
    • B65D17/401Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions at lines or points of weakness characterised by having the line of weakness provided in an end wall
    • B65D17/4011Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions at lines or points of weakness characterised by having the line of weakness provided in an end wall for opening completely by means of a tearing tab
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D7/00Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal
    • B65D7/02Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by shape
    • B65D7/04Containers having bodies formed by interconnecting or uniting two or more rigid, or substantially rigid, components made wholly or mainly of metal characterised by shape of curved cross-section, e.g. cans of circular or elliptical cross-section
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/055 or more layers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/06Coating on the layer surface on metal layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00Coating on the layer surface
    • B32B2255/20Inorganic coating
    • B32B2255/205Metallic coating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2270/00Resin or rubber layer containing a blend of at least two different polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/30Properties of the layers or laminate having particular thermal properties
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/514Oriented
    • B32B2307/518Oriented bi-axially
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    • B32B2307/70Other properties
    • B32B2307/732Dimensional properties
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2435/00Closures, end caps, stoppers
    • B32B2435/02Closures, end caps, stoppers for containers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2439/00Containers; Receptacles
    • B32B2439/40Closed containers
    • B32B2439/66Cans, tins
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D17/00Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions
    • B65D17/02Rigid or semi-rigid containers specially constructed to be opened by cutting or piercing, or by tearing of frangible members or portions of curved cross-section, e.g. cans of circular or elliptical cross-section
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    • B65D2517/00Containers specially constructed to be opened by cutting, piercing or tearing of wall portions, e.g. preserving cans or tins
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    • B65D2517/00Containers specially constructed to be opened by cutting, piercing or tearing of wall portions, e.g. preserving cans or tins
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/14Copolymers of propene

Definitions

  • the present invention relates to a can lid made of a resin laminate steel sheet for a resin-metal composite container, a can bottom made of a resin laminate steel sheet for a resin-metal composite container, and a resin-metal composite container, and particularly to a can lid made of a resin laminate steel sheet for a resin-metal composite container and a can bottom made of a resin laminate steel sheet for a resin-metal composite container to be seamed and fused to a container body having a can body made of a polypropylene-based thermoplastic resin, and a resin-metal composite container having a can body made of a polypropylene-based thermoplastic resin.
  • Priority is claimed on Japanese Patent Application No. 2019-020682, filed Feb. 7, 2019, the content of which is incorporated herein by reference.
  • the mainstream container for long-term storage of food is a food can consisting of a can body, a can lid, and a can bottom made of metal.
  • a metal since the contents of a metal can cannot be seen unless the can is opened, in recent years, retort pouch containers made of a transparent resin have become widespread for applications that do not require as long-term storage as cans do.
  • a retort pouch container made of a resin is a container obtained by filling a container having a bag shape formed by heat-sealing a resin film with food and heat-sealing the opening end, and has an advantage that the contents in the container can be visually confirmed by using a transparent film.
  • the container itself is a resin film, there is a disadvantage that the piercing strength is low.
  • Patent Document 1 Japanese Unexamined Patent Application, First Publication No. H10-305871
  • the surfaces of the steel sheets of the can lid and the can bottom are coated with a resin layer that can be fused to the resin on the can body side.
  • the resin on the can body side and the resin layer coating the surface on the can lid and the can bottom side need to be a thermoplastic resin. It is preferable that the melting point of the thermoplastic resin in the resin layer to be coated is low.
  • a polyethylene (hereinafter, referred to as PE)-based resin may meet this condition, but is not suitable for practical use because its melting point is near the retort sterilization treatment temperature (120° C. to 130° C.).
  • the polypropylene (PP)-based resin has excellent retort resistance and can be thermally fusion-bonded at a relatively low temperature of about 200° C. Therefore, the polypropylene-based resin is preferable as the kind of resin.
  • the resin coating the can lid is the same on the inner and outer surfaces, there are cases where the resin on the outer surface side of the can lid also melts when the can body and the can lid are fused, and the film is damaged.
  • the metal sheet of the can lid and the can bottom is aluminum, it is difficult to generate heat even if electromagnetic induction heating (IH) is performed, so the heating tool is pressed directly against the can lid and the can bottom fuse the can body, the can lid, and the can bottom in many cases. However, in these cases, the coating of the can lid and the can bottom is easily damaged.
  • IH electromagnetic induction heating
  • the present invention is an invention that has been made in view of the above-described circumstances, and an object thereof is to provide a can lid made of a resin laminate steel sheet for a resin-metal composite container, and a can bottom made of a resin laminate steel sheet for a resin-metal composite container capable of obtaining high seaming strength with a can body when seamed and fused to the can body made of a transparent to translucent thermoplastic resin, and having excellent manufacturability and surface quality.
  • Another object of the present invention to provide a resin-metal composite container having excellent surface quality and high seaming strength, using a can lid made of a resin laminate steel sheet for a resin-metal composite container, and a can bottom made of a resin laminate steel sheet for a resin-metal composite container.
  • a laminate steel sheet including a thermoplastic polyester-based resin layer provided at a first surface of a steel sheet on the outside of a resin-metal composite container to be in contact with the steel sheet, a modified polypropylene-based resin layer provided at a second surface of the steel sheet on the inside of the resin-metal composite container to be in contact with the steel sheet, a polypropylene-based resin layer provided as an upper layer of the modified polypropylene-based resin layer to be in contact with the modified polypropylene-based resin layer, and an ethylene-propylene copolymer resin layer provided as an upper layer of the polypropylene-based resin layer to be in contact with the polypropylene-based resin layer and having a specific ethylene component proportion, and controlling the thickness and melting point of each layer, high sealability for a can body (can body made of a polypropylene-based resin) made of a polypropylene-based resin is provided.
  • the layers are simply called (1) the PE-PP layer, (2) the PP layer, (3) the modified PP layer, (4) the steel sheet, and (5) the PET layer, and the entirety of (1) the PE-PP layer, (2) the PP layer, and (3) the modified PP layer of the resin layer to be thermally fusion-bonded to the can body side is called a PP-based resin layer (PP-based laminated resin layer) 5 .
  • the can lid and the can bottom made of a resin laminate steel sheet for a resin-metal composite container of the present invention can obtain high seaming strength with the can body when seamed and fused to the can body made of a transparent to translucent thermoplastic resin, do not cause fusion of the film to a laminating roll when the resin laminate steel sheet is manufactured, and thus have excellent manufacturability and surface quality.
  • the resin-metal composite container of the present invention uses the can lid and the can bottom made of a resin laminate steel sheet for a resin-metal composite container and thus has excellent surface quality and high seaming strength.
  • FIG. 1 is a perspective view of a can lid made of a resin laminate steel sheet for a resin-metal composite container according to an embodiment of the present invention.
  • FIG. 2 is a cross-sectional view taken along the line A-A′ of the can lid made of a resin laminate steel sheet for a resin-metal composite container according to the embodiment of the present invention.
  • FIG. 5 is a perspective view of a can bottom made of a resin laminate steel sheet for a resin-metal composite container according to the embodiment of the present invention.
  • FIG. 7 is a perspective view of the can bottom made of a resin laminate steel sheet for a resin-metal composite container according to the embodiment of the present invention, which is seamed onto the can body.
  • FIG. 8 is a cross-sectional view taken along the line B-B′ of the can bottom made of a resin laminate steel sheet for a resin-metal composite container according to the embodiment of the present invention, which is seamed onto the can body.
  • FIG. 10 is an example of an enlarged schematic view of the region A of a cross section of the can lid and the can bottom made of a resin laminate steel sheet for a resin-metal composite container according to the embodiment of the present invention.
  • FIG. 11 is a diagram showing the proportion of a PE component in an ethylene-propylene copolymer resin layer of a resin laminate steel sheet and determination results of the sealability of a seamed portion.
  • FIG. 16 is a diagram showing the thickness of a polypropylene-based resin layer of the resin laminate steel sheet and the result of determining resin fusion to a heating roll during film laminating.
  • FIG. 19 is an example of the external appearance of a resin-metal composite container in the related art.
  • a can lid and a can bottom are made of a resin laminate steel sheet, the can lid and the can bottom include, in order from the content side of the can, (1) a PE-PP layer (ethylene-propylene copolymer resin layer) 4 , (2) a PP layer (polypropylene-based resin layer) 3 , (3) a modified PP layer (modified polypropylene-based resin layer) 2 , (4) a steel sheet (steel sheet) 1 , and (5) a PET layer (thermoplastic polyester-based resin layer) 6 , and by setting the ranges of the PE proportion (the proportion of an ethylene component), melting point, and thickness of (1) the PE-PP layer (ethylene-propylene copolymer resin layer) 4 , the thickness of (2) the PP layer (polypropylene-based resin layer) 3 , and the thickness of (3) the modified PP layer (modified polypropylene-based resin layer) 2 , the
  • a can lid and a can bottom made of a resin laminate steel sheet for a resin-metal composite container include: a top sheet portion made of a resin laminate steel sheet; and a curved portion made of the resin laminate steel sheet and located at an outer periphery of the top sheet portion, in which the resin laminate steel sheet uses a laminate steel sheet including a thermoplastic polyester-based resin layer provided at a first surface of a steel sheet which is on the outside of a resin-metal composite container to be in contact with the steel sheet, a modified polypropylene-based resin layer provided at a second surface of the steel sheet which is on the inside of the resin-metal composite container to be in contact with the steel sheet, a polypropylene-based resin layer provided as an upper layer of the modified polypropylene-based resin layer to be in contact with the modified polypropylene-based resin layer, and an ethylene-propylene copolymer resin layer provided as an upper layer of the polypropylene-based resin layer to be in
  • FIG. 1 is a perspective view of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container according to the present embodiment.
  • FIG. 2 is a cross-sectional view taken along the line A-A′ of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container.
  • FIG. 3 is a perspective view of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container after being seamed onto a can body 102 .
  • FIG. 1 is a perspective view of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container according to the present embodiment.
  • FIG. 2 is a cross-sectional view taken along the line A-A′ of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container.
  • FIG. 3 is a perspective view of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container after being seamed onto a can body 102 .
  • FIG. 4 is a cross-sectional view taken along the line B-B′ of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container, which is seamed onto the can body 102 .
  • FIG. 5 is a perspective view of the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container according to the present embodiment.
  • FIG. 6 is a cross-sectional view taken along the line A-A′ of the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container.
  • FIG. 7 is a perspective view of the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container after being seamed onto the can body 102 .
  • FIG. 5 is a perspective view of the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container according to the present embodiment.
  • FIG. 6 is a cross-sectional view taken along the line A-A′ of the can bottom 101 made of a resin laminate steel sheet for
  • FIG. 8 is a cross-sectional view taken along the line B-B′ of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container, which is seamed onto the can body 102 .
  • FIG. 9 is a perspective view of the resin-metal composite container 200 according to the present embodiment.
  • FIG. 10 is an enlarged view of a portion (region A) of the cross-sectional views taken along the line A-A′ of FIGS. 2 and 6 for describing the configuration of a resin laminate steel sheet 20 used in the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container and the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container.
  • the resin-metal composite container (can) 200 includes the can lid 100 and the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container according to the present embodiment, and the can body 102 .
  • the resin-metal composite container 200 includes a first seamed portion 21 formed by seaming the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container and the can body 102 .
  • the first seamed portion 21 includes a first fused portion 23 in which the can body 102 and the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container are fused.
  • thermoplastic polyester-based resin layer 6 is at an outside bend of the curved portion 30 and a second surface provided with the PP-based resin layer 5 is at an inside bend of the curved portion 30 so as to be fused to the can body 102 .
  • the melting point of the ethylene-propylene copolymer resin layer 4 which is the outermost layer of the PP-based resin layer 5 , is lower than 135° C.
  • the ethylene-propylene copolymer resin layer 4 is softened when a retort sterilization treatment (at a temperature of 120° C. to 130° C.), and there are cases where the content leaks from the seamed portion.
  • the melting point of the ethylene-propylene copolymer resin layer 4 exceeds 150° C., it takes time for the ethylene-propylene copolymer resin layer 4 of the seamed portion to melt, so that the adhesion of the seamed portion becomes unstable in a case where the seamed portion is fused within a short period of time, which is not preferable. Furthermore, in a case where the melting point of the ethylene-propylene copolymer resin layer 4 exceeds 150° C., the ethylene-propylene copolymer resin layer 4 may be partially crystallized and whitened during the retort treatment, which is not preferable.
  • the melting point of the ethylene-propylene copolymer resin layer 4 is defined as the temperature of the main endothermic peak when thermal analysis was performed with a differential scanning-type calorimeter (DSC).
  • the main endothermic peak means a peak having the largest endothermic amount.
  • the DSC apparatus used for the melting point measurement is DSC7030 manufactured by Hitachi High-Tech Science Corporation, and measurement was performed by enclosing 5 to 8 mg of the resin in an aluminum pan and raising the temperature in a nitrogen atmosphere at a temperature rising rate of 10° C./min.
  • the adhesion between the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container and the can body 102 is good, and the outer surface side of the can lid 100 made of a resin laminate steel sheet for a resin-metal composite container is not easily damaged and is beautiful, which is preferable.
  • the heating temperature of the resin laminate steel sheet 20 of the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container preferably has the same condition as that of the can lid.
  • the PE proportion (sometimes referred to as the proportion of the ethylene component) of the ethylene-propylene copolymer resin layer 4 will be described below.
  • the proportion of the ethylene component was obtained from the following confirmation experiment of the proportion of the ethylene component.
  • the upper and lower limits of the amount of the ethylene component (the proportion of the ethylene component) of the ethylene-propylene copolymer in the ethylene-propylene copolymer resin layer 4 are determined by two methods including a method of performing determination by a weight reduction ratio of the can after a water-packed can is subjected to a retort treatment (can sealability determination method) and a method of aligning the same resin sheet as the polypropylene-based resin forming the can body and the PP-based resin layer 5 side of the resin laminate steel sheet 20 , performing heating and pressure bonding thereon, and thereafter performing determination with a peeling strength after performing a retort treatment.
  • a retort treatment can sealability determination method
  • a film attached to the can lid inner surface side of a steel sheet for a can lid and a can lid, that is, a PP-based resin film forming the PP-based resin layer was produced as follows.
  • a film was produced by extruding an ethylene-propylene copolymer resin (ethylene-propylene random copolymer) as a first layer (5.0 ⁇ m, ethylene component proportion 0 to 60 mass %), a polypropylene-based resin (homopolypropylene) as a second layer (intermediate layer) (10.0 ⁇ m), and a modified polypropylene-based resin (maleic acid-modified polypropylene) as a third layer (5.0 ⁇ m) at 200° C. with a three layer co-extrusion film forming apparatus.
  • ethylene-propylene copolymer resin ethylene-propylene random copolymer
  • first layer 5.0 ⁇ m, ethylene component proportion 0 to 60 mass %
  • a polypropylene-based resin homopolypropylene
  • second layer intermediate layer
  • a modified polypropylene-based resin maleic acid-modified polypropylene
  • the above-mentioned PP-based resin film (the modified polypropylene-based resin layer side was bonded to the steel sheet) and an existing PET-based resin film were rolled and pressure-bonded to be laminated on 0.2 mm thick tinfree steel heated to 250° C. to produce a laminate steel sheet for a can lid and a can bottom.
  • a method of evaluating the can lid according to the embodiment of the present invention and a method of evaluating the can bottom according to the embodiment of the present invention were carried out in the same manner.
  • the method of evaluating the can lid will be described below as a representative example.
  • the produced resin laminate steel sheet was subjected to forming so that the surface on the can inner surface side of the can lid was the PP-based resin layer side was and the can outer surface side was the thermoplastic polyester-based resin layer side.
  • the can bottom made of the above-mentioned resin laminate steel sheet was seamed onto a cylindrical can body (2.0 mm) made of a polypropylene-based resin so that the can inner surface side was the PP-based resin layer and the can outer surface side was the thermoplastic polyester-based resin layer, and thereafter the seamed portion was heated by an IH heating device (200° C., heating time 1.0 second) so that the PP-based resin layer of the can bottom on the can inner surface side and the polypropylene-based resin of the can body were thermally fusion-bonded together.
  • IH heating device 200° C., heating time 1.0 second
  • the seamed portion of the can lid was heated by the IH heating device, thereby producing a can sample.
  • the can weight of the water-packed test can thus produced was measured with an electronic balance to the number of grams with three decimal places, and the can was subjected to a retort treatment in a retort oven at 125° C. for 30 minutes.
  • the weight of the can subjected to the retort treatment was measured again with the electronic balance to the number of grams with three decimal places. In a case where the weight was reduced by 0.20 mass % or more, it was considered that liquid leakage had occurred and the case was regarded as being unacceptable. In a case where the weight reduction ratio was 0.05 mass % or more and less than 0.20 mass %, the weight loss was not so high that liquid leakage was determined and was determined to be acceptable. In a case where the weight reduction ratio was less than 0.05 mass %, the weight reduction ratio was within a measurement error range, so that the sealability of the can was determined to be good.
  • the fusibility between the polypropylene resin of the can body and the resin laminate steel sheet was determined by the following method, and the resin configuration of the film on the inner surface side of the can lid was determined.
  • the proportion of the ethylene component in the ethylene-propylene copolymer in the ethylene-propylene copolymer resin layer exceeds 45.0 mass %, the surface layer of the film becomes soft, and irregularities are likely to be generated on the surface of the film during film lamination and cause the surface to be rough, which is not preferable.
  • the proportion of the ethylene component in the ethylene-propylene copolymer can be obtained, for example, by infrared micro-spectrometry.
  • the ratio (peak intensity ratio) between a peak intensity at 974 cm ⁇ 1 and a peak intensity at 721 cm ⁇ 1 attributed to propylene is obtained from an IR spectrum obtained by measuring the ethylene-propylene copolymer in which the proportion of the ethylene component is changed, with an infrared micro-spectrometer.
  • a calibration curve is created from the proportion of the ethylene component and the peak intensity ratio.
  • the proportion of the ethylene component can be obtained from the peak intensity ratio of the ethylene-propylene copolymer of the ethylene-propylene copolymer resin layer 4 and the calibration curve.
  • the peeling strength which is an index of the fusibility between the can body made of a polypropylene resin and the seamed portion of the can lid, is good when the proportion of the ethylene component in the ethylene-propylene copolymer in the ethylene-propylene copolymer resin layer is in a range of 1.0 mass % or more and 55.0 mass % or less.
  • FIG. 13 is a diagram in which the horizontal axis represents the melting point of the ethylene-propylene copolymer resin layer (the melting point of the PE-PP layer) of the resin laminate steel sheet and the vertical axis represents the determination result of the peeling strength.
  • FIG. 16 is a diagram showing the relationship between the determination result of the fusibility of the film to a heating roll when the PP-based resin film is laminated by a film laminating apparatus ( FIG. 18 ) described later (the determination result of the fusibility of the film to the heating roll during lamination) and the average thickness of the polypropylene-based resin layer 3 (the thickness of the PP layer). As can be seen from FIG.
  • the can lid made of a resin laminate steel sheet for a resin-metal composite container or the can bottom 101 made of a resin laminate steel sheet for a resin-metal composite container and the can body 102 are seamed and fused together, even if the heating tool for sealing comes into contact with the resin layer on the outer surface side, the case where the film is damaged can be reduced.
  • a method of seaming and fusing the can body 102 made of the PP resin and the can lid and the can bottom in addition to a method of pressing the heating tool against the can lid and the can bottom, a method of locally heating and melting the resin of the seamed portion by performing electromagnetic induction heating on the steel sheet of the can lid and the can bottom made of a resin laminate steel sheet by IH heating is preferable because the film is less likely to be damaged due to the heating tool coming into contact with the film.
  • the resin of the thermoplastic polyester-based resin layer 6 may be a stretched film or an unstretched film, and is not particularly limited. However, a stretched film is superior in corrosion resistance and strength to an unstretched film, is less expensive than an unstretched film, and is thus more preferable.
  • the resin of the thermoplastic polyester-based resin layer 6 specifically, there are polyethylene terephthalate, a copolymer of ethylene terephthalate and ethylene isophthalate (IA-PET), a copolymer of polyethylene terephthalate and polybutylene terephthalate (PET-PBT), a copolymer of polyethylene terephthalate and cyclohexanedimethanol (PETG), and mixtures thereof.
  • IA-PET ethylene terephthalate
  • PET-PBT polybutylene terephthalate
  • PETG cyclohexanedimethanol
  • the average thickness of the thermoplastic polyester-based resin layer 6 of the resin laminate steel sheet 20 is not particularly limited, but may be about 30.0 ⁇ m or less because the thermoplastic polyester-based resin layer 6 is on the outer surface side of the can lid and the can bottom and does not particularly require corrosion resistance.
  • the lower limit of the thickness of the thermoplastic polyester-based resin layer 6 is not particularly limited, but is preferably 10.0 ⁇ m or more because if the thickness is too small, film wrinkles are likely to occur in the laminate when the laminated steel sheet is manufactured.
  • a coloring pigment or dye such as titanium white or carbon black may be mixed and dispersed in the thermoplastic polyester-based resin.

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  • Engineering & Computer Science (AREA)
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  • Laminated Bodies (AREA)
  • Wrappers (AREA)
  • Rigid Containers With Two Or More Constituent Elements (AREA)
US17/290,453 2019-02-07 2020-02-06 Can lid made of resin laminate steel sheet for resin-metal composite container, can bottom made of resin laminate steel sheet for resin-metal composite container, and resin-metal composite container Active 2041-12-16 US12030702B2 (en)

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JP6753557B1 (ja) 2020-09-09
EP3922455C0 (en) 2024-06-19
EP3922455A4 (en) 2022-11-23
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CN113195228B (zh) 2022-12-20
EP3922455B1 (en) 2024-06-19

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