TWI633932B - 用於半導體之多價光催化非均相材料 - Google Patents
用於半導體之多價光催化非均相材料 Download PDFInfo
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- TWI633932B TWI633932B TW103109809A TW103109809A TWI633932B TW I633932 B TWI633932 B TW I633932B TW 103109809 A TW103109809 A TW 103109809A TW 103109809 A TW103109809 A TW 103109809A TW I633932 B TWI633932 B TW I633932B
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- Prior art keywords
- type semiconductor
- heterogeneous material
- copper
- material according
- compound
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- 239000004065 semiconductor Substances 0.000 title claims abstract description 228
- 239000000463 material Substances 0.000 title claims abstract description 198
- 230000001699 photocatalysis Effects 0.000 title abstract description 34
- 229910052751 metal Inorganic materials 0.000 claims abstract description 37
- 239000002184 metal Substances 0.000 claims abstract description 36
- 238000004891 communication Methods 0.000 claims abstract description 13
- 229910044991 metal oxide Inorganic materials 0.000 claims abstract description 8
- 230000003647 oxidation Effects 0.000 claims abstract description 7
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 7
- 239000010936 titanium Substances 0.000 claims description 169
- 150000001875 compounds Chemical class 0.000 claims description 106
- 239000010949 copper Substances 0.000 claims description 101
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 63
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 47
- 229910052802 copper Inorganic materials 0.000 claims description 44
- 238000000034 method Methods 0.000 claims description 42
- 230000001590 oxidative effect Effects 0.000 claims description 42
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 40
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 36
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 36
- 239000011941 photocatalyst Substances 0.000 claims description 36
- 239000011701 zinc Substances 0.000 claims description 30
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical group [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 27
- 229910052799 carbon Inorganic materials 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 27
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 25
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 22
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 21
- -1 metal oxide compound Chemical class 0.000 claims description 21
- 229910052760 oxygen Inorganic materials 0.000 claims description 21
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 17
- 229910052707 ruthenium Inorganic materials 0.000 claims description 17
- 239000005751 Copper oxide Substances 0.000 claims description 15
- 229910000431 copper oxide Inorganic materials 0.000 claims description 15
- 229910052718 tin Inorganic materials 0.000 claims description 15
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 14
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 14
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 13
- 229910052725 zinc Inorganic materials 0.000 claims description 12
- 229910052697 platinum Inorganic materials 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 229910052720 vanadium Inorganic materials 0.000 claims description 10
- 229910052721 tungsten Inorganic materials 0.000 claims description 9
- 239000010937 tungsten Substances 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 8
- 229910017682 MgTi Inorganic materials 0.000 claims description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
- 229910000510 noble metal Inorganic materials 0.000 claims description 8
- 239000010948 rhodium Substances 0.000 claims description 8
- 229910052703 rhodium Inorganic materials 0.000 claims description 8
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 8
- 229910052746 lanthanum Inorganic materials 0.000 claims description 7
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910002367 SrTiO Inorganic materials 0.000 claims description 6
- 229910017052 cobalt Inorganic materials 0.000 claims description 6
- 239000010941 cobalt Substances 0.000 claims description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 6
- 229910052738 indium Inorganic materials 0.000 claims description 6
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 6
- 244000005700 microbiome Species 0.000 claims description 6
- 229910052762 osmium Inorganic materials 0.000 claims description 6
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical group [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229910008839 Sn—Ti Inorganic materials 0.000 claims description 5
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052735 hafnium Inorganic materials 0.000 claims description 5
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 5
- 230000002147 killing effect Effects 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 229910052759 nickel Inorganic materials 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 229910052726 zirconium Inorganic materials 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 4
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 4
- 239000000356 contaminant Substances 0.000 claims description 4
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 4
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- 239000010931 gold Substances 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052763 palladium Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 229910052715 tantalum Inorganic materials 0.000 claims description 4
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 4
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical group [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 3
- 229910052750 molybdenum Inorganic materials 0.000 claims description 3
- 239000011733 molybdenum Chemical group 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical group O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- BPUBBGLMJRNUCC-UHFFFAOYSA-N oxygen(2-);tantalum(5+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Ta+5].[Ta+5] BPUBBGLMJRNUCC-UHFFFAOYSA-N 0.000 claims description 2
- 229910001936 tantalum oxide Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 150000004706 metal oxides Chemical class 0.000 abstract description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 66
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 35
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 27
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical group CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 26
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 25
- 239000008103 glucose Substances 0.000 description 25
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- 239000000203 mixture Substances 0.000 description 24
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- 239000000758 substrate Substances 0.000 description 18
- 235000001014 amino acid Nutrition 0.000 description 17
- 229940024606 amino acid Drugs 0.000 description 17
- 230000000694 effects Effects 0.000 description 17
- 150000001413 amino acids Chemical class 0.000 description 16
- 238000011068 loading method Methods 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- 239000003570 air Substances 0.000 description 14
- 239000007864 aqueous solution Substances 0.000 description 14
- 239000008367 deionised water Substances 0.000 description 14
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- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 12
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 12
- 238000002441 X-ray diffraction Methods 0.000 description 12
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- VMQMZMRVKUZKQL-UHFFFAOYSA-N Cu+ Chemical compound [Cu+] VMQMZMRVKUZKQL-UHFFFAOYSA-N 0.000 description 10
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- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
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- 238000002474 experimental method Methods 0.000 description 8
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- 238000000354 decomposition reaction Methods 0.000 description 7
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- FJOLTQXXWSRAIX-UHFFFAOYSA-K silver phosphate Chemical compound [Ag+].[Ag+].[Ag+].[O-]P([O-])([O-])=O FJOLTQXXWSRAIX-UHFFFAOYSA-K 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 229910003468 tantalcarbide Inorganic materials 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- FGMPLJWBKKVCDB-UHFFFAOYSA-N trans-L-hydroxy-proline Natural products ON1CCCC1C(O)=O FGMPLJWBKKVCDB-UHFFFAOYSA-N 0.000 description 1
- 238000004627 transmission electron microscopy Methods 0.000 description 1
- OUYCCCASQSFEME-UHFFFAOYSA-N tyrosine Natural products OC(=O)C(N)CC1=CC=C(O)C=C1 OUYCCCASQSFEME-UHFFFAOYSA-N 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000001429 visible spectrum Methods 0.000 description 1
- 238000011179 visual inspection Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/007—Mixed salts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/72—Copper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US13/840,859 | 2013-03-15 | ||
| US13/840,859 US9376332B2 (en) | 2013-03-15 | 2013-03-15 | Multivalence photocatalytic semiconductor elements |
| US201361835399P | 2013-06-14 | 2013-06-14 | |
| US61/835,399 | 2013-06-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| TW201500112A TW201500112A (zh) | 2015-01-01 |
| TWI633932B true TWI633932B (zh) | 2018-09-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW103109809A TWI633932B (zh) | 2013-03-15 | 2014-03-14 | 用於半導體之多價光催化非均相材料 |
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|---|---|
| EP (1) | EP2969186A1 (de) |
| JP (1) | JP6462658B2 (de) |
| CN (1) | CN105163847B (de) |
| TW (1) | TWI633932B (de) |
| WO (1) | WO2014151861A1 (de) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP6685328B2 (ja) | 2015-05-14 | 2020-04-22 | 日東電工株式会社 | 光触媒コーティングされた顆粒およびそれを作る方法 |
| RU2624620C1 (ru) * | 2016-04-14 | 2017-07-04 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный университет" (СПбГУ) | Способ получения фотокатализатора на основе полупроводниковой нано-гетероструктуры CdS-WO3-TiO2 |
| CN105797740B (zh) * | 2016-05-09 | 2018-04-24 | 国家纳米科学中心 | 一种Fe掺杂的氧化钽立方体、其制备方法及用途 |
| JP6696838B2 (ja) * | 2016-06-16 | 2020-05-20 | 株式会社フジコー | 内装材及びその製造方法 |
| CN107519889B (zh) * | 2017-08-02 | 2020-06-30 | 肇庆市华师大光电产业研究院 | 一种铜掺杂三氧化钨复合纳米纤维材料的制备方法 |
| CN110538656B (zh) * | 2019-09-12 | 2021-04-30 | 中国科学院生态环境研究中心 | 一种用于光催化剂降解甲醛的催化剂及其制备方法和用途 |
| CN111185137A (zh) * | 2020-01-22 | 2020-05-22 | 青岛农业大学 | 一种利用辣椒秸秆制备同时具有磁性和光催化性的生物炭的方法 |
| JP7422552B2 (ja) * | 2020-02-03 | 2024-01-26 | 公益財団法人電磁材料研究所 | 光触媒 |
| WO2023122693A1 (en) * | 2021-12-21 | 2023-06-29 | Nitto Denko Corporation | Deactivation resistant catalytic materials and method for making the same |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101259422A (zh) * | 2008-04-24 | 2008-09-10 | 南开大学 | 高效率纳米Ti1－xO2－Snx/TiO2－x－Nx复合薄膜可见光催化剂的制备方法 |
| TW201036180A (en) * | 2009-03-26 | 2010-10-01 | Ritdisplay Corp | Photovoltaic cell structure |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3780592B2 (ja) * | 1995-12-21 | 2006-05-31 | 旭硝子株式会社 | 光触媒組成物とその製造方法および光触媒組成物付き基体 |
| JP4135907B2 (ja) * | 2003-03-25 | 2008-08-20 | コバレントマテリアル株式会社 | 可視光活性型光触媒粒子 |
| JP4135921B2 (ja) * | 2002-09-18 | 2008-08-20 | コバレントマテリアル株式会社 | 二酸化チタン微粒子およびその製造方法 |
| CN100475335C (zh) * | 2003-09-22 | 2009-04-08 | 中国科学院化学研究所 | 具有可见光响应的光催化剂及其制备方法和应用 |
| US20070154561A1 (en) | 2004-02-18 | 2007-07-05 | Nippon Shokubai Co., Ltd. | Metal oxide particle and its uses |
| WO2007136488A2 (en) | 2006-04-20 | 2007-11-29 | The Trustees Of Columbia University In The City Of New York | Copper oxide nanoparticle system |
| WO2008075615A1 (en) * | 2006-12-21 | 2008-06-26 | Semiconductor Energy Laboratory Co., Ltd. | Light-emitting element and light-emitting device |
| CN105536882A (zh) * | 2009-06-26 | 2016-05-04 | Toto株式会社 | 光催化剂涂装体及光催化剂涂布液 |
| JP2011224534A (ja) | 2009-09-16 | 2011-11-10 | Sumitomo Chemical Co Ltd | 光触媒複合体、およびこれを用いた光触媒機能製品 |
| KR20120082899A (ko) * | 2009-10-19 | 2012-07-24 | 고쿠리츠다이가쿠호우진 도쿄다이가쿠 | 바이러스를 불활화하는 방법 및 항바이러스성 부여 물품 |
| JP5129897B1 (ja) * | 2011-06-27 | 2013-01-30 | 昭和電工株式会社 | 銅化合物担持酸化チタン光触媒及びその製造方法 |
| CN102527421A (zh) * | 2011-11-10 | 2012-07-04 | 重庆工商大学 | C和N双掺杂纳米TiO2光催化剂及其制备方法 |
| CN102836715B (zh) * | 2012-08-27 | 2014-08-27 | 华中科技大学 | 一种可见光响应型CuxO-TiO2光催化剂及其制备方法 |
| CN103386306B (zh) * | 2013-08-07 | 2015-05-20 | 上海师范大学 | 一种Cu/CuxO/TiO2异质结可见光催化剂及其应用 |
-
2014
- 2014-03-13 EP EP14720807.8A patent/EP2969186A1/de not_active Withdrawn
- 2014-03-13 JP JP2016502184A patent/JP6462658B2/ja not_active Expired - Fee Related
- 2014-03-13 CN CN201480017897.7A patent/CN105163847B/zh active Active
- 2014-03-13 WO PCT/US2014/026580 patent/WO2014151861A1/en active Application Filing
- 2014-03-14 TW TW103109809A patent/TWI633932B/zh active
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| CN101259422A (zh) * | 2008-04-24 | 2008-09-10 | 南开大学 | 高效率纳米Ti1－xO2－Snx/TiO2－x－Nx复合薄膜可见光催化剂的制备方法 |
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Also Published As
| Publication number | Publication date |
|---|---|
| EP2969186A1 (de) | 2016-01-20 |
| JP2016512164A (ja) | 2016-04-25 |
| CN105163847A (zh) | 2015-12-16 |
| WO2014151861A1 (en) | 2014-09-25 |
| TW201500112A (zh) | 2015-01-01 |
| CN105163847B (zh) | 2018-04-03 |
| JP6462658B2 (ja) | 2019-01-30 |
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