TWI637004B - 摻雜共軛聚合物及裝置 - Google Patents
摻雜共軛聚合物及裝置 Download PDFInfo
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- TWI637004B TWI637004B TW100116358A TW100116358A TWI637004B TW I637004 B TWI637004 B TW I637004B TW 100116358 A TW100116358 A TW 100116358A TW 100116358 A TW100116358 A TW 100116358A TW I637004 B TWI637004 B TW I637004B
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- Prior art keywords
- composition
- polymer
- conjugated polymer
- dopant
- polythiophene
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- 229920000547 conjugated polymer Polymers 0.000 title claims abstract description 122
- 239000000203 mixture Substances 0.000 claims abstract description 160
- -1 silver tetrakis(pentafluorophenyl)borate Chemical compound 0.000 claims abstract description 110
- 239000002019 doping agent Substances 0.000 claims abstract description 108
- 229920000123 polythiophene Polymers 0.000 claims abstract description 71
- 239000000463 material Substances 0.000 claims abstract description 50
- 230000005525 hole transport Effects 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims description 78
- 229920000642 polymer Polymers 0.000 claims description 72
- 239000011159 matrix material Substances 0.000 claims description 55
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 36
- 229910052709 silver Inorganic materials 0.000 claims description 35
- 239000004332 silver Substances 0.000 claims description 34
- 150000001450 anions Chemical class 0.000 claims description 30
- 239000007787 solid Substances 0.000 claims description 30
- 229910052751 metal Inorganic materials 0.000 claims description 29
- 239000002184 metal Substances 0.000 claims description 29
- 238000002347 injection Methods 0.000 claims description 24
- 239000007924 injection Substances 0.000 claims description 24
- 239000000843 powder Substances 0.000 claims description 23
- 125000003545 alkoxy group Chemical group 0.000 claims description 22
- 229910052794 bromium Inorganic materials 0.000 claims description 19
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 18
- 229910052801 chlorine Inorganic materials 0.000 claims description 18
- 229910052731 fluorine Inorganic materials 0.000 claims description 17
- 229910052740 iodine Inorganic materials 0.000 claims description 17
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 14
- 229910052796 boron Inorganic materials 0.000 claims description 14
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims description 11
- 239000007795 chemical reaction product Substances 0.000 claims description 9
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 6
- 229920005613 synthetic organic polymer Polymers 0.000 claims description 2
- URSLCTBXQMKCFE-UHFFFAOYSA-N dihydrogenborate Chemical compound OB(O)[O-] URSLCTBXQMKCFE-UHFFFAOYSA-N 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 239000000758 substrate Substances 0.000 abstract description 30
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 abstract description 20
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- 238000000034 method Methods 0.000 description 34
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- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 23
- 125000001424 substituent group Chemical group 0.000 description 22
- DHXVGJBLRPWPCS-UHFFFAOYSA-N Tetrahydropyran Chemical compound C1CCOCC1 DHXVGJBLRPWPCS-UHFFFAOYSA-N 0.000 description 21
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- 125000003118 aryl group Chemical group 0.000 description 20
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- 150000003839 salts Chemical class 0.000 description 13
- 229910052787 antimony Inorganic materials 0.000 description 12
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 12
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Classifications
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- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
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- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
- C08G61/122—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides
- C08G61/123—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds
- C08G61/126—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule derived from five- or six-membered heterocyclic compounds, other than imides derived from five-membered heterocyclic compounds with a five-membered ring containing one sulfur atom in the ring
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- H—ELECTRICITY
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- H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
- H10K85/30—Coordination compounds
- H10K85/321—Metal complexes comprising a group IIIA element, e.g. Tris (8-hydroxyquinoline) gallium [Gaq3]
- H10K85/322—Metal complexes comprising a group IIIA element, e.g. Tris (8-hydroxyquinoline) gallium [Gaq3] comprising boron
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- C08G2261/322—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed
- C08G2261/3223—Monomer units or repeat units incorporating structural elements in the main chain incorporating heteroaromatic structural elements in the main chain non-condensed containing one or more sulfur atoms as the only heteroatom, e.g. thiophene
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- C08G2261/50—Physical properties
- C08G2261/51—Charge transport
- C08G2261/512—Hole transport
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- C08G2261/70—Post-treatment
- C08G2261/79—Post-treatment doping
- C08G2261/792—Post-treatment doping with low-molecular weight dopants
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- C08G2261/90—Applications
- C08G2261/91—Photovoltaic applications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G2261/90—Applications
- C08G2261/92—TFT applications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G2261/94—Applications in sensors, e.g. biosensors
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/549—Organic PV cells
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- Life Sciences & Earth Sciences (AREA)
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| US9203030B2 (en) * | 2011-05-16 | 2015-12-01 | Georgia Tech Research Corporation | Recyclable organic solar cells on substrates comprising cellulose nanocrystals (CNC) |
| EP2764518A1 (en) * | 2011-10-04 | 2014-08-13 | Plextronics, Inc. | Improved doping methods for hole injection and transport layers |
| JP6098042B2 (ja) * | 2012-04-24 | 2017-03-22 | 日立化成株式会社 | 色変化防止剤、該色変化防止剤を含むインク組成物、該インク組成物を用いて形成した有機薄膜、有機エレクトロニクス素子、有機エレクトロルミネセンス素子、表示素子、照明装置、及び表示装置 |
| WO2014039687A1 (en) | 2012-09-06 | 2014-03-13 | Plextronics, Inc. | Electroluminescent devices comprising insulator-free metal grids |
| US10003024B2 (en) * | 2012-09-27 | 2018-06-19 | Merck Patent Gmbh | Materials for organic electroluminescent devices |
| JP6152648B2 (ja) * | 2013-01-25 | 2017-06-28 | 日本ケミコン株式会社 | 有機エレクトロルミネッセンス素子及びその製造方法 |
| WO2014141367A1 (ja) * | 2013-03-11 | 2014-09-18 | 昭和電工株式会社 | 導電性重合体含有分散液の製造方法 |
| WO2015179665A1 (en) * | 2014-05-22 | 2015-11-26 | Rhodia Operations | Polymer compositions, polymer films, and electronic devices containing such films |
| US10435579B2 (en) | 2014-12-15 | 2019-10-08 | Nissan Chemical Industries, Ltd. | Compositions containing hole carrier materials and fluoropolymers, and uses thereof |
| WO2016100321A1 (en) * | 2014-12-15 | 2016-06-23 | Solvay Usa, Inc. | Compositions containing hole carrier materials and poly(aryl ether sulfone)s, and uses thereof |
| EP3325560A4 (en) | 2015-07-17 | 2019-03-27 | Nissan Chemical Corporation | Nonaqueous ink compositions containing metal nanoparticles for use in organic electronics |
| EP3364475B1 (en) * | 2017-02-20 | 2024-05-29 | Novaled GmbH | Electronic semiconducting device, method for preparing the electronic semiconducting device and compound |
| KR102478039B1 (ko) * | 2017-02-20 | 2022-12-14 | 노발레드 게엠베하 | 전자 반도전성 소자, 전자 반도전성 소자를 제조하기 위한 방법, 및 화합물 |
| JP2018203889A (ja) * | 2017-06-06 | 2018-12-27 | 日立化成株式会社 | 硬化性重合体、重合液、導電性膜及び有機発光素子 |
| CN108032641B (zh) * | 2017-12-07 | 2020-01-17 | 南京邮电大学 | 一种印刷制备大面积图案化有机发光薄膜的方法 |
| US11315739B2 (en) * | 2017-12-28 | 2022-04-26 | Panasonic Inteilectual Property Management Co., Ltd. | Electrolytic capacitor and method for manufacturing same |
| WO2020262419A1 (ja) * | 2019-06-26 | 2020-12-30 | 日産化学株式会社 | 電荷輸送性ワニス |
| CN111192966B (zh) * | 2020-01-09 | 2023-07-25 | 通威太阳能(眉山)有限公司 | 钙钛矿太阳能电池及其制备方法 |
| JP7637950B2 (ja) * | 2020-05-01 | 2025-03-03 | 国立大学法人 東京大学 | 導体材料 |
| EP4106034B1 (en) * | 2021-06-18 | 2025-01-08 | Novaled GmbH | Organic electronic device comprising a metal compound comprising metal cation and at least one borate anion of formula (i), display device comprising the organic electronic device, use of the metal compound in an organic electronic device, and method for preparation of the organic electronic device |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003238773A (ja) * | 2002-02-14 | 2003-08-27 | Nippon Telegr & Teleph Corp <Ntt> | 導電性組成物 |
| WO2009126918A1 (en) * | 2008-04-11 | 2009-10-15 | Plextronics, Inc. | Doped conjugated polymers, devices, and methods of making devices |
Family Cites Families (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4356429A (en) | 1980-07-17 | 1982-10-26 | Eastman Kodak Company | Organic electroluminescent cell |
| US4539507A (en) | 1983-03-25 | 1985-09-03 | Eastman Kodak Company | Organic electroluminescent devices having improved power conversion efficiencies |
| US4737557A (en) | 1986-03-20 | 1988-04-12 | Agency Of Industrial Science And Technology | 3-N-higher alkylthiophene polymer and composition thereof |
| FR2596566B1 (fr) | 1986-04-01 | 1989-03-10 | Solvay | Polymeres conducteurs derives de 3-alkylthiophenes, procede pour leur fabrication et dispositifs electroconducteurs les contenant |
| GB8909011D0 (en) | 1989-04-20 | 1989-06-07 | Friend Richard H | Electroluminescent devices |
| US5047687A (en) | 1990-07-26 | 1991-09-10 | Eastman Kodak Company | Organic electroluminescent device with stabilized cathode |
| GB9018698D0 (en) | 1990-08-24 | 1990-10-10 | Lynxvale Ltd | Semiconductive copolymers for use in electroluminescent devices |
| JP2998268B2 (ja) * | 1991-04-19 | 2000-01-11 | 三菱化学株式会社 | 有機電界発光素子 |
| US5331183A (en) | 1992-08-17 | 1994-07-19 | The Regents Of The University Of California | Conjugated polymer - acceptor heterojunctions; diodes, photodiodes, and photovoltaic cells |
| US5834080A (en) | 1994-10-18 | 1998-11-10 | Xerox Corporation | Controllably conductive polymer compositions for development systems |
| US5853906A (en) | 1997-10-14 | 1998-12-29 | Xerox Corporation | Conductive polymer compositions and processes thereof |
| US6166172A (en) | 1999-02-10 | 2000-12-26 | Carnegie Mellon University | Method of forming poly-(3-substituted) thiophenes |
| AT410729B (de) | 2000-04-27 | 2003-07-25 | Qsel Quantum Solar Energy Linz | Photovoltaische zelle mit einer photoaktiven schicht aus zwei molekularen organischen komponenten |
| AT411306B (de) | 2000-04-27 | 2003-11-25 | Qsel Quantum Solar Energy Linz | Photovoltaische zelle mit einer photoaktiven schicht aus zwei molekularen organischen komponenten |
| US6602974B1 (en) | 2001-12-04 | 2003-08-05 | Carnegie Mellon University | Polythiophenes, block copolymers made therefrom, and methods of forming the same |
| US20040113127A1 (en) | 2002-12-17 | 2004-06-17 | Min Gary Yonggang | Resistor compositions having a substantially neutral temperature coefficient of resistance and methods and compositions relating thereto |
| US7070867B2 (en) | 2003-12-05 | 2006-07-04 | The University Of Southern California | OLEDs having n-type doping |
| KR20070024464A (ko) | 2003-12-10 | 2007-03-02 | 노쓰웨스턴유니버시티 | 정공 수송층 조성물 및 관련 다이오드 장치 |
| KR100963457B1 (ko) | 2004-03-11 | 2010-06-17 | 미쓰비시 가가꾸 가부시키가이샤 | 전하 수송막용 조성물 및 이온 화합물, 이를 이용한 전하수송막 및 유기 전계 발광 장치, 및 유기 전계 발광 장치의제조 방법 및 전하 수송막의 제조 방법 |
| US7785740B2 (en) | 2004-04-09 | 2010-08-31 | Air Products And Chemicals, Inc. | Overcharge protection for electrochemical cells |
| CN100583485C (zh) | 2004-09-24 | 2010-01-20 | 普莱克斯托尼克斯公司 | 含杂原子立体规则性聚（3-取代噻吩）的光电池 |
| EP1805826B1 (en) | 2004-09-24 | 2010-03-24 | Plextronics, Inc. | Heteroatomic regioregular poly(3-substitutedthiophenes) in electroluminescent devices |
| CN101107258A (zh) * | 2005-02-04 | 2008-01-16 | 株式会社日本触媒 | 硼酸盐和近红外线吸收材料 |
| US7887920B2 (en) | 2005-02-04 | 2011-02-15 | Nippon Shokubai Co., Ltd. | Borate and near-infrared ray absorption material |
| EP1851048B1 (en) | 2005-02-10 | 2016-06-29 | Solvay USA Inc. | Hole injection/transport layer compositions and devices |
| CN101563388B (zh) * | 2006-07-21 | 2013-05-15 | 普莱克斯托尼克斯公司 | 导电聚合物的磺化和oled器件、光电器件以及esd器件 |
| KR100860411B1 (ko) | 2006-12-08 | 2008-09-26 | 한국전자통신연구원 | 멀티캐스트를 이용한 양방향 지역 광고 시스템 및 방법 |
| WO2009102027A1 (ja) | 2008-02-15 | 2009-08-20 | Mitsubishi Chemical Corporation | 共役ポリマー、不溶化ポリマー、有機電界発光素子材料、有機電界発光素子用組成物、ポリマーの製造方法、有機電界発光素子、有機ｅｌディスプレイ、及び有機ｅｌ照明 |
| ATE540069T1 (de) | 2008-02-29 | 2012-01-15 | Plextronics Inc | Planierungsmittel und vorrichtungen |
| EP2257594B1 (en) | 2008-03-06 | 2014-11-12 | Plextronics, Inc. | Modified planarizing agents and devices |
| EP2291427B1 (en) | 2008-06-09 | 2016-03-30 | Solvay USA Inc. | Sulfonated polythiophenes comprising fused ring repeat units |
| CN102077381B (zh) | 2008-06-27 | 2014-10-22 | 通用显示公司 | 可交联的离子掺杂剂 |
| WO2010051259A1 (en) | 2008-10-27 | 2010-05-06 | Plextronics, Inc. | Polyarylamine ketones |
| US8283002B2 (en) | 2008-11-18 | 2012-10-09 | Plextronics, Inc. | Aminobenzene compositions and related devices and methods |
| EP2360162A1 (en) | 2008-12-01 | 2011-08-24 | Sumitomo Chemical Company, Limited | Luminescent silver complexes |
| JP2010198793A (ja) * | 2009-02-23 | 2010-09-09 | Fujifilm Corp | 導電性膜、導電性ポリマー組成物、導電性ポリマー材料、デバイス、及び抵抗膜式タッチパネル |
| WO2011143196A1 (en) * | 2010-05-11 | 2011-11-17 | Plextronics, Inc. | Doping conjugated polymers and devices |
| CN202676329U (zh) | 2012-07-04 | 2013-01-16 | 永运电子有限公司 | 一种压力传感器 |
-
2011
- 2011-05-10 WO PCT/US2011/035897 patent/WO2011143196A1/en not_active Ceased
- 2011-05-10 CN CN2011800225508A patent/CN102884102A/zh active Pending
- 2011-05-10 EP EP11720688A patent/EP2569347A1/en not_active Withdrawn
- 2011-05-10 CN CN201710388821.0A patent/CN107236258A/zh active Pending
- 2011-05-10 JP JP2013510236A patent/JP5770268B2/ja active Active
- 2011-05-10 TW TW100116358A patent/TWI637004B/zh active
- 2011-05-10 US US13/104,598 patent/US8674047B2/en not_active Expired - Fee Related
- 2011-05-10 KR KR1020127031717A patent/KR101848523B1/ko active Active
-
2014
- 2014-02-10 US US14/176,951 patent/US20140217334A1/en not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003238773A (ja) * | 2002-02-14 | 2003-08-27 | Nippon Telegr & Teleph Corp <Ntt> | 導電性組成物 |
| WO2009126918A1 (en) * | 2008-04-11 | 2009-10-15 | Plextronics, Inc. | Doped conjugated polymers, devices, and methods of making devices |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20130113930A (ko) | 2013-10-16 |
| WO2011143196A1 (en) | 2011-11-17 |
| JP2013526636A (ja) | 2013-06-24 |
| KR101848523B1 (ko) | 2018-04-12 |
| US20110278559A1 (en) | 2011-11-17 |
| EP2569347A1 (en) | 2013-03-20 |
| CN102884102A (zh) | 2013-01-16 |
| CN107236258A (zh) | 2017-10-10 |
| US8674047B2 (en) | 2014-03-18 |
| JP5770268B2 (ja) | 2015-08-26 |
| TW201200537A (en) | 2012-01-01 |
| US20140217334A1 (en) | 2014-08-07 |
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