TWI820180B - 感光性樹脂組成物、感光性薄片、以及彼等之硬化膜及其製造方法、電子零件 - Google Patents
感光性樹脂組成物、感光性薄片、以及彼等之硬化膜及其製造方法、電子零件 Download PDFInfo
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- TWI820180B TWI820180B TW108128213A TW108128213A TWI820180B TW I820180 B TWI820180 B TW I820180B TW 108128213 A TW108128213 A TW 108128213A TW 108128213 A TW108128213 A TW 108128213A TW I820180 B TWI820180 B TW I820180B
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- photosensitive resin
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- resin composition
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- 239000011342 resin composition Substances 0.000 title claims abstract description 78
- 238000004519 manufacturing process Methods 0.000 title claims description 9
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- 229920005989 resin Polymers 0.000 claims abstract description 75
- 239000011347 resin Substances 0.000 claims abstract description 75
- 229920001721 polyimide Polymers 0.000 claims abstract description 70
- 239000004642 Polyimide Substances 0.000 claims abstract description 66
- 239000002243 precursor Substances 0.000 claims abstract description 55
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- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000003505 polymerization initiator Substances 0.000 claims abstract description 15
- 150000004283 biguanides Chemical class 0.000 claims abstract description 9
- 150000002357 guanidines Chemical class 0.000 claims abstract description 7
- 239000003504 photosensitizing agent Substances 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 96
- 238000000034 method Methods 0.000 claims description 96
- 150000001875 compounds Chemical class 0.000 claims description 56
- 239000000758 substrate Substances 0.000 claims description 45
- 239000002585 base Substances 0.000 claims description 43
- 125000000217 alkyl group Chemical group 0.000 claims description 28
- 238000010438 heat treatment Methods 0.000 claims description 27
- 125000003118 aryl group Chemical group 0.000 claims description 26
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 21
- 125000003545 alkoxy group Chemical group 0.000 claims description 16
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 16
- 125000005843 halogen group Chemical group 0.000 claims description 14
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 10
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 10
- 125000003342 alkenyl group Chemical group 0.000 claims description 9
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 8
- 125000001544 thienyl group Chemical group 0.000 claims description 8
- 125000000304 alkynyl group Chemical group 0.000 claims description 7
- 125000005015 aryl alkynyl group Chemical group 0.000 claims description 7
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- 125000000168 pyrrolyl group Chemical group 0.000 claims description 7
- 125000002541 furyl group Chemical group 0.000 claims description 6
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 claims description 5
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- 150000007942 carboxylates Chemical class 0.000 claims description 2
- 238000010030 laminating Methods 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 35
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- 229910052710 silicon Inorganic materials 0.000 description 15
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 14
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- 230000018044 dehydration Effects 0.000 description 9
- 238000006297 dehydration reaction Methods 0.000 description 9
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- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 9
- 239000000178 monomer Substances 0.000 description 9
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- 125000000962 organic group Chemical group 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 8
- 239000006087 Silane Coupling Agent Substances 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
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- OZUCXGWYZVDFOU-UHFFFAOYSA-N 2-(diethylamino)ethyl 6-hydroxy-4,7-dimethoxy-1-benzofuran-5-carboxylate;hydrochloride Chemical class [Cl-].CC[NH+](CC)CCOC(=O)C1=C(O)C(OC)=C2OC=CC2=C1OC OZUCXGWYZVDFOU-UHFFFAOYSA-N 0.000 description 5
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- ARUIMKUOHIINGI-UHFFFAOYSA-N trifluoro(methylsulfonyl)methane Chemical compound CS(=O)(=O)C(F)(F)F ARUIMKUOHIINGI-UHFFFAOYSA-N 0.000 description 1
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- ZNOCGWVLWPVKAO-UHFFFAOYSA-N trimethoxy(phenyl)silane Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1 ZNOCGWVLWPVKAO-UHFFFAOYSA-N 0.000 description 1
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- HTVULPNMIHOVRU-UHFFFAOYSA-N trimethoxy-[2-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CC(C)OCC1CO1 HTVULPNMIHOVRU-UHFFFAOYSA-N 0.000 description 1
- ZQPNGHDNBNMPON-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)butyl]silane Chemical compound CO[Si](OC)(OC)CCC(C)OCC1CO1 ZQPNGHDNBNMPON-UHFFFAOYSA-N 0.000 description 1
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- CESKYMDZTHKIPO-UHFFFAOYSA-N tris(2-methoxyethoxy)-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound COCCO[Si](OCCOC)(OCCOC)CCCOCC1CO1 CESKYMDZTHKIPO-UHFFFAOYSA-N 0.000 description 1
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- 230000002087 whitening effect Effects 0.000 description 1
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Classifications
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
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- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
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- G—PHYSICS
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/038—Macromolecular compounds which are rendered insoluble or differentially wettable
- G03F7/0387—Polyamides or polyimides
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/075—Silicon-containing compounds
- G03F7/0757—Macromolecular compounds containing Si-O, Si-C or Si-N bonds
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/16—Coating processes; Apparatus therefor
- G03F7/168—Finishing the coated layer, e.g. drying, baking, soaking
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/20—Exposure; Apparatus therefor
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/26—Processing photosensitive materials; Apparatus therefor
- G03F7/40—Treatment after imagewise removal, e.g. baking
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Materials For Photolithography (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2018-150108 | 2018-08-09 | ||
| JP2018150108 | 2018-08-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW202018411A TW202018411A (zh) | 2020-05-16 |
| TWI820180B true TWI820180B (zh) | 2023-11-01 |
Family
ID=69414677
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW108128213A TWI820180B (zh) | 2018-08-09 | 2019-08-08 | 感光性樹脂組成物、感光性薄片、以及彼等之硬化膜及其製造方法、電子零件 |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JP7409087B2 (https=) |
| KR (1) | KR102683127B1 (https=) |
| CN (1) | CN112368641B (https=) |
| TW (1) | TWI820180B (https=) |
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| CN115335771B (zh) * | 2020-03-30 | 2025-03-25 | 富士胶片株式会社 | 感光性转印材料、树脂图案的制造方法及电路配线的制造方法 |
| KR102848086B1 (ko) * | 2020-09-29 | 2025-08-22 | 후지필름 가부시키가이샤 | 경화물의 제조 방법, 적층체의 제조 방법, 및, 반도체 디바이스의 제조 방법 |
| JP7787641B2 (ja) * | 2020-12-09 | 2025-12-17 | 旭化成株式会社 | ネガ型感光性樹脂組成物及びこれを用いた硬化レリーフパターンの製造方法 |
| JP7639354B2 (ja) * | 2021-01-19 | 2025-03-05 | Hdマイクロシステムズ株式会社 | 感光性樹脂組成物、パターン硬化物の製造方法、硬化物、層間絶縁膜、カバーコート層、表面保護膜及び電子部品 |
| CN115678005B (zh) * | 2021-07-13 | 2024-10-01 | 上海邃铸科技有限公司 | 聚合物、树脂组合物、树脂膜以及半导体器件和发光器件 |
| KR20240058111A (ko) * | 2021-09-24 | 2024-05-03 | 도레이 카부시키가이샤 | 수지 조성물, 차광막 및 격벽 구비 기판 |
| WO2023163209A1 (ja) * | 2022-02-28 | 2023-08-31 | 太陽インキ製造株式会社 | 硬化性樹脂組成物、ドライフィルム、硬化物、および、プリント配線板 |
| US20250199401A1 (en) * | 2022-03-23 | 2025-06-19 | Toray Industries, Inc. | Resin composition, cured product, electronic component, and display device |
| CN116731063A (zh) * | 2022-06-14 | 2023-09-12 | 北京鼎材科技有限公司 | 一种硅烷偶联剂及其应用、包含其的光敏树脂组合物 |
| JPWO2024162116A1 (https=) * | 2023-02-01 | 2024-08-08 | ||
| CN116552074B (zh) * | 2023-05-05 | 2023-12-19 | 江门建滔电子发展有限公司 | 一种高散热低介电覆铜板及其制备方法 |
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| TW201817749A (zh) * | 2016-06-30 | 2018-05-16 | 東麗股份有限公司 | 負型感光性樹脂組成物、硬化膜、具備硬化膜之元件、具備元件之顯示裝置、及有機el顯示器 |
| WO2018123836A1 (ja) * | 2016-12-28 | 2018-07-05 | 富士フイルム株式会社 | 感光性樹脂組成物、硬化膜、積層体、硬化膜の製造方法、積層体の製造方法および半導体デバイス |
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| JPH07134414A (ja) * | 1993-05-07 | 1995-05-23 | Nitto Denko Corp | 耐熱性ポジ型フォトレジスト組成物 |
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| JP5223633B2 (ja) | 2008-12-02 | 2013-06-26 | 大日本印刷株式会社 | 感光性樹脂組成物、およびこれを用いた物品、及びネガ型パターン形成方法 |
| TWI430024B (zh) * | 2010-08-05 | 2014-03-11 | 旭化成電子材料股份有限公司 | A photosensitive resin composition, a method for manufacturing a hardened bump pattern, and a semiconductor device |
| US8808969B2 (en) * | 2011-04-12 | 2014-08-19 | Brewer Science Inc. | Method of making radiation-sensitive sol-gel materials |
| WO2015083331A1 (ja) * | 2013-12-04 | 2015-06-11 | サンアプロ株式会社 | 光塩基発生剤 |
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| CN105739239B (zh) * | 2014-12-10 | 2020-04-03 | 太阳油墨(苏州)有限公司 | 光固化性热固化性树脂组合物、干膜、固化物、及印刷电路板 |
| JP6785538B2 (ja) | 2015-06-17 | 2020-11-18 | 株式会社ダイセル | ポリオルガノシルセスキオキサン、硬化性組成物、接着シート、積層物及び装置 |
| TW201710390A (zh) * | 2015-08-31 | 2017-03-16 | Fujifilm Corp | 組成物、硬化膜、硬化膜的製造方法、半導體元件的製造方法及半導體元件 |
| US10101654B2 (en) * | 2016-09-20 | 2018-10-16 | Shin-Etsu Chemical Co., Ltd. | Resist composition and patterning process |
| KR102517695B1 (ko) * | 2017-01-20 | 2023-04-03 | 제이에스알 가부시끼가이샤 | 감광성 조성물, 경화막 및 그의 제조 방법, 그리고 표시 소자, 발광 소자 및 수광 소자 |
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| TW201719278A (zh) * | 2015-04-01 | 2017-06-01 | Toray Industries | 感光性著色樹脂組成物 |
| TW201817749A (zh) * | 2016-06-30 | 2018-05-16 | 東麗股份有限公司 | 負型感光性樹脂組成物、硬化膜、具備硬化膜之元件、具備元件之顯示裝置、及有機el顯示器 |
| WO2018123836A1 (ja) * | 2016-12-28 | 2018-07-05 | 富士フイルム株式会社 | 感光性樹脂組成物、硬化膜、積層体、硬化膜の製造方法、積層体の製造方法および半導体デバイス |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20210040936A (ko) | 2021-04-14 |
| CN112368641B (zh) | 2025-05-02 |
| CN112368641A (zh) | 2021-02-12 |
| KR102683127B1 (ko) | 2024-07-10 |
| TW202018411A (zh) | 2020-05-16 |
| JP7409087B2 (ja) | 2024-01-09 |
| WO2020031958A1 (ja) | 2020-02-13 |
| JPWO2020031958A1 (ja) | 2021-08-10 |
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