UA80800C2 - Catalyst for oxychlorination of ethylene to 1,2-dichloroethane, process of its producing and process for producing 1,2-dichloroethane - Google Patents
Catalyst for oxychlorination of ethylene to 1,2-dichloroethane, process of its producing and process for producing 1,2-dichloroethane Download PDFInfo
- Publication number
- UA80800C2 UA80800C2 UA2002108391A UA2002108391A UA80800C2 UA 80800 C2 UA80800 C2 UA 80800C2 UA 2002108391 A UA2002108391 A UA 2002108391A UA 2002108391 A UA2002108391 A UA 2002108391A UA 80800 C2 UA80800 C2 UA 80800C2
- Authority
- UA
- Ukraine
- Prior art keywords
- catalyst
- copper
- ratio
- magnesium
- dichloroethane
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 89
- 238000000034 method Methods 0.000 title claims abstract description 40
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 239000005977 Ethylene Substances 0.000 title claims abstract description 19
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 230000008569 process Effects 0.000 title abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 26
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000010949 copper Substances 0.000 claims abstract description 22
- 229910052802 copper Inorganic materials 0.000 claims abstract description 21
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 17
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000011777 magnesium Substances 0.000 claims abstract description 13
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 19
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 12
- 239000001301 oxygen Substances 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 12
- 239000000243 solution Substances 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 10
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- 229910021591 Copper(I) chloride Inorganic materials 0.000 claims description 5
- OXBLHERUFWYNTN-UHFFFAOYSA-M copper(I) chloride Chemical compound [Cu]Cl OXBLHERUFWYNTN-UHFFFAOYSA-M 0.000 claims description 5
- 239000011148 porous material Substances 0.000 claims description 5
- 239000005749 Copper compound Substances 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 150000001880 copper compounds Chemical class 0.000 claims description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- 239000007800 oxidant agent Substances 0.000 claims description 4
- 150000007513 acids Chemical class 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 150000002681 magnesium compounds Chemical class 0.000 claims description 2
- 159000000003 magnesium salts Chemical class 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 239000012495 reaction gas Substances 0.000 claims 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 19
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 13
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 13
- 238000012360 testing method Methods 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 9
- 238000005470 impregnation Methods 0.000 description 8
- UBOXGVDOUJQMTN-UHFFFAOYSA-N 1,1,2-trichloroethane Chemical compound ClCC(Cl)Cl UBOXGVDOUJQMTN-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 238000005054 agglomeration Methods 0.000 description 6
- 230000002776 aggregation Effects 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 6
- 238000002485 combustion reaction Methods 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 235000011147 magnesium chloride Nutrition 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 150000001879 copper Chemical class 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000005243 fluidization Methods 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000003313 weakening effect Effects 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical class [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- 229910021592 Copper(II) chloride Inorganic materials 0.000 description 2
- 239000003929 acidic solution Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000000428 dust Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000008092 positive effect Effects 0.000 description 2
- 229910052761 rare earth metal Chemical class 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000002829 reductive effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical class [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical class [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000004838 photoelectron emission spectroscopy Methods 0.000 description 1
- -1 physical Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Chemical class 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/08—Halides
- B01J27/122—Halides of copper
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/15—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination
- C07C17/152—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons
- C07C17/156—Preparation of halogenated hydrocarbons by replacement by halogens with oxygen as auxiliary reagent, e.g. oxychlorination of hydrocarbons of unsaturated hydrocarbons
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT2001MI002241A ITMI20012241A1 (it) | 2001-10-25 | 2001-10-25 | Catalizzatori per l'ossiclorurazione dell'etilene a 1,2-dicloroetano |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| UA80800C2 true UA80800C2 (en) | 2007-11-12 |
Family
ID=11448546
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| UA2002108391A UA80800C2 (en) | 2001-10-25 | 2002-10-22 | Catalyst for oxychlorination of ethylene to 1,2-dichloroethane, process of its producing and process for producing 1,2-dichloroethane |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US6759365B2 (fr) |
| EP (1) | EP1306130B9 (fr) |
| JP (1) | JP3982577B2 (fr) |
| KR (1) | KR100908419B1 (fr) |
| CN (1) | CN100384796C (fr) |
| AR (1) | AR036953A1 (fr) |
| BR (1) | BR0204329A (fr) |
| CA (1) | CA2409080A1 (fr) |
| DE (1) | DE60208295T2 (fr) |
| DK (1) | DK1306130T3 (fr) |
| DZ (1) | DZ3330A1 (fr) |
| EG (1) | EG23186A (fr) |
| ES (1) | ES2252377T3 (fr) |
| IL (1) | IL152407A (fr) |
| IT (1) | ITMI20012241A1 (fr) |
| MX (1) | MX231271B (fr) |
| RU (1) | RU2281806C2 (fr) |
| SA (1) | SA02230440B1 (fr) |
| TW (1) | TW576754B (fr) |
| UA (1) | UA80800C2 (fr) |
| ZA (1) | ZA200208497B (fr) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ITMI20030630A1 (it) | 2003-03-31 | 2004-10-01 | Sued Chemie Mt Srl | Catalizzatori per ossiclorurazione dell'etilene a 1,2-dicloroetano. |
| US20050096211A1 (en) * | 2003-10-31 | 2005-05-05 | Hiroshi Takeda | Catalyst for the conversion of carbon monoxide |
| TWI341218B (en) * | 2005-11-14 | 2011-05-01 | Oxy Vinyls Lp | Catalyst compositions and process for oxychlorination |
| US8080224B2 (en) * | 2006-05-05 | 2011-12-20 | Sud-Chemie Inc. | Catalyst for the conversion of carbon monoxide |
| CN101519602B (zh) * | 2008-02-28 | 2013-04-24 | 中国石油化工股份有限公司 | 一种烃类原料中不饱和烃的捕集材料 |
| EP2208528A1 (fr) * | 2008-12-23 | 2010-07-21 | Süd Chemie - Catalysts Italia S.R.L. | Catalyseurs pour l'oxychloration de l'éthylène en 1,2-dichloroéthane sur lit fixé |
| JP2014117673A (ja) * | 2012-12-18 | 2014-06-30 | Tosoh Corp | オキシ塩素化触媒およびそれを用いた１，２−ジクロロエタンの製造方法 |
| CN111330517B (zh) * | 2020-03-18 | 2022-04-29 | 山东凯泰科技股份有限公司 | 一种催化剂添加及过滤的自动控制系统 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1447823A (fr) * | 1964-10-02 | 1966-11-07 | ||
| JPS5948169A (ja) * | 1982-09-13 | 1984-03-19 | Fuji Xerox Co Ltd | サ−マルヘツド駆動制御装置 |
| IT1163160B (it) * | 1983-03-22 | 1987-04-08 | Montepolimeri Spa | Catalizzatori supportati per la sintesi di 1-2 dicloroetano per ossiclorurazione di etilene in letto fluidizzato |
| IT1176719B (it) * | 1984-09-19 | 1987-08-18 | Ausind | Metodo per la preparazione di un catalizzatore per la sintesi di 1,2-dicloroetano |
| FR2600643B1 (fr) * | 1986-06-27 | 1988-09-23 | Solvay | Procede d'oxychloration de l'ethylene et compositions catalytiques pour l'oxychloration |
| GB8829706D0 (en) * | 1988-12-20 | 1989-02-15 | Ici Plc | Oxychlorination catalyst composition |
| US5192733A (en) * | 1989-12-15 | 1993-03-09 | Vulcan Materials Company | Oxychlorination catalysts comprising copper chloride supported on rare-earth-modified alumina, process for making such catalysts, and oxychlorination processes using them |
| JP2527750Y2 (ja) * | 1990-11-09 | 1997-03-05 | 株式会社豊田自動織機製作所 | 車両用メカニカルウインチのための安全装置 |
| ES2064893T3 (es) * | 1991-01-11 | 1995-02-01 | Solvay | Composicion catalitica para la oxicloracion y procedimiento de oxicloracion de etileno empleando dicha composicion. |
| BE1007818A3 (fr) * | 1993-12-08 | 1995-10-31 | Solvay | Composition catalytique et procede d'oxychloration de l'ethylene utilisant une telle composition. |
-
2001
- 2001-10-25 IT IT2001MI002241A patent/ITMI20012241A1/it unknown
-
2002
- 2002-09-24 TW TW091121841A patent/TW576754B/zh not_active IP Right Cessation
- 2002-10-09 KR KR1020020061410A patent/KR100908419B1/ko not_active IP Right Cessation
- 2002-10-18 DE DE60208295T patent/DE60208295T2/de not_active Revoked
- 2002-10-18 EP EP02023624A patent/EP1306130B9/fr not_active Revoked
- 2002-10-18 ES ES02023624T patent/ES2252377T3/es not_active Expired - Lifetime
- 2002-10-18 DK DK02023624T patent/DK1306130T3/da active
- 2002-10-21 DZ DZ020263A patent/DZ3330A1/fr active
- 2002-10-21 ZA ZA200208497A patent/ZA200208497B/xx unknown
- 2002-10-22 US US10/277,466 patent/US6759365B2/en not_active Expired - Lifetime
- 2002-10-22 UA UA2002108391A patent/UA80800C2/uk unknown
- 2002-10-22 EG EG2002101155A patent/EG23186A/xx active
- 2002-10-22 CA CA002409080A patent/CA2409080A1/fr not_active Abandoned
- 2002-10-22 IL IL15240702A patent/IL152407A/en not_active IP Right Cessation
- 2002-10-22 BR BR0204329-7A patent/BR0204329A/pt active Search and Examination
- 2002-10-23 JP JP2002308586A patent/JP3982577B2/ja not_active Expired - Fee Related
- 2002-10-24 RU RU2002128662/04A patent/RU2281806C2/ru active
- 2002-10-24 AR ARP020104023A patent/AR036953A1/es active IP Right Grant
- 2002-10-24 MX MXPA02010521 patent/MX231271B/es active IP Right Grant
- 2002-10-25 CN CNB021470448A patent/CN100384796C/zh not_active Expired - Fee Related
- 2002-11-18 SA SA02230440A patent/SA02230440B1/ar unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DK1306130T3 (da) | 2006-04-24 |
| AR036953A1 (es) | 2004-10-13 |
| DZ3330A1 (fr) | 2005-05-29 |
| DE60208295D1 (de) | 2006-02-02 |
| EG23186A (en) | 2004-07-31 |
| EP1306130B9 (fr) | 2006-06-28 |
| JP3982577B2 (ja) | 2007-09-26 |
| KR100908419B1 (ko) | 2009-07-21 |
| ZA200208497B (en) | 2003-05-15 |
| EP1306130A1 (fr) | 2003-05-02 |
| ES2252377T3 (es) | 2006-05-16 |
| TW576754B (en) | 2004-02-21 |
| US6759365B2 (en) | 2004-07-06 |
| SA02230440B1 (ar) | 2007-04-03 |
| BR0204329A (pt) | 2003-09-16 |
| US20030096700A1 (en) | 2003-05-22 |
| KR20030035886A (ko) | 2003-05-09 |
| EP1306130B1 (fr) | 2005-12-28 |
| ITMI20012241A1 (it) | 2003-04-25 |
| CN100384796C (zh) | 2008-04-30 |
| MXPA02010521A (es) | 2004-07-30 |
| EP1306130B8 (fr) | 2006-03-22 |
| CN1413970A (zh) | 2003-04-30 |
| IL152407A (en) | 2006-03-12 |
| RU2281806C2 (ru) | 2006-08-20 |
| DE60208295T2 (de) | 2006-08-17 |
| MX231271B (es) | 2005-10-11 |
| JP2003181291A (ja) | 2003-07-02 |
| CA2409080A1 (fr) | 2003-04-25 |
| IL152407A0 (en) | 2003-05-29 |
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