UA80800C2 - Catalyst for oxychlorination of ethylene to 1,2-dichloroethane, process of its producing and process for producing 1,2-dichloroethane - Google Patents
Catalyst for oxychlorination of ethylene to 1,2-dichloroethane, process of its producing and process for producing 1,2-dichloroethane Download PDFInfo
- Publication number
- UA80800C2 UA80800C2 UA2002108391A UA2002108391A UA80800C2 UA 80800 C2 UA80800 C2 UA 80800C2 UA 2002108391 A UA2002108391 A UA 2002108391A UA 2002108391 A UA2002108391 A UA 2002108391A UA 80800 C2 UA80800 C2 UA 80800C2
- Authority
- UA
- Ukraine
- Prior art keywords
- catalyst
- copper
- ratio
- magnesium
- dichloroethane
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 89
- 238000000034 method Methods 0.000 title claims abstract description 40
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000005977 Ethylene Substances 0.000 title claims abstract description 19
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 230000008569 process Effects 0.000 title abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 26
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000010949 copper Substances 0.000 claims abstract description 22
- 229910052802 copper Inorganic materials 0.000 claims abstract description 21
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 17
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011777 magnesium Substances 0.000 claims abstract description 13
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 5
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 239000005749 Copper compound Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 150000001880 copper compounds Chemical class 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 150000002681 magnesium compounds Chemical class 0.000 claims description 2
- 159000000003 magnesium salts Chemical class 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000012495 reaction gas Substances 0.000 claims 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 19
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 13
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 13
- 238000012360 testing method Methods 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- 238000005470 impregnation Methods 0.000 description 8
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000005054 agglomeration Methods 0.000 description 6
- 230000002776 aggregation Effects 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 235000011147 magnesium chloride Nutrition 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 150000001879 copper Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005243 fluidization Methods 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000003313 weakening effect Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 229910052761 rare earth metal Chemical class 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical class [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical class [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000004838 photoelectron emission spectroscopy Methods 0.000 description 1
- -1 physical Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Chemical class 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/122—Halides of copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2001MI002241A ITMI20012241A1 (it) | 2001-10-25 | 2001-10-25 | Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA80800C2 true UA80800C2 (en) | 2007-11-12 |
Family
ID=11448546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA2002108391A UA80800C2 (en) | 2001-10-25 | 2002-10-22 | Catalyst for oxychlorination of ethylene to 1,2-dichloroethane, process of its producing and process for producing 1,2-dichloroethane |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US6759365B2 (ko) |
| EP (1) | EP1306130B9 (ko) |
| JP (1) | JP3982577B2 (ko) |
| KR (1) | KR100908419B1 (ko) |
| CN (1) | CN100384796C (ko) |
| AR (1) | AR036953A1 (ko) |
| BR (1) | BR0204329A (ko) |
| CA (1) | CA2409080A1 (ko) |
| DE (1) | DE60208295T2 (ko) |
| DK (1) | DK1306130T3 (ko) |
| DZ (1) | DZ3330A1 (ko) |
| EG (1) | EG23186A (ko) |
| ES (1) | ES2252377T3 (ko) |
| IL (1) | IL152407A (ko) |
| IT (1) | ITMI20012241A1 (ko) |
| MX (1) | MX231271B (ko) |
| RU (1) | RU2281806C2 (ko) |
| SA (1) | SA02230440B1 (ko) |
| TW (1) | TW576754B (ko) |
| UA (1) | UA80800C2 (ko) |
| ZA (1) | ZA200208497B (ko) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20030630A1 (it) * | 2003-03-31 | 2004-10-01 | Sued Chemie Mt Srl | Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano. |
| US20050096211A1 (en) * | 2003-10-31 | 2005-05-05 | Hiroshi Takeda | Catalyst for the conversion of carbon monoxide |
| TWI341218B (en) | 2005-11-14 | 2011-05-01 | Oxy Vinyls Lp | Catalyst compositions and process for oxychlorination |
| US8080224B2 (en) * | 2006-05-05 | 2011-12-20 | Sud-Chemie Inc. | Catalyst for the conversion of carbon monoxide |
| CN101519602B (zh) * | 2008-02-28 | 2013-04-24 | 中国石油化工股份有限公司 | 一种烃类原料中不饱和烃的捕集材料 |
| EP2208528A1 (en) * | 2008-12-23 | 2010-07-21 | Süd Chemie - Catalysts Italia S.R.L. | Catalysts for fixed bed oxychlorination of ethylene to 1.2-dichloroethane |
| JP2014117673A (ja) * | 2012-12-18 | 2014-06-30 | Tosoh Corp | オキシ塩素化触媒およびそれを用いた１，２−ジクロロエタンの製造方法 |
| CN111330517B (zh) * | 2020-03-18 | 2022-04-29 | 山东凯泰科技股份有限公司 | 一种催化剂添加及过滤的自动控制系统 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE670176A (ko) * | 1964-10-02 | |||
| JPS5948169A (ja) * | 1982-09-13 | 1984-03-19 | Fuji Xerox Co Ltd | サ−マルヘツド駆動制御装置 |
| IT1163160B (it) * | 1983-03-22 | 1987-04-08 | Montepolimeri Spa | Catalizzatori supportati per la sintesi di 1-2 dicloroetano per ossiclorurazione di etilene in letto fluidizzato |
| IT1176719B (it) * | 1984-09-19 | 1987-08-18 | Ausind | Metodo per la preparazione di un catalizzatore per la sintesi di 1,2-dicloroetano |
| FR2600643B1 (fr) * | 1986-06-27 | 1988-09-23 | Solvay | Procede d'oxychloration de l'ethylene et compositions catalytiques pour l'oxychloration |
| GB8829706D0 (en) * | 1988-12-20 | 1989-02-15 | Ici Plc | Oxychlorination catalyst composition |
| US5192733A (en) * | 1989-12-15 | 1993-03-09 | Vulcan Materials Company | Oxychlorination catalysts comprising copper chloride supported on rare-earth-modified alumina, process for making such catalysts, and oxychlorination processes using them |
| JP2527750Y2 (ja) * | 1990-11-09 | 1997-03-05 | 株式会社豊田自動織機製作所 | 車両用メカニカルウインチのための安全装置 |
| EP0494474B1 (fr) * | 1991-01-11 | 1994-09-21 | SOLVAY (Société Anonyme) | Composition catalytique pour l'oxychloration et procédé d'oxychloration de l'éthylène utilisant une telle composition |
| BE1007818A3 (fr) * | 1993-12-08 | 1995-10-31 | Solvay | Composition catalytique et procede d'oxychloration de l'ethylene utilisant une telle composition. |
-
2001
- 2001-10-25 IT IT2001MI002241A patent/ITMI20012241A1/it unknown
-
2002
- 2002-09-24 TW TW091121841A patent/TW576754B/zh not_active IP Right Cessation
- 2002-10-09 KR KR1020020061410A patent/KR100908419B1/ko not_active IP Right Cessation
- 2002-10-18 ES ES02023624T patent/ES2252377T3/es not_active Expired - Lifetime
- 2002-10-18 DK DK02023624T patent/DK1306130T3/da active
- 2002-10-18 DE DE60208295T patent/DE60208295T2/de not_active Revoked
- 2002-10-18 EP EP02023624A patent/EP1306130B9/en not_active Revoked
- 2002-10-21 ZA ZA200208497A patent/ZA200208497B/xx unknown
- 2002-10-21 DZ DZ020263A patent/DZ3330A1/fr active
- 2002-10-22 US US10/277,466 patent/US6759365B2/en not_active Expired - Lifetime
- 2002-10-22 UA UA2002108391A patent/UA80800C2/uk unknown
- 2002-10-22 BR BR0204329-7A patent/BR0204329A/pt active Search and Examination
- 2002-10-22 EG EG2002101155A patent/EG23186A/xx active
- 2002-10-22 CA CA002409080A patent/CA2409080A1/en not_active Abandoned
- 2002-10-22 IL IL15240702A patent/IL152407A/en not_active IP Right Cessation
- 2002-10-23 JP JP2002308586A patent/JP3982577B2/ja not_active Expired - Fee Related
- 2002-10-24 RU RU2002128662/04A patent/RU2281806C2/ru active
- 2002-10-24 MX MXPA02010521 patent/MX231271B/es active IP Right Grant
- 2002-10-24 AR ARP020104023A patent/AR036953A1/es active IP Right Grant
- 2002-10-25 CN CNB021470448A patent/CN100384796C/zh not_active Expired - Fee Related
- 2002-11-18 SA SA02230440A patent/SA02230440B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1306130A1 (en) | 2003-05-02 |
| EP1306130B8 (en) | 2006-03-22 |
| EP1306130B9 (en) | 2006-06-28 |
| IL152407A (en) | 2006-03-12 |
| JP2003181291A (ja) | 2003-07-02 |
| DE60208295D1 (de) | 2006-02-02 |
| KR20030035886A (ko) | 2003-05-09 |
| DK1306130T3 (da) | 2006-04-24 |
| SA02230440B1 (ar) | 2007-04-03 |
| US20030096700A1 (en) | 2003-05-22 |
| IL152407A0 (en) | 2003-05-29 |
| CN1413970A (zh) | 2003-04-30 |
| DE60208295T2 (de) | 2006-08-17 |
| BR0204329A (pt) | 2003-09-16 |
| EP1306130B1 (en) | 2005-12-28 |
| TW576754B (en) | 2004-02-21 |
| MX231271B (es) | 2005-10-11 |
| ZA200208497B (en) | 2003-05-15 |
| US6759365B2 (en) | 2004-07-06 |
| EG23186A (en) | 2004-07-31 |
| MXPA02010521A (es) | 2004-07-30 |
| ITMI20012241A1 (it) | 2003-04-25 |
| AR036953A1 (es) | 2004-10-13 |
| KR100908419B1 (ko) | 2009-07-21 |
| RU2281806C2 (ru) | 2006-08-20 |
| DZ3330A1 (fr) | 2005-05-29 |
| CN100384796C (zh) | 2008-04-30 |
| JP3982577B2 (ja) | 2007-09-26 |
| ES2252377T3 (es) | 2006-05-16 |
| CA2409080A1 (en) | 2003-04-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5053493B2 (ja) | エチレンを塩化ビニルに転化する方法および該方法のために有用な新規触媒組成物 | |
| US5366949A (en) | CeBr3 catalyst | |
| JP3566320B2 (ja) | 触媒組成物 | |
| JP2645467B2 (ja) | オキシ塩素化用触媒 | |
| JPH07194981A (ja) | 触媒組成物及び該組成物を使用するエチレンのオキシ塩素化方法 | |
| KR19990045511A (ko) | 지지된 촉매, 이의 제조방법 및 에틸렌의 옥시염소화에 있어서의 이의 용도 | |
| JP4084044B2 (ja) | 酢酸ビニルを製造するための統合された方法 | |
| UA80800C2 (en) | Catalyst for oxychlorination of ethylene to 1,2-dichloroethane, process of its producing and process for producing 1,2-dichloroethane | |
| AU7868800A (en) | Process for vinyl chloride manufacture from ethane and ethylene with secondary reactive consumption of reactor effluent hcl | |
| CN101041135A (zh) | 催化氧化乙烷和/或乙烯选择性制备乙酸的方法 | |
| US7687429B2 (en) | Catalysts for oxychlorination of ethylene to 1,2-dichlorethane | |
| EP1020222B1 (en) | Oxychlorination catalytic composition for controlling exothermic reactions in a fixed bed | |
| WO1993006039A1 (en) | Process for producing bromine from bromide salts | |
| JP2015522409A (ja) | 炭化水素流から酸素を除去するための触媒およびその方法 | |
| JPS5951933B2 (ja) | エチレンおよび塩素の除去方法 | |
| JP4548556B2 (ja) | エピクロロヒドリンの製造方法 | |
| JP4385487B2 (ja) | ジクロロプロパノールの製造方法 | |
| WO2018080333A1 (en) | Process for production of acrylic acid, process for the selective oxidation of carbon monoxide, catalyst for the selective oxidation of carbon monoxide, process for producing the same | |
| JPH11343265A (ja) | ジクロロアセトキシプロパン及びその誘導体の製造方法 | |
| US2914575A (en) | Method for preparing perchloroethylene | |
| RU2093506C1 (ru) | Способ получения винилацетата | |
| WO1993006037A1 (en) | Process and catalyst for producing bromine | |
| JP4157241B2 (ja) | ジクロロアセトキシプロパン及びその誘導体の製造方法 | |
| WO2023141191A2 (en) | Catalysts for oxychlorination of ethylene to 1,2-dichloroethane and methods of preparation thereof | |
| JPS61130240A (ja) | 末端に二重結合を有する化合物の製法 |