TWI843814B - 改質磷酸鎢酸鋯、負熱膨脹填料和高分子組成物 - Google Patents
改質磷酸鎢酸鋯、負熱膨脹填料和高分子組成物 Download PDFInfo
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- TWI843814B TWI843814B TW109106984A TW109106984A TWI843814B TW I843814 B TWI843814 B TW I843814B TW 109106984 A TW109106984 A TW 109106984A TW 109106984 A TW109106984 A TW 109106984A TW I843814 B TWI843814 B TW I843814B
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- Prior art keywords
- zwp
- modified
- zirconium tungstate
- tungstate phosphate
- thermal expansion
- Prior art date
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- -1 Modified zirconium tungstate phosphate Chemical class 0.000 title claims abstract description 76
- 229920000642 polymer Polymers 0.000 title claims abstract description 51
- 229910019142 PO4 Inorganic materials 0.000 title claims abstract description 50
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- 239000000945 filler Substances 0.000 title claims abstract description 34
- 239000000203 mixture Substances 0.000 title claims description 53
- 239000002245 particle Substances 0.000 claims abstract description 118
- 150000002484 inorganic compounds Chemical class 0.000 claims abstract description 47
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 47
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 29
- 239000011574 phosphorus Substances 0.000 claims abstract description 28
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- OJLGWNFZMTVNCX-UHFFFAOYSA-N dioxido(dioxo)tungsten;zirconium(4+) Chemical compound [Zr+4].[O-][W]([O-])(=O)=O.[O-][W]([O-])(=O)=O OJLGWNFZMTVNCX-UHFFFAOYSA-N 0.000 claims abstract description 25
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 24
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
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- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 12
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- OXAGUGIXGVHDGD-UHFFFAOYSA-H trizinc;2-hydroxypropane-1,2,3-tricarboxylate;dihydrate Chemical compound O.O.[Zn+2].[Zn+2].[Zn+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O OXAGUGIXGVHDGD-UHFFFAOYSA-H 0.000 description 6
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- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- SLYCYWCVSGPDFR-UHFFFAOYSA-N octadecyltrimethoxysilane Chemical compound CCCCCCCCCCCCCCCCCC[Si](OC)(OC)OC SLYCYWCVSGPDFR-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003050 poly-cycloolefin Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920013716 polyethylene resin Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 239000009719 polyimide resin Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005990 polystyrene resin Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- 229910052714 tellurium Inorganic materials 0.000 description 1
- HMXCZSOLWMJNGA-UHFFFAOYSA-N titanium(4+);tetraphosphite Chemical compound [Ti+4].[Ti+4].[Ti+4].[O-]P([O-])[O-].[O-]P([O-])[O-].[O-]P([O-])[O-].[O-]P([O-])[O-] HMXCZSOLWMJNGA-UHFFFAOYSA-N 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 1
- XYJRNCYWTVGEEG-UHFFFAOYSA-N trimethoxy(2-methylpropyl)silane Chemical compound CO[Si](OC)(OC)CC(C)C XYJRNCYWTVGEEG-UHFFFAOYSA-N 0.000 description 1
- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 239000005051 trimethylchlorosilane Substances 0.000 description 1
- PQDJYEQOELDLCP-UHFFFAOYSA-N trimethylsilane Chemical compound C[SiH](C)C PQDJYEQOELDLCP-UHFFFAOYSA-N 0.000 description 1
- 150000003658 tungsten compounds Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000001238 wet grinding Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/45—Phosphates containing plural metal, or metal and ammonium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/37—Phosphates of heavy metals
- C01B25/372—Phosphates of heavy metals of titanium, vanadium, zirconium, niobium, hafnium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
- C01P2004/82—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases
- C01P2004/84—Particles consisting of a mixture of two or more inorganic phases two phases having the same anion, e.g. both oxidic phases one phase coated with the other
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
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| JP2019041281 | 2019-03-07 | ||
| JP2019-041281 | 2019-03-07 | ||
| JP2019-228647 | 2019-12-18 | ||
| JP2019228647A JP6907295B2 (ja) | 2019-03-07 | 2019-12-18 | 改質リン酸タングステン酸ジルコニウム、負熱膨張フィラー及び高分子組成物 |
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| TW202033444A TW202033444A (zh) | 2020-09-16 |
| TWI843814B true TWI843814B (zh) | 2024-06-01 |
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| JP (1) | JP6907295B2 (enExample) |
| KR (1) | KR102787961B1 (enExample) |
| CN (1) | CN113544089B (enExample) |
| TW (1) | TWI843814B (enExample) |
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| CN114634663A (zh) * | 2022-02-25 | 2022-06-17 | 武汉材料保护研究所有限公司 | 低热膨胀系数耐磨超高分子量聚乙烯材料及其制备方法 |
| TW202337821A (zh) | 2022-03-23 | 2023-10-01 | 日商日本化學工業股份有限公司 | 負熱膨脹材、其製造方法及複合材料 |
| CN115094520B (zh) * | 2022-07-11 | 2023-11-03 | 中国科学院合肥物质科学研究院 | 一种负热膨胀材料(Ni1-xFex)1-δS及其制备方法 |
| CN116237456A (zh) * | 2023-01-18 | 2023-06-09 | 浦江微砂新材料有限公司 | 基于应力诱导实现烧结型砂自行溃散的溃散剂及制作方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2006137635A (ja) * | 2004-11-12 | 2006-06-01 | Nippon Electric Glass Co Ltd | フィラー粉末、封着用粉末およびペースト |
| TW201713781A (zh) * | 2015-10-07 | 2017-04-16 | Nippon Chemical Ind | 磷酸鎢酸鋯的製造方法 |
| TW201731764A (zh) * | 2015-10-07 | 2017-09-16 | Nippon Chemical Industrial Co Ltd | 負熱膨脹材及含有其的複合材料 |
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| JP4498765B2 (ja) * | 2004-01-30 | 2010-07-07 | 日本山村硝子株式会社 | 封着用組成物 |
| JP2005264135A (ja) * | 2004-02-20 | 2005-09-29 | Fuji Photo Film Co Ltd | 有機・無機複合体組成物、プラスチック基板、ガスバリア性積層フィルムおよび画像表示素子 |
| JP5311274B2 (ja) * | 2008-07-14 | 2013-10-09 | 日本電気硝子株式会社 | ビスマス系ガラス組成物および封着材料 |
| JP5717462B2 (ja) * | 2011-02-18 | 2015-05-13 | 株式会社トクヤマ | 表面処理無機酸化物粒子の製造方法 |
| CN103078081B (zh) * | 2013-01-15 | 2016-04-06 | 宁德新能源科技有限公司 | 表面包覆的锂离子电池正极活性材料颗粒及其制备方法 |
| JP2015024945A (ja) * | 2013-07-29 | 2015-02-05 | サムソン エレクトロ−メカニックス カンパニーリミテッド． | 無機フィラー、およびこれを含む絶縁樹脂組成物、絶縁フィルム、プリプレグ、並びに印刷回路基板 |
| CN104347853B (zh) * | 2014-09-24 | 2017-04-12 | 秦皇岛中科远达电池材料有限公司 | 一种锰酸锂复合正极材料、其制备方法及锂离子电池 |
| JP6501570B2 (ja) * | 2015-03-20 | 2019-04-17 | テイカ株式会社 | 無機化合物を固着又は被覆させた、アルミニウムのリン酸塩組成物からなるフィラーおよびその製造方法、そのフィラーを配合した熱伝導性組成物 |
| JP6105140B1 (ja) * | 2015-10-07 | 2017-03-29 | 日本化学工業株式会社 | 負熱膨張材及びそれを含む複合材料 |
| JP2017088642A (ja) * | 2015-11-02 | 2017-05-25 | 住友化学株式会社 | 充填剤 |
| JP6428588B2 (ja) * | 2015-12-08 | 2018-11-28 | 信越化学工業株式会社 | 表面処理無機酸化物粒子、該粒子を含む分散液、及びその製造方法 |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006137635A (ja) * | 2004-11-12 | 2006-06-01 | Nippon Electric Glass Co Ltd | フィラー粉末、封着用粉末およびペースト |
| TW201713781A (zh) * | 2015-10-07 | 2017-04-16 | Nippon Chemical Ind | 磷酸鎢酸鋯的製造方法 |
| TW201731764A (zh) * | 2015-10-07 | 2017-09-16 | Nippon Chemical Industrial Co Ltd | 負熱膨脹材及含有其的複合材料 |
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| KR20210135237A (ko) | 2021-11-12 |
| CN113544089A (zh) | 2021-10-22 |
| JP6907295B2 (ja) | 2021-07-21 |
| CN113544089B (zh) | 2024-06-18 |
| TW202033444A (zh) | 2020-09-16 |
| KR102787961B1 (ko) | 2025-03-27 |
| JP2020147486A (ja) | 2020-09-17 |
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