UA63966C2 - A partial oxidation of light carbohydrates with oxygen by means of electric discharge - Google Patents

A partial oxidation of light carbohydrates with oxygen by means of electric discharge Download PDF

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Publication number
UA63966C2
UA63966C2 UA2000021175A UA2000021175A UA63966C2 UA 63966 C2 UA63966 C2 UA 63966C2 UA 2000021175 A UA2000021175 A UA 2000021175A UA 2000021175 A UA2000021175 A UA 2000021175A UA 63966 C2 UA63966 C2 UA 63966C2
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UA
Ukraine
Prior art keywords
plasma
conversion
oxygen
hydrocarbons
reactor
Prior art date
Application number
UA2000021175A
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English (en)
Ukrainian (uk)
Original Assignee
Lacsarco Holding Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lacsarco Holding Ltd filed Critical Lacsarco Holding Ltd
Priority claimed from PCT/US1998/018027 external-priority patent/WO1999011572A1/en
Publication of UA63966C2 publication Critical patent/UA63966C2/uk

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/36Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using oxygen or mixtures containing oxygen as gasifying agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J19/087Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy
    • B01J19/088Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor employing electric or magnetic energy giving rise to electric discharges
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/342Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents with the aid of electrical means, electromagnetic or mechanical vibrations, or particle radiations
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/80Processes with the aid of electrical means
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/48Generating plasma using an arc
    • H05H1/482Arrangements to provide gliding arc discharges
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/08Processes employing the direct application of electric or wave energy, or particle radiation; Apparatus therefor
    • B01J2219/0894Processes carried out in the presence of a plasma
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0211Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
    • C01B2203/0216Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0211Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step
    • C01B2203/0222Processes for making hydrogen or synthesis gas containing a reforming step containing a non-catalytic reforming step containing a non-catalytic carbon dioxide reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/025Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0255Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a non-catalytic partial oxidation step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06Integration with other chemical processes
    • C01B2203/062Hydrocarbon production, e.g. Fischer-Tropsch process
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0861Methods of heating the process for making hydrogen or synthesis gas by plasma
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1241Natural gas or methane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205Composition of the feed
    • C01B2203/1211Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235Hydrocarbons
    • C01B2203/1247Higher hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1614Controlling the temperature
    • C01B2203/1619Measuring the temperature
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1628Controlling the pressure
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1628Controlling the pressure
    • C01B2203/1633Measuring the pressure
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/1628Controlling the pressure
    • C01B2203/1638Adjusting the pressure
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/16Controlling the process
    • C01B2203/169Controlling the feed

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Toxicology (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Electromagnetism (AREA)
  • Mechanical Engineering (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Oxygen, Ozone, And Oxides In General (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
UA2000021175A 1997-09-01 1998-08-28 A partial oxidation of light carbohydrates with oxygen by means of electric discharge UA63966C2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9710989A FR2768424B1 (fr) 1997-09-01 1997-09-01 Assistance electrique d'oxydation partielle d'hydrocarbures legers par l'oxygene
PCT/US1998/018027 WO1999011572A1 (en) 1997-09-01 1998-08-28 Electrically assisted partial oxidation of light hydrocarbons by oxygen

Publications (1)

Publication Number Publication Date
UA63966C2 true UA63966C2 (en) 2004-02-16

Family

ID=9510745

Family Applications (1)

Application Number Title Priority Date Filing Date
UA2000021175A UA63966C2 (en) 1997-09-01 1998-08-28 A partial oxidation of light carbohydrates with oxygen by means of electric discharge

Country Status (16)

Country Link
EP (1) EP1012113B1 (pt)
JP (1) JP2001514150A (pt)
KR (1) KR100428402B1 (pt)
CN (1) CN1271329A (pt)
AP (1) AP2000001749A0 (pt)
AU (1) AU740520B2 (pt)
BR (1) BR9812137A (pt)
CA (1) CA2300962C (pt)
DE (1) DE69829481D1 (pt)
EA (1) EA002038B1 (pt)
FR (1) FR2768424B1 (pt)
GE (1) GEP20032949B (pt)
ID (1) ID26947A (pt)
NZ (1) NZ502700A (pt)
OA (1) OA11460A (pt)
UA (1) UA63966C2 (pt)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2872149B1 (fr) * 2004-06-28 2007-10-19 Physiques Sarl Et Chimiques Conversion plasma-catalytique de matieres carbonees
KR100581476B1 (ko) * 2004-08-23 2006-05-23 엄환섭 전자파 플라즈마 토치를 이용한 메탄의 이산화탄소 개질방법
DE102004063743A1 (de) * 2004-12-29 2006-07-13 Volkswagen Ag Verfahren zur Emissionsverminderung von Fahrzeugen und Vorrichtung zur Durchführung des Verfahrens
EP2016378B1 (en) 2006-05-08 2017-11-01 Ceramatec, Inc. Plasma-catalyzed, thermally-integrated, reformer for fuel cell systems
US8618436B2 (en) * 2006-07-14 2013-12-31 Ceramatec, Inc. Apparatus and method of oxidation utilizing a gliding electric arc
US8350190B2 (en) * 2007-02-23 2013-01-08 Ceramatec, Inc. Ceramic electrode for gliding electric arc
WO2010017513A2 (en) 2008-08-08 2010-02-11 Ceramatec, Inc. Plasma-catalyzed fuel reformer
JP5496503B2 (ja) * 2008-12-25 2014-05-21 石油資源開発株式会社 水素生成装置を備える燃料電池システム
JP5681357B2 (ja) * 2009-11-24 2015-03-04 愛知電機株式会社 マイクロ波非平衡プラズマを用いた有機物質の処理方法
KR101255152B1 (ko) * 2010-12-01 2013-04-22 한국기초과학지원연구원 플라즈마 가스화기를 이용한 발전 시스템
DE102011002617A1 (de) * 2011-01-13 2012-07-19 Siemens Aktiengesellschaft Verfahren zur Herstellung von Synthesegas enthaltend Kohlenmonoxid (CO) und Wasserstoff (H2)
CN104114264A (zh) * 2012-01-20 2014-10-22 纽卡斯尔大学 用于气体向液体转化的一体化强化生物精炼
CA2776369C (en) * 2012-05-09 2014-01-21 Steve Kresnyak Enhancement of fischer-tropsch process for hydrocarbon fuel formulation in a gtl environment
US9017437B2 (en) 2012-12-11 2015-04-28 Ceramatec, Inc. Method for forming synthesis gas using a plasma-catalyzed fuel reformer
KR101501261B1 (ko) * 2013-07-05 2015-03-12 한국기계연구원 액화석유가스 개질기
CN103539067A (zh) * 2013-07-26 2014-01-29 路运龙 一种组合电弧放电等离子体解水制氢方法及其制氢系统
KR101471070B1 (ko) * 2013-09-16 2014-12-09 한국기계연구원 플라즈마 반응을 이용한 순환형 가스연료 개질기
CN104528643A (zh) * 2014-12-23 2015-04-22 中山大学 一种等离子体流化床重整垃圾填埋气制合成气方法
CN104528642A (zh) * 2014-12-23 2015-04-22 中山大学 一种等离子体流化床重整沼气制合成气方法
FR3085370B1 (fr) * 2018-08-28 2020-09-04 Europlasma Procede de production d'un gaz de synthese par traitement d'un flux gazeux contenant du co2 et un ou plusieurs hydrocarbures
KR102075657B1 (ko) * 2018-10-25 2020-02-10 서강대학교 산학협력단 유전체 장벽 방전 플라즈마 반응기에서 비활성화된 메탄 이량화 반응 베드의 재생방법
EP3705452A1 (en) * 2019-03-05 2020-09-09 Casale Sa A method for the suppression of soot formation in an atr or pox reactor
CN110252419A (zh) * 2019-07-11 2019-09-20 广东石油化工学院 一种降低催化重整催化剂积碳失活速率的方法及其应用
CN111530509A (zh) * 2020-05-25 2020-08-14 大唐国际化工技术研究院有限公司 一种甲烷化催化剂的保护方法
CN114111028A (zh) * 2021-11-12 2022-03-01 长春大学 热水器

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1059065A (en) * 1975-12-12 1979-07-24 Terence E. Dancy Arc reforming of hydrocarbons
NL9300833A (nl) * 1993-05-13 1994-12-01 Gastec Nv Werkwijze voor de produktie van waterstof/koolmonoxide mengsels of waterstof uit methaan.
FR2724806A1 (fr) * 1994-09-16 1996-03-22 Pompes Maupu Entreprise Procede et dispositif d'assistance par plasma au vapo-craquage non-catalytique de composes hydrocarbones et halogeno-organiques

Also Published As

Publication number Publication date
AU740520B2 (en) 2001-11-08
EA200000189A1 (ru) 2000-10-30
JP2001514150A (ja) 2001-09-11
KR20010023517A (ko) 2001-03-26
CA2300962C (en) 2007-09-04
FR2768424A1 (fr) 1999-03-19
ID26947A (id) 2001-02-22
EA002038B1 (ru) 2001-12-24
KR100428402B1 (ko) 2004-04-27
NZ502700A (en) 2002-11-26
CA2300962A1 (en) 1999-03-11
EP1012113B1 (en) 2005-03-23
FR2768424B1 (fr) 1999-10-29
CN1271329A (zh) 2000-10-25
BR9812137A (pt) 2000-07-18
EP1012113A1 (en) 2000-06-28
AP2000001749A0 (en) 2000-02-28
OA11460A (en) 2003-11-18
DE69829481D1 (de) 2005-04-28
AU9126798A (en) 1999-03-22
GEP20032949B (en) 2003-04-25

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