TWI503170B - 氫化觸媒及藉由羰基化合物之氫化而製造醇類的方法 - Google Patents

氫化觸媒及藉由羰基化合物之氫化而製造醇類的方法 Download PDF

Info

Publication number
TWI503170B
TWI503170B TW097132379A TW97132379A TWI503170B TW I503170 B TWI503170 B TW I503170B TW 097132379 A TW097132379 A TW 097132379A TW 97132379 A TW97132379 A TW 97132379A TW I503170 B TWI503170 B TW I503170B
Authority
TW
Taiwan
Prior art keywords
hydrogenation
catalyst
mass
hydrogenation catalyst
reaction
Prior art date
Application number
TW097132379A
Other languages
English (en)
Chinese (zh)
Other versions
TW200927284A (en
Inventor
Alfred Kaizik
Thomas Quandt
Hans-Gerd Lueken
Wilfried Bueschken
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Publication of TW200927284A publication Critical patent/TW200927284A/zh
Application granted granted Critical
Publication of TWI503170B publication Critical patent/TWI503170B/zh

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/868—Chromium copper and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/143—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones
    • C07C29/145—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of ketones with hydrogen or hydrogen-containing gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/86—Chromium
    • B01J23/866—Nickel and chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
TW097132379A 2007-08-31 2008-08-25 氫化觸媒及藉由羰基化合物之氫化而製造醇類的方法 TWI503170B (zh)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE102007041380A DE102007041380A1 (de) 2007-08-31 2007-08-31 Hydrierkatalysator und Verfahren zur Herstellung von Alkoholen durch Hydrierung von Carbonylverbindungen

Publications (2)

Publication Number Publication Date
TW200927284A TW200927284A (en) 2009-07-01
TWI503170B true TWI503170B (zh) 2015-10-11

Family

ID=39817112

Family Applications (1)

Application Number Title Priority Date Filing Date
TW097132379A TWI503170B (zh) 2007-08-31 2008-08-25 氫化觸媒及藉由羰基化合物之氫化而製造醇類的方法

Country Status (10)

Country Link
US (1) US20110060169A1 (enExample)
EP (1) EP2180947B1 (enExample)
JP (1) JP5564714B2 (enExample)
KR (1) KR101518083B1 (enExample)
CN (1) CN101376104B (enExample)
AR (1) AR068199A1 (enExample)
DE (1) DE102007041380A1 (enExample)
ES (1) ES2476606T3 (enExample)
TW (1) TWI503170B (enExample)
WO (1) WO2009027135A1 (enExample)

Families Citing this family (51)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
DE102009001594A1 (de) 2009-03-17 2010-09-30 Evonik Oxeno Gmbh Verfahren zur Herstellung von alpha, beta-ungesättigten C10-Aldehyden
DE102009027406A1 (de) 2009-07-01 2011-01-05 Evonik Oxeno Gmbh Verfahren zur Herstellung von geruchsarmen n-Butan
DE102009028975A1 (de) 2009-08-28 2011-03-03 Evonik Oxeno Gmbh Esterderivate der 2,5-Furandicarbonsäure und ihre Verwendung als Weichmacher
DE102009045139A1 (de) 2009-09-30 2011-03-31 Evonik Oxeno Gmbh Herstellung von alpha,beta-ungesättigten Aldehyden mittels einer Reaktionsmischpumpe
DE102009045718A1 (de) * 2009-10-15 2011-04-21 Evonik Oxeno Gmbh Verfahren zur Herstellung von Decanolen durch Hydrierung von Decenalen
DE102010029924A1 (de) 2010-06-10 2011-12-15 Evonik Oxeno Gmbh Verfahren zur Regenerierung von gebrauchten Hydrierkatalysatoren
DE102011005608A1 (de) 2011-03-16 2012-09-20 Evonik Oxeno Gmbh Mischoxidzusammensetzungen und Verfahren zur Herstellung von Isoolefinen
CN103030528B (zh) * 2011-09-29 2015-08-12 中国石油化工股份有限公司 苯甲醛液相加氢制备苯甲醇
US9000234B2 (en) 2011-12-22 2015-04-07 Celanese International Corporation Calcination of modified support to prepare hydrogenation catalysts
US9233899B2 (en) 2011-12-22 2016-01-12 Celanese International Corporation Hydrogenation catalysts having an amorphous support
US9333496B2 (en) 2012-02-29 2016-05-10 Celanese International Corporation Cobalt/tin catalyst for producing ethanol
US9079172B2 (en) 2012-03-13 2015-07-14 Celanese International Corporation Promoters for cobalt-tin catalysts for reducing alkanoic acids
US8975200B2 (en) 2012-01-06 2015-03-10 Celanese International Corporation Hydrogenation catalysts with cobalt-modified supports
US9024086B2 (en) 2012-01-06 2015-05-05 Celanese International Corporation Hydrogenation catalysts with acidic sites
US8981164B2 (en) 2012-01-06 2015-03-17 Celanese International Corporation Cobalt and tin hydrogenation catalysts
US9050585B2 (en) 2012-02-10 2015-06-09 Celanese International Corporation Chemisorption of ethyl acetate during hydrogenation of acetic acid to ethanol
DE102012105878A1 (de) 2012-07-02 2014-01-02 Oxea Gmbh Verfahren zur Herstellung von Isopentanderivaten
US8772553B2 (en) 2012-10-26 2014-07-08 Celanese International Corporation Hydrogenation reaction conditions for producing ethanol
US8729318B1 (en) 2012-11-20 2014-05-20 Celanese International Corporation Process for producing ethanol from methyl acetate
US8853469B2 (en) 2012-11-20 2014-10-07 Celanese International Corporation Combined column for separating products of different hydrogenation reactors
DE102013203117A1 (de) * 2013-02-26 2014-08-28 Evonik Industries Ag Optimierte Trenntechnik zur Aufarbeitung von homogen katalysierten Hydroformylierungsmischungen
CN104513131B (zh) * 2013-09-30 2017-08-22 中国石油化工股份有限公司 癸烯醛液相加氢制备癸醇的方法
DE102013113724A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten alpha, beta-ungesättigter Decenale aus Propylen
DE102013113719A1 (de) 2013-12-09 2015-06-11 Oxea Gmbh Verfahren zur Herstellung von Pentanderivaten und Derivaten α,β-ungesättigter Decenale
US9024088B1 (en) 2014-04-28 2015-05-05 Celanese International Corporation Hydrogenation catalysts comprising a mixed oxide comprising nickel
US9382177B2 (en) 2014-04-28 2016-07-05 Celanese International Corporation Hydrogenation catalysts comprising a mixed oxide comprising a promoter metal
US9073815B1 (en) 2014-04-28 2015-07-07 Celanese International Corporation Hydrogenation catalysts comprising a mixed oxide and processes for producing ethanol
US9353035B2 (en) 2014-04-28 2016-05-31 Celanese International Corporation Process for producing ethanol with zonal catalysts
EP3037400B1 (de) 2014-12-23 2018-08-01 Evonik Degussa GmbH Chromfreie hydrierung von hydroformylierungsgemischen
CN106179373A (zh) * 2015-05-07 2016-12-07 中国石油化工股份有限公司 一种用于癸烯醛液相加氢制异癸醇的催化剂及其制备方法
CN106008156A (zh) * 2016-05-19 2016-10-12 山东成泰化工有限公司 一种癸醇的制备方法
CN105884575A (zh) * 2016-05-24 2016-08-24 山东成泰化工有限公司 一种利用正戊醛制备戊醇的方法
RU2625452C1 (ru) * 2016-06-24 2017-07-14 Федеральное государственное бюджетное образовательное учреждение высшего образования "Иркутский государственный университет" (ФГБОУ ВО "ИГУ") Никелевый катализатор гидрирования аренов
CN106083527A (zh) * 2016-06-27 2016-11-09 山东成泰化工有限公司 一种戊醇的制备方法
CN106111184A (zh) * 2016-06-27 2016-11-16 山东成泰化工有限公司 一种异癸醇制备用催化剂及其制备方法
CN106187682A (zh) * 2016-06-27 2016-12-07 山东成泰化工有限公司 一种癸醇的制备方法
JP2019531873A (ja) 2016-08-18 2019-11-07 ザ ユニバーシティ オブ シカゴＴｈｅ Ｕｎｉｖｅｒｓｉｔｙ Ｏｆ Ｃｈｉｃａｇｏ 高度に効率的な有機変換のための金属酸化物に支持された地球に豊富な金属の触媒
US10245578B2 (en) * 2016-11-09 2019-04-02 Evonik Degussa Gmbh Chromium- and nickel-free hydrogenation of hydroformylation mixtures
KR101884928B1 (ko) * 2017-03-28 2018-08-30 금호석유화학 주식회사 금속산화물 촉매, 그 제조방법, 및 이를 이용한 알코올의 제조방법
FR3065175A1 (fr) * 2017-04-14 2018-10-19 IFP Energies Nouvelles Procede de transformation d'alcools par des catalyseurs solides a base de cuivre et d'un element choisi parmi na, ca, ba et k
CN107020102B (zh) * 2017-04-26 2019-05-31 浙江大学 一种镍-铬酸镁催化剂及其制备方法以及在甘油制备乙醇中的应用
CN107011107A (zh) * 2017-05-16 2017-08-04 中国科学技术大学 一种采用负载型金属催化剂制备醇的方法
CN111556785B (zh) 2017-12-20 2023-11-03 巴斯夫欧洲公司 用于制备二甲醚的催化剂和方法
GB201814682D0 (en) 2018-09-10 2018-10-24 Johnson Matthey Davy Technologies Ltd Process for the activation of oxidised catalysts
CN111215081A (zh) * 2018-11-26 2020-06-02 中国科学院大连化学物理研究所 一种醛类加氢制醇类催化剂及其制备方法
JP7681002B2 (ja) 2019-08-30 2025-05-21 コベストロ、ドイチュラント、アクチエンゲゼルシャフト 芳香族ニトロ化合物を水素化する方法
WO2022184614A1 (de) 2021-03-01 2022-09-09 Covestro Deutschland Ag Verfahren zur hydrierung von aromatischen nitroverbindungen
CN112979416A (zh) * 2021-03-09 2021-06-18 浙江建业化工股份有限公司 一种高选择性甲基异丁基醇的制备方法
CN117800811A (zh) * 2022-09-30 2024-04-02 中国科学院大连化学物理研究所 一种3-龙脑烯基-2-丁醇的制备方法
CN117534541A (zh) * 2023-11-14 2024-02-09 山东京博石油化工有限公司 一种c12醇及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3894140A (en) * 1973-05-09 1975-07-08 Chemical Construction Corp Stabilization of alumina catalyst supports
US5561217A (en) * 1992-12-23 1996-10-01 Basf Aktiengesellschaft Preparation of polyether glycols
US20020183564A1 (en) * 2001-05-30 2002-12-05 Hiroto Tanigawa Process for producing an alicyclic unsaturated alcohol
TW200403102A (en) * 2002-07-19 2004-03-01 Oxeno Olefinchemie Gmbh Fine-pored catalyst and process for hydrogenating aromatic compounds

Family Cites Families (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2809220A (en) 1954-05-11 1957-10-08 Exxon Research Engineering Co Hydrogenation of oxo aldehydes in the presence of sulfactive catalysts and water
US2795600A (en) * 1954-06-25 1957-06-11 Union Carbide & Carbon Corp Production of nitriles
US3781406A (en) * 1971-07-07 1973-12-25 Monsanto Co Process of treating auto exhaust with shrinkage resistant copper aluminaterare earth catalysts
US4401834A (en) 1982-06-01 1983-08-30 Exxon Research & Engineering Co. Process for producing alcohols
GB2142010B (en) 1983-06-23 1987-04-29 Exxon Research Engineering Co Improved process for production of aliphatic alcohols
US4666879A (en) * 1985-09-11 1987-05-19 Harshaw/Filtrol Partnership Extruded copper chromite-alumina hydrogenation catalyst
US5059710A (en) 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5124295A (en) * 1990-12-13 1992-06-23 Engelhard Corporation Copper chromite catalyst and process for preparation said catalyst
ES2171539T3 (es) * 1994-05-19 2002-09-16 Basf Ag Procedimiento para la elaboracion de alcoholes.
US5962741A (en) * 1996-11-19 1999-10-05 Novartis Ag Process for the production of aromatic halogen-amino compounds
DE19842369A1 (de) * 1998-09-16 2000-03-23 Oxeno Oelfinchemie Gmbh Verfahren zur Hydrierung von Hydroformylierungsgemischen
DE19842370A1 (de) * 1998-09-16 2000-03-23 Oxeno Oelfinchemie Gmbh Verfahren zur selektiven Hydrierung von Hydroformylierungsgemischen
DE19905838A1 (de) * 1999-02-12 2000-08-17 Basf Ag Verfahren zur Racemisierung von optisch aktiven Aminen
DE19933348B4 (de) 1999-07-16 2005-11-17 Oxeno Olefinchemie Gmbh Verfahren zur Reduzierung oxidischer Hydrierkontakte
US6255358B1 (en) * 2000-03-17 2001-07-03 Energy International Corporation Highly active Fischer-Tropsch synthesis using doped, thermally stable catalyst support
DE10024542A1 (de) 2000-05-18 2001-11-22 Basf Ag Verfahren zur Herstellung von gesättigten C3-C20-Alkoholen
DE10062448A1 (de) * 2000-12-14 2002-06-20 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Hydroformylierungsgemischen
GB0119327D0 (en) * 2001-08-08 2001-10-03 Johnson Matthey Plc Catalyst
DE10220799A1 (de) * 2002-05-10 2003-12-11 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von C13-Alkoholgemischen
DE10225565A1 (de) * 2002-06-10 2003-12-18 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Hydrierung von aromatischen Verbindungen
US7304526B2 (en) * 2003-10-23 2007-12-04 Nxp B.V. Switching circuit for handling signal voltages greater than the supply voltage
DE102004021128A1 (de) * 2004-04-29 2005-11-24 Oxeno Olefinchemie Gmbh Vorrichtung und Verfahren für die kontinuierliche Umsetzung einer Flüssigkeit mit einem Gas an einem festen Katalysator
DE102004055189B4 (de) * 2004-11-16 2007-02-08 Süd-Chemie AG Verfahren zur Hydrierung von Acetophenon
DE102004059292A1 (de) * 2004-12-09 2006-06-14 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von Alkoholen aus Olefinen durch Hydroformylierung und Hydrierung
DE102004063637A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von alicyclischen Carbonsäuren oder deren Derivaten
DE102004063673A1 (de) * 2004-12-31 2006-07-13 Oxeno Olefinchemie Gmbh Verfahren zur kontinuierlichen katalytischen Hydrierung von hydrierbaren Verbindungen an festen, im Festbett angeordneten Katalysatoren mit einem wasserstoffhaltigen Gas
DE102005035816A1 (de) * 2005-07-30 2007-02-01 Oxeno Olefinchemie Gmbh Verfahren zur Hydrierung von Oxo-Aldehyden mit hohen Estergehalten
EP1922146A1 (en) * 2005-09-08 2008-05-21 Evonik Degussa GmbH The production and use of supported activated base metal catalysts for organic transformation
DE102006040432A1 (de) * 2006-08-29 2008-03-20 Oxeno Olefinchemie Gmbh Katalysator und Verfahren zur Herstellung von Isoolefinen

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3894140A (en) * 1973-05-09 1975-07-08 Chemical Construction Corp Stabilization of alumina catalyst supports
US5561217A (en) * 1992-12-23 1996-10-01 Basf Aktiengesellschaft Preparation of polyether glycols
US20020183564A1 (en) * 2001-05-30 2002-12-05 Hiroto Tanigawa Process for producing an alicyclic unsaturated alcohol
TW200403102A (en) * 2002-07-19 2004-03-01 Oxeno Olefinchemie Gmbh Fine-pored catalyst and process for hydrogenating aromatic compounds

Also Published As

Publication number Publication date
EP2180947A1 (de) 2010-05-05
AR068199A1 (es) 2009-11-11
US20110060169A1 (en) 2011-03-10
DE102007041380A1 (de) 2009-03-05
EP2180947B1 (de) 2014-04-23
KR101518083B1 (ko) 2015-05-06
JP2010536569A (ja) 2010-12-02
WO2009027135A1 (de) 2009-03-05
CN101376104B (zh) 2014-08-20
ES2476606T3 (es) 2014-07-15
TW200927284A (en) 2009-07-01
JP5564714B2 (ja) 2014-08-06
CN101376104A (zh) 2009-03-04
KR20100046234A (ko) 2010-05-06

Similar Documents

Publication Publication Date Title
TWI503170B (zh) 氫化觸媒及藉由羰基化合物之氫化而製造醇類的方法
CN1165504C (zh) 加氢甲酰化混合物的选择氢化方法
KR920001303B1 (ko) 개선된 알데하이드 수소화 방법
RU2249587C2 (ru) Способ получения высших оксоспиртов из смесей олефинов
KR100618929B1 (ko) 2단계 하이드로포밀화에 의한 올레핀 혼합물로부터의 고급 옥소 알콜의 제조방법
EP2994229B1 (en) Process for the production of 1,3-butadiene
Kelly et al. Waste elimination in condensation reactions of industrial importance
TWI490036B (zh) 具有高酯含量之合氧基醛類的氫化方法
JP2016153389A (ja) クロムを使用しないヒドロホルミル化混合物の水素化
CA2364826A1 (en) Process for the hydrogenation of hydroformylation mixtures
CN102548946A (zh) 制备癸酸的方法
US5399793A (en) Hydrogenation catalyst for oxo alcohol process
SA111330025B1 (ar) محفز نحاس/ زنك معزز لهدرجة الألدهيدات إلى كحولات
JP5187675B2 (ja) ３価以上のアルコールからのヒドロキシケトン製造方法およびそれに用いる触媒
CN106179373A (zh) 一种用于癸烯醛液相加氢制异癸醇的催化剂及其制备方法
EP3388410A1 (en) Method for producing high-octane components from olefins from catalytic cracking
MXPA99008459A (en) Procedure for obtaining oxo-alcohol superior from olef mixtures

Legal Events

Date Code Title Description
MM4A Annulment or lapse of patent due to non-payment of fees