TWI688042B - 半導體元件的製作方法 - Google Patents

半導體元件的製作方法 Download PDF

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TWI688042B
TWI688042B TW105121146A TW105121146A TWI688042B TW I688042 B TWI688042 B TW I688042B TW 105121146 A TW105121146 A TW 105121146A TW 105121146 A TW105121146 A TW 105121146A TW I688042 B TWI688042 B TW I688042B
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patent application
item
epitaxial
substrate
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洪裕祥
傅思逸
許智凱
程偉麒
鄭志祥
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聯華電子股份有限公司
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Abstract

本發明提供一種形成半導體元件的方法,其特徵在於包含以下步驟:首先,提供一基底,接著形成至少一閘極結構位於該基底上,然後依序形成一蝕刻停止層以及一第一介電層,覆蓋於該基底上,之後進行一第一蝕刻步驟,將該第一介電層移除,並曝露該蝕刻停止層的一底部與一側壁,接下來,進行一第二蝕刻步驟,移除部分該蝕刻停止層,並於該基底中形成至少一磊晶凹槽,進行一磊晶成長步驟,於該磊晶凹槽中形成一磊晶層,以及形成一接觸結構於該磊晶層上。

Description

半導體元件的製作方法
本發明係有關於半導體製程領域,尤其是一種配合自對準製程(self-aligned process)形成磊晶層與接觸結構的半導體結構製作方法。
隨著積體電路(IC)積集度不斷提升以及特徵尺寸(feature size)持續降低,半導體元件的內連線線寬與幾何尺寸也越來越小。一般而言,積體電路中的各個獨立的半導體元件係藉由接觸插塞以及內連線結構而使其互相電連接。因此,插塞結構及其製程在次世代的半導體製程中也愈顯重要。
本發明提供一種形成半導體元件的方法,其特徵在於包含以下步驟:首先,提供一基底,接著形成至少一閘極結構位於該基底上,然後依序形成一蝕刻停止層以及一第一介電層,覆蓋於該基底上,之後進行一第一蝕刻步驟,將該第一介電層移除,並曝露該蝕刻停止層的一底部與一側壁,接下來,進行一第二蝕刻步驟,移除部分該蝕刻停止層,並於該基底中形成至少一磊晶凹槽,進行一磊晶成長步驟,於該磊晶凹槽中形成一磊晶層,以及形成一接觸結構於該磊晶層上。
本發明的特徵在於,在進行第一蝕刻步驟時,以氮化矽材質的第一遮罩層、蝕刻停止層與襯墊層作為保護層,完全移除氧化矽材質的第一介電層,而不需要形成其他的保護層等,就可形成第一凹槽。第一凹槽位於金屬閘極旁,且第一凹槽與金屬閘極之間不包含有其他氧化矽材質。也就是說,上述步驟屬於一自對準步驟(self-aligned process),可以精準決定第一凹槽的位置,而後續所形成的磊晶層的位置也隨之被決定。磊晶層以及接觸結構不會過於接近或遠離金屬閘極的位置,可以避免金屬閘極與磊晶層之間產生錯位(mis-alignment)的問題,提高半導體元件的良率。
10:基底
12:金屬閘極
14:淺溝隔離
18:襯墊層
20:蝕刻停止層
20A:頂面
20B:側壁
22:第一介電層
24:第一遮罩層
24’:第一遮罩層
25:光阻層
26:第一凹槽
27:第二凹槽
28:磊晶凹槽
30:磊晶層
32:第二遮罩層
34:光阻層
36:磊晶凹槽
38:磊晶層
40:阻障層
42:導電層
44:介電層
P1:第一蝕刻步驟
P2:第二蝕刻步驟
P3:第三蝕刻步驟
P4:選擇性磊晶成長步驟
P5:第五蝕刻步驟
P6:第六蝕刻步驟
P7:選擇性磊晶成長步驟
P8:離子佈植製程
R1:第一區域
R2:第二區域
第1~8圖繪示製作本發明第一較佳實施例之半導體結構示意圖,其中:第1圖繪示兩金屬閘極、至少一襯墊層、至少一蝕刻停止層與至少一第一介電層形成於一基底上的示意圖;第2圖繪示進行一第一蝕刻步驟之後的半導體結構示意圖;第3圖繪示進行一第二蝕刻步驟之後的半導體結構示意圖;第4圖繪示進行一第三蝕刻步驟與一選擇性磊晶成長步驟之後的半導體結構示意圖;第5圖繪示形成一第二遮罩層之後的半導體結構示意圖;第6圖繪示依序進行一第五蝕刻步驟、一第六蝕刻步驟與一選擇性磊晶成長步驟之後的半導體結構示意圖;第7圖繪示移除一第二遮罩層之後的半導體結構示意圖;第8圖繪示形成一阻障層與一導電層之後的半導體結構示意圖。
第9~11圖繪示製作本發明第二較佳實施例之半導體結構示意圖,其中:第9圖繪示兩金屬閘極、至少一襯墊層、至少一蝕刻停止層與至少一第一介電層形成於一基底上的示意圖;第10圖繪示形成兩磊晶層與一介電層之後的半導體結構示意圖;第11圖繪示形成一第一遮罩層之後的半導體結構示意圖。
為使熟習本發明所屬技術領域之一般技藝者能更進一步了解本發明,下文特列舉本發明之較佳實施例,並配合所附圖式,詳細說明本發明的構成內容及所欲達成之功效。
為了方便說明,本發明之各圖式僅為示意以更容易了解本發明,其詳細的比例可依照設計的需求進行調整。在文中所描述對於圖形中相對元件之上下關係,在本領域之人皆應能理解其係指物件之相對位置而言,因此皆可以翻轉而呈現相同之構件,此皆應同屬本說明書所揭露之範圍,在此容先敘明。
請參考第1~8圖,其繪示製作本發明第一較佳實施例之半導體結構示意圖,如第1圖所示,首先,提供一基底10,基底10上包含有至少兩區域,分別定義為第一區域R1與第二區域R2,在後續的步驟中,第一區域R1與第二區域R2內將分別形成不同導電型態的半導體元件。例如在第一區域R1內形成一n型電晶體,而在第二區域R2內形成 一p型電晶體,但本發明不限於此。
基底10上包含有至少兩金屬閘極12分別位於第一區域R1與第二區域R2內,此外,基底10上可選擇性包含有至少一鰭狀結構(圖未示),在本實施例中,金屬閘極12包含金屬材料,例如可藉由一金屬閘極置換步驟(replacement metal gate,RMG)所形成,在此不多加贅述。在金屬閘極12周圍的基底10中,更包含形成有至少一淺溝隔離14,以電性隔離位於基底10上的鰭狀結構以及其他的半導體元件。
此外,更可能選擇性包含形成一襯墊層18以及一蝕刻停止層20在各金屬閘極12的兩側壁上,此外,本實施例中,襯墊層18以及一蝕刻停止層20也會位於金屬閘極12之間的基底10上。另外,在襯墊層18形成後,可額外於基底10中形成至少一輕摻雜汲極(light doped drain,LDD,圖未示)。接著覆蓋上一第一介電層22後,進行一平坦化步驟,例如為一化學機械研磨製程(CMP),使得金屬閘極12的頂端與第一介電層22的頂端齊平。值得注意的是,本實施例中,在金屬閘極12完成之後,將以一蝕刻製程,移除金屬閘極12的部分頂端,並且形成一第一遮罩層24取代頂端部分的金屬閘極12,且進行另一次平坦化步驟去除多餘的第一遮罩層24。也就是說,本實施例在金屬閘極12的頂端,更包含有一第一遮罩層24,且第一遮罩層24的頂端與第一介電層22的頂端切齊,此外,由於第一遮罩層24是取代原先金屬閘極12的部分頂端,因此第一遮罩層24只位於金屬閘極12上,且位於襯墊層18之間。另外,因為進行上述另一次平坦化的過程中,也會移除部分的襯墊層18與蝕刻停止層20,因此襯墊層18與蝕刻停止層20的頂端有一截 面(truncated surface)。本實施例中,襯墊層18、蝕刻停止層20以及第一遮罩層24材質主要為氮化矽,而第一介電層22的主要材質為氧化矽,但不限於此。上述各元件的材料與製作方式,皆為本發明的技術人員所熟知的技術,在此不多贅述。
接下來如第2圖所示,先進行一第一蝕刻步驟P1,將第一區域R1以及第二區域R2內的第一介電層22完全移除,並形成複數個第一凹槽26,值得注意的是,第一介電層22移除後,第一凹槽26將曝露出蝕刻停止層20的一頂面20A以及至少一側壁20B(如第2圖所示)。然後如第3圖所示,先形成一光阻層25覆蓋第二區域R2,然後進行一第二蝕刻步驟P2,將第一區域R1內的蝕刻停止層20與襯墊層18部分移除,以形成一第二凹槽27,其中第二凹槽27曝露出基底10。值得注意的是,由於本實施例中,蝕刻停止層20、襯墊層18與第一遮罩層24的材質皆包含例如氮化矽,因此在第二蝕刻步驟P2過程中,第一遮罩層24也會被部分蝕刻(圖未示),但是由於本實施例中第一遮罩層24的厚度較佳大於蝕刻停止層20與襯墊層18的厚度總和,舉例來說,在本實施例中,第一遮罩層24的厚度大約為400埃(angstroms),而襯墊層18的厚度約為30埃,蝕刻停止層20的厚度則約為20埃,因此在第二蝕刻步驟P2進行之後,第一遮罩層24未被完全移除,而金屬閘極12仍被第一遮罩層24所覆蓋。
本實施例中所用的第一蝕刻步驟P1以氣體蝕刻為主,可包含有全氟化碳氣體(Perfluorocarbon gases),例如四氟化碳(Tetrafluoromethane,CF4)、三氟甲烷(Fluoroform,CHF3)、全氟丁二烯 (Hexa-fluoro-1,3+butadiene,C4F6)等,另外包含氧氣與氬氣(Argon,Ar),但不限於此。值得注意的是,若蝕刻氣體中所包含的全氟化碳氣體與氧氣比值愈高,則該蝕刻氣體對於氧化矽/氮化矽的蝕刻選擇比愈高。換句話說,若蝕刻氣體中所包含的全氟化碳氣體比例較高,則在蝕刻過程中,蝕刻氧化矽的速率將會大於蝕刻氮化矽的速率愈多。由於本實施例中,第一介電層22材質主要為氧化矽,而蝕刻停止層20材質主要包含有氮化矽,本實施例中,第一蝕刻步驟P1選用對於氧化矽/氮化矽的蝕刻選擇相對較高(較佳大於5)的氣體,所以蝕刻第一介電層22的速率較快,但蝕刻蝕刻停止層20的速率較慢,因此第一蝕刻步驟P1不容易蝕穿蝕刻停止層20,將會停在蝕刻停止層20的表面。接著在第二蝕刻步驟P2中,再選用其他氣體進行蝕刻,以部分移除蝕刻停止層20與襯墊層18。
如第4圖所示,繼續進行一第三蝕刻步驟P3,於第一區域R1內,蝕刻曝露出的基底10,以於第一區域R1內形成至少一磊晶凹槽28,然後再進行一選擇性磊晶成長(SEG)步驟P4,以於磊晶凹槽28內形成一磊晶層30,且磊晶層30係填滿磊晶凹槽28。熟習該項技藝之人士應知,在進行SEG步驟P4時,磊晶層30係沿著磊晶凹槽28的各表面成長。因此,形成如第4圖所示形狀之磊晶層30。值得注意的是,光阻層25將會在上述選擇性磊晶成長步驟P4執行之前被移除(例如光阻層25可以在上述第二蝕刻步驟P2與第三蝕刻步驟P3之間被移除,或是在上述第三蝕刻步驟P3執行後至SEG步驟P4之間被移除),以免光阻層25被SEG步驟P4過程中的高溫所破壞。此外,在本較佳實施例中,磊晶層30係依據電性要求(p型或n型)而可包含一矽鍺(SiGe)、一矽碳(SiC)、或一矽磷(SiP)等磊晶 層,例如在本實實施中,由於第一區域R1內預定形成n型電晶體,因此磊晶層30包含一矽碳磊晶層。
在第一區域R1內的磊晶層30形成後,如第5圖所示,再另外形成一第二遮罩層32覆蓋於第一區域R1與第二區域R2內。其中第二遮罩層32覆蓋於第一區域R1內的磊晶層30上,並覆蓋於第二區域R2內的第一凹槽26中。另外,本實施例中,第二遮罩層32的材質例如為氮化矽,材質與蝕刻停止層20、襯墊層18以及第一遮罩層24相同。
如第6圖所示,於第一區域R1內形成一光阻層34,覆蓋於金屬閘極12以及磊晶層30上。接下來,依序於第二區域R2內進行一第五蝕刻步驟P5與一第六蝕刻步驟P6。此處的第五蝕刻步驟P5與第六蝕刻步驟P6分別與上述的第二蝕刻步驟P2與第三蝕刻步驟P3相似,可參考上述段落所述內容以及第3圖與第4圖。其中第五蝕刻步驟P5移除第二區域R2內部分的第二遮罩層32、蝕刻停止層20與襯墊層18,並將基底10曝露出來;第六蝕刻步驟P6移除部分第二區域R2內的基底10,並形成一磊晶凹槽36。
如第7圖所示,將光阻層34移除後,進行一選擇性磊晶成長步驟P7,其步驟相似上述的選擇性磊晶成長步驟P4(可參考第4圖),於磊晶凹槽36中形成一磊晶層38。在本實施例中,由於第二區域R2內預定形成p型電晶體,因此磊晶層38包含例如一矽鍺磊晶層。
此外,亦可一製程或產品需要,選擇性進行一金屬矽化物製程,而至少於磊晶層30與磊晶層38表面形成金屬矽化物。另外,上述 實施例中,以平面式的電晶體結構為例說明,但本發明也可應用於非平面式的電晶體(例如鰭狀電晶體,finFET)等,也屬於本發明的涵蓋範圍內。
接下來,將第二遮罩層32移除後,磊晶層30與磊晶層38被曝露出來。此處可再進行一離子佈植製程P8以植入適當之摻質,或者於上述進行選擇性磊晶成長步驟P4、P7時,同時摻雜適當之摻質,如此,磊晶層30、38便可用以作為一源/汲極區。另外,為了保護形成的磊晶層30、38,可以在此處另外形成一介電層(圖未示)覆蓋於磊晶層30、38上,之後欲形成接觸結構時,再將上述的介電層移除。或是如第8圖所示,在磊晶層30、38被曝露出來後,直接於磊晶層30、38上例如以一化學氣相沈積(chemical vapor deposition,CVD)製程、一物理氣相沈積(physical vapor deposition,PVD)製程、或一原子層沉積(atomic layer deposition,ALD)製程,以形成一阻障層40以及一導電層42。阻障層40例如包含鈦(Ti)、氮化鈦(TiN)、鉭(Ta)與氮化鉭(TaN)等,而導電層42係用以填滿磊晶層30、38上的凹槽,並可選擇具有優良填充能力與較低阻值的金屬或金屬氧化物,例如鎢(tungsten,W)、鋁(aluminum,Al)、鋁化鈦(titanium aluminide,TiAl)或氧化鋁鈦(titanium aluminum oxide,TiAlO)等。
本發明的特徵在於,在進行第一蝕刻步驟P1時(可參考第2圖),以氮化矽材質的第一遮罩層24、蝕刻停止層20與襯墊層18作為保護層,完全移除氧化矽材質的第一介電層22,而不需要形成其他的保護層等,就可形成第一凹槽26。第一凹槽26位於金屬閘極12旁,且第一凹槽26與金屬閘極12之間不包含有其他氧化矽材質。也就是說,上述步驟屬於一自對準步驟(self-aligned process),可 以精準決定第一凹槽26的位置,而後續所形成的磊晶層30、38的位置也隨之被決定。磊晶層以及接觸結構不會過於接近或遠離金屬閘極的位置,可以避免金屬閘極與磊晶層之間產生錯位(mis-alignment)的問題,提高半導體元件的良率。
下文將針對本發明之半導體結構及其製作方法的不同實施樣態進行說明,且為簡化說明,以下說明主要針對各實施例不同之處進行詳述,而不再對相同之處作重覆贅述。此外,本發明之各實施例中相同之元件係以相同之標號進行標示,以利於各實施例間互相對照。
在本發明的其他實施例中,可以參考第9圖與第10圖,如第9圖所示,與上述第一較佳實施例相同,同樣提供一基底10,基底10上定義有第一區域R1與第二區域R2,且形成金屬閘極12、襯墊層18、蝕刻停止層20與第一介電層22於基底10上。與上述第一較佳實施例不同之處在於,本實施例中,第一凹槽、磊晶凹槽等一同藉由上述自對準步驟所形成,所以可以先不用形成第一遮罩層24於金屬閘極12的頂端。更詳細說明,進行第一蝕刻步驟P1之前,尚未形成第一遮罩層24於金屬閘極12的頂端,因此金屬閘極12的頂端與第一介電層22的一頂面切齊。
接下來的步驟與上述第一較佳實施例相同,包括於第一區域R1與第二區域R2內分別形成第一凹槽、磊晶凹槽與磊晶層等。如第10圖所示,當磊晶層30與磊晶層38分別被形成於第一區域R1與第二區域R2後,先形成一介電層44於基底10上,覆蓋並保護磊晶層30與磊晶層38,接著進行一平坦化步驟以移除多餘的介電層44。接著如第11圖所示,由於金屬閘極12的頂端被曝露出來,在此處才以一蝕刻製程,移除金屬閘極12的部分頂端,並且形成一第一遮罩層24’取代 頂端部分的金屬閘極12,且進行另一次平坦化步驟去除多餘的第一遮罩層24’。後續步驟也與上述第一較佳實施例相同,包含形成阻障層40與導電層42分別位於磊晶層30、38上,在此不多加贅述。本實施例所述的方法也屬於本發明的涵蓋範圍內。
以上所述僅為本發明之較佳實施例,凡依本發明申請專利範圍所做之均等變化與修飾,皆應屬本發明之涵蓋範圍。
10:基底
12:金屬閘極
14:淺溝隔離
18:襯墊層
20:蝕刻停止層
22:第一介電層
24:第一遮罩層
28:磊晶凹槽
30:磊晶層
36:磊晶凹槽
38:磊晶層
40:阻障層
42:導電層
R1:第一區域
R2:第二區域

Claims (18)

  1. 一種形成半導體元件的方法,其特徵在於包含以下步驟:提供一基底;形成至少一閘極結構位於該基底上;依序形成一蝕刻停止層以及一第一介電層,覆蓋於該基底上;進行一第一蝕刻步驟,將該第一介電層移除,並曝露該蝕刻停止層的一底部與一側壁;進行一第二蝕刻步驟,移除部分該蝕刻停止層,並於該基底中形成至少一磊晶凹槽;進行一磊晶成長步驟,於該磊晶凹槽中形成一磊晶層;以及形成一接觸結構於該磊晶層上。
  2. 如申請專利範圍第1項所述的方法,其中更包含一襯墊層,位於該閘極結構的兩側。
  3. 如申請專利範圍第2項所述的方法,其中形成該襯墊層之後,才形成該蝕刻停止層。
  4. 如申請專利範圍第3項所述的方法,其中該襯墊層與該蝕刻停止層材質皆包含有氮化矽。
  5. 如申請專利範圍第1項所述的方法,其中該第一介電層的材質包含有氧化矽。
  6. 如申請專利範圍第1項所述的方法,其中更包含有至少一鰭狀結構位於該基底上,且該閘極結構橫跨該鰭狀結構。
  7. 如申請專利範圍第1項所述的方法,更包含:於該基底形成一淺溝隔離,該淺溝隔離環繞該鰭狀結構。
  8. 如申請專利範圍第1項所述的方法,更包含對該磊晶層進行一離子佈植步驟。
  9. 如申請專利範圍第1項所述的方法,其中更包含在該閘極結構頂端形成一第一遮罩層。
  10. 如申請專利範圍第9項所述的方法,其中該第一遮罩層的一頂面與該第一介電層的一頂面切齊。
  11. 如申請專利範圍第9項所述的方法,其中在該第一遮罩層形成之後,才進行該第一蝕刻步驟。
  12. 如申請專利範圍第9項所述的方法,其中在該磊晶層形成之後,才形成該第一遮罩層。
  13. 如申請專利範圍第9項所述的方法,其中該第一遮罩層的厚度大於該蝕刻停止層的厚度。
  14. 如申請專利範圍第1項所述的方法,其中該閘極結構包含一金屬閘極。
  15. 如申請專利範圍第1項所述的方法,其中該磊晶層形成之後,更包含形成一第二遮罩層,覆蓋於該磊晶層上方。
  16. 如申請專利範圍第15項所述的方法,其中該第二遮罩層在該接觸結構形成之前被移除。
  17. 如申請專利範圍第1項所述的方法,其中更包含形成一第二閘極結構位於該基底上。
  18. 如申請專利範圍第17項所述的方法,其中更包含形成至少一第二磊晶層於該第二閘極結構旁的該基底中,且該第二磊晶層具有與該磊晶層互補的電性。
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