TWI653277B - 高氟化彈性體 - Google Patents
高氟化彈性體 Download PDFInfo
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- TWI653277B TWI653277B TW103143102A TW103143102A TWI653277B TW I653277 B TWI653277 B TW I653277B TW 103143102 A TW103143102 A TW 103143102A TW 103143102 A TW103143102 A TW 103143102A TW I653277 B TWI653277 B TW I653277B
- Authority
- TW
- Taiwan
- Prior art keywords
- ether
- highly fluorinated
- formula
- perfluoro
- mol
- Prior art date
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- 229920001971 elastomer Polymers 0.000 title claims abstract description 54
- 239000000806 elastomer Substances 0.000 title claims abstract description 50
- 239000000178 monomer Substances 0.000 claims abstract description 85
- 229910052740 iodine Inorganic materials 0.000 claims abstract description 67
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 44
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims abstract description 43
- 239000011630 iodine Substances 0.000 claims abstract description 39
- 150000001875 compounds Chemical class 0.000 claims abstract description 31
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000002170 ethers Chemical class 0.000 claims abstract description 11
- 229920001774 Perfluoroether Polymers 0.000 claims abstract description 10
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 50
- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 claims description 33
- -1 perfluoro Chemical group 0.000 claims description 30
- 238000006116 polymerization reaction Methods 0.000 claims description 28
- 150000002978 peroxides Chemical class 0.000 claims description 24
- 238000002835 absorbance Methods 0.000 claims description 23
- 229910052731 fluorine Inorganic materials 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 19
- 238000006243 chemical reaction Methods 0.000 claims description 18
- 239000003292 glue Substances 0.000 claims description 17
- 239000003999 initiator Substances 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 239000003995 emulsifying agent Substances 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 229920001973 fluoroelastomer Polymers 0.000 claims description 8
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- UUAGAQFQZIEFAH-UHFFFAOYSA-N chlorotrifluoroethylene Chemical compound FC(F)=C(F)Cl UUAGAQFQZIEFAH-UHFFFAOYSA-N 0.000 claims description 3
- 125000005394 methallyl group Chemical group 0.000 claims description 3
- FOKCKXCUQFKNLD-UHFFFAOYSA-N pent-1-enyl hypofluorite Chemical compound C(CC)C=COF FOKCKXCUQFKNLD-UHFFFAOYSA-N 0.000 claims description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 3
- WFJINAXLTGKWLB-UHFFFAOYSA-N 1-ethenoxy-1,1,2,2,3,3-hexafluoro-3-(trifluoromethoxy)propane Chemical compound FC(F)(F)OC(F)(F)C(F)(F)C(F)(F)OC=C WFJINAXLTGKWLB-UHFFFAOYSA-N 0.000 claims description 2
- ZLFSOCVJMGQPTE-UHFFFAOYSA-N 1-ethenoxy-1,1,2,2-tetrafluoro-2-(trifluoromethoxy)ethane Chemical compound FC(F)(F)OC(F)(F)C(F)(F)OC=C ZLFSOCVJMGQPTE-UHFFFAOYSA-N 0.000 claims description 2
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 claims description 2
- FGEGZNORXGGFML-UHFFFAOYSA-N C(C)C=COF Chemical compound C(C)C=COF FGEGZNORXGGFML-UHFFFAOYSA-N 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
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- 239000012736 aqueous medium Substances 0.000 claims 2
- SXWUSKUNDTYYNV-UHFFFAOYSA-N FC(=C(C(C(C(F)(F)F)(OC(C(C(F)(F)F)(F)F)(F)F)F)(F)F)F)OC(=C(F)C(C(C(F)(F)F)(F)OC(C(C(F)(F)F)(F)F)(F)F)(F)F)F Chemical compound FC(=C(C(C(C(F)(F)F)(OC(C(C(F)(F)F)(F)F)(F)F)F)(F)F)F)OC(=C(F)C(C(C(F)(F)F)(F)OC(C(C(F)(F)F)(F)F)(F)F)(F)F)F SXWUSKUNDTYYNV-UHFFFAOYSA-N 0.000 claims 1
- 239000001294 propane Substances 0.000 claims 1
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- 239000000370 acceptor Substances 0.000 description 15
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 15
- 239000012935 ammoniumperoxodisulfate Substances 0.000 description 15
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 229910052794 bromium Inorganic materials 0.000 description 8
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- 238000004132 cross linking Methods 0.000 description 5
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- RRZIJNVZMJUGTK-UHFFFAOYSA-N 1,1,2-trifluoro-2-(1,2,2-trifluoroethenoxy)ethene Chemical compound FC(F)=C(F)OC(F)=C(F)F RRZIJNVZMJUGTK-UHFFFAOYSA-N 0.000 description 4
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- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
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- 239000002184 metal Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
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- 125000005385 peroxodisulfate group Chemical group 0.000 description 3
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- 238000011417 postcuring Methods 0.000 description 3
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- 230000035882 stress Effects 0.000 description 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
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- 150000001721 carbon Chemical class 0.000 description 2
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- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
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- 125000006551 perfluoro alkylene group Chemical group 0.000 description 2
- FYJQJMIEZVMYSD-UHFFFAOYSA-N perfluoro-2-butyltetrahydrofuran Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)OC(F)(F)C(F)(F)C1(F)F FYJQJMIEZVMYSD-UHFFFAOYSA-N 0.000 description 2
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- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- PGFXOWRDDHCDTE-UHFFFAOYSA-N hexafluoropropylene oxide Chemical compound FC(F)(F)C1(F)OC1(F)F PGFXOWRDDHCDTE-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
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- 229960001545 hydrotalcite Drugs 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229940117601 lead diphosphate Drugs 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004811 liquid chromatography Methods 0.000 description 1
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- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
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- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- DYUWTXWIYMHBQS-UHFFFAOYSA-N n-prop-2-enylprop-2-en-1-amine Chemical compound C=CCNCC=C DYUWTXWIYMHBQS-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 1
- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 1
- 229920005548 perfluoropolymer Polymers 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
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- 239000004014 plasticizer Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
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- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- UVWPITJZIUKWRR-UHFFFAOYSA-N propyl hypofluorite Chemical class C[CH][CH]OF UVWPITJZIUKWRR-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
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- 238000000518 rheometry Methods 0.000 description 1
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- 239000004065 semiconductor Substances 0.000 description 1
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- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- UUCCCPNEFXQJEL-UHFFFAOYSA-L strontium dihydroxide Chemical compound [OH-].[OH-].[Sr+2] UUCCCPNEFXQJEL-UHFFFAOYSA-L 0.000 description 1
- 229910001866 strontium hydroxide Inorganic materials 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-N sulfurothioic S-acid Chemical compound OS(O)(=O)=S DHCDFWKWKRSZHF-UHFFFAOYSA-N 0.000 description 1
- PFBLRDXPNUJYJM-UHFFFAOYSA-N tert-butyl 2-methylpropaneperoxoate Chemical compound CC(C)C(=O)OOC(C)(C)C PFBLRDXPNUJYJM-UHFFFAOYSA-N 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- KJWHEZXBZQXVSA-UHFFFAOYSA-N tris(prop-2-enyl) phosphite Chemical compound C=CCOP(OCC=C)OCC=C KJWHEZXBZQXVSA-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
- C08F214/262—Tetrafluoroethene with fluorinated vinyl ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/28—Emulsion polymerisation with the aid of emulsifying agents cationic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/002—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds
- C08G65/005—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens
- C08G65/007—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from unsaturated compounds containing halogens containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/095—Carboxylic acids containing halogens
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/18—Applications used for pipes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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| US201361914457P | 2013-12-11 | 2013-12-11 | |
| US61/914,457 | 2013-12-11 |
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| TW201533126A TW201533126A (zh) | 2015-09-01 |
| TWI653277B true TWI653277B (zh) | 2019-03-11 |
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| EP (2) | EP3597676B1 (https=) |
| JP (1) | JP6605471B2 (https=) |
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| CN (1) | CN105814102A (https=) |
| TW (1) | TWI653277B (https=) |
| WO (1) | WO2015088784A2 (https=) |
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| US20200055971A1 (en) * | 2016-11-09 | 2020-02-20 | 3M Innovative Properties Company | Peroxide curable partially fluorinated polymer |
| US11292763B2 (en) | 2017-05-19 | 2022-04-05 | 3M Innovative Properties Company | Methods of making a polyfluorinated allyl ether and compounds relating to the methods |
| JPWO2019009250A1 (ja) * | 2017-07-05 | 2020-05-07 | Ａｇｃ株式会社 | 含フッ素弾性共重合体組成物および架橋ゴム物品 |
| CN112262172B (zh) | 2018-06-12 | 2023-08-01 | 3M创新有限公司 | 包含胺固化剂的含氟聚合物涂料组合物、经涂覆的基底以及相关方法 |
| WO2019239320A1 (en) | 2018-06-12 | 2019-12-19 | 3M Innovative Properties Company | Fluoropolymer compositions comprising fluorinated additives, coated substrates and methods |
| EP3824001A1 (en) * | 2018-07-20 | 2021-05-26 | 3M Innovative Properties Company | Tetrafluroethylene fluoropolymers containing perfluorinated allyl ethers |
| JP2021535261A (ja) | 2018-08-27 | 2021-12-16 | スリーエム イノベイティブ プロパティズ カンパニー | 内部フッ素化可塑剤を含む過酸化物硬化性高フッ素化ポリマー及びそれからの物品 |
| WO2020116394A1 (ja) | 2018-12-04 | 2020-06-11 | 株式会社バルカー | エラストマー組成物及びシール材 |
| CN109762091B (zh) * | 2018-12-29 | 2021-01-15 | 山东华夏神舟新材料有限公司 | 四氟乙烯基共聚物及其制备方法 |
| EP4055109A1 (en) | 2019-11-04 | 2022-09-14 | 3M Innovative Properties Company | Fluoropolymer compositions comprising a curing agent with ethylenically unsaturated and electron donor groups, and substrates coated therewith |
| WO2021088198A1 (en) | 2019-11-04 | 2021-05-14 | 3M Innovative Properties Company | Electronic telecommunications articles comprising crosslinked fluoropolymers and methods |
| CN114230737B (zh) * | 2020-09-09 | 2023-08-01 | 中昊晨光化工研究院有限公司 | 一种全氟醚氟橡胶及其制备方法和应用 |
| US20240209217A1 (en) | 2021-05-05 | 2024-06-27 | 3M Innovative Properties Company | Fluoropolymer compositions comprising uncrosslinked fluoropolymer suitable for copper and electronic telecommunications articles |
| US20240194371A1 (en) | 2021-05-05 | 2024-06-13 | 3M Innovative Properties Company | Fluoropolymer compositions comprising fluoropolymer with polymerized unsaturated fluorinated alkyl ether suitable for copper and electronic telecommunications articles |
| WO2022234365A1 (en) | 2021-05-05 | 2022-11-10 | 3M Innovative Properties Company | Fluoropolymer compositions comprising amorphous fluoropolymer and crystalline fluoropolymer suitable for copper and electronic telecommunications articles |
| WO2023042005A1 (en) | 2021-09-16 | 2023-03-23 | 3M Innovative Properties Company | Core shell fluoropolmyers with functional groups suitable for copper and electronic telecommunications articles |
| CN116063640B (zh) * | 2021-11-04 | 2024-09-27 | 中昊晨光化工研究院有限公司 | 一种耐高温全氟醚氟橡胶及其制备方法 |
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| US3467638A (en) | 1967-03-07 | 1969-09-16 | Du Pont | Fluorinated cure-site monomers and vulcanizable fluorocarbon polymers made therewith |
| US3682872A (en) | 1970-03-18 | 1972-08-08 | Du Pont | Perfluoro(3-phenoxypropyl vinyl ether) monomer and copolymers made therefrom |
| US4035565A (en) | 1975-03-27 | 1977-07-12 | E. I. Du Pont De Nemours And Company | Fluoropolymer containing a small amount of bromine-containing olefin units |
| US4281092A (en) | 1978-11-30 | 1981-07-28 | E. I. Du Pont De Nemours And Company | Vulcanizable fluorinated copolymers |
| DE3662142D1 (en) * | 1985-03-28 | 1989-03-30 | Daikin Ind Ltd | Novel fluorovinyl ether and copolymer comprising the same |
| US4694045A (en) * | 1985-12-11 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Base resistant fluoroelastomers |
| JPS63238115A (ja) | 1987-03-27 | 1988-10-04 | Asahi Glass Co Ltd | 環状構造を有する含フツ素共重合体の製造法 |
| US4897457A (en) | 1987-08-14 | 1990-01-30 | Asahi Glass Company Ltd. | Novel fluorine-containing cyclic polymer |
| US4972038A (en) | 1989-05-19 | 1990-11-20 | E. I. Du Pont De Nemours And Company | Cyano-containing perfluoropolymers having iodine curesites |
| DE69617042T2 (de) | 1995-12-28 | 2002-06-06 | Daikin Industries, Ltd. | Fluorhaltige, elastische copolymere, härtbare zusammensetzung und daraus hergestellte dichtungsmasse |
| CN1083440C (zh) * | 1996-07-01 | 2002-04-24 | 大金工业株式会社 | 氟化三聚异氰尿酸三烯丙酯、含有该物质的硫化用弹性体的组合物以及硫化方法 |
| US6114452A (en) | 1996-11-25 | 2000-09-05 | E. I. Du Pont De Nemours And Company | Perfluoroelastomer composition having excellent heat stability |
| WO2002044264A2 (en) | 2000-12-01 | 2002-06-06 | 3M Innovative Properties Company | Curable fluoroelastomer compositions comprising hydro siloxanes or hydro silazanes |
| US6730760B2 (en) * | 2001-01-31 | 2004-05-04 | 3M Innovative Properties Company | Perfluoroelastomers having a low glass transition temperature and method of making them |
| JP4491547B2 (ja) * | 2002-04-23 | 2010-06-30 | Ｎｏｋ株式会社 | 含フッ素エラストマー組成物 |
| JP2004059597A (ja) * | 2002-07-24 | 2004-02-26 | Daikin Ind Ltd | フッ素ゴム共重合体 |
| US7312289B2 (en) | 2003-03-03 | 2007-12-25 | Unimatec Co., Ltd. | Fluorine-containing elastomer and its composition |
| JP2006036861A (ja) | 2004-07-23 | 2006-02-09 | Daikin Ind Ltd | 加硫可能な含フッ素エラストマーの製造方法 |
| GB0427913D0 (en) * | 2004-12-21 | 2005-01-19 | 3M Innovative Properties Co | Fluoropolymer for making a fluoroelastomer |
| US7671112B2 (en) | 2005-07-15 | 2010-03-02 | 3M Innovative Properties Company | Method of making fluoropolymer dispersion |
| JP5131198B2 (ja) | 2006-12-26 | 2013-01-30 | ダイキン工業株式会社 | 含フッ素エラストマーの製造方法および該製造方法により得られる含フッ素エラストマー |
| US8198386B2 (en) * | 2007-04-16 | 2012-06-12 | Daikin Industries, Ltd. | Fluorine-containing elastomer composition and sealing material made of same |
| EP2154204A4 (en) * | 2007-05-16 | 2011-11-23 | Daikin Ind Ltd | FINE PARTICLES OF NETWORKED FLUOROUS ELASTOMER, METHOD OF MANUFACTURING THEREOF AND COMPOSITION |
| JP5617243B2 (ja) * | 2007-11-28 | 2014-11-05 | ユニマテック株式会社 | フルオロエラストマーの製造法 |
| TW200940572A (en) | 2008-01-28 | 2009-10-01 | Asahi Glass Co Ltd | Curable composition, fluorine-containing cured product, optical material using the cured product, and light-emitting device |
| US8604137B2 (en) | 2008-02-29 | 2013-12-10 | 3M Innovative Properties Company | Perfluoroelastomers with low carbonyl endgroup ratios |
| WO2010076876A1 (en) | 2008-12-29 | 2010-07-08 | Daikin Industries, Ltd. | Perfluoroelastomer composition and crosslinked molded article made by crosslinking and molding said perfluoroelastomer composition |
| JP5644504B2 (ja) | 2009-01-16 | 2014-12-24 | 旭硝子株式会社 | 含フッ素弾性共重合体およびその製造方法、架橋ゴム物品 |
| TWI496796B (zh) | 2009-02-13 | 2015-08-21 | Solvay Solexis Spa | 全氟彈性體 |
| CN103221479B (zh) * | 2010-11-18 | 2016-06-22 | 3M创新有限公司 | 凝聚无定形含氟聚合物胶乳的方法 |
| CN103370346B (zh) * | 2010-12-20 | 2016-12-14 | 索尔维特殊聚合物意大利有限公司 | 低粘度氟弹性体 |
| CN104583253A (zh) * | 2012-08-21 | 2015-04-29 | 旭硝子株式会社 | 固化性含氟聚合物、其制造方法以及含氟聚合物固化物 |
| JP6571639B2 (ja) | 2013-06-14 | 2019-09-04 | スリーエム イノベイティブ プロパティズ カンパニー | ビニルペルフルオロアルキル又はビニルペルフルオロアルキレンオキシドペルフルオロビニルエーテルに由来するモノマー単位を含むフルオロポリマー |
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2014
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| CN105814102A (zh) | 2016-07-27 |
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| EP3597676B1 (en) | 2020-12-23 |
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| US20160280824A1 (en) | 2016-09-29 |
| EP3080174A2 (en) | 2016-10-19 |
| EP3597676A1 (en) | 2020-01-22 |
| TW201533126A (zh) | 2015-09-01 |
| WO2015088784A2 (en) | 2015-06-18 |
| KR102268379B1 (ko) | 2021-06-23 |
| EP3080174B1 (en) | 2019-09-18 |
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